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1. Two distinct tetranuclear motifs, rectangular vs. extended, are observed for complexes of a bis-tetradentate pyrimidine-based ligand

Author:
Brooker, Sally,   et al.   ; Gobeze, Worku A.;     Show all 2 Author
Source:
RSC advances 2013 v.3 no.46 pp. 24307-24312
ISSN:
2046-2069
Subject:
anions; chlorides; crystal structure; encapsulation; ligands; methanol; moieties; nitrogen
Abstract:
... The 1 : 2 reactions of 4,6-bis[N,N-bis(2′-pyridylmethyl)aminomethyl]-2-phenylpyrimidine (Lᴹᵉ) and Mnᴵᴵ, Coᴵᴵ, Niᴵᴵ and Cuᴵᴵ chloride salts in MeOH gave the tetranuclear complexes [Mnᴵᴵ₄(Lᴹᵉ)₂Cl₈]·2H₂O (1), Coᴵᴵ₄(Lᴹᵉ)₂Cl₈·10H₂O (2), [Ni₄ᴵᴵ(Lᴹᵉ)₂Cl₄]Cl₄·8H₂O (3) and [Cuᴵᴵ₄(Lᴹᵉ)₂Cl₆]Cl₂·8H₂O (4), respectively. X-ray crystal structure determinations carried out on three of the complexes revealed that ...
DOI:
10.1039/c3ra45091k