Jump to Main Content
- Dong, Zhili, et al. Show all 8 Authors
- ACS sustainable chemistry 2017 v.5 no.9 pp. 7887-7893
- carbon dioxide; coordination polymers; crystallites; crystallization; dimethyl sulfoxide; methanol; scanning electron microscopy; solvents; sorption; transmission electron microscopy
- ... It is shown that a crystalline metal–organic framework (HKUST-1) can be rapidly synthesized from a DMSO/MeOH solution with greatly reduced amounts of organic solvents using a supercritical CO₂ (scCO₂) solvent expansion technique. The precursor solution is stable for months under ambient conditions, and CO₂-driven MOF (metal–organic framework) crystallization is achieved under mild conditions (40 ° ...