Jump to Main Content
- Bora, Porag; Bez, Ghanashyam
- Chemical communications 2018 v.54 no.60 pp. 8363-8366
- Lewis bases; aromatic amines; catalysts; chemical bonding; chemoselectivity; metals; polymerization; toxicity
- ... Insertion of isocyanides into the N–H bond gives access to many medicinally important and structurally diverse complex nitrogen-containing heterocycles. Although the transition metal catalyzed isocyanide insertion into the N–H bond is very common, polymerization of isocyanides in the presence of a transition metal and their strong coordination with metals are the common drawbacks. On the other han ...