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- Carnovale, Irene Maria; Lolli, Marco Lucio; Serra, Sonia Colombo; Mingo, Alberto Fringuello; Napolitano, Roberta; Boi, Valeria; Guidolin, Nicol; Lattuada, Luciano; Tedoldi, Fabio; Baranyai, Zsolt; Aime, Silvio
- Chemical communications 2018 v.54 no.72 pp. 10056-10059
- catalytic activity; chemical reactions; gadolinium; hydrogen bonding; ligands; moieties; molybdenum; phenol
- ... The Gd(iii)-complexes of three novel HP-DO3A-like ligands have been investigated to assess the relationship between relaxometry and intramolecular catalysis of the proton exchange. The structures of these ligands differ from the parent HP-DO3A because the methyl group of the hydroxy-propyl arm has been replaced by –Ph–OH, –Ph–NH₂ and –Ph–COOH, respectively. The phenol, amine and carboxylate functi ...