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You searched for: Author "Lyssenko, K. A." Remove constraint Author: "Lyssenko, K. A." Journal Chemical communications Remove constraint Journal: Chemical communications Subject magnetism Remove constraint Subject: magnetism
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1. (Et₄N)[Moᴵᴵᴵ(DAPBH)Cl₂], the first pentagonal-bipyramidal Mo(iii) complex with a N₃O₂-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy

Author:
Lyssenko, K. A.,   et al.   ; Manakin, Yu. V.; Mironov, V. S.; Bazhenova, T. A.; Gilmutdinov, I. F.; Bikbaev, K. Sh.; Masitov, A. A.; Yagubskii, E. B.;     Show all 8 Authors
Source:
Chemical communications 2018 v.54 no.72 pp. 10084-10087
ISSN:
1364-548X
Subject:
anisotropy; chemical reactions; ligands; magnetism; momentum; schiff bases; tetraethylammonium compounds
Abstract:
... The first paramagnetic pentagonal-bipyramidal complex of Mo(iii) with a N₃O₂-type Schiff-base ligand was synthesized by the comproportionation reaction between Mo(ii) and Mo(iv) congeners. The complex has a low-spin (S = 1/2) ground state of Moᴵᴵᴵ(4d³) with double orbital degeneracy and unquenched orbital momentum, which result in strong Ising-type magnetic anisotropy. ...
DOI:
10.1039/c8cc06038j