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Citrus; arsenic; cytotoxicity; enzyme inhibitors; epithelial cells; genes; human diseases; lungs; mitogen-activated protein kinase; oxidative stress; pathogenesis; phosphatidylinositol 3-kinase; polymethoxyflavones; protein kinase C; sodium; toxic substances; ubiquitination
Abstract:
... Exogenous toxicants (e.g. arsenic, cigarette smoke), trigger oxidative stress, and initiate the pathogenesis of many human diseases. Induction of nuclear factor E2-related factor 2 (Nrf2) counteract exogenous toxicant-induced oxidative insults. Using a high-throughput screen, we firstly identified a citrus polymethoxyflavone, (2S)-5,6,7,3',4'-pentamethoxyflavanone (PMF), to be an Nrf2 activator, a ...
arsenic; cesium; coastal sediments; coasts; copper; highlands; hydrology; lead; mining; models; plutonium; radionuclides; salt marshes; upland soils; watersheds; zinc; Irish Sea; Isle of Man
Abstract:
... The Isle of Man, situated in the central Irish Sea, was a significant centre for Pb and Zn mineral extraction during the Industrial Revolution. Comminuted mining debris from the East Snaefell and North Laxey mining areas was transported, through hydrological action, from upland catchments to the coast. This study focuses on an eastern coastal sediment sink and a salt marsh sediment sequence from P ...
... In this study, the effect of 24-Epibrassinolide (EBL) on antioxidant system in Arabidopsis thaliana were investigated under arsenate [As(V)] stress. The enzyme activity of superoxide dismutase (SOD) and catalase (CAT), total antioxidant status, malondialdehyde (MDA) level and free proline content, as well as the expression levels of SOD isoforms (Cu-ZnSODs, FeSODs and MnSOD), CAT isoforms (CAT1, C ...
Khanghyun Lee; Changhee Han; Sang-Bum Hong; Seong-Joon Jun; Yeongcheol Han; Cunde Xiao; Zhiheng Du; Soon Do Hur; Jong Ik Lee; Claude F. Boutron; Sungmin Hong
air pollution; arsenic; coal; combustion; ice; snow; technology; toxicity; China; Europe; Greenland; North America
Abstract:
... We report the first high-resolution record of arsenic (As) observed in Greenland snow and ice for the periods 1711–1970 and 2003–2009 AD. The results show well-defined large-scale atmospheric pollution by this toxic element in the northern hemisphere, beginning as early as the 18th century. The most striking feature is an abrupt, unprecedented enrichment factor (EF) peak in the late 1890s, with an ...
... Recently indoor air quality (IAQ) has become a key issue, especially in schools, where children spend most of the day. Only in a few cases IAQ was investigated using lichens as biomonitors. During autumn 2017, lichens (Evernia prunastri) were exposed for two months indoors and outdoors in public (schools) and private (dwellings) environments, in both rural and urban areas of Slovakia. The bioaccum ...
... Arsenic is one of the most widespread global environmental toxicants associated with endemic poisoning. ATP-binding cassette (ABC) proteins are transmembrane channels that transport and dispose of lipids and metabolic products across the plasma membrane. The majority of ABC family members (including ABCB1 and ABCC1) are reported to play a role in the development of arsenic and drug resistance in m ...
air; aquatic organisms; arsenic; carbon dioxide; compliance; electrical conductivity; environmental assessment; environmental audits; environmental performance; gold; greenhouses; habitats; issues and policy; methylmercury compounds; nitrogen; pH; public health; recreation; rivers; sulfur; sustainable development; time series analysis; toxicity; water quality; Ghana
Abstract:
... The AKOBEN Programme, an environmental performance rating and disclosure initiative that show the environmental performance of gold mining firms with reference to their daily activities post environmental impact assessment and issuance of an environmental permit was introduced in Ghana to serve as a monitoring and verification tool towards environmental compliance and responsible mining. As to whe ...
... This study aimed to investigate nine heavy metal concentrations (As, Cd, Cr, Pb, Cu, Fe, Zn, Mn and Ni) in water, sediment and snakehead fish (Channa striata) and to identify abnormal chromosomes in C. striata from a reservoir near an industrial factory and a reference area. Heavy metal concentrations were measured by inductively coupled plasma optical emission spectrometry (ICP-OES). The metal co ...
... Arsenic (As) and cadmium (Cd) are known to be toxic to humans, and elevated concentrations have been documented in food crops worldwide. However, little is known regarding their uptake, translocation, and distribution in wheat plants during plant development. A series of experiments were conducted to investigate the spatial distribution and dynamics of As and Cd in two wheat cultivars (cv. JN12 an ...
arsenic; cadmium; chromium; cobalt; copper; heavy metals; humic substances; hydroxides; iron; lead; manganese; molybdenum; nickel; rivers; sediments; sorption; vanadium; zinc; Sea of Japan
Abstract:
... The average concentrations of elements Fe, Mn, Zn, Pb, Cu, Cr, V, Co, Cd, Ni, As, and Mo in the subcolloidal fraction of bottom sediments were determined in the northern and central parts of the Amur Bay. The concentrations of metals Pb, Co, Ni, Zn, Cr, V, and As in bottom sediments subject to direct influence of the Razdol’naya River were shown to increase by 5–17% because of their sorption on Fe ...
... A non-invasive study of trace element accumulation in tail feathers of the Kentish plover (Charadrius alexandrinus) was performed along the coastline of the northern littoral strip of the Venice Lagoon, with the aim to verify whether contamination may be a factor affecting conservation status of Kentish plover populations.Body burdens in feathers of 11 trace elements including toxic metals/metallo ...
... Plants that have grown for many years in the special environmental conditions prevailing in mining areas are naturally screened and show strong capacity to adapt to their environment. The present study investigated the enrichment characteristics of U and other heavy metals (As, Cu, Pb, Mn, Mo, Zn, Cd, Co, and Ni) in the soil–plant system in Xiazhuang uranium mine. Four dominant plants (Castanopsis ...
... The heavy metals Al, Cr, Cu, Ni, Pb, Zn, Fe, Mn, As, and Cd in the rainfall-driven supratidal wetlands along the west coast of the Bohai Sea (the areas are named site 1, site 2, site 3, and site 4 from south to north in the gradient in this study) are tested for their accumulation risks and sources. Results show that the distribution and enrichment of the heavy metals in the supratidal wetlands ar ...
agricultural soils; arsenic; basins; cadmium; case studies; coal; combustion; copper; ecosystems; environmental health; fertilizers; food security; heavy metals; human health; irrigation water; lead; mercury; paddy soils; pollution; rice; risk; risk assessment; soil sampling; transportation; zinc; China
Abstract:
... Contamination of agricultural soil by heavy metals has become a global issue concerning food security and human health risk. In this study, a soil investigation was conducted to evaluate metals accumulation, potential ecological and health risks as well as to identify sources of metals in paddy soils in Hanzhong City, which is located in a sedimentary basin. Ninety-two (92) surface soil samples (b ...
anthropogenic activities; arsenic; chromium; copper; heavy metals; industrialization; industry; lead; multivariate analysis; nickel; pollution; principal component analysis; river deltas; sand; zinc; China; Yellow River
Abstract:
... In 2014, three sediment cores were collected from the northern [Xinyanggang (XYG)], middle [Chuandonggang (CDG)], and southern [Xiaoyangkou (XYK)] parts of the coastal tidal flats of the North Jiangsu radial sand ridges (NJRSR), East China. The grain size and contents of heavy metals (Cu, Zn, Cr, Ni, Pb and As) in the cores were detected. The features of sediments and the accumulation of heavy met ...
... The Fenhe River basin is the main agricultural and industrial developed area in Shanxi province, China. In recent years, agricultural non-point source pollution in the Fenhe River basin intensified, threatening soil quality and safety in the area. Accumulation of eight heavy metals (HMs) including chromium (Cr), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), cadmium (Cd), lead (Pb) and mercury ...
advection; anthropogenic activities; arsenic; belowground biomass; bioaccumulation; coasts; dust; ecosystems; ecotoxicology; estuaries; metals; models; plant litter; pollution; sediments; toxicity; Bay of Bengal; India
Abstract:
... Arsenic (As), a toxic element is a concern for the habitants in and around the coastal areas of West Bengal (India) where world's largest Sundarbans mangrove is situated. Little is known about the potential of these mangroves in storing As within their biomass and transporting to the Bay of Bengal. A comprehensive yearly data of above ground and below ground biomass (AGB, BGB), and exchange fluxes ...
T. L. Tasker; W. D. Burgos; M. A. Ajemigbitse; N. E. Lauer; A. V. Gusa; M. Kuatbek; D. May; J. D. Landis; D. S. Alessi; A. M. Johnsen; J. M. Kaste; K. L. Headrick; F. D. H. Wilke; M. McNeal; M. Engle; A. M. Jubb; R. D. Vidic; A. Vengosh; N. R. Warner
arsenic; atomic absorption spectrometry; basins; calibration; cations; chromium; copper; data quality; environmental protection; lead; monitoring; nickel; oils; radioactivity; radium; radon; sediments; sludge; wastewater; zinc; United States
Abstract:
... Accurate and precise analyses of oil and gas (O&G) wastewaters and solids (e.g., sediments and sludge) are important for the regulatory monitoring of O&G development and tracing potential O&G contamination in the environment. In this study, 15 laboratories participated in an inter-laboratory comparison on the chemical characterization of three O&G wastewaters from the Appalachian Basin and four so ...
World Health Organization; X-ray absorption spectroscopy; arsenic; electrocoagulation; electrolysis; magnetite; pH; research; sorption; water; water treatment; water utilities; Netherlands
Abstract:
... Consumption of drinking water containing arsenic at concentrations even below the World Health Organization provisional limit of 10 μg/L can still lead to unacceptable health risks. Consequently, the drinking water sector in the Netherlands has recently agreed to target 1 μg/L of arsenic in treated water. Unfortunately, in many poor, arsenic-affected countries, the costs and complexity of current ...
Xiaohui Zhang; Song Tang; Mao Wang; Weimin Sun; Yuwei Xie; Hui Peng; Aimin Zhong; Hongling Liu; Xiaowei Zhang; Hongxia Yu; John P. Giesy; Markus Hecker
... Acid mine drainage (AMD) is one of the most hazardous byproducts of some types of mining. However, research on how AMD affects the bacterial community structure of downstream riverine ecosystems and the distribution of metal resistance genes (MRGs) along pollution gradient is limited. Comprehensive geochemical and high-throughput next-generation sequencing analyses can be integrated to characteriz ...
... To investigate the acid-extractable heavy metals in fine particulate matter (PM₂.₅) over Xi’an, China, 24-h PM₂.₅ samples were collected every 3 days from December 2015 through November 2016. The bioavailable fraction, termed here the bioavailability index (BI), of PM₂.₅-bound metal (As, Ba, Cd, Co, Cu, Mn, Ni, Pb, Ti, V, and Zn) and potential influencing factors, including relative humidity, temp ...
... A highly lead(II) resistant (up to 2200 mg/l) bacterium PbRPSD202 was selected among 210 lead resistant bacteria isolated from marine environment of Paradeep Port, Odisha for possible biosoption of toxic Pb (II) ions from metals polluted environments. The bacterium was identified as Bacillus xiamenensis following the phenotypic as well as 16S rRNA gene sequence analysis. In addition to Pb(II), it ...
arsenic; artificial intelligence; automation; bias; case studies; cost effectiveness; data collection; experts; health effects assessments; human health; model validation; models; prediction; risk assessment; toxicology
Abstract:
... Machine learning has emerged as a cost-effective innovation to support systematic literature reviews in human health risk assessments and other contexts. Supervised machine learning approaches rely on a training dataset, a relatively small set of documents with human-annotated labels indicating their topic, to build models that automatically classify a larger set of unclassified documents. “Active ...
... Field monitoring was conducted to evaluate the effects of active mine water treatment on improving the water quality of receiving river in a densely populated catchment. Microcosm experiment was also performed to assess the effects of treated mine water on the growth of the vegetable and the uptake of trace elements by the vegetable. The results show that the treatment process was very effective i ...
... The surrounding of the poorly maintained tailing ponds is endangered by the toxic substances and represents a serious risk for the health of the local population. The aim of the study was to determine the soil pollution by the hazardous elements (As, Cr, Cd, Cu, Fe, Mn, Ni, Pb, Zn) around the tailing pond using contamination factor (Cf), degree of contamination (Cd) and pollution load index (PLI). ...
... We describe and illustrate lesions in an outbreak of lead arsenate poisoning in beef cattle that ingested pesticide residues stored in an abandoned building of a former orange orchard. Of 70 exposed cattle, 14 had diarrhea, paresis, ataxia, recumbency, and/or seizures. Ten of the affected animals died after a clinical course of 12–18 h. Pathologic findings in 3 steers included extensive necrohemor ...
... MnO₂ is one of the most widespread and cheapest materials in nature that can both adsorb arsenic and oxidize arsenite [As(III)] to arsenate [As(V)]. In this study, column β-MnO₂ [CM] with the main facet of {110} and pincer β-MnO₂ [PM] with the facets of {110} and {101} are synthesized and used to remove arsenic in water under different conditions. For the adsorption process, the experimental data ...
... The adsorption behavior of thioarsenite (TAsIII) on the surface of hematite (α-Fe2O3) is unknown at present. In the present study, we have investigated the transformation and reactions of TAsIII [monothioarsenite (MTAsIII) and dithioarsneite (DTAsIII)] on the surface of α-Fe2O3 in the presence of sulfide at S/As = 1 and 3 by X-ray absorption spectroscopy (XAS) and Raman spectroscopy. The adsorptio ...
... Arsenic-containing water poses a serious threat to human health. In this study, two types of Fe-modified rice straw biochars [(Fe-impregnated biochar (FeIm char) and pre-modified rice straw biochar (PMRS char)] were prepared, in which three ratios [1, 5, and 10% (w/w)] of Fe modification were evaluated, resulting in six different Fe-modified biochars. Then, a series of adsorption experiments, usin ...
... Arsenic species are regarded as typical water pollutants due to their toxicity. The chemical structures of arsenic species greatly influence their migration and transformation in the environment. Metal-organic frameworks (MOFs) are used as reliable adsorbents to control arsenic contamination, so it is urgently needed to study the effect of chemical structure of arsenic species during adsorption pr ...
... In the present paper, used cigarette filter ash was prepared and used as an active adsorbent to remove As(III) ions from aqueous solutions. The prepared adsorbent structure was identified by scanning electron microscopy analysis, Brunauer–Emmett–Teller method and energy-dispersive X-ray spectroscopy analysis. The influence of contact time, pH, adsorbent dose and initial concentration of As(III) on ...
... Microplastics exhibit active environmental behavior and unique surface characteristics, and act as carriers for the migration of trivalent arsenic (As(III)) in the environment. Herein, the mechanism by which polytetrafluoroethylene (PTFE) microplastic particles adsorb As(III) is systematically determined. The larger the size of PTFE particles, the smaller the specific surface area, the higher the ...
adsorption; arsenic; arsenites; chemical bonding; chemical treatment; endothermy; ferrous chloride; fly ash; groundwater; ions; pH; temperature; toxicity; water treatment; zeolites
Abstract:
... The high toxicity of arsenite and the difficulty to remove it is one of the main challenges for water treatment. In the present work the surface of a low cost zeolite was modified by chemical treatment with a ferrous chloride to enhance its arsenite adsorption capacity. The effect of pH, ions coexistence, concentration, temperature and dosage was studied on the adsorption process. Additionally, th ...
... Gold nanoparticles (AuNPs) have been extensively used for detecting arsenite, As(III). Many methods rely on a DNA aptamer that claimed to bind specifically to inorganic arsenic. In these cases, the focus was on arsenic binding to the aptamer, while the potential interactions between As(III) and the AuNP surface were ignored. Herein, a set of spectroscopic and isothermal titration calorimetry (ITC) ...
... Arsenic (As) is considered as one of the most hazardous elements found in the groundwater. It is present in water in both arsenate (As(V)) and arsenite (As(III)) forms. On exposure for a considerable length of time to water having As concentration above the maximum permissible limit of 10 μg/L, there is a serious threat of developing various health problems including cancer. There is frequent repo ...
... The characteristic of adsorption of As(V) onto ferric oxide-impregnated anion resin Dowex marathon MSA (FO-Dowex) was investigated. Batch adsorption experiment was studied as a function of pH, contact time, initial As(V) concentration, and temperature. The results revealed that the adsorption of As(V) onto FO-Dowex was highly pH-dependent and that the equilibrium time was attained within 360 min. ...
... Recently, arsenic-contaminated water has become a big concern. Therefore, the present study aimed to absorb arsenic from the aqueous solution using modified saxaul tree ash. Arsenic adsorption process was performed in vitro by investigating the effect of various parameters such as pH, contact time, arsenic concentrations, temperature and adsorbent dosage on the adsorption efficiency. Isotherms, ki ...
... The magnetite-enriched particles (MEP) were separated from the mill scale on low magnetic intensity ranging from 300 to 500 gauss. The characterization of the MEP was done with scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). The adsorption efficiency of MEP was investigated with batch tests and column operation. The maximum adsorption cap ...
... As(III) is more toxic and harder to remove than As(V) though they are always co-exist in water. In order to effectively eliminate pollution of arsenic and explore the adsorption mechanism, a novel-innovative hydrated zirconium oxide (ZrO(OH)₂) and manganese dioxide (MnO₂) coated modified activated charcoal (Zr/Mn/C) prepared via a co-precipitation-hydrothermal method. Results showed that As(III) c ...
... Chitosan-magnetic-graphene oxide (CMGO) nanocomposite was prepared for arsenic adsorption. The nanocomposite was characterized through BET, FTIR, FESEM, EDX, and VSM analyses. These characterizations confirmed the formation of CMGO nanocomposites with high specific surface area (152.38 m2/g) and excellent saturation magnetization (49.30 emu/g). Batch adsorption experiments were conducted to evalua ...
X-ray absorption spectroscopy; adsorption; arsenic; binding capacity; ferrihydrite; goethite; iron oxides; models; nanosheets; pH; sorbents; sorption isotherms; surface area
Abstract:
... Adsorption onto two-dimensional nanosheet materials offers new possibilities for fast and efficient removal of contaminants from waters. Here, the adsorption of As(V) to a new type of iron oxides – single sheet iron oxide (SSI) – has been studied as a function of time, loading and pH. Adsorption of As(V) onto SSI was very fast compared to other iron oxides, with 80% of total As(V) adsorbed within ...
arsenic; arsenites; asymmetric membranes; carbon nanotubes; copper; copper nanoparticles; decontamination; drinking water; drinking water treatment; ferrimagnetic materials; hot water treatment; microfiltration; organic matter; phosphates; sodium hydroxide
Abstract:
... BACKGROUND: For effective removal of arsenite [As(III)] from drinking water, copper ferrite (CuFe₂O₄) particles were prepared by using a hydrothermal method and incorporated into layered carbon nanotube (CNT) membranes. The prepared composite membranes were used in the filtration of As(III) under conditions representative of drinking water treatment. RESULTS: The results demonstrated that the CNT ...
... Developing affordable and efficient materials for the removal of arsenic from drinking water is crucial for human and environmental safety. In the present study, the adsorptive performance of magnetic GO/ZnFe₂O₄ nanocomposite and ZnFe₂O₄ nanospinel for arsenic removal from aqueous water was analyzed. The adsorbents were characterized using Fourier-transform infrared spectroscopy, X-ray powder diff ...
... The study of aerosol dispersion characteristics in wastewater treatment plants (WWTPs) has attracted extensive attention. Oxidation ditch (OD) is a commonly implemented process during biological wastewater treatment. This study assessed the component characteristics, source apportionment, and exposure risks of aerosols generated from a WWTP using the OD process (AWO). The results indicated that th ...
adsorbents; adsorption; arsenic; carbon; carbon dioxide; ferric chloride; fly ash; iodine value; iron; kinetics; models; raw materials; rural water supply; sorption isotherms; steam; temperature
Abstract:
... The fly ash from the Corner Brook Pulp and Paper (CBPP) mill was used in this study as the raw material for the preparation of a low-cost adsorbent for arsenic removal from the well water of Bell Island. The CBPP fly ash was physically activated in two different ways: (a) activation with pure CO2 (CAC) with the iodine number and methylene value of 704.53 mg/g and 292.32 mg/g, respectively; and (b) ...
... Clean drinking water is a basic need of human beings around the world. In the past few decades, many research groups have been trying different methods to exploit quantum dots (QDs) to decontaminate water but, due to either cost or cumbersome steps, they have been unsuccessful. We have tried exploiting graphene quantum dots (GQDs) for heavy metal ion detection, particularly for arsenic ions in con ...
... The study was aimed to evaluate the ability of native lichen Xanthoria (X.) parietina to biomonitor and bioaccumulate some heavy metals (As, Cd, Co, Cr, Ni, Pb), PAHs, PCDDs, PCDFs, PCBs and PBDEs and to evaluate the use of the native X. parietina as a multi-tracer tool for scenarios characterized by different anthropogenic pressures. Samples of native X. parietina were collected in six different ...
... Arsenic (As) contamination in soils has posed a severe threat to safe crop production. The previous studies showed the antagonism between phosphorus (P) and As in plant growth and As uptake, while the mechanisms of alleviating As toxicity by P is not completely clear. Due to the limiting P condition, it is imperative to understand how low P addition can be used to suppress arsenate As (V) uptake a ...
... Abiotic stresses enhance the cellular level of reactive oxygen species (ROS) which consequently leads to toxic methylglyoxal (MG) production. Glyoxalases (GlyI & GlyII) catalyze the conversion of toxic MG into non-toxic lactic acid but their properties and functions have been overlooked in cyanobacteria. This is the first attempt to conduct a genome-wide analysis of GlyI protein (PF00903) from Ana ...
... Currently, most arsenic (As) studies in populations are concerned with water-borne arsenicosis. However, residents in Xingren County of Guizhou Province, Southwest of China, represent a unique case of arsenicosis which is related to indoor combustion of high As-containing coal. This study aimed to assess the alterations of As levels and its risk factors in coal-borne arsenicosis residents during t ...
... Arsenic is an important toxic chemical affecting millions of people around the world. Exposure to inorganic arsenic results in various health problems including skin lesions, hypertension, hematological disturbance, cardiovascular disease, spleen enlargement and cancer. Gallic acid (GA) is an important phenolic compound possessing various pharmacological properties including anti-inflammatory, ant ...
... Highly efficient decontamination of naturally occurring As(iii) from aqueous media remains a rigorous task for public health and ecosystem protection. As its increasingly acute toxicity and mobile characteristics than those of As(v), it is imperative to exploit a technique for the simultaneous removal and detoxication of As(iii). Herein, a novel strategy involving outer and inner structural engine ...
... Millions of people worldwide are at risk of arsenic poisoning from their drinking water. In Bangladesh the problem extends to rural drinking water wells, where non-biological solutions are not feasible. In serial enrichment cultures of water from various Bangladesh drinking water wells, we found transfer-persistent arsenite oxidation activity under four conditions (aerobic/anaerobic; heterotrophic ...
... The lack of efficient methods to treat As-rich biomass is a drawback for phytoremediation technology. In this study, we applied anaerobic digestion to reduce biomass and remove As from As-rich Pteris vittata biomass. P. vittata biomass including control (3.1 mg kg−1 As) and As-rich (2665 mg kg−1 As), together with positive and negative controls, was anaerobically digested at 35 °C for 35 d. Arseni ...
... In this study, the levels of arsenic (As), cadmium (Cd) and lead (Pb) have been determined in the flesh of two species of fish, sardine (Sardina pilchardus) and swordfish (Xiphias gladius) fished in the Algerian coast. Quantification of As, Cd and Pb was carried out using an ICP-MS method and the results were compared with the thresholds set by national and international regulatory bodies. In a fu ...
... Trace elements have been acknowledged as one of the subtlest environmental hazards in all compartments of the total environment. Enhanced by activities in the anthroposphere, they accumulate in the atmosphere, lithosphere, and hydrosphere. Eventually, trace elements can bioaccumulate or biomagnifiy in the biosphere, with harmful effects on animals occupying higher trophic levels, including humans. ...
... Whole blood, serum, and feather samples from 29 Humboldt Penguins (Spheniscus humboldti) at the Punta San Juan Marine Protected Area, Peru, were analyzed for 55 toxic and essential elements by using inductively coupled plasma mass spectrometry. Mercury (Hg) was analyzed by cold vapor atomic fluorescence. Maximum Hg concentrations in serum (0.0056 mg/g), whole blood (0.297 mg/kg), and feathers (1.8 ...
... Crop productivity and yield are adversely affected by abiotic and biotic stresses. Therefore, finding out the genes responsible for stress tolerance is a significant stride towards crop improvement. A gene co-expression network is a powerful tool to detect the most connected genes during heavy metal (HM) stress in plants. The most connected genes may be responsible for HM tolerance by altering the ...
... The risks for human health and the ecosystem due to potentially toxic elements (PTEs) were investigated in a farmland classified as potentially contaminated by Cr and Zn by analysing native vegetation and relative rhizo-soils. Rhizo-soils of different plant species were found to be enriched by Cr and Zn as well as by elements omitted from official environmental characterization, namely Cd, As and ...
... In Latin America, the high proportion of arsenic (As) in many groundwaters and phreatic aquifers is related to the volcanism of the Andean Range. Nevertheless, there is still very little published research on As and other elements occurrence, and/or transference to biota in Southern regions such as Argentinean Patagonia and the South Shetland Islands in Antarctica, where there are active volcanoes ...
Francisco M. Barajas-Olmos; Elizabeth Ortiz-Sánchez; Ivan Imaz-Rosshandler; Emilio J. Córdova-Alarcón; Adolfo Martínez-Tovar; Jairo Villanueva-Toledo; Mirna E. Morales-Marín; José L. Cruz-Colín; Claudia Rangel; Lorena Orozco; Federico Centeno
DNA methylation; arsenic; carcinogenesis; carcinogens; chronic exposure; cluster analysis; epigenetics; gene expression; genes; microarray technology; models; neoplasms; promoter regions
Abstract:
... Inorganic arsenic is a well-known carcinogen associated with several types of cancer, but the mechanisms involved in arsenic-induced carcinogenesis are not fully understood. Recent evidence points to epigenetic dysregulation as an important mechanism in this process; however, the effects of epigenetic alterations in gene expression have not been explored in depth. Using microarray data and applyin ...
absorption; arsenic; dietary exposure; human food chain; humans; hydrides; parboiling; rice; risk; spectroscopy; staple foods; Andes region; Ecuador
Abstract:
... Natural and anthropogenic sources contribute to arsenic contamination in water and human food chain in Andean countries. Human exposure to arsenic via rice consumption is of great concern in countries where this crop is the dominant staple food, and limited information is available on the arsenic contamination on rice in Ecuador. This work was to contribute to the lack of knowledge analysing total ...
... Trace element distribution in the human body varies across regions and countries due to their different living environment and lifestyle. Thus, it is of great significance to investigate the reference level of trace element in a specific population. Wuhan is the largest metropolitan area in central China with highly developed heavy industries. This study aimed at determining the reference urinary ...
... 659 water samples from springs and wells in the Sabatini and Vicano-Cimino Volcanic Districts (central Italy) were analyzed for arsenic (As), fluoride (F⁻) and radon (²²²Rn) concentrations. Waters mostly sourced from a shallow and cold aquifer hosted within volcanic rocks, which represents the main public drinking water supply. Cold waters from perched aquifers within sedimentary formations and th ...
... The current research focuses on anaerobic respiration of arsenic and other toxic metals by purple nonsulfur bacteria (PNSB). Among the optimization assays performed were carbon utilization, cross metal resistance, and metal respiration, along with a comparison of each assay in photoheterotrophic and chemoheterotrophic growth. The bacteria were identified by the classification of 16S ribosomal RNA ...
... Soils are often co-contaminated with As, Pb, and Cd. To what extent ingested metal(loid)s interact with each other in the gastrointestinal tract and influence their RBA (relative bioavailability) is largely unknown. Three soils predominantly contaminated with As (MS, mining/smelting impacted), Pb (WR, wire rope production impacted), and Cd (EP, enamel pottery production impacted) were administered ...
adverse effects; arsenic; batteries; bioavailability; cadmium; cement; chromium; coal; combustion; emissions; emissions factor; factories; fluorescent lamps; gasoline; human health; humans; inventories; iron; issues and policy; lead; mercury; particulates; risk; river deltas; steel; toxicity; uncertainty; China
Abstract:
... Atmospheric toxic metals (TMs) may cause adverse effects on the environment and human health due to their bioavailability and toxicity. High-resolution TMs emission inventory is important input data for assessing human exposure risks, especially synergistic toxicity of multiple toxic metals. By using the latest city- and enterprise-level environment statistical data, an emission inventory of five ...
... In this study we report silica rich anthropogenic spherules from the marine environment. We found spherical, dumbbell, teardrop and fused spherules in Zuari estuary (near the Dona paula jetty), south west coast of India. The spherules were composed of SiO2 (69.8%), Na2O (13.2%), CaO (8.8%), MgO (3.8%), and traces of Al2O3, and FeO. Their high Na and Ca contents rules out the possibility of being a ...
antimony; arsenic; basins; cadmium; chromium; copper; eutrophication; fabrics; freshwater; lead; nickel; risk; river valleys; sediments; statistical analysis; toxic substances; toxicity; water pollution; water treatment; wetlands; zinc; China; Yangtze River
Abstract:
... Increasing attention is being paid to Sb as a primary hazardous substance, and further systematic studies of Sb behavior in freshwater wetlands are required. The plain wetlands in Lake Taihu basin located in lower Yangtze River valley, are heavily populated and economically developed area in China. The plain wetlands receive polluted water from point sources (textile and printing plants). In this ...
... AIMS: Antimony (Sb) is locally found at potentially toxic concentrations in mineralized soils, usually together with arsenic (As). However, local adaptation of plant populations to Sb toxicity has never been shown thus far. Here we compared Sb tolerance and accumulation between a non-metallicolous (NM) population of Salvia spinosa, and a con-specific metallicolous (M) population from a strongly Sb ...
... A fraction with molecular weight of 0.2–1.0 kDa was prepared from abalone viscera hydrolysate by ultrafiltration and nanofiltration. The contents of protein, carbohydrate, and fat in abalone viscera were 45.75%, 18.19%, and 13.60%, respectively. The protein in abalone viscera hydrolysate faction (AVHF) reached up to 75.73%, while carbohydrate and fat fell to 1.80% and 0.20%, respectively. The leuc ...
arsenic; pollution control; rivers; standard deviation; water pollution; China
Abstract:
... Water samples were collected from the Pu River in 2017 to research the distribution and accumulation characteristics of dissolved arsenic. We mainly built three types of expectation and standard deviation calculations corresponding to discrete, weighted and continuous random variables. The continuous expectation and standard deviation calculations are defined based on the concentration function an ...
... To reduce sludge volume, Mg–Al layered double hydroxide (LDH) was used to remove pollutants from mine wastewater. Mg–Al LDH can remove both cations and anions from mine wastewater via co-precipitation and anion exchange mechanisms, respectively. We herein investigated the difference in removal efficiencies between Mg–Al LDH and Ca(OH)₂. Initial As and Fe concentrations of 8.4 and 308.6 mg/L led to ...
... Arsenic pollution in groundwater has been identified as a major hazard in developing countries. In this purview, Karanja or Pongamia pinnata seed cake, a biodiesel residue has been proposed to being utilized to curb the arsenic menace using an agro-industrial waste. The study investigates the biosorption of As (III) onto thermally activated de-oiled karanja seed cake (TAKB) with a surface area of ...
... Heavy metal(loid) extraction from soils in overlapped areas of farmland and coal resources (OAFCR) is crucial in understanding heavy metal bioavailability in soil and the subsequent risks to crops and consumers. However, limited attention has been paid to the extraction procedure of heavy metal(loid)s in OAFCR soils in the research. This study therefore explored different single and mixed extracti ...
aqua regia; arsenic; atomic absorption spectrometry; barium; cadmium; chromium; coasts; cobalt; copper; guidelines; issues and policy; lead; nickel; pollutants; pollution; risk; sediments; zinc; Malaysia
Abstract:
... Sediment can accumulate trace elements in the environment. This study profiled the magnitude of As, Ba, Cd, Co, Cu, Cr, Ni, Pb, Se, and Zn pollution in surface sediments of the west coast of Peninsular Malaysia. Trace elements were digested using aqua regia and were analyzed using the inductively coupled plasma-mass spectrometry. The extent of elemental pollution was evaluated using with the enric ...
United States Environmental Protection Agency; adsorbents; adsorption; arsenic; boron; experimental design; pH; pollutants; pollution control; response surface methodology; scanning electron microscopes; slags; toxicity; wastewater; wastewater irrigation
Abstract:
... The reuse of geothermal wastewater for irrigation is an attractive alternative for supplying water demand in agriculture, due to the high volumes generated in geothermal plants. This application is limited by the presence of toxic semimetals such as arsenic and boron, which generally require high-cost commercial adsorbents for removal. This work studies the removal mechanism and process optimizati ...
... In the present study, electrospun nanofiber membranes (ENMs) of polyacrylonitrile (PAN) were modified by dispersing α-Fe₂O₃ nanoparticles, synthesized using a thermal solvent process, in a PAN solution. The morphology and physiochemical properties of the prepared ENMs and the α-Fe₂O₃ were characterized using FESEM, EDX, BET, XRD, FTIR, porosity, and contact angle measurement. XPS was used to inves ...
agricultural land; arsenic; cadmium; case studies; chromium; copper; heavy metals; lead; mercury; models; nickel; pollution; soil types; traffic; zinc; China
Abstract:
... As we all know, geochemical data usually contain outliers and they are heterogeneous, which will severely affect the use of receptor models based on classical estimates. In this paper, an advanced modified RAPCS-RGWR (robust absolute principal component scores-robust geographically weighted regression) receptor model was introduced to analyze the pollution sources of eight heavy metals (Cd, Hg, As ...
... Recovery of heavy metals in acid mine drainage (AMD) such as Mn, Fe, Cu, Zn, As, Cd and Pb was evaluated using volume retarded osmosis and low-pressure membrane (VRO-LPM) process. In VRO-LPM process, the draw solution (DS) is regenerated by the naturally generated pressure, giving its economic value. Ethylenediaminetetraacetic acid tetrasodium salt (EDTA-4Na) and Poly (sodium-4-styrenesulfonate, P ...
... The application of biological sulfate reduction technologies have an excellent potential for removing arsenic from groundwater, acid mine drainage, and sediments, among other matrices. Under sulfate reducing conditions, arsenic can be removed from waters by precipitating as an orpiment-like phase (As2S3), a realgar-like phase (AsS) or an arsenopyrite-like phase (FeAsS). Alternatively, it can be re ...
... Various genesis of epithermal veins as well as host rock cause complication in the modeling process. Thus LINEST and controlling function were applied to improve the accuracy and the quality of the model. The LINEST is a model which is based on multiple linear regression and refers to a branch of applied statistics. This method concerns directly to the application of t-test (TINV and TDIST to anal ...
World Health Organization; adults; arsenic; basins; children; drinking water; geographic information systems; geostatistics; groundwater; guidelines; health effects assessments; ingestion; iron; kriging; manganese; minerals; nitrates; risk; risk characterization; rocks; spatial variation; water quality standards; weathering; Bangladesh
Abstract:
... This study aims to appraise the spatial variations and pathways of groundwater contaminations and associated health risks in the Surma basin, Bangladesh using geostatistics, Fuzzy GIS technique and health risk modelbased on ninety groundwater samples. The results show that the mean concentrations of As, Fe, Mn and NO₃ are below the Bangladesh water quality standard, whereas As, Fe and Mn concentra ...
... Arsenic (As) is a significant contaminant in the environment and its detection through macrophytes can provide a powerful tool. Myriophyllum alterniflorum constitutes a good candidate by virtue of its ability to accumulate contaminants, and moreover its biomarkers can respond to the presence of trace metals and metalloids. The objective of this study therefore is to evaluate the watermilfoil respo ...
... The present study aims to compare the contents of minerals (essential major—K, Ca, Mg, Na, P, S; essential trace—Fe, Mn, Zn, Cu, B, Mo, As, Se, Ni, V, Cr, Co; non-essential—Sn, Ga, Li, Be, Rb, Sr, Al, Pd, Cd, Hg, Pb, Ge) in strawberry (stem, leaf, and fruit) cultivated in two different cultivation systems, soil and hydroponic. The concentrations of 30 minerals in the acid-digested strawberry sampl ...
adults; arsanilic acid; arsenic; bladder; chicken meat; cities; dietary exposure; geographical variation; health effects assessments; lung neoplasms; poultry production; roxarsone; world markets; China
Abstract:
... Organoarsenicals have been used in poultry production for years, however, studies focused on roxarsone (ROX), with little attention to p-arsanilic acid (ASA). We assessed As concentration and speciation in chicken meat collected from 10 cities in China. The geometric mean for total As in 249 paired raw and cooked samples was 4.85 and 7.27 μg kg–1 fw, respectively. Among 81 paired raw and cooked sa ...
... Biologically toxic arsenate is physicochemically similar to biologically essential phosphate. Because arsenate and phosphate are indiscriminately incorporated by microbes, their ambient concentration ratios can be an important factor controlling microbial growth and metabolism. This study investigated the spatial distributions of arsenate and phosphate and the associated biogeochemical dynamics in ...
... Arsenic (As) pollution is a significant environmental problem worldwide. Although this metalloid affects plant growth and productivity, it is usually associated with oxidative stress which affects a diverse range of metabolic pathways. However, an additional hazard of As is its presence in edible parts of plants which constitutes a potential animal and human health risk. We exposed 20-d-old pea (P ...
... The aim of the study was to evaluate the As phytoextraction potential of four tree species: Acer pseudoplatanus L., Betula pendula Roth., Quercus robur L., and Ulmus laevis Pall. in light of their prospective use in the phytoremediation of arsenate [As(V)] contaminated soils. The content of nutritional elements: B, Ca, K, Mg, Na, Si, P, and S was also analyzed. The trees were grown for 1 month in ...
... The elevation of arsenic (As) content in soils is of considerable concern with respect to its uptake by plant and subsequent entry into wildlife and human food chains. The treatment of sorghum seedlings with As as NaH₂As₄O. 7H₂O at various concentrations (A₁ = 0, A₂ = 20, A₃ = 40 and A₄ = 60 mg As kg⁻¹ soil) and salinity at four different levels (S₁ = 0, S₂ = 3, S₃ = 6 and S₃ = 9 dS m⁻¹) reduced f ...
... High arsenic (As) concentrations are found in marine clams, usually as less-toxic arsenobetaine (AsB). However, when clams were exposed to elevated As concentrations in the environments, As species distribution within them may be altered. This study aimed to determine As bioaccumulation and biotransformation in marine clams (Asaphis violascens) along As concentration gradients for 10 days. Nine tr ...
... Arsenic (As) concentrations in fine (2) and coarse (3) rice varieties belonging to Hafizabad, Gujranwala and Sheikhupura districts was assessed initially by means of field survey, followed by pot experiments. Bulk soil samples collected from same rice districts (Hafizabad and Gujtanwala) were spiked with As (0, 10, 20 mg kg⁻¹) and each was amended with iron sulphate (0, 25, 50 g kg⁻¹) to investiga ...
United States Environmental Protection Agency; arsenic; carcinogenicity; environmental science; information systems; maximum contaminant level; public health
Abstract:
... Arsenic poses a threat to public health due to widespread environmental prevalence and known carcinogenic effects. In 2001, the US EPA published the Final Arsenic Rule (FAR) for public drinking water, reducing the maximum contaminant level (MCL) from 50 to 10 μg/L. We investigated impacts of the FAR on drinking water violations temporally and geographically using the Safe Drinking Water Informatio ...
aquifers; arsenic; foods; herbicides; humans; mining; physicochemical properties; sediments; surface water; toxicity; water pollution; wood preservatives; Brazil
Abstract:
... Arsenic (As) is widely studied in several countries due to its toxicity to biota in the environment. Arsenic sources may be natural or anthropogenic, and the mobility of the element is ruled by physicochemical conditions that also define the dominant As species in the environment. Arsenic levels are evaluated in various abiotic and biotic environmental samples. The highest As levels are observed i ...
... Flavins are ubiquitous redox-active compounds capable of producing reactive oxygen (O₂•–, •OH, and H₂O₂) and flavin radical species in natural environments, yet their roles in the redox transformations of environmental contaminants, such as arsenic (As), remain to be investigated. Here, we show that reduced flavins can be a source of effective oxidants for As(III) under both oxic and anoxic condit ...
... Using the computation method of thermodynamic equilibrium, effects of sewage sludge (SS) co-combustion conditions and interactions with Fe₂O₃, SiO₂, CaO and Al₂O₃ on migration and transformation of arsenic (As) were simulated in oxy-fuel (CO₂/O₂) and air (N₂/O₂) atmospheres. Arsenic mainly existed as As(s), As₄(g), As₂O₅(s), As₄O₆(g) and AsO(g) and volatilized more easily in reducing than oxidizin ...
... A temperature-controlled ash deposition probe was applied to collect temporally resolved deposit samples in a 100 kW rated down-fired pilot-scale combustor under two atmospheres: (1) air condition and (2) 70% O₂ as inlet gas (named as OXY70). The mineral compositions, particle size distributions, and partitioning of arsenic in the inside and outside deposits were measured. The properties of the as ...
... Arsenic in groundwater in excess of the drinking water limit is usually from natural sources. The release of As, however, can be amplified by anthropogenic inputs of carbon, including those associated with the remediation of chlorinated solvents such as trichloroethylene (TCE). Large laboratory columns (15.2 cm diameter, 183 cm long) packed with aquifer solids from a TCE contaminated site near Hil ...
... The aim of the present experimental study was to perform a technical-economic evaluation of a combined treatment system, consisting of coagulation-flocculation or rapid sand filtration as pre-treatment followed by column adsorption, for reducing the arsenic concentration from approximately 1 mg/L to below the limit set for groundwater remediation and drinking water, i.e., 0.01 mg/L, according to t ...
... This research has been carried out for assessing phytoremediation of contaminated soils with 4 concentrations of arsenic by three plants, namely Vetiver grass (Vetiveria zizanioides), Chara algae (Chara vulgaris) and Water hyacinth (Hyacintus orientalis). The experimental results showed that at least two sampling times were significantly different. In addition, at least two plants were also signif ...