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- Ebert, Marc-Olivier, et al. Show all 4 Authors
- Chemical communications 2019 v.55 no.16 pp. 2253-2256
- amides; chemical reactions; nuclear magnetic resonance spectroscopy; solvents
- ... A combined experimental and computational approach provided insight into the nature and conformational dependence of long-range ⁴JHF couplings in α-fluoro amides. The dependence of ⁴JHF on substituents and the solvent was investigated. H–F coupling constants determined by NMR spectroscopy are in agreement with DFT calculations. NBO analysis revealed that a favourable nF→σNH* interaction correlates ...