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- Halder, Gregory J., et al. Show all 4 Authors
- Chemical communications 2006 no.17 pp. 1857-1859
- cations; chemical reactions; desorption; erbium; nanopores; thermal expansion
- ... Desorption of bound and unbound water molecules from the nanoporous coordination framework Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆]·4H₂O to form the apohost, Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties. ...