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You searched for: Subject "carbon dioxide" Remove constraint Subject: "carbon dioxide" Journal Chemical communications Remove constraint Journal: Chemical communications Publication Year 2014 Remove constraint Publication Year: 2014 Subject hydrogen Remove constraint Subject: hydrogen
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1. Electrocatalytic CO₂ reduction with a membrane supported manganese catalyst in aqueous solution

Author:
Walsh, James J.; Neri, Gaia; Smith, Charlotte L.; Cowan, Alexander J.
Source:
Chemical communications 2014 v.50 no.84 pp. 12698-12701
ISSN:
1364-548X
Subject:
carbon dioxide,   etc   ; aqueous solutions; carbon monoxide; carbon nanotubes; catalysts; chemical reactions; electrolytes; hydrogen; manganese; pH; silver; silver chloride;     Show all 12 Subjects
Abstract:
... [Mn(bpy)(CO)₃Br] cast in a Nafion membrane is an active heterogeneous electrocatalyst with good selectivity for CO₂ reduction to CO in neutral aqueous electrolyte. Addition of multi-walled carbon nanotubes (MWCNT) leads to a ∼10 fold current enhancement and stable CO : H₂ yields (1 : 2) at −1.4 V vs. Ag/AgCl at pH 7. ...
DOI:
10.1039/c4cc06404f