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emulsions; magnetism; nanofluids; nuclear magnetic resonance spectroscopy; silica
Abstract:
... The purpose of this research is to investigate 1-D Magnetic Resonance Imaging (MRI) and low-field Nuclear Magnetic Resonance (NMR) relaxation characteristics of silica nanofluids. The results show that presence of silica nanoparticles increases the MRI signal intensity and influences the NMR relaxation by shifting the relaxation peaks toward faster times compared to deionized water (DIW). Addition ...
carbon dioxide; energy; hot water treatment; light; nanosheets; photocatalysis; photocatalysts; solar energy
Abstract:
... The development of photocatalytic technology can not only reduce CO₂ emissions, but also realize the effective utilization of solar energy, thus alleviating the global energy crisis. In this work, BiOIO₃/g-C₃N₄ Z-scheme heterojunction modified by Ti₃C₂ nanosheets was designed and fabricated through hydrothermal method and electrostatic self-assembly strategy. The g-C₃N₄/BiOIO₃/Ti₃C₂ (4 wt%) photoc ...
... In this work, we demonstrated a facile approach for preparation of Au popcorns by using 3-aminopropyltriethoxysilane (APTES) as ligand. It was identified that APTES monomers acted as ligand to tune activity of the gold precursor and direct the preferential growth of (111) plane of face-centered cubic (fcc) Au, resulting in the formation of Au particles popcorn-like in shape via random attachment f ...
... In recent years, the development of low-cost and reusable green catalysts to reduce the organic pollutant of 4-nitrophenol (4-NP) into the utilizable intermediate of 4-aminophenol (4-AP) had attracted more and more attention. Herein, we reported a facile strategy to synthesize 3D N-doped graphene/bismuth (NGR/Bi) composites with efficient catalytic properties for 4-NP reduction. TGA exhibited NGR/ ...
... Nanofibrous dressings exhibit high specific surface areas, good histocompatibility, enhanced wound healing, and reduced inflammation, which have broad technological implications for treating diabetic foot ulcers (DFUs). However, current nanofibrous dressings still suffer from high resistance to cell infiltration and multiple dressing changes. In this study, polycaprolactone (PCL) and collagen were ...
alloy nanoparticles; bismuth; durability; ethylene glycol; oxidation; palladium; tin
Abstract:
... A porous 3D prism-folding layered GO/MOF-74(Co) supported PdBiSn nanoalloys electrocatalyst (PdBiSn@GM-74) was synthesized via a facile assemble-reduction approach. Compared with Pd@GM-74, PdBi@GM-74, PdSn@GM-74, and commercial Pd/C, the trimetallic PdBiSn@GM-74 exhibits superior electrocatalytic activity and durability for ethylene glycol oxidation reaction (EGOR) in alkaline media, and the forwa ...
... Herein, the hydrogen storage property of the Mg decorated isoreticular metal organic framework-16 (IRMOF-16) is investigated by Density Functional Theory (DFT) method. The WB97XD hybrid method (including dispersion) was used for hydrogen adsorption on Mg decorated IRMOF-16 structure. It was determined that the adsorption enthalpy for the structure was negative (−4.2 kJ/mol) at room temperature and ...
bacterial infections; bone formation; bone resorption; cytokines; drugs; inflammation; osteomyelitis; pH
Abstract:
... Chronic osteomyelitis (COM) is an inflammatory bone disease caused by bacterial infection. Conventional treatment with antibiotics is prone to resistance and other side effects, and it is ineffective against inflammation caused by infection and bone loss. To treat COM comprehensively, based on the acidic microenvironment of osteomyelitis, we used ZIF-8 and celecoxib to construct a multifunctional ...
... Carbon dioxide (CO₂) responsive fluorescent systems mainly focus on modification of fluorophores with specific CO₂-responsive groups, the processes of which are usually tedious and time-consuming. Here, we report a facile strategy for fabricating CO₂-responsive fluorescent system by employing a surfactant, N,N-Dimethyl-1- dodecanamine (C₁₂A), to form an oil-in-water (O/W) emulsion and a fluorophor ...
... In the field of coatings, there is a major trend towards the reduction of volatile organic compounds by developing water-based alternatives for traditional solvent-based paints. Complexes of oppositely charged polyelectrolytes have recently emerged as a promising candidate for such coatings. Recently, we developed an ammonia-evaporation induced complexation approach to form polyelectrolyte complex ...
... The development of bio-based conductive hydrogel has become the research frontier of flexible sensors. However, it is a challenge to prepare a simple method to prepare bio-based conductive hydrogel with excellent stability, tensile strength, and conductivity. Here, we show a simple strategy to prepare conductive, stretchable, and stable hydrogel (KKLN). The KKLN consists of the conductive polyanil ...
... The present study is focused on the adsorption of monomeric molybdate anions on the surface of lepidocrocite investigated by several infrared spectroscopy methods. To study the surface speciation of molybdates on lepidocrocite, the behavior of the anion at the interface upon increasing anion concentration (fixed pH) or decreasing pH (fixed concentration) was analyzed in situ. The obtained results ...
... Block copolymers based on poly(vinylamine) and poly(N-isopropylacrylamide), PVAmₘ-b-PNIPAMₙ, were synthetized by hydrazinolysis of poly(N-vinylphthalimide) based copolymers, PVPIₘ-b-PNIPAMₙ, obtained by RAFT polymerization. The effect of molar mass and pH on the thermoresponsive and aggregation properties of these polymers in aqueous solution was studied with UV–vis spectroscopy, differential scan ...
... Fe-based biocomposites are emerging as temporary orthopedic implants due to natural biodegradability and high mechanical strength. Yet, the slow degradation kinetics restricts their biomedical applications. In this work, Cu-initiated redox system was established to accelerate the biodegradation of Fe-C composite scaffold prepared by selective laser melting. On the one hand, Cu induced micro-galvan ...
... Effective separation of industrial oily wastewater and oil leak has long been treated as an important link to ensure rapid and harmonious development of economy and society. In this article, a robust superhydrophobic/superlipophilic brass mesh with micro/nano dual-scale structures was successfully fabricated by a fast pulse electrodeposition followed by a two-step simple and nonfluorinated immersi ...
... A facile electrochemical sensor for tryptophan detection was designed and constructed by using Cs/Ce-MOF modified glass carbon electrode. The synthesis strategy of Cs/Ce-MOF composite not only greatly saved both energy and time costs, but also prevented the aggregation of Ce-MOF. The electrochemical sensor possessed excellent performance with wide linear range (0.25–331μM) and a low limit of detec ...
... Nanoparticles (NPs) are widely used in industry and technology due to their small size and versatility, which makes them easy to enter organisms and pose threats to human and ecological health. Given the particularity and complex structure of NPs, statistical models alone cannot reliably predict uptake. Hence, we developed a generic model for predicting the cellular uptake of NPs with organic coat ...
... Salvia miltiorrhiza and Carthamus tinctorius are traditional Chinese medicines that have been widely used for the treatment of cardiovascular disease. Salvianic acid A (SAA), salvianic acid B (SAB), protocatechuic aldehyde (PCA) and hydroxysafflor yellow A (HSYA) are the major hydrophilic polyphenols of Salvia miltiorrhiza and Carthamus tinctorius, all of which have been documented as active compo ...
... In this article, we have reported synthesizing a novel mesoporous CuO@barley straw derived SiO₂ (CuO@BSS) as a photocatalyst and adsorbent for methylene blue (MB) removal from aqueous media. Silica nanoparticle as a platform was prepared from barley straw, then modified by grafting of CuO nanoparticles. Our strategy represents a significant development in recycling agricultural waste, such as barl ...
... In this study, we investigate the emulsion type, droplet morphology and emulsion stability that can be achieved using a novel combination emulsifier system which consists of water-soluble α-zirconium phosphate tetrabutyl ammonium (α-ZrP-TBA) nanosheets as the particulate emulsifier and Span 80 as the oil-soluble emulsifier, with the two emulsifiers present in distinct phases. We find that water-in ...