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- Wang, Yi; Fantin, Marco; Park, Sangwoo; Gottlieb, Eric; Fu, Liye; Matyjaszewski, Krzysztof
- Macromolecules 2017 v.50 no.20 pp. 7872-7879
- acrylates; composite polymers; electrochemistry; electrodes; free radicals; polymerization
- ... An electrochemically mediated reversible addition–fragmentation chain-transfer polymerization (eRAFT) of (meth)acrylates was successfully carried out via electroreduction of either benzoyl peroxide (BPO) or 4-bromobenzenediazonium tetrafluoroborate (BrPhN₂⁺) which formed aryl radicals, acting as initiators for RAFT polymerization. Direct electroreduction of chain transfer agents was unsuccessful s ...
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