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coal; combustion; control methods; emissions; glaciers; gold; heavy metals; mercury; mining; pollution; silver; toxicity; traditional technology; Central Asia; Europe; North America
Abstract:
... Anthropogenic emissions of the toxic heavy metal mercury (Hg) have substantially increased atmospheric Hg levels during the 20th century compared to preindustrial times. However, on a regional scale, atmospheric Hg concentration or deposition trends vary to such an extent during the industrial period that the consequences of recent Asian emissions on atmospheric Hg levels are still unclear. Here w ...
biochar; carbon nanotubes; chemical bonding; chemical structure; fullerene; global warming; ingredients; mass spectrometry; pyrolysis; soil; soil quality; solvents; temperature; transmission electron microscopy
Abstract:
... Biochar is a promising carbon material to improve soil quality and relieve global warming by adding it into soil. Though biochar has been used for millennia as a soil ingredient, fundamental studies on the structure of biochar have only recently attracted great interest, and molecular-level structures are being pursued. In this study, by applying solvent exfoliation, high-resolution transmission e ...
... A controlled field study was performed to evaluate the effectiveness of transgenic poplars for phytoremediation. Three hydraulically contained test beds were planted with 12 transgenic poplars, 12 wild type (WT) poplars, or left unplanted, and dosed with equivalent concentrations of trichloroethylene (TCE). Removal of TCE was enhanced in the transgenic tree bed, but not to the extent of the enhanc ...
... Ultrafine particle (UFP) emissions and particle number size distributions (PNSD) are critical in the evaluation of air pollution impacts; however, data on UFP number emissions from cookstoves, which are a major source of many pollutants, are limited. In this study, 11 fuel-stove combinations covering a variety of fuels and different stoves are investigated for UFP emissions and PNSD. The combustio ...
markets; perfluorooctane sulfonic acid; perfluorooctanoic acid; society
Abstract:
... More than 3000 per- and polyfluoroalkyl substances (PFASs) are, or have been, on the global market, yet most research and regulation continues to focus on a limited selection of rather well-known long-chain PFASs, particularly perfluorooctanesulfonate (PFOS), perfluorooctanoic acid (PFOA) and their precursors. Continuing to overlook the vast majority of other PFASs is a major concern for society. ...
... A new prototype air–liquid interface (ALI) exposure system, a flatbed aerosol exposure chamber termed NAVETTA, was developed to investigate deposition of engineered nanoparticles (NPs) on cultured human lung A549 cells directly from the gas phase. This device mimics human lung cell exposure to NPs due to a low horizontal gas flow combined with cells exposed at the ALI. Electrostatic field assistan ...
... We report a fast, simple, and green coating method using the coordination complex of tannic acid (TA) and ferric ion (Fe³⁺) to enhance the removal of trace organic contaminants (TrOCs) by polyamide membranes. The entire coating process can be completed in less than 2 min; quartz crystal microbalance characterization revealed that a TA–Fe thin film formed in merely 10–20 s. Coating this TA–Fe thin ...
... Atmospheric mercury (Hg) is deposited to Polar Regions during springtime atmospheric mercury depletion events (AMDEs) that require halogens and snow or ice surfaces. The fate of this Hg during and following snowmelt is largely unknown. We measured Hg, major ions, and stable water isotopes from the snowpack through the entire spring melt runoff period for two years. Our small (2.5 ha) watershed is ...
air; combustion; data collection; electron paramagnetic resonance spectroscopy; free radicals; leaves; oxygen; pollution; risk; samplers; Tennessee
Abstract:
... Stable, bioreactive, radicals known as environmentally persistent free radicals (EPFRs) have been found to exist on the surface of airborne PM₂.₅. These EPFRs have been found to form during many combustion processes, are present in vehicular exhaust, and persist in the environment for weeks and biological systems for up to 12 h. To measure EPFRs in PM samples, high volume samplers are required and ...
distillation; drainage; electrolytes; geothermal energy; heat; heavy metals; hydrophobicity; iron oxyhydroxides; methodology; minerals; models; oxidation; pH; rivers; sulfates; temperature; vapors; wastewater; water quality; United States
Abstract:
... Acid rock drainage (ARD) is a metal-rich wastewater that forms upon oxidation of sulfidic minerals. Although ARD impacts >12,000 miles of rivers in the U.S. and has an estimated cleanup cost of $32–$72 billion, the low pH and high metal concentrations in ARD make rapid, high volume treatment without chemical addition difficult. This research focuses on a novel method of ARD treatment, membrane dis ...
... Multiple metals are usually present in surface waters, sometimes leading to toxicity that currently is difficult to predict due to potentially non-additive mixture toxicity. Previous toxicity tests with Daphnia magna exposed to binary mixtures of Ni combined with Cd, Cu, or Zn demonstrated that Ni and Zn strongly protect against Cd toxicity, but Cu–Ni toxicity is more than additive, and Ni–Zn toxi ...
... We characterized spatial patterns of surface sediment concentrations of seven polychlorinated biphenyls (PCBs), seven polycyclic aromatic hydrocarbons (PAHs), three chlorinated pesticides, and five metals in Norwegian waters and Skagerrak. In total, we analyzed 5036 concentrations of 22 chemical substances that were measured between 1986 and 2014 at 333 sampling sites by means of generalized addit ...
bioaccumulation; biodegradability; carbon cycle; cosmetics; issues and policy; laws and regulations; microbeads; plastics; pollution; sustainable technology; toxicity; United States
Abstract:
... The United States Microbead-Free Waters Act was signed into law in December 2015. It is a bipartisan agreement that will eliminate one preventable source of microplastic pollution in the United States. Still, the bill is criticized for being too limited in scope, and also for discouraging the development of biodegradable alternatives that ultimately are needed to solve the bigger issue of plastics ...
... Adsorption of two estrogen contaminants (17β-estradiol and 17α-ethynyl estradiol) by graphene nanomaterials was investigated and compared to those of a multi-walled carbon nanotube (MWCNT), a single-walled carbon nanotube (SWCNT), two biochars, a powdered activated carbon (PAC), and a granular activate carbon (GAC) in ultrapure water and in the competition of natural organic matter (NOM). Graphene ...
Zodrow Katherine R.; Li Qilin; Buono Regina M.; Chen Wei; Daigger Glen; Dueñas-Osorio Leonardo; Elimelech Menachem; Huang Xia; Jiang Guibin; Kim Jae-Hong; Logan Bruce E.; Sedlak David L.; Westerhoff Paul; Alvarez Pedro J. J.
cities; climate change; energy; infrastructure; materials science; population growth; systems analysis; water pollution; water stress; water supply; water treatment
Abstract:
... Innovation in urban water systems is required to address the increasing demand for clean water due to population growth and aggravated water stress caused by water pollution, aging infrastructure, and climate change. Advances in materials science, modular water treatment technologies, and complex systems analyses, coupled with the drive to minimize the energy and environmental footprints of cities ...
... Sulfidation has gained increasing interest in recent years for improving the sequestration of contaminants by zerovalent iron (ZVI). In view of the bright prospects of the sulfidated ZVI (S-ZVI), this review comprehensively summarized the latest developments in sulfidation of ZVI, particularly that of nanoscale ZVI (S-nZVI). The milestones in development of S-ZVI technology including its backgroun ...
... Pressures to ban bisphenol A (BPA) has led to the use of alternate chemicals such as BPA analogues bisphenol S (BPS) and bisphenol AF (BPAF) in production of consumer products; however, information on their environmental fate is scarce. In this study, aerobic degradation of BPA, BPAF, and BPS at 100 μg/kg soil and 22 ± 2 °C was monitored for up to 180 days in a forest soil and an organic farm soil ...
... Three-dimensional (3D) printers are known to emit aerosols, but questions remain about their composition and the fundamental processes driving emissions. The objective of this work was to characterize the aerosol emissions from the operation of a fuse-deposition modeling 3D printer. We modeled the time- and size-resolved emissions of submicrometer aerosols from the printer in a chamber study, gain ...
... The cooperative effects of pH and electrolytes on the aggregation of GQDs and the aggregate morphologies are characterized. Because GQDs have an average size of 9 nm with abundant O-functionalized edges, their suspension was very stable even in a high electrolyte concentration and low pH solution. Divalent cations (Mg²⁺ and Ca²⁺) excelled at aggregating the GQD nanoplates, while monovalent cations ...
... To understand their fate and transport in estuarine systems, the aggregation, sedimentation, and dissolution of CdSe quantum dots (QDs) in seawater were investigated. Hydrodynamic size increased from 40 to 60 nm to >1 mm within 1 h in seawater, and the aggregates were highly polydispersed. Their sedimentation rates in seawater were measured to be 4–10 mm/day. Humic acid (HA), further increased the ...
... Air pollution and climate change are potential drivers for the increasing burden of allergic diseases. The molecular mechanisms by which air pollutants and climate parameters may influence allergic diseases, however, are complex and elusive. This article provides an overview of physical, chemical and biological interactions between air pollution, climate change, allergens, adjuvants and the immune ...
Smith Mackenzie L.; Gvakharia Alexander; Kort Eric A.; Sweeney Colm; Conley Stephen A.; Faloona Ian; Newberger Tim; Schnell Russell; Schwietzke Stefan; Wolter Sonja
United States Environmental Protection Agency; aircraft; basins; coalbed methane; greenhouse gas emissions; greenhouse gases; inventories; methane; oils; satellites; seepage; shale; United States
Abstract:
... Methane (CH₄) is a potent greenhouse gas and the primary component of natural gas. The San Juan Basin (SJB) is one of the largest coal-bed methane producing regions in North America and, including gas production from conventional and shale sources, contributed ∼2% of U.S. natural gas production in 2015. In this work, we quantify the CH₄ flux from the SJB using continuous atmospheric sampling from ...
... The benefits and impacts of unconventional natural gas development are realized at different spatial scales, calling into question the appropriate jurisdictional level at which to set and enforce environmental policy. This paper evaluates impact fee allocation under Pennsylvania Act 13, which authorizes Commonwealth payments to Pennsylvania counties to offset damages from unconventional natural ga ...
... The concentrations and enantiomer fractions (EFs) of α-, β-, and γ-hexabromocyclododecanes (HBCDs) were measured in chicken diet sources (soil and chicken feed), home-raised adult chicken (Gallus domesticus) tissues, eggs during incubation, and hatchling chicken tissues. HBCD concentrations were not detected–0.69 ng/g dry weight (dw) and 25.6–48.4 ng/g dw in chicken feed and soil, respectively. HB ...
... Ambient particulate matter may upset redox homeostasis, leading to oxidative stress and adverse health effects. Size distributions of water-insoluble and water-soluble OPᴰᵀᵀ (dithiothreitol assay, measure of oxidative potential per air volume) are reported for a roadside site and an urban site. The average water-insoluble fractions were 23% and 51%, and 37% and 39%, for fine and coarse modes at th ...
air pollution; ammonia; ammonium; emissions; fertilizer application; livestock; mineral fertilizers; monitoring; nitrogen; pollution control; satellites; China
Abstract:
... China is a global hotspot of atmospheric ammonia (NH₃) emissions and, as a consequence, very high nitrogen (N) deposition levels are documented. However, previous estimates of total NH₃ emissions in China were much lower than inference from observed deposition values would suggest, highlighting the need for further investigation. Here, we reevaluated NH₃ emissions based on a mass balance approach, ...
Sipes Nisha S.; Wambaugh John F.; Pearce Robert; Auerbach Scott S.; Wetmore Barbara A.; Hsieh Jui-Hua; Shapiro Andrew J.; Svoboda Daniel; DeVito Michael J.; Ferguson Stephen S.
Internet; United States Environmental Protection Agency; blood; decision making; dose response; drug interactions; environmental science; human health; humans; models; prediction; risk; risk assessment; screening; toxicology
Abstract:
... In vitro–in vivo extrapolation (IVIVE) analyses translating high-throughput screening (HTS) data to human relevance have been limited. This study represents the first report applying IVIVE approaches and exposure comparisons using the entirety of the Tox21 federal collaboration chemical screening data, incorporating assay response efficacy and quality of concentration–response fits, and providing ...
... This study focuses on revealing the interaction of sulfur oxides (SOₓ) and nitrogen oxides (NOₓ) and investigating the application of Fourier transform infrared (FTIR) spectroscopy to quantify SOₓ and NOₓ emissions from gas-phase oxy-combustion systems. The authors aim to contribute to the current state of knowledge by providing speciation data of NOₓ and SOₓ species and it elucidates the influenc ...
Dehalobacter; Dehalococcoides mccartyi; aromatic compounds; cobalt; dechlorination; electron transfer; microorganisms
Abstract:
... Dehalococcoides mccartyi strain CBDB1 and Dehalobacter strain 14DCB1 are organohalide-respiring microbes of the phyla Chloroflexi and Firmicutes, respectively. Here, we report the transformation of chloroanilines by these two bacterial strains via dissimilar dehalogenation pathways and discuss the underlying mechanism with quantum chemically calculated net atomic charges of the substrate Cl, H, an ...
... Anaerobic digestion is a widely used organic waste treatment process. However, little is known on how it could alter the speciation of contaminants in organic waste. This study was focused on determining the influence of anaerobic digestion on the speciation of copper and zinc, two metals that generally occur at high concentration in organic waste. Copper and zinc speciation was investigated by X- ...
... The problems of antibiotic overuse compel us to seek alternative antibacterial agents. Some clays have been shown to kill antibiotic-resistant human pathogens and may provide an alternative to known antibiotics. Here we show that Al toxicity plays a central role in the antibacterial action of a kaolin-rich clay from the Colombian Amazon (AMZ). Antibacterial susceptibility testing shows minimum inh ...
analysis of variance; antibiotic resistance; antibiotic resistance genes; antibiotics; environmental factors; heavy metals; interspersed repetitive sequences; landfills; leachates; microbial communities; municipal solid waste; risk
Abstract:
... Landfills receive about 350 million tons of municipal solid wastes (MSWs) per year globally, including antibiotics and other coselecting agents that impact antimicrobial resistance (AMR). However, little is known about AMR in landfills, especially as a function of landfill ages. Here we quantified antibiotics, heavy metals, and AMR genes (ARGs) in refuse and leachates from landfills of different a ...
... Jarosite can be an important scavenger for arsenic (As) and antimony (Sb) in acid mine drainage (AMD) and acid sulfate soil (ASS) environments. When subjected to reducing conditions, jarosite may undergo reductive dissolution, thereby releasing As, Sb, and Fe²⁺ coincident with a rise in pH. These conditions can also trigger the Fe²⁺-induced transformation of jarosite to more stable Fe(III) mineral ...
... Dietary Cd intake is often estimated without considering Cd bioavailability. Measured urinary Cd for a cohort of 119 nonsmokers with rice as a staple was compared to predicted values from rice-Cd intake with and without considering Cd relative bioavailability (RBA) in rice based on a steady state mouse kidney bioassay and toxicokinetic model. The geometric mean (GM) of urinary Cd and β₂-microglobu ...
... Basaluminite precipitation may play an important role in the behavior of trace elements in water and sediments affected by acid mine drainage and acid sulfate soils. In this study, the affinity of basaluminite and schwertmannite for arsenate and selenate is compared, and the coordination geometries of these oxyanions in both structures are reported. Batch isotherm experiments were conducted to exa ...
... Methylated arsenic (As) species represent a significant fraction of the As accumulating in rice grains, and there are geographic patterns in the abundance of methylated arsenic in rice that are not understood. The microorganisms driving As biomethylation in paddy environments, and thus the soil conditions conducive to the accumulation of methylated arsenic, are unknown. We tested the hypothesis th ...
... Arsenic is an ubiquitous toxic element in the environment, and organisms have evolved different arsenic detoxification strategies. Studies on arsenic biotransformation mechanisms have mainly focused on arsenate (As(V)) reduction, arsenite (As(III)) oxidation, and arsenic methylation; little is known, however, about the pathway for the biosynthesis of arsenosugars, which are significant arsenic tra ...
aerosols; air quality; atmospheric chemistry; emissions; models; nitrate reduction; nitrogen dioxide; pollutants; river deltas; uncertainty; urban areas; vehicles (equipment); China; Yangtze River
Abstract:
... There have been significant advancements in electric vehicles (EVs) in recent years. However, the different changing patterns in emissions at upstream and on-road stages and complex atmospheric chemistry of pollutants lead to uncertainty in the air quality benefits from fleet electrification. This study considers the Yangtze River Delta (YRD) region in China to investigate whether EVs can improve ...
environmental science; gallium; germanium; issues and policy; material flow analysis; models; raw materials; rhenium; uncertainty; United States
Abstract:
... Decision-makers traditionally expect “hard facts” from scientific inquiry, an expectation that the results of material flow analyses (MFAs) can hardly meet. MFA limitations are attributable to incompleteness of flowcharts, limited data quality, and model assumptions. Moreover, MFA results are, for the most part, based less on empirical observation but rather on social knowledge construction proces ...
air pollution; geometry; highways; land use; models; prediction; regression analysis; residential areas; urban areas; wind direction; Massachusetts
Abstract:
... Comparative evaluations are needed to assess the suitability of near-road air pollution models for traffic-related ultrafine particle number concentration (PNC). Our goal was to evaluate the ability of dispersion (CALINE4, AERMOD, R-LINE, and QUIC) and regression models to predict PNC in a residential neighborhood (Somerville) and an urban center (Chinatown) near highways in and near Boston, Massa ...
drugs; effluents; filtration; ozonation; ozone; tandem mass spectrometry; wastewater; Germany
Abstract:
... Worldwide, ozonation of secondary wastewater effluents is increasingly considered in order to decrease the load of organic contaminants before environmental discharge. However, despite the constantly growing knowledge of ozonation over the past few years, the characterization of transformation products (TPs) is still a major concern, particularly because such TPs might remain biologically active. ...
... Petroleum coke or “petcoke” is a granular carbonaceous material produced during the upgrading of heavy crude oils, including bitumen. Petcoke dust was recently reported as an environmental contaminant in the Athabasca oil sands region, but the ecotoxicological hazards posed by this complex bitumen-derived material-including those to avian species-have not been characterized. In this study, solvent ...
environmental science; hydrology; oxygen; sediments; soil; temporal variation; time series analysis
Abstract:
... Optical sensing technologies provide opportunities for in situ oxygen sensing capable of capturing the whole range of spatial and temporal variability. We developed a miniaturized Distributed Oxygen Sensor (“mDOS”) specifically for long-term in situ application in soil and sediment. The mDOS sensor system enables the unattended, repeated acquisition of time series of in situ oxygen profiles at a s ...
Hackenberg Sina C.; Andrews Stephen J.; Airs Ruth L.; Arnold Steve R.; Bouman Heather A.; Cummings Denise; Lewis Alastair C.; Minaeian Jamie K.; Reifel Kristen M.; Small Alison; Tarran Glen A.; Tilstone Gavin H.; Carpenter Lucy J.
... We report novel in situ speciated observations of monoterpenes (α- and β-pinene, myrcene, δ3-carene, ocimene, limonene) in seawater and air during three cruises in the Arctic and Atlantic Oceans, in/over generally oligotrophic waters. Oceanic concentrations of the individual monoterpenes ranged from below the detection limit of <1 pmol L–¹ to 5 pmol L–¹, with average concentrations of between 0.5 ...
... One of the major challenges in environmental science is monitoring and assessing the risk of complex environmental mixtures. In vitro bioassays with limited key toxicological end points have been shown to be suitable to evaluate mixtures of organic pollutants in wastewater and recycled water. Omics approaches such as transcriptomics can monitor biological effects at the genome scale. However, few ...
... Graphene nanomaterials have many diverse applications, but are considered to be emerging environmental pollutants. Thus, their potential environmental risks and biosafety are receiving increased attention. Bioaccumulation and toxicity evaluations in plants are essential for biosafety assessment. In this study, ¹³C-stable isotope labeling of the carbon skeleton of graphene oxide (GO) was applied to ...
... The indigenous microorganisms responsible for degrading phenanthrene (PHE) in polycyclic aromatic hydrocarbons (PAHs)-contaminated wastewater were identified by DNA-based stable isotope probing (DNA-SIP). In addition to the well-known PHE degraders Acinetobacter and Sphingobium, Kouleothrix and Sandaracinobacter were found, for the first time, to be directly responsible for indigenous PHE biodegra ...
anaerobic digesters; biogas; biomass; carbon; combustion; electricity; emissions; energy; energy recovery; food waste; landfills; methane; municipal solid waste; nutrient content; California
Abstract:
... Food waste makes up approximately 15% of municipal solid waste generated in the United States, and 95% of food waste is ultimately landfilled. Its bioavailable carbon and nutrient content makes it a major contributor to landfill methane emissions, but also presents an important opportunity for energy recovery. This paper presents the first detailed analysis of monthly food waste generation in Cali ...
Crustacea; air pollution; air quality; bark; humans; insects; issues and policy; leaves; lichens; magnetic properties; magnetism; minerals; monitoring; mosses and liverworts; particulates; pollutants; polycyclic aromatic hydrocarbons; researchers; trace elements; wood
Abstract:
... Biomagnetic monitoring of atmospheric pollution is a growing application in the field of environmental magnetism. Particulate matter (PM) in atmospheric pollution contains readily measurable concentrations of magnetic minerals. Biological surfaces, exposed to atmospheric pollution, accumulate magnetic particles over time, providing a record of location-specific, time-integrated air quality informa ...
United States Environmental Protection Agency; air quality; autumn; biomass; burning; climatology; coasts; emissions; issues and policy; national parks; particulates; pollution; river deltas; smoke; spring; summer; wildfires; winter; Great Plains region; Gulf of Mexico; Louisiana; Mississippi River; Texas
Abstract:
... We utilize the NOAA Hazard Mapping System smoke product for the period of 2005 to 2016 to develop climatology of smoke occurrence over the Continental United States (CONUS) region and to study the impact of wildland fires on particulate matter air quality at the surface. Our results indicate that smoke is most frequently found over the Great Plains and western states during the summer months. Othe ...