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- Kazmierczak, Lukasz; Wolszczak, Marian; Swiatla-Wojcik, Dorota
- TheJournal of physical chemistry 2019 v.123 no.2 pp. 528-533
- absorption; chlorine; density functional theory; hydroxyl radicals; ionic strength; ions; radiolysis
- ... A new mechanism for the dichloride radical anion (Cl₂•–) formation in diluted acidic chloride solutions is proposed on the grounds of pulse radiolysis measurements of the optical absorption growth at 340 nm and the density functional theory and Hartree–Fock computations. We show that the rate of •OH conversion into Cl₂•– is determined by the equilibrium concentration of the ionic pair H₃O⁺·Cl–. Ac ...