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1. Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane

Author:
Duan, Xuezhi,   et al.   ; Chen, Wenyao; Ji, Jian; Qian, Gang; Li, Ping; Zhou, Xinggui; Chen, De; Yuan, Weikang;     Show all 8 Authors
Source:
Chemical communications 2014 v.50 no.17 pp. 2142-2144
ISSN:
1364-548X
Subject:
ammonia; catalysts; catalytic activity; dehydrogenation; hydrogen production; nanomaterials; oxidation; oxygen; particle size; texture
Abstract:
... We demonstrate an unprecedented H₂ generation activity in the hydrolytic dehydrogenation of ammonia borane over acid oxidation- and subsequent high temperature-treated CNT immobilized Pt nanocatalysts to combine the merits of defect-rich and oxygen group-deficient surfaces and unique textural properties of supports as well as optimum particle size of Pt. ...
DOI:
10.1039/c3cc48027e