Jump to Main Content
- Shindo, Mitsuru, et al. Show all 6 Authors
- Journal of organic chemistry 2017 v.82 no.8 pp. 4305-4316
- anthracenes; catalysts; chemical structure; organic chemistry; oxidants; oxidation; oxygen; regioselectivity; rhodium
- ... A novel, practical protocol for the aerobic direct C–H acetoxylation of arenes, employing a recyclable heterogeneous rhodium catalyst, is reported herein. The trifluoroacetoxylation of 2-amido-substituted anthracenes proceeded at the 9-position with exclusive regioselectivity. The oxidation of variously substituted anthracenes and other polycyclic aromatics with molecular oxygen as a terminal oxid ...