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Fourier transform infrared spectroscopy; X-ray diffraction; X-ray photoelectron spectroscopy; anions; carbon nitride; carbonates; catalysts; chemical composition; chlorides; energy-dispersive X-ray analysis; hot water treatment; irradiation; light; nanocomposites; nanorods; nanosheets; ofloxacin; optical properties; photocatalysis; pollutants; pollution control; scanning electron microscopy; sulfates; transmission electron microscopy; ultrasonic treatment
Abstract:
... Herein, MnWO₄ nanorods coupled with g-C₃N₄ nanosheets were fabricated by a simple hydrothermal method, followed by an ultrasonication method. Morphological features, chemical composition, optical properties and crystallographic information of the prepared materials were obtained using SEM-EDX, TEM, XRD, XPS, FT-IR, UV–vis DRS, and PL techniques. The synthesized MnWO₄@g-C₃N₄ nanocomposite displayed ...
... This study aimed to characterize the physicochemical properties of 3,3′-diindolylmethane (DIM)-loaded nanocapsules (NCs) as well as the antinociceptive effect using distinct animal models (hot plate test, formalin-induced nociception and complete Freud’s adjuvant induced paw inflammation). The DIM-loaded NCs (composed by primula oil and ethylcellulose) were characterized using differential scannin ...
... Extrusion-based 3D bioprinting of cell-laden hydrogels is a potential technology for regenerative medicine, which enables the fabrication of constructs with spatially defined cell distribution. However, the limited assessment of rheological behaviors of hydrogel before printing is still a major issue for the advancement of 3D bioprinting. In this work, we systematically investigated the rheologica ...
... Polystyrene (PS) microspheres are wrapped by reduced graphene oxide (rGO) nanosheets based on the thermodynamically driven heterocoagulation method, and in order to acquire PS/rGO@PtRuNPs composite particles, the resultant PS/rGO composite particles should be used as matrix to deposit Pt-Ru alloyed nanoparticles (PtRuNPs), taking unique advantages of both alloying effect and the 3D structure. A di ...
... Micro/nano-topography (MNT) is an important variable affecting osseointegration of bone biomaterials, but the underlying mechanisms are not fully understood. We probed the role of a AMOT130/YAP pathway in osteoblastic differentiation of bone marrow mesenchymal stems cultured on titanium (Ti) carrying MNTs. Ti surfaces with two well-defined MNTs (TiO2 nanotubes of different diameters and wall thick ...
... Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and thermogravimetric analysis (TGA) were evaluated as useful techniques to study bulk and hydration water in hydrogels. Hydrogels formed by cationized dextran (DEAE-dextran) and anionic surfactants were used as model materials. The IR technique was applied both on fresh samples and on dehydrating samples during the eva ...
... Acellular blood vessels have clinical potential as tissue-engineered vascular grafts. However, neointima is hard to form on their luminal surface. We recently reported the integrin α4β1 ligand peptide (Arg-Glu-Asp-Val) conjugated with a repetitive Pro-Hyp-Gly sequence as luminal surface modifier. By using this peptide, excellent patency of tissue-engineered small-caliber long-bypass grafts in mini ...
... The monoclinic vanadium dioxide, VO2(M), undergoes reversible phase transition from monoclinic (semiconductor) to tetragonal (metal), which exhibits a good thermochromic property. VOSO4, as a vanadium source, is easy to handle produces VO2(M) under mild condition in the presence of alkali species. In this study, the effects of the additions of NH4HCO3, NH3·H2O, and NaOH on the VO2 crystal formatio ...
... The major challenge in bacterial infection in clinical settings is the development of antimicrobial materials in the treatment of drug-resistant bacteria. Herein, we report a new strategy for efficient near-infrared radiation (NIR) photothermal sterilization and focal infection treatment by acetylcysteine-modified Prussian blue nanoparticles (AC-PB). Specifically, AC-PB is fabricated as a multifun ...
Fourier transform infrared spectroscopy; X-ray photoelectron spectroscopy; adsorbents; adsorption; aqueous solutions; colloids; heavy metals; human health; hydrogen bonding; lead; metal ions; methylene blue; moieties; pollution control; surface area; wastewater; water pollution
Abstract:
... Water pollution from heavy metal ions and organic have threatened human health and the removal of those pollutions from wastewater has become a critical issue around the world. Herein, we synthesized the ultrathin, high surface area graphene-like TiO₂@C adsorbent via a simple solvothermal process. Benefiting from the unique structure, abundant active functional groups and high surface area (417 m² ...
... Microalgae are valuable sources of proteins due to their ability to accumulate high levels of nitrogen in their cells’ interior. Similar to plant-derived proteins though, many microalgae proteins are not structural but storage proteins and consequently have low aqueous solubility limiting their use in food, pharmaceutical or personal care applications. Since a number of studies had previously show ...
... Polyaniline nanotubes (PANI-NTs) were prepared by a green approach via the aniline oxidation using ammonium peroxydisulfate as an oxidant in the presence of methyl orange (MO) as a structure-guiding agent without any acid for the dual removal of anionic and cationic dyes from aqueous solutions. The structure, morphology and the physicochemical properties of the synthesized PANI-NTs were examined b ...
... Ultrasound and light-based measurements were used to monitor changes in agitated and quiescent solution characteristics such as particle size distribution during casein aggregation and redistribution in a model colloidal system. The precipitation of casein micelles was controlled by adjusting the pH of the solution to alter the stability of the micelles. The studied dispersions were prepared at hi ...
air; atomic force microscopy; colloids; kinetics; liquid-air interface; neurotoxins; protein subunits
Abstract:
... The growing research interest about neurotoxin Vipoxin is inspired by its intriguing heterodimeric structure and the resulting interactions between Vipoxin’s basic catalytic subunit and the acidic regulatory subunit.In this paper we studied the enzymatic action of Vipoxin and its individual components on Dilauroylphosphatidylcholine (DLPC) monolayers at air-water interfaces. We applied the classic ...
... New biochar-based materials were synthesized via iron salt loading on biochar (derived from bamboo and poplar) or activated biochar and were used for Cr (VI) removal from aqueous solution. Surface morphology structure characterizations revealed that KOH-activated biochar possessed a large surface area and porosity with uniform distribution of iron particles on the biochar’s surface. In particular, ...
... In the present work, a commercial activated carbon was impregnated with MnO2 through a facile and efficient one-pot synthesis method. The impregnated carbon was characterized for the Mn content, the textural characteristics, the surface chemistry and the efficiency for removal and degradation of RB5. The MnO2 nanoparticles with an average size of 35 nm, were homogeneously dispersed in the carbon m ...
bacteria; bioassays; biosensors; colloids; encapsulation; enzyme activity; heavy metals; hydrogels; metal ions; shelf life; toxicity; toxicity testing; viability
Abstract:
... Toxicity test sensor for heavy metal ions is developed in this work. It founds that toxic heavy metal ions leads both bacterial enzymatic activity and viability. Moreover, the hydrogel encapsulation of bacteria was performed to achieve two purposes: (1) to enhance the viability/activity of the biological sensing agent and thus prolong the shelf life of biosensors based on bacteria; and (2) to furt ...
... Uncapped and Glutathione capped Cupric oxide nanospheres were synthesized by the interaction of Berberis lycium (Bl) root extract with corresponding salt solution. CuO nanospheres were best optimized by mixing 2% Bl extract solution with 1 mM CuSO4·5H2O (pH 11, 90 °C) Reduced glutathione (0.25 mM) in solution form was added in respective emulsion after 24 h. Synthesis of nanospheres was ensured by ...
... The current knowledge of bacterial migration is mainly derived from work using bare or Fe-coated quartz sands as porous media. However, mineral coatings on quartz by phyllosilicates and Al-oxides prevail in natural soils, and their effect on bacterial transport remains unknown. Herein, we systematically explored the transport of two bacterial pathogens (Escherichia coli and Staphylococcus aureus) ...
Ekaterina A. Chudinova; Maria A. Surmeneva; Alexander S. Timin; Timofey E. Karpov; Alexandra Wittmar; Mathias Ulbricht; Anna Ivanova; Kateryna Loza; Oleg Prymak; Andrey Koptyug; Matthias Epple; Roman A. Surmenev
... In the present study, biocomposites based on 3D porous additively manufactured Ti6Al4V (Ti64) scaffolds modified with biocompatible calcium phosphate nanoparticles (CaPNPs) were investigated. Ti64 scaffolds were manufactured via electron beam melting technology using an Arcam machine. Electrophoretic deposition was used to modify the scaffolds with CaPNPs, which were synthesized by precipitation i ...
X-ray photoelectron spectroscopy; aerosols; air flow; carbon; chemical bonding; coatings; colloids; combustion; environmental impact; fossil fuels; global warming; hydrophobicity; light transmission; nanoparticles; rapeseed oil; scanning electron microscopy; soot; transmittance; wastes
Abstract:
... Soot aerosol formation in the ambient atmosphere, due to inappropriate and incomplete incineration of various fossil fuels or waste materials, has been considered as one of the major anthropogenic contributions to the global warming. However, despite of their adverse environmental impact, the soot nanoparticles are extremely useful in many practical applications if deposited as coatings, since the ...
X-ray diffraction; adsorbents; adsorption; ambient temperature; desorption; detection limit; iron oxides; lead; magnetic properties; magnetism; manganese oxides; nanocomposites; scanning electron microscopy; solid phase extraction; solvents; standard deviation; surface area; thermodynamics; transmission electron microscopy; vegetables
Abstract:
... This article focuses on adsorption and desorption of Pb²⁺ on a novel adsorbent consisting of Mn₂O₃ and Fe₃O₄. The adsorbent was prepared through combining Sol-Gel and precipitation methods to in-situ magnetization. Decreasing preparation time, synthesizing at room temperature, not using organic solvents are advantages of the presented approach. The characterizations were done by X-ray diffraction, ...
... In this investigation, a mixed collector (MC) of dodecane and n-valeric acid was used to improve low rank coal flotation. Fourier transformation infrared spectroscopy (FTIR) measurements and contact angle measurements were conducted to explain flotation responses. Furthermore, using a molecular dynamics (MD) simulation, the changes of water/collector (dodecane or MC)/coal systems were studied befo ...
... In this study, the flotation behavior of quartz samples with different particle sizes was systematically studied by conducting a microflotation experiment wherein different quaternary ammonium salt (QAS) collectors were used. The mechanism of QAS adsorption on the surfaces of the quartz samples was revealed by adsorption experiments and micro-polarity characteristics at the quartz-water interface. ...
... In this paper, a new β-cyclodextrin polymer (β-CDBEP) was successfully prepared by derivatizing with 1H-benzotriazole followed by cross-linking with epichlorohydrin. The adsorption behaviour of β-CDBEP for anionic Eriochrome Black T (EBT) was studied by batch experiments. The results showed that the highest adsorption capacity was obtained in acidic medium (pH = 5), and the pseudo-second-order mod ...
... In this study, the interfacial tension behavior of halloysite nanotube (HNT) as a hydrophilic nanoparticle and modified APTES-HNT as a hydrophobic nanoparticle at the palm oil-water interface was investigated. The result of this study was used to determine the stability and potential formation of Pickering emulsion as a novel dispersed system. The diffusion coefficients at the initial and late sta ...
... Carboxymethyl cellulose (CMC) is a versatile polymer for several industrial applications such as oil drilling, detergents, food and beverage, papers, ceramics, coatings, and other promising utilization. However, the deficiency for exploring the binding mechanism of the CMC onto the solid surfaces in aqueous system retards its applications. Herein, the binding aspect of CMC onto mesoporous mustard ...
... Herein a series of chemically modified hyper-crosslinked resins were prepared and the four resins had been employed to remove 3-Aminoacetanilide from aqueous solution. Pore size and BET specific surface area of the four resins were improved by characterization, and specific surface area size was SAMR > PRLMR > TAMR > IDLMR. The results showed that Freundlich model could fit the adsorption isotherm ...
... This study examined the feasibility and characteristics of microalgae waste treatment using a mixture of Spirulina platensis and polyacrylamide (SP-PAM) as an adsorbent system for removing Pb²⁺ and Cd²⁺ from simulated wastewater in single and binary solution systems. Multiple techniques, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), energy-dispersiv ...
... The adsorption, diffusion and migration behaviors of uranium may be highly influenced by organics in natural environments. Ethylenediaminetetraacetic acid (EDTA) is one of the most important small organics in groundwaters, especially at the radioactive contaminated sites. In this work, we studied U(VI) adsorption on montmorillonite in the presence of EDTA with batch method. Our results indicated t ...
... Almost all clay minerals carry an abundance of surface charges. The role and impacts of surface charges during adsorption of amino acids and biochemical reactions are of great importance while currently remain elusive, which are to be tackled in this study by first-principles density functional calculations. A wide range of surface charges (−0.42˜ + 0.42 C m⁻²) have been considered. Distribution o ...
... As(III) is more toxic and harder to remove than As(V) though they are always co-exist in water. In order to effectively eliminate pollution of arsenic and explore the adsorption mechanism, a novel-innovative hydrated zirconium oxide (ZrO(OH)₂) and manganese dioxide (MnO₂) coated modified activated charcoal (Zr/Mn/C) prepared via a co-precipitation-hydrothermal method. Results showed that As(III) c ...
... Here we report the adsorption behavior of protein at an oil-water interface, that is covered with polyelectrolytes (PE) and the interaction forces involved. The weak and strong PE’s used are poly(acrylic acid), PAA and poly(diallyldimethylammonium chloride), PDDA, respectively. The protein and oil used are bovine serum albumin (BSA) and octane droplets in water, containing superparamagnetic magnet ...
... Chia proteins were extracted by solubilisation at pH 10 or 12 and precipitated at pH 4.5. Isolates were named as CPI10 and CPI12, according to their extraction pH, 10 or 12, respectively. The surface properties of both isolates were studied at neutral conditions. Foams were formed by air bubbling and both the formation and destabilization processes were analysed by conductimetry. The extraction pH ...
... In spite of the outstanding adsorption properties of microporous silica and hybrid silica xerogels, the selectivity of these materials towards gases and vapours has been studied to a little extent. In this work we studied selected silica and hybrid xerogels of microporous nature to evaluate their adsorption properties for the following molecular separations: carbon dioxide / methane; ethane/ethyle ...
... Adsorption and desorption of phosphorus (P) at sediment-water interface is one of the key processes of biogeochemical cycling of P in lakes. Thus, adsorption of phosphate by sediments from Lake Dianchi, a eutrophic lake, was investigated in this study. Importantly, the influence of dissolved organic matter (DOM) with fulvic acid (FA) as a representative example on these processes was further studi ...
... Adsorption of proteins on nanoparticles is a complex and poorly studied process. The mechanisms of protein layer formation can fundamentally differ depending on the composition of the medium, the nanoparticles’ structure, the protein’s nature, and other factors. In particular, monolayer or multilayer immobilization may occur. In the present work, the composition of conjugates of bovine serum album ...
... The contaminantsin environment generally do not exist alone and possess different physical and chemical properties, their environmental behavior and mechanism of action in environment are more complicated. Montmorillonite was employed as adsorbent to remove tetracycline (TC) and sulfamethoxazole (SMZ) respectively and simultaneously under batch kinetic and different solution conditions. As the con ...
... The extensive application of antibiotics in livestock industry inescapably leads to their release to the aquatic environment. The occurrence of multiple engineered nanomaterials (ENMs) in various water systems also has been widely observed. The interaction between the coexisting antibiotics and ENMs will affect their transport and fate in water. In this study, the adsorption of two representative ...
... The purpose of this study was to determine the properties of biochar prepared at higher than normal biochar production temperature and to evaluate adsorption/desorption characteristics for three commonly used dyes of different charge and molecular nature: Methylene Blue (MB), Orange G (OG) and Congo Red (CR). The switchgrass-biochar was prepared at common pyrolysis temperature of 600 °C (SB600) an ...
... Multi-walled carbon nanotubes functionalised by di-t-butyl selenophosphoryl groups were used to remove Pb(II) ions from synthetic and real aqueous solutions. The effects of the initial Pb(II) ion concentrations, pH, and volume of the synthetic aqueous solution, adsorbent dosage, and temperature on the efficiency of the adsorption process were investigated in batch experiments. The highest Pb(II) r ...
... Sulfonamide antibiotics are widely detected in soil, surface water, sediments and drinking water due to their stable nature, which has huge potential risks. In this study, we reclaimed activated carbon with hexadecyl trimethyl ammonium bromide (CTAB) modification (MAC) as the adsorbents to remove aqueous sulfamethazine (SMX) and sulfamethoxazole (SMZ). It was best described by the pseudo second-or ...
... For the first time, recycled car tire fibers (RCTF) shredded from car tire waste are developed successfully into a novel material, a rubber aerogel, using polyvinyl alcohol (PVA) and glutaraldehyde (GA) as crosslinkers through a cost-effective freeze-drying method. Its structure and main physical properties are investigated comprehensively for high-value applications, such as heat and sound insula ...
NAD (coenzyme); biosynthesis; catalysts; catalytic activity; cost effectiveness; drug carriers; enzymes; metal ions; microalgae; nanoparticles; photosynthetic bacteria; pigments; polysaccharides; proteins
Abstract:
... The last decade has witnessed significant developments in the biosynthesis of noble metal nanoparticles (NMNPs) due to their distinct advantages in various practical applications. Many photosynthetic organisms, including plants, microalgae, and photosynthetic bacteria, have been explored for NMNP synthesis in an eco-friendly and cost-effective manner. These biomasses were used for NMNP biosynthesi ...
Kesiane M. Costa; Talita C.B. Pereira; Cristhiane A. Valente; Kenia Pissinate; Jéssica C. Soares; Fernanda F. Cruz; Temis W.F. Corte; Pablo Machado; Nara R.S. Basso; Maurício R. Bogo
in vivo studies; heart rate; locomotion; dose response; nanomaterials; chorion; colloids; pyrroles; nanomedicine; hatching; body length; mortality; polymers; larvae; Danio rerio; embryogenesis; sulfonic acids; adverse effects
Abstract:
... Nanomaterials have been attracting attention due to the wide range of applications in nanomedicine. Polypyrrole (PPy), a conductive polymer, has been employed in the biomedical field due to its stimulus-responsive properties, although in vivo studies to assess its potential undesirable effects are limited. This study evaluated the effects of PPy doped with p-toluene sulfonic acid ((p-TSA); PPy/p-T ...
... DNA nanostructures are effective intermediates for immobilizing biomolecules because of their high level of controllability, the flexibility to create desired nanostructures through precision “bottom-up” assembly and the convenience to building fine nanostructures. The purpose of this study was to demonstrate the potential use of aptamers bound to agarose through a DNA tetrahedral structure to mak ...
... Ag₂CO₃ anchored on BiOI/CoFe₂O₄ composites with p-n-p heterojunctions were synthesized by means of a facile modified deposition-precipitation method and were utilized to explore their activities for toxic elemental mercury (Hg⁰) removal under fluorescent light (FSL) irradiation. The obtained samples were characterized via N₂ adsorption-desorption, XRD, VSM, SEM, TEM, XPS, EDS, UV–vis DRS, ESR, Tra ...
... A plethora of studies have shown the ability of cereal dietary fiber to improve intestinal health and to protect the colon from diseases. Lowering of blood cholesterol levels and a reduced risk of coronary heart diseases are just examples for beneficial health effects often directly related to β-glucan from cereal grains. β-Glucan is one of the major components of dietary fiber and is found with h ...
... The effect of solvent (N,N-dimethylformamide, dimethyl sulfoxide, and 1,4-dioxane) on the micellization of tri(trimethylsiloxy)silylpropylpyridinnium chloride (Si₄PyrCl) in aqueous solution were investigated by surface tension, electrical conductivity, dynamic light scattering (DLS), and ¹H NMR. The solvents can obviously affect the aggregation behavior of Si₄PyrCl. However, Si₄PyrCl has excellent ...
... Au₁₁(SG)₇ gold nanoparticles (GNPs) were synthesized from HAuCl₄ using thiol compounds containing an amino group to serve as both the reducing agent and the ligand. A three-dimensional network structure (…Au-SNH₂→Mⁿ⁺⟵H₂NS-Au…) was formed after the Mⁿ⁺ (Pb²⁺, Cd²⁺, Zn²⁺ and Ag⁺) coordinated the gold nanoparticles through the amino group in the thiol ligand, which promoted aurophilicity (…Au…Au…) an ...