Jump to Main Content
- Secen, Hasan, et al. Show all 5 Authors
- Organic letters 2013 v.15 no.18 pp. 4790-4793
- azides; chemical bonding; chemical reactions; chemical structure; cleavage (chemistry); furans; triazoles
- ... Photooxygenation of azidoalkyl furans has revealed both a novel triazole formation method and a unique endoperoxide rearrangement. The key step of this method is a 3 + 2 cycloaddion of the azide to the endoperoxide intermediate. The reduction of the peroxide bond and two subsequent C–C bond cleavages provide a triazole having a newly formed carboxylic acid functionality. The reactions are clean an ...