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You searched for: Journal Journal of polymer science Remove constraint Journal: Journal of polymer science Source 2019 v.57 no.3 Remove constraint Source: 2019 v.57 no.3 Subject polymers Remove constraint Subject: polymers Text Availability Full Text Remove constraint Text Availability: Full Text
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1. What happens in the dark? Assessing the temporal control of photo‐mediated controlled radical polymerizations

Author:
Dolinski, Neil D.; Page, Zachariah A.; Discekici, Emre H.; Meis, David; Lee, In‐Hwan; Jones, Glen R.; Whitfield, Richard; Pan, Xiangcheng; McCarthy, Blaine G.; Shanmugam, Sivaprakash; Kottisch, Veronika; Fors, Brett P.; Boyer, Cyrille; Miyake, Garret M.; Matyjaszewski, Krzysztof; Haddleton, David M.; de Alaniz, Javier Read; Anastasaki, Athina; Hawker, Craig J.
Source:
Journal of polymer science 2019 v.57 no.3 pp. 268-273
ISSN:
0887-624X
Subject:
monitoring; nuclear magnetic resonance spectroscopy; polymerization; polymers
Abstract:
... A signature of photo‐mediated controlled polymerizations is the ability to modulate the rate of polymerization by turning the light source ‘on’ and ‘off.’ However, in many reported systems, growth can be reproducibly observed during dark periods. In this study, emerging photo‐mediated controlled radical polymerizations are evaluated with in situ ¹H NMR monitoring to assess their behavior in the da ...
DOI:
10.1002/pola.29247
PubMed:
31011240
PubMed Central:
PMC6474683