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Current opinion in colloid & interface science
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2014
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2014 v.19 no.2
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- Author:
- Voronov, Stanislav; Kohut, Ananiy; Tarnavchyk, Ihor; Voronov, Andriy
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 95-121
- ISSN:
- 1359-0294
- Subject:
- adsorption; composite materials; dispersions; latex; peroxidation; polymers; surfactants; thermodynamics
- Abstract:
- ... Continued development of up-to-date polymer composite materials demands the design of certain interfacial layers in composite structure. The aim of this paper was to review recent advances in the synthesis of reactive polymeric surfactants (RPSs) and the application of 14 different RPSs for the modification of the interface in aqueous dispersions of polymers, reinforced polymer-based composites, a ...
- DOI:
- 10.1016/j.cocis.2014.03.010
- http://dx.doi.org/10.1016/j.cocis.2014.03.010
2. Cononsolvency of poly-N-isopropyl acrylamide (PNIPAM): Microgels versus linear chains and macrogels
- Author:
- Scherzinger, Christine; Schwarz, Annett; Bardow, André; Leonhard, Kai; Richtering, Walter
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 84-94
- ISSN:
- 1359-0294
- Subject:
- acrylamides; methanol; models; molecular dynamics; quantum mechanics; solvents
- Abstract:
- ... Poly-N-isopropyl acryl amide (PNIPAM) is swollen in both pure water and pure methanol but collapses in mixtures of these solvents. In this review, this cononsolvency of PNIPAM in water/methanol mixtures is discussed. Experimental studies of linear PNIPAM chains and macrogels are compared to microgels. Theoretical studies are presented based on molecular dynamics simulation and quantum mechanical c ...
- DOI:
- 10.1016/j.cocis.2014.03.011
- http://dx.doi.org/10.1016/j.cocis.2014.03.011
- Author:
- Zielinska, Agnieszka; Leonowicz, Marcin; Li, Hongguang; Nakanishi, Takashi
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 131-139
- ISSN:
- 1359-0294
- Subject:
- alkylation; crystal structure; electronics; hydrophobicity; liquids; moieties; solubility; solvents; surfactants
- Abstract:
- ... Organic and polymeric molecules based on π-conjugated units represent an important class of components for optical and optoelectronic functionalized soft materials. Inspired by the innovative molecular design made by synthetic chemists, new functions and applications of π-conjugated molecules are continuously emerging. However, a challenge that remains is to soften these molecules. Alkylation is a ...
- DOI:
- 10.1016/j.cocis.2014.03.007
- http://dx.doi.org/10.1016/j.cocis.2014.03.007
- Author:
- Texter, John
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 163-174
- ISSN:
- 1359-0294
- Subject:
- absorption; centrifugation; coatings; dispersants; dispersions; graphene; polymers; solvents; stabilizers; surfactants; transmission electron microscopy; value added; wavelengths
- Abstract:
- ... Aqueous dispersions of graphene are of interest to afford environmentally safe handing of graphene for coating, composite, and other material applications. The dispersion of graphene in water and some other solvents using surfactants, polymers, and other dispersants is reviewed and results show that nearly completely exfoliated graphene may be obtained at concentrations from 0.001 to 5% by weight ...
- DOI:
- 10.1016/j.cocis.2014.04.004
- http://dx.doi.org/10.1016/j.cocis.2014.04.004
- Author:
- Tonga, Gulen Yesilbag; Moyano, Daniel F.; Kim, Chang Soo; Rotello, Vincent M.
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 49-55
- ISSN:
- 1359-0294
- Subject:
- image analysis; medicine; nanoparticles; therapeutics
- Abstract:
- ... Inorganic nanomaterials have a wide array of physical and structural properties that make them attractive candidates for imaging and therapeutic delivery. Nanoparticle platforms have been intensely studied for these applications, and examples are starting to enter the clinic. This review looks at why inorganic particles provide promising platforms for biomedicine, and what issues need to be addres ...
- DOI:
- 10.1016/j.cocis.2014.03.004
- http://dx.doi.org/10.1016/j.cocis.2014.03.004
- Author:
- Lapitsky, Yakov
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 122-130
- ISSN:
- 1359-0294
- Subject:
- crosslinking; drugs; electrolytes; food science; image analysis; nanocarriers
- Abstract:
- ... Over the past two decades, nanocarriers prepared through ionic crosslinking of polyelectrolytes have been explored in a wide range of applications, including drug delivery, medical imaging and food science. The design and use of these materials require control over their size distributions, stability, and payload uptake and release properties. To this end, we focus on recent progress made towards ...
- DOI:
- 10.1016/j.cocis.2014.03.014
- http://dx.doi.org/10.1016/j.cocis.2014.03.014
- Author:
- Ma, Ming-Guo; Cölfen, Helmut
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 56-65
- ISSN:
- 1359-0294
- Subject:
- crystallization; electrodes; lithium batteries; nanoparticles; photocatalysis
- Abstract:
- ... Mesocrystals are superstructures of nanoparticles with mutual order and can be intermediates in a non-classical particle-mediated crystallization reaction. Mesocrystals have various potential applications as functional materials due to their unique combination of nanoparticle properties and order combined with a microscopic or even macroscopic size. They can also show collective and emergent prope ...
- DOI:
- 10.1016/j.cocis.2014.03.001
- http://dx.doi.org/10.1016/j.cocis.2014.03.001
- Author:
- Gysling, Henry J.
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 155-162
- ISSN:
- 1359-0294
- Subject:
- dispersions; electric field; nanotechnology; photocatalysts; radio frequency identification
- Abstract:
- ... Recent advances in the development of stable dispersions of nanophase metal particles have allowed the direct fabrication of metal patterns (e.g., printed circuits, RFID tags, touch screens, etc.) by simple additive type inkjet processes. Such processes replace the more costly and less environmentally friendly subtractive lithographic type photoprocesses involving selective etching of photoresists ...
- DOI:
- 10.1016/j.cocis.2014.03.013
- http://dx.doi.org/10.1016/j.cocis.2014.03.013
- Author:
- Men, Yongjun; Kuzmicz, Danuta; Yuan, Jiayin
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 76-83
- ISSN:
- 1359-0294
- Subject:
- carbon; catalytic activity; chemical structure; colloids; composite polymers; electrolytes; ionic liquids; micelles; nanocomposites; nanoparticles; physical properties; sorption
- Abstract:
- ... In recent years a subclass of polyelectrolytes named poly(ionic liquid)s (PILs) have attracted intensive interest in the field of polymer and materials science due to some of their unusual physical properties, compared to traditional polyelectrolytes. They are characterized as multifunctional polyelectrolytes in a wide application spectrum, such as solid ion conductor, separation, sorption, cataly ...
- DOI:
- 10.1016/j.cocis.2014.03.012
- http://dx.doi.org/10.1016/j.cocis.2014.03.012
- Author:
- Kunitake, Masashi; Higuchi, Rintaro; Tanoue, Ryota; Uemura, Shinobu
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 140-154
- ISSN:
- 1359-0294
- Subject:
- aqueous solutions; chemical structure; condensation reactions; electronics; hydrophobicity; liquids; nanosheets; polymers; schiff bases; solubility
- Abstract:
- ... Two-dimensional supramolecular covalent macromolecular architectures were visualized directly by in-situ scanning tunneling microcopy and colorful π-conjugated nanofilms with unique mesostructures formed spontaneously on hydrophobic substrates from aqueous solutions in the presence of simple aromatic building block molecules under ambient conditions. We thus report the results of surface-mediated ...
- DOI:
- 10.1016/j.cocis.2014.03.003
- http://dx.doi.org/10.1016/j.cocis.2014.03.003
- Author:
- Urban, Marek W.
- Source:
- Current opinion in colloid & interface science 2014 v.19 no.2 pp. 66-75
- ISSN:
- 1359-0294
- Subject:
- colloids; color; dispersants; environmental factors; hydrophobic bonding; nanoparticles; nanotubes; polymers
- Abstract:
- ... Although stratification in polymeric colloids and films has been known for a long time, its significance has not been recognized until surface-interfacial properties driven by mobility of dispersing agents became one of the key features that impact structure–property relationships. Learning from these studies, the last decade resulted in significant advances that have led to the development of a n ...
- DOI:
- 10.1016/j.cocis.2014.04.002
- http://dx.doi.org/10.1016/j.cocis.2014.04.002