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- Author:
- Duan, Xuezhi, et al. ; Chen, Wenyao; Ji, Jian; Qian, Gang; Li, Ping; Zhou, Xinggui; Chen, De; Yuan, Weikang; Show all 8 Authors
- Source:
- Chemical communications 2014 v.50 no.17 pp. 2142-2144
- ISSN:
- 1364-548X
- Subject:
- ammonia; catalysts; catalytic activity; dehydrogenation; hydrogen production; nanomaterials; oxidation; oxygen; particle size; texture
- Abstract:
- ... We demonstrate an unprecedented H₂ generation activity in the hydrolytic dehydrogenation of ammonia borane over acid oxidation- and subsequent high temperature-treated CNT immobilized Pt nanocatalysts to combine the merits of defect-rich and oxygen group-deficient surfaces and unique textural properties of supports as well as optimum particle size of Pt. ...
- DOI:
- 10.1039/c3cc48027e
-
http://dx.doi.org/10.1039/c3cc48027e
- Author:
- Duan, Xuezhi, et al. ; Zhou, Xiangping; Ji, Jian; Wang, Di; Qian, Gang; Chen, De; Zhou, Xinggui; Show all 7 Authors
- Source:
- Chemical communications 2015 v.51 no.42 pp. 8853-8856
- ISSN:
- 1364-548X
- Subject:
- Fischer-Tropsch reaction; alkenes; aluminum oxide; carbon; catalysts; iron; sulfur; synthesis gas
- Abstract:
- ... Hierarchical structured α-Al₂O₃ is shown to be able to effectively disperse and immobilize iron species, in comparison with commercial α-Al₂O₃. After promotion using an appropriate amount of sulfur, iron catalysts exhibit not only enhanced Fischer–Tropsch synthesis activity and selectivity toward lower olefins, but also increased resistance against carbon deposits. ...
- DOI:
- 10.1039/c5cc00786k
-
http://dx.doi.org/10.1039/c5cc00786k
- Author:
- Duan, Xuezhi, et al. ; Jian, Jian; You, Kuiyi; Gao, Hongxu; Luo, Qing; Deng, Renjie; Liu, Pingle; Ai, Qiuhong; Luo, He'an; Show all 9 Authors
- Source:
- Chemical communications 2016 v.52 no.16 pp. 3320-3323
- ISSN:
- 1364-548X
- Subject:
- adipic acid; catalysts; cyclohexanes; nitrogen dioxide; nitrous oxide; oxidation
- Abstract:
- ... We demonstrate VPO composites as efficient catalysts for highly selective oxidation of cyclohexane to adipic acid with NO₂. In particular, the Ni–Al–VPO composite catalyst exhibits the striking conversion of cyclohexane (60.6%) and exceptionally high selectivity towards adipic acid (85.0%). Moreover, N₂O is an environmentally harmful gas, and its yield in the present process is only 0.03 t/t adipi ...
- DOI:
- 10.1039/c5cc09840h
-
http://dx.doi.org/10.1039/c5cc09840h