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- Author:
- Vengosh, Avner; Jackson, Robert B.; Warner, Nathaniel; Darrah, Thomas
H.; Kondash, Andrew
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8334-8348
- ISSN:
- 1520-5851
- Subject:
- aquifers; case studies; drilling; gases; groundwater; human health; isotopes; natural gas; oil fields; radium; risk; sediments; shale; soil; streams; subsurface flow; surface water; toxicity; wastewater; water shortages; United States
- Abstract:
- ... The rapid rise of shale gas development through horizontal drilling and high volume hydraulic fracturing has expanded the extraction of hydrocarbon resources in the U.S. The rise of shale gas development has triggered an intense public debate regarding the potential environmental and human health effects from hydraulic fracturing. This paper provides a critical review of the potential risks that s ...
- DOI:
- 10.1021/es405118y
-
http://dx.doi.org/10.1021%2Fes405118y
- Author:
- Rattner, Barnett A.; Lazarus, Rebecca S.; Elliott, John E.; Shore, Richard
F.; van den Brink, Nico
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8433-8445
- ISSN:
- 1520-5851
- Subject:
- European Union; anticoagulants; exposure pathways; guidelines; habitats; hemorrhage; invasive species; mortality; physicochemical properties; public health; risk; risk assessment; rodenticides; sublethal effects; vitamin K epoxide reductase; wildlife; North America
- Abstract:
- ... Despite a long history of successful use, routine application of some anticoagulant rodenticides (ARs) may be at a crossroad due to new regulatory guidelines intended to mitigate risk. An adverse outcome pathway for ARs was developed to identify information gaps and end points to assess the effectiveness of regulations. This framework describes chemical properties of ARs, established macromolecula ...
- DOI:
- 10.1021/es501740n
-
http://dx.doi.org/10.1021%2Fes501740n
- Author:
- Domingo-Félez, Carlos; Mutlu, A. Gizem; Jensen, Marlene M.; Smets, Barth F.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8679-8687
- ISSN:
- 1520-5851
- Subject:
- aeration; air flow; anaerobic ammonium oxidation; correlation; greenhouse gas emissions; nitric oxide; nitrogen; nitrous oxide; oxidation; oxygen; streams
- Abstract:
- ... Autotrophic nitrogen removal is regarded as a resource efficient process to manage nitrogen-rich residual streams. However, nitrous oxide emissions of these processes are poorly documented and strategies to mitigate emissions unknown. In this study, two sequencing batch reactors performing single-stage nitritation/anammox were operated under different aeration strategies, gradually adjusted over s ...
- DOI:
- 10.1021/es501819n
-
http://dx.doi.org/10.1021%2Fes501819n
- Author:
- Kuhn, K. M.; DuBois, J. L.; Maurice, P. A.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8664-8670
- ISSN:
- 1520-5851
- Subject:
- Pseudomonas mendocina; alginates; bioavailability; biofilm; exopolysaccharides; ferrihydrite; iron; iron oxides; iron oxyhydroxides; ligands; mutants; nanoparticles; siderophores; soil bacteria
- Abstract:
- ... This research compared the bioavailability of Fe associated with two forms of the hydrous Fe oxyhydroxide nanomineral ferrihydrite (Fh)-the smaller (1–3 nm), less ordered 2-line (2L) phase and the slightly larger, (2–6 nm) more ordered 6-line (6L) phase-to the common aerobic soil bacterium Pseudomonas mendocina ymp. P. mendocina can acquire Fe from minerals using high-affinity Fe(III) binding liga ...
- DOI:
- 10.1021/es501308b
-
http://dx.doi.org/10.1021/es501308b
- Author:
- Moore, Christopher W.; Zielinska, Barbara; Pétron, Gabrielle; Jackson, Robert
B.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8349-8359
- ISSN:
- 1520-5851
- Subject:
- air; air quality; case studies; climate; coalbed methane; emissions; emissions factor; environmental impact; greenhouse gases; inventories; nitrogen oxides; ozone; particulates; sand; shale; volatile organic compounds; Canada; United States
- Abstract:
- ... During the past decade, technological advancements in the United States and Canada have led to rapid and intensive development of many unconventional natural gas plays (e.g., shale gas, tight sand gas, coal-bed methane), raising concerns about environmental impacts. Here, we summarize the current understanding of local and regional air quality impacts of natural gas extraction, production, and use ...
- DOI:
- 10.1021/es4053472
-
http://dx.doi.org/10.1021%2Fes4053472
- Author:
- Simpson, Isobel J.; Aburizaiza, Omar S.; Siddique, Azhar; Barletta, Barbara; Blake, Nicola J.; Gartner, Aaron; Khwaja, Haider; Meinardi, Simone; Zeb, Jahan; Blake, Donald
R.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8529-8537
- ISSN:
- 1520-5851
- Subject:
- air; air pollution; air quality; alkenes; carbon monoxide; cities; combustion; evaporation; gasoline; human health; ozone; petroleum; surveys; volatile organic compounds; Saudi Arabia
- Abstract:
- ... The Arabian Peninsula experiences severe air pollution, the extent and sources of which are poorly documented. Each year in Saudi Arabia this situation is intensified during Hajj, the Holy Pilgrimage of Islam that draws millions of pilgrims to Mecca. An initial study of air quality in Mecca and surrounding holy sites during the 2012 Hajj (October 24–27) revealed strongly elevated levels of the com ...
- DOI:
- 10.1021/es5017476
-
http://dx.doi.org/10.1021%2Fes5017476
- Author:
- Cahill, Thomas M.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8507-8513
- ISSN:
- 1520-5851
- Subject:
- acrolein; analytical methods; environmental protection; summer; toxicity; urban areas; California
- Abstract:
- ... Acrolein (2-propenal) is a reactive chemical that is very toxic and has many sources. Acrolein is commonly detected in the atmosphere, but understanding the ambient concentrations of this compound has been hampered by analytical difficulties. The objective of this research was to utilize an analytical method specifically designed for acrolein to determine acrolein concentrations in remote regions. ...
- DOI:
- 10.1021/es5014533
-
http://dx.doi.org/10.1021%2Fes5014533
- Author:
- Zhou, Feng; Shang, Ziyin; Ciais, Philippe; Tao, Shu; Piao, Shilong; Raymond, Peter; He, Canfei; Li, Bengang; Wang, Rong; Wang, Xuhui; Peng, Shushi; Zeng, Zhenzhong; Chen, Han; Ying, Na; Hou, Xikang; Xu, Peng
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8538-8547
- ISSN:
- 1520-5851
- Subject:
- emissions factor; energy; geographical distribution; greenhouse gas emissions; industry; nitrous oxide; urban population; urbanization; wastes; wildfires; China
- Abstract:
- ... The amount and geographic distribution of N₂O emissions over China remain largely uncertain. In this study, county-level and 0.1° × 0.1° gridded anthropogenic N₂O emission inventories for China (PKU-N₂O) in 2008 are developed based on high-resolution activity data and regional emission factors (EFs) and parameters. These new estimates are compared with previous inventories, and with two sensitivit ...
- DOI:
- 10.1021/es5018027
-
http://dx.doi.org/10.1021%2Fes5018027
- Author:
- Gou, Na; Yuan, Songhu; Lan, Jiaqi; Gao, Ce; Alshawabkeh, Akram
N.; Gu, April Z.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8855-8863
- ISSN:
- 1520-5851
- Subject:
- DNA; bisphenol A; cell membranes; genotoxicity; hydroquinone; ibuprofen; mineralization; oxidation; oxidative stress; pollutants; process design; proteins; remediation; risk reduction; stress response; toxicogenomics
- Abstract:
- ... The incomplete mineralization of contaminants of emerging concern (CECs) during the advanced oxidation processes can generate transformation products that exhibit toxicity comparable to or greater than that of the original contaminant. In this study, we demonstrated the application of a novel, fast, and cost-effective quantitative toxicogenomics-based approach for the evaluation of the evolution a ...
- DOI:
- 10.1021/es501222t
- PubMed:
- 25010344
- PubMed Central:
- PMC4123925
-
http://dx.doi.org/10.1021%2Fes501222t
- Author:
- Li, Miling; Sherman, Laura S.; Blum, Joel D.; Grandjean, Philippe; Mikkelsen, Bjarni; Weihe, Pál; Sunderland, Elsie
M.; Shine, James
P.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8800-8806
- ISSN:
- 1520-5851
- Subject:
- diet recall; dietary exposure; dietary surveys; exposure assessment; fish; fishermen; hairs; isotope fractionation; mercury; methylmercury compounds; muscle tissues; seafoods; stable isotopes; statistical models; uncertainty; whales; Gulf of Mexico
- Abstract:
- ... Seafood consumption is the primary route of methylmercury (MeHg) exposure for most populations. Inherent uncertainties in dietary survey data point to the need for an empirical tool to confirm exposure sources. We therefore explore the utility of Hg stable isotope ratios in human hair as a new method for discerning MeHg exposure sources. We characterized Hg isotope fractionation between humans and ...
- DOI:
- 10.1021/es500340r
- PubMed:
- 24967674
- PubMed Central:
- PMC4123924
-
http://dx.doi.org/10.1021%2Fes500340r
- Author:
- Li, Hong-Bo; Cui, Xin-Yi; Li, Kan; Li, Jie; Juhasz, Albert L.; Ma, Lena Q.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8548-8555
- ISSN:
- 1520-5851
- Subject:
- bioavailability; blood; cities; coal; combustion; coprecipitation; dust; gastrointestinal system; in vitro studies; iron; isotopes; lead; mice; models; pH; prediction; solubility; China
- Abstract:
- ... House dust samples containing 25–738 mg of Pb kg–¹ from 15 cities in China were assessed for in vitro Pb bioaccessibility and in vivo Pb relative bioavailability. On the basis of stable Pb isotope ratios, the Pb in dust samples mainly originated from coal combustion. Lead bioaccessibility was determined using gastric (GP) and intestinal phase (IP) of solubility bioaccessibility research consortium ...
- DOI:
- 10.1021/es501899j
-
http://dx.doi.org/10.1021%2Fes501899j
- Author:
- Zheng, Shudong; Tao, Mengna; Liu, Qing; Ning, Liqi; He, Yi; Shi, Yao
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8905-8910
- ISSN:
- 1520-5851
- Subject:
- absorption; amines; carbon dioxide; chemical reactions; energy; ethanol; solubility; solvents
- Abstract:
- ... The major drawback of aqueous alkanolamine-based CO₂ capture processes is the high energy penalty for regeneration. To overcome this weakness, we studied the absorption of CO₂ with amines dissolved in nonaqueous solvents. It was observed that triethylenetetramine (TETA) dissolved in ethanol produces a solid precipitate after absorption, which can then be easily separated and regenerated. As a comp ...
- DOI:
- 10.1021/es501554h
-
http://dx.doi.org/10.1021%2Fes501554h
- Author:
- Verdier, Bruno; Jouanneau, Isabelle; Simonnet, Benoit; Rabin, Christian; Van Dooren, Tom J.
M.; Delpierre, Nicolas; Clobert, Jean; Abbadie, Luc; Ferrière, Régis; Le Galliard, Jean-François
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8744-8753
- ISSN:
- 1520-5851
- Subject:
- carbon dioxide; climatic factors; ecosystems; environmental science; equipment; global change; humidity; light intensity; models; oxygen; plants (botany); rain; seasonal variation; soil; superoxide anion; temperature
- Abstract:
- ... Grand challenges in global change research and environmental science raise the need for replicated experiments on ecosystems subjected to controlled changes in multiple environmental factors. We designed and developed the Ecolab as a variable climate and atmosphere simulator for multifactor experimentation on natural or artificial ecosystems. The Ecolab integrates atmosphere conditioning technolog ...
- DOI:
- 10.1021/es405467s
-
http://dx.doi.org/10.1021%2Fes405467s
- Author:
- Kent, Ronald
D.; Oser, Joel G.; Vikesland, Peter J.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8564-8572
- ISSN:
- 1520-5851
- Subject:
- atomic force microscopy; chemical composition; crystal structure; ions; laboratory experimentation; nanosilver; nanospheres; silver; toxicity; transmission electron microscopy; wastewater treatment
- Abstract:
- ... Sulfidation of silver nanoparticles (AgNPs), which is known to alter AgNP toxicity, occurs during transport through wastewater treatment plants. In this study, arrays of immobilized AgNPs fabricated by nanosphere lithography (NSL) were used to study AgNP sulfidation in a full-scale wastewater treatment plant (WWTP). A detailed laboratory study preceded field deployment. The characteristic NSL patt ...
- DOI:
- 10.1021/es404989t
-
http://dx.doi.org/10.1021%2Fes404989t
- Author:
- Ryan, Brooke M.; Kirby, Jason K.; Degryse, Fien; Scheiderich, Kathleen; McLaughlin, Mike J.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8620-8626
- ISSN:
- 1520-5851
- Subject:
- EDTA (chelating agent); biogeochemical cycles; copper; deferoxamine; dialysis; fulvic acids; isotope fractionation; ligands; nitrilotriacetic acid; rivers; stable isotopes; uptake mechanisms
- Abstract:
- ... As copper (Cu) stable isotopes emerge as a tool for tracing Cu biogeochemical cycling, an understanding of how Cu isotopes fractionate during complexation with soluble organic ligands in natural waters and soil solutions is required. A Donnan dialysis technique was employed to assess the isotopic fractionation of Cu during complexation with the soluble synthetic ligands ethylenediaminetetraacetic ...
- DOI:
- 10.1021/es500764x
-
http://dx.doi.org/10.1021%2Fes500764x
- Author:
- Liao, Shaohua; Pan, Bo; Li, Hao; Zhang, Di; Xing, Baoshan
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8581-8587
- ISSN:
- 1520-5851
- Subject:
- biochar; biomass; biopolymers; cellulose; corn; corn stover; electron paramagnetic resonance spectroscopy; germination; growth retardation; heavy metals; humans; hydroxyl radicals; lignin; oxygen; plasma membrane; polycyclic aromatic hydrocarbons; pyrolysis; rice; risk; roots; seedlings; shoots; society; soil amendments; standard operating procedures; temperature; wheat; wheat straw
- Abstract:
- ... Biochar can benefit human society as a carbon-negative material and soil amendment. However, negative biochar impacts on plant germination and growth have been observed, and they have not been fully explained. Therefore, protocols to avoid these risks cannot be proposed. We hypothesized that the free radicals generated during charring may inhibit plant germination and growth. Significant electron ...
- DOI:
- 10.1021/es404250a
- CHORUS:
- 10.1021/es404250a
-
http://dx.doi.org/10.1021%2Fes404250a
- Author:
- Cao, Zhiguo; Xu, Fuchao; Covaci, Adrian; Wu, Min; Wang, Haizhu; Yu, Gang; Wang, Bin; Deng, Shubo; Huang, Jun; Wang, Xiaoyan
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8839-8846
- ISSN:
- 1520-5851
- Subject:
- dust; flame retardants; humans; isomers; kindergarten; particle size; phosphorus; polybrominated diphenyl ethers; volatilization; China
- Abstract:
- ... Dust samples were collected in Beijing, China, from four different indoor microenvironments (office, hotel, kindergarten, and student dormitory) and one outdoor (road dust) microenvironment. These five composite samples were fractionated into 13 sequential size fractions and an individual fraction of <50 μm for further analysis. In the fractions of <50 μm, nine phosphorus flame retardants (∑PFRs), ...
- DOI:
- 10.1021/es501224b
-
http://dx.doi.org/10.1021%2Fes501224b
- Author:
- Pölkki, Mari; Kangassalo, Katariina; Rantala, Markus J.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8793-8799
- ISSN:
- 1520-5851
- Subject:
- Protophormia terraenovae; copper; encapsulation; environmental exposure; environmental factors; females; gender differences; heavy metals; imagos; immune response; innate immunity; insect larvae; life history; males; pollution; rearing; temperature; tissues; toxic substances
- Abstract:
- ... Environmental pollution is considered one of the major threats to organisms. Direct effects of heavy metal pollution on various life-history traits are well recognized, while the effects of potential interactions between two distinct environmental conditions on different traits are poorly understood. Here, we have tested the effects of interactions between temperature conditions and heavy metal ex ...
- DOI:
- 10.1021/es501880b
-
http://dx.doi.org/10.1021%2Fes501880b
- Author:
- Wong, Fiona; MacLeod, Matthew; Mueller, Jochen
F.; Cousins, Ian T.
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8807-8814
- ISSN:
- 1520-5851
- Subject:
- National Health and Nutrition Examination Survey; body weight; data collection; environmental monitoring; gender differences; half life; humans; men; menstruation; models; perfluorooctane sulfonic acid; pharmacokinetics; women; United States
- Abstract:
- ... Human biomonitoring studies have shown that concentrations of perfluorooctane sulfonic acid (PFOS) in men are higher than in women. We investigate sex differences in elimination of PFOS by fitting a population-based pharmacokinetic model to six cross-sectional data sets from 1999 to 2012 from the US National Health and Nutrition Examination Survey (NHANES) and derive human first-order elimination ...
- DOI:
- 10.1021/es500796y
-
http://dx.doi.org/10.1021%2Fes500796y
- Author:
- Vannini, Andrea; Nicolardi, Valentina; Bargagli, Roberto; Loppi, Stefano
- Source:
- Environmental Science & Technology 2014 v.48 no.15 pp. 8754-8759
- ISSN:
- 1520-5851
- Subject:
- Xanthoria; air; bioaccumulation; epiphytes; equations; exposure duration; lichens; mercury; temperature
- Abstract:
- ... The uptake kinetics of elemental gaseous Hg (Hg⁰) in three species of epiphytic lichens (Pseudevernia furfuracea, Evernia prunastri, and Xanthoria parietina) were investigated under four different Hg concentrations (10, 15, 30, and 45 μg/m³) and three different temperatures (10, 20, and 30 °C) with the aim of evaluating the lichen efficiency for Hg⁰ accumulation and their potential use in the esti ...
- DOI:
- 10.1021/es500866k
-
http://dx.doi.org/10.1021%2Fes500866k