Jump to Main Content
- Tiniakos, Alexander F.; Wittmann, Stéphane; Audic, Alexandre; Prunet, Joëlle
- Organic letters 2018 v.21 no.3 pp. 589-592
- alcohols; alkenes; chemical reactions; chemical structure
- ... A silicon-tether ring-closing metathesis strategy is reported for the synthesis of trisubstituted olefins flanked by allylic or homoallylic alcohols, which are difficult to obtain by classical ring-closing or cross-metathesis reactions. In addition, a novel Peterson olefination reaction has been developed for the preparation of the allyldimethylsilane precursors, which are versatile synthetic inte ...