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- Author:
- Ponomarev, V. A.; Sukhorukova, I. V.; Sheveyko, A. N.; Permyakova, E. S.; Manakhov, A. M.; Ignatov, S. G.; Gloushankova, N. A.; Zhitnyak, I. Y.; Lebedev, O. I.; Polčak, J.; Kozmin, A. M.; Shtansky, D. V.
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24406-24420
- ISSN:
- 1944-8252
- Subject:
- Escherichia coli; Staphylococcus aureus; antibacterial properties; bacteria; bacterial colonization; electrochemistry; ions; leaching; microbial culture; microscopy; nanoparticles; nanosilver; osteoblasts; platinum; silver; synergism; zinc
- Abstract:
- ... It is very important to prevent bacterial colonization at the early postoperative stages. There are four major strategies and their corresponding types of antibacterial surfaces specifically designed to fight infection: bactericide release, anti-adhesion, pH-sensitive, and contact-killing. Herein, we aimed at determining the antibacterial efficiency of different types of bactericidal ions and reve ...
- DOI:
- 10.1021/acsami.8b06671
-
http://dx.doi.org/10.1021/acsami.8b06671
- Author:
- Han, Jian-Ping; Zhang, Bo; Wang, Li-Ying; Qi, Yong-Xin; Zhu, Hui-Ling; Lu, Gui-Xia; Yin, Long-Wei; Li, Hui; Lun, Ning; Bai, Yu-Jun
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24910-24919
- ISSN:
- 1944-8252
- Subject:
- electrical conductivity; electrochemistry; lithium; materials science; nitrates; titanium dioxide; zirconium
- Abstract:
- ... The low electrical conductivity and ordinary lithium-ion transfer capability of Li₄Ti₅O₁₂ restrict its application to some degree. In this work, dual-phase Li₄Ti₅O₁₂–TiO₂ (LTOT) was modified by composite zirconates of Li₂ZrO₃, Li₆Zr₂O₇ (LZO) to boost the rate capabilities and cyclability. When the homogeneous mixture of LiNO₃, Zr(NO₃)₄·5H₂O and LTOT was roasted at 700 °C for 5 h, the obtained comp ...
- DOI:
- 10.1021/acsami.8b07003
-
http://dx.doi.org/10.1021/acsami.8b07003
- Author:
- Wang, Yang; Lin, Chuan-Fu; Rao, Jiancun; Gaskell, Karen; Rubloff, Gary; Lee, Sang Bok
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24554-24563
- ISSN:
- 1944-8252
- Subject:
- X-ray photoelectron spectroscopy; anodes; batteries; cathodes; corrosion; electrochemistry; electrolytes; lithium; materials science; scanning electron microscopy; sulfur
- Abstract:
- ... Lithium–sulfur (Li–S) batteries suffer from shuttle reactions during electrochemical cycling, which cause the loss of active material sulfur from sulfur–carbon cathodes, and simultaneously incur the corrosion and degradation of the lithium metal anode by forming passivation layers on its surface. These unwanted reactions therefore lead to the fast failure of batteries. The preservation of the high ...
- DOI:
- 10.1021/acsami.8b07248
-
http://dx.doi.org/10.1021/acsami.8b07248
- Author:
- André, Alexander; Weber, Michelle; Wurst, Kai M.; Maiti, Santanu; Schreiber, Frank; Scheele, Marcus
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24708-24714
- ISSN:
- 1944-8252
- Subject:
- electrochemistry; nanocrystals; quantum mechanics; semiconductors; spectroscopy; terthiophenes
- Abstract:
- ... PbS nanocrystals are surface-functionalized with the organic semiconductor 5,5″-dithiol-[2,2′:5,2″-terthiophene] and assembled to afford hybrid nanostructured thin films with a large structural coherence and an electron mobility of 0.2 cm²/(V s). Electrochemistry, optical spectroscopy, and quantum mechanical calculations are applied to elucidate the electronic structure at the inorganic/organic in ...
- DOI:
- 10.1021/acsami.8b06044
-
http://dx.doi.org/10.1021/acsami.8b06044
- Author:
- Chuong, Nguyen Dinh; Thanh, Tran Duy; Kim, Nam Hoon; Lee, Joong Hee
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24523-24532
- ISSN:
- 1944-8252
- Subject:
- adsorption; alcohol tolerance; catalysts; catalytic activity; electrochemistry; electron transfer; fuel cells; graphene; hematite; nanoparticles; nanosheets; oxygen; physicochemical properties; topology
- Abstract:
- ... In this study, a facile approach has been successfully applied to synthesize a hierarchical three-dimensional architecture of ultrasmall hematite nanoparticles homogeneously encapsulated in MoS₂/nitrogen-doped graphene nanosheets, as a novel non-Pt cathodic catalyst for oxygen reduction reaction in fuel cell applications. The intrinsic topological characteristics along with unique physicochemical ...
- DOI:
- 10.1021/acsami.8b06485
-
http://dx.doi.org/10.1021/acsami.8b06485
- Author:
- Wang, Kai; Zhang, Xiaohua; Han, Jianwei; Zhang, Xiong; Sun, Xianzhong; Li, Chen; Liu, Wenhao; Li, Qingwen; Ma, Yanwei
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24573-24582
- ISSN:
- 1944-8252
- Subject:
- anions; anodes; batteries; cathodes; electrochemistry; electronics; gels; manganese dioxide; nanotubes; polymers; specific energy; zinc; zinc sulfate
- Abstract:
- ... Nowadays, linear-shaped batteries have received increasing attentions because the unique one-dimensional architecture offers an omni-directional flexibility. We developed a cable-type flexible rechargeable Zn microbattery based on a microscale MnO₂@carbon nanotube fiberlike composite cathode and Zn wire anode. The Zn–MnO₂ cable microbattery exhibits a large specific capacity, good rate performance ...
- DOI:
- 10.1021/acsami.8b07756
-
http://dx.doi.org/10.1021/acsami.8b07756
- Author:
- Moore, Matthew D.; Bowler, Melanie H.; Reynolds, Joseph E.; Lynch, Vincent M.; Shen, Yulong; Slinker, Jason D.; Sessler, Jonathan L.
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24699-24707
- ISSN:
- 1944-8252
- Subject:
- X-ray diffraction; absorption; cost effectiveness; electrochemiluminescence; electrochemistry; energy transfer; iridium; light emitting diodes; materials science; methylene chloride; moieties; oxidation; photoluminescence
- Abstract:
- ... Light-emitting electrochemical cells (LEECs) from ionic transition-metal complexes (iTMCs) offer the potential for high-efficiency electroluminescence in a simple, single-layer device. However, LEECs typically rely on the use of rare metal complexes. This has limited their cost effectiveness and put constraints on their applicability. With a view to leveraging the efficient emission of these compl ...
- DOI:
- 10.1021/acsami.8b08176
-
http://dx.doi.org/10.1021/acsami.8b08176
- Author:
- Wang, Xinzhi; Zhang, Yibo; Zhang, Xue; Liu, Ting; Lin, Yuan-Hua; Li, Liangliang; Shen, Yang; Nan, Ce-Wen
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24791-24798
- ISSN:
- 1944-8252
- Subject:
- ambient temperature; ceramics; composite polymers; electrochemistry; electrolytes; lithium; lithium batteries; polyethylene glycol; salt concentration; strength (mechanics); thermal stability
- Abstract:
- ... Solid electrolytes with high ionic conductivity and good mechanical properties are required for solid-state lithium-ion batteries. In this work, we synthesized composite polymer electrolytes (CPEs) with a three-dimensional (3D) Li₀.₃₃La₀.₅₅₇TiO₃ (LLTO) network as a nano-backbone in poly(ethylene oxide) matrix by hot-pressing and quenching. Self-standing 3D-CPE membranes were obtained with the supp ...
- DOI:
- 10.1021/acsami.8b06658
-
http://dx.doi.org/10.1021/acsami.8b06658
- Author:
- Hou, Peiyu; Li, Feng; Sun, Yanyun; Li, Huiqiao; Xu, Xijin; Zhai, Tianyou
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24508-24515
- ISSN:
- 1944-8252
- Subject:
- cathodes; cations; commercialization; electrochemistry; lithium; lithium batteries; longevity; materials science
- Abstract:
- ... The rational design of concentration-gradient (CG) structure is demonstrated as an available approach to improve the electrochemical performances of high-energy nickel-rich cathodes for lithium-ion batteries (LIBs). However, the complicated preparing processes, especially the CG-precursors, generally result in the less-than-ideal repeatability and consistency that is regarded as an extreme challen ...
- DOI:
- 10.1021/acsami.8b06286
-
http://dx.doi.org/10.1021/acsami.8b06286
- Author:
- Maleski, Kathleen; Ren, Chang E.; Zhao, Meng-Qiang; Anasori, Babak; Gogotsi, Yury
- Source:
- ACS applied materials & interfaces 2018 v.10 no.29 pp. 24491-24498
- ISSN:
- 1944-8252
- Subject:
- capacitance; carbides; density gradient centrifugation; electrical equipment; electrochemistry; electrodes; materials science; sonication; spectral analysis; titanium
- Abstract:
- ... Two-dimensional (2D) particles, including transition metal carbides (MXenes), often exhibit large lateral-size polydispersity in delaminated colloidal solutions. This heterogeneity results in challenges when conducting fundamental studies, such as investigating correlations between properties and the 2D flake size. To resolve this challenge, we have developed solution-processable techniques to con ...
- DOI:
- 10.1021/acsami.8b04662
-
http://dx.doi.org/10.1021/acsami.8b04662