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- Lyssenko, K. A., et al. Show all 8 Authors
- Chemical communications 2018 v.54 no.72 pp. 10084-10087
- anisotropy; chemical reactions; ligands; magnetism; momentum; schiff bases; tetraethylammonium compounds
- ... The first paramagnetic pentagonal-bipyramidal complex of Mo(iii) with a N₃O₂-type Schiff-base ligand was synthesized by the comproportionation reaction between Mo(ii) and Mo(iv) congeners. The complex has a low-spin (S = 1/2) ground state of Moᴵᴵᴵ(4d³) with double orbital degeneracy and unquenched orbital momentum, which result in strong Ising-type magnetic anisotropy. ...