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Citrus; arsenic; cytotoxicity; enzyme inhibitors; epithelial cells; genes; human diseases; lungs; mitogen-activated protein kinase; oxidative stress; pathogenesis; phosphatidylinositol 3-kinase; polymethoxyflavones; protein kinase C; sodium; toxic substances; ubiquitination
Abstract:
... Exogenous toxicants (e.g. arsenic, cigarette smoke), trigger oxidative stress, and initiate the pathogenesis of many human diseases. Induction of nuclear factor E2-related factor 2 (Nrf2) counteract exogenous toxicant-induced oxidative insults. Using a high-throughput screen, we firstly identified a citrus polymethoxyflavone, (2S)-5,6,7,3',4'-pentamethoxyflavanone (PMF), to be an Nrf2 activator, a ...
... Recently indoor air quality (IAQ) has become a key issue, especially in schools, where children spend most of the day. Only in a few cases IAQ was investigated using lichens as biomonitors. During autumn 2017, lichens (Evernia prunastri) were exposed for two months indoors and outdoors in public (schools) and private (dwellings) environments, in both rural and urban areas of Slovakia. The bioaccum ...
air; aquatic organisms; arsenic; carbon dioxide; compliance; electrical conductivity; environmental assessment; environmental audits; environmental performance; gold; greenhouses; habitats; issues and policy; methylmercury compounds; nitrogen; pH; public health; recreation; rivers; sulfur; sustainable development; time series analysis; toxicity; water quality; Ghana
Abstract:
... The AKOBEN Programme, an environmental performance rating and disclosure initiative that show the environmental performance of gold mining firms with reference to their daily activities post environmental impact assessment and issuance of an environmental permit was introduced in Ghana to serve as a monitoring and verification tool towards environmental compliance and responsible mining. As to whe ...
... This study aimed to investigate nine heavy metal concentrations (As, Cd, Cr, Pb, Cu, Fe, Zn, Mn and Ni) in water, sediment and snakehead fish (Channa striata) and to identify abnormal chromosomes in C. striata from a reservoir near an industrial factory and a reference area. Heavy metal concentrations were measured by inductively coupled plasma optical emission spectrometry (ICP-OES). The metal co ...
... Arsenic (As) and cadmium (Cd) are known to be toxic to humans, and elevated concentrations have been documented in food crops worldwide. However, little is known regarding their uptake, translocation, and distribution in wheat plants during plant development. A series of experiments were conducted to investigate the spatial distribution and dynamics of As and Cd in two wheat cultivars (cv. JN12 an ...
arsenic; cadmium; chromium; cobalt; copper; heavy metals; humic substances; hydroxides; iron; lead; manganese; molybdenum; nickel; rivers; sediments; sorption; vanadium; zinc; Sea of Japan
Abstract:
... The average concentrations of elements Fe, Mn, Zn, Pb, Cu, Cr, V, Co, Cd, Ni, As, and Mo in the subcolloidal fraction of bottom sediments were determined in the northern and central parts of the Amur Bay. The concentrations of metals Pb, Co, Ni, Zn, Cr, V, and As in bottom sediments subject to direct influence of the Razdol’naya River were shown to increase by 5–17% because of their sorption on Fe ...
... A non-invasive study of trace element accumulation in tail feathers of the Kentish plover (Charadrius alexandrinus) was performed along the coastline of the northern littoral strip of the Venice Lagoon, with the aim to verify whether contamination may be a factor affecting conservation status of Kentish plover populations.Body burdens in feathers of 11 trace elements including toxic metals/metallo ...
... Plants that have grown for many years in the special environmental conditions prevailing in mining areas are naturally screened and show strong capacity to adapt to their environment. The present study investigated the enrichment characteristics of U and other heavy metals (As, Cu, Pb, Mn, Mo, Zn, Cd, Co, and Ni) in the soil–plant system in Xiazhuang uranium mine. Four dominant plants (Castanopsis ...
agricultural soils; arsenic; basins; cadmium; case studies; coal; combustion; copper; ecosystems; environmental health; fertilizers; food security; heavy metals; human health; irrigation water; lead; mercury; paddy soils; pollution; rice; risk; risk assessment; soil sampling; transportation; zinc; China
Abstract:
... Contamination of agricultural soil by heavy metals has become a global issue concerning food security and human health risk. In this study, a soil investigation was conducted to evaluate metals accumulation, potential ecological and health risks as well as to identify sources of metals in paddy soils in Hanzhong City, which is located in a sedimentary basin. Ninety-two (92) surface soil samples (b ...
... The Fenhe River basin is the main agricultural and industrial developed area in Shanxi province, China. In recent years, agricultural non-point source pollution in the Fenhe River basin intensified, threatening soil quality and safety in the area. Accumulation of eight heavy metals (HMs) including chromium (Cr), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), cadmium (Cd), lead (Pb) and mercury ...
advection; anthropogenic activities; arsenic; belowground biomass; bioaccumulation; coasts; dust; ecosystems; ecotoxicology; estuaries; metals; models; plant litter; pollution; sediments; toxicity; Bay of Bengal; India
Abstract:
... Arsenic (As), a toxic element is a concern for the habitants in and around the coastal areas of West Bengal (India) where world's largest Sundarbans mangrove is situated. Little is known about the potential of these mangroves in storing As within their biomass and transporting to the Bay of Bengal. A comprehensive yearly data of above ground and below ground biomass (AGB, BGB), and exchange fluxes ...
World Health Organization; X-ray absorption spectroscopy; arsenic; electrocoagulation; electrolysis; magnetite; pH; research; sorption; water; water treatment; water utilities; Netherlands
Abstract:
... Consumption of drinking water containing arsenic at concentrations even below the World Health Organization provisional limit of 10 μg/L can still lead to unacceptable health risks. Consequently, the drinking water sector in the Netherlands has recently agreed to target 1 μg/L of arsenic in treated water. Unfortunately, in many poor, arsenic-affected countries, the costs and complexity of current ...
Xiaohui Zhang; Song Tang; Mao Wang; Weimin Sun; Yuwei Xie; Hui Peng; Aimin Zhong; Hongling Liu; Xiaowei Zhang; Hongxia Yu; John P. Giesy; Markus Hecker
... Acid mine drainage (AMD) is one of the most hazardous byproducts of some types of mining. However, research on how AMD affects the bacterial community structure of downstream riverine ecosystems and the distribution of metal resistance genes (MRGs) along pollution gradient is limited. Comprehensive geochemical and high-throughput next-generation sequencing analyses can be integrated to characteriz ...
... The surrounding of the poorly maintained tailing ponds is endangered by the toxic substances and represents a serious risk for the health of the local population. The aim of the study was to determine the soil pollution by the hazardous elements (As, Cr, Cd, Cu, Fe, Mn, Ni, Pb, Zn) around the tailing pond using contamination factor (Cf), degree of contamination (Cd) and pollution load index (PLI). ...
... We describe and illustrate lesions in an outbreak of lead arsenate poisoning in beef cattle that ingested pesticide residues stored in an abandoned building of a former orange orchard. Of 70 exposed cattle, 14 had diarrhea, paresis, ataxia, recumbency, and/or seizures. Ten of the affected animals died after a clinical course of 12–18 h. Pathologic findings in 3 steers included extensive necrohemor ...
... MnO₂ is one of the most widespread and cheapest materials in nature that can both adsorb arsenic and oxidize arsenite [As(III)] to arsenate [As(V)]. In this study, column β-MnO₂ [CM] with the main facet of {110} and pincer β-MnO₂ [PM] with the facets of {110} and {101} are synthesized and used to remove arsenic in water under different conditions. For the adsorption process, the experimental data ...
... In the present paper, used cigarette filter ash was prepared and used as an active adsorbent to remove As(III) ions from aqueous solutions. The prepared adsorbent structure was identified by scanning electron microscopy analysis, Brunauer–Emmett–Teller method and energy-dispersive X-ray spectroscopy analysis. The influence of contact time, pH, adsorbent dose and initial concentration of As(III) on ...
... Microplastics exhibit active environmental behavior and unique surface characteristics, and act as carriers for the migration of trivalent arsenic (As(III)) in the environment. Herein, the mechanism by which polytetrafluoroethylene (PTFE) microplastic particles adsorb As(III) is systematically determined. The larger the size of PTFE particles, the smaller the specific surface area, the higher the ...
adsorption; arsenic; arsenites; chemical bonding; chemical treatment; endothermy; ferrous chloride; fly ash; groundwater; ions; pH; temperature; toxicity; water treatment; zeolites
Abstract:
... The high toxicity of arsenite and the difficulty to remove it is one of the main challenges for water treatment. In the present work the surface of a low cost zeolite was modified by chemical treatment with a ferrous chloride to enhance its arsenite adsorption capacity. The effect of pH, ions coexistence, concentration, temperature and dosage was studied on the adsorption process. Additionally, th ...
... Arsenic (As) is considered as one of the most hazardous elements found in the groundwater. It is present in water in both arsenate (As(V)) and arsenite (As(III)) forms. On exposure for a considerable length of time to water having As concentration above the maximum permissible limit of 10 μg/L, there is a serious threat of developing various health problems including cancer. There is frequent repo ...
X-ray absorption spectroscopy; adsorption; arsenic; binding capacity; ferrihydrite; goethite; iron oxides; models; nanosheets; pH; sorbents; sorption isotherms; surface area
Abstract:
... Adsorption onto two-dimensional nanosheet materials offers new possibilities for fast and efficient removal of contaminants from waters. Here, the adsorption of As(V) to a new type of iron oxides – single sheet iron oxide (SSI) – has been studied as a function of time, loading and pH. Adsorption of As(V) onto SSI was very fast compared to other iron oxides, with 80% of total As(V) adsorbed within ...
... Developing affordable and efficient materials for the removal of arsenic from drinking water is crucial for human and environmental safety. In the present study, the adsorptive performance of magnetic GO/ZnFe₂O₄ nanocomposite and ZnFe₂O₄ nanospinel for arsenic removal from aqueous water was analyzed. The adsorbents were characterized using Fourier-transform infrared spectroscopy, X-ray powder diff ...
... The study of aerosol dispersion characteristics in wastewater treatment plants (WWTPs) has attracted extensive attention. Oxidation ditch (OD) is a commonly implemented process during biological wastewater treatment. This study assessed the component characteristics, source apportionment, and exposure risks of aerosols generated from a WWTP using the OD process (AWO). The results indicated that th ...
adsorbents; adsorption; arsenic; carbon; carbon dioxide; ferric chloride; fly ash; iodine value; iron; kinetics; models; raw materials; rural water supply; sorption isotherms; steam; temperature
Abstract:
... The fly ash from the Corner Brook Pulp and Paper (CBPP) mill was used in this study as the raw material for the preparation of a low-cost adsorbent for arsenic removal from the well water of Bell Island. The CBPP fly ash was physically activated in two different ways: (a) activation with pure CO2 (CAC) with the iodine number and methylene value of 704.53 mg/g and 292.32 mg/g, respectively; and (b) ...
... Clean drinking water is a basic need of human beings around the world. In the past few decades, many research groups have been trying different methods to exploit quantum dots (QDs) to decontaminate water but, due to either cost or cumbersome steps, they have been unsuccessful. We have tried exploiting graphene quantum dots (GQDs) for heavy metal ion detection, particularly for arsenic ions in con ...
... Arsenic (As) contamination in soils has posed a severe threat to safe crop production. The previous studies showed the antagonism between phosphorus (P) and As in plant growth and As uptake, while the mechanisms of alleviating As toxicity by P is not completely clear. Due to the limiting P condition, it is imperative to understand how low P addition can be used to suppress arsenate As (V) uptake a ...
... Currently, most arsenic (As) studies in populations are concerned with water-borne arsenicosis. However, residents in Xingren County of Guizhou Province, Southwest of China, represent a unique case of arsenicosis which is related to indoor combustion of high As-containing coal. This study aimed to assess the alterations of As levels and its risk factors in coal-borne arsenicosis residents during t ...
... Arsenic is an important toxic chemical affecting millions of people around the world. Exposure to inorganic arsenic results in various health problems including skin lesions, hypertension, hematological disturbance, cardiovascular disease, spleen enlargement and cancer. Gallic acid (GA) is an important phenolic compound possessing various pharmacological properties including anti-inflammatory, ant ...
... Highly efficient decontamination of naturally occurring As(iii) from aqueous media remains a rigorous task for public health and ecosystem protection. As its increasingly acute toxicity and mobile characteristics than those of As(v), it is imperative to exploit a technique for the simultaneous removal and detoxication of As(iii). Herein, a novel strategy involving outer and inner structural engine ...
... Trace elements have been acknowledged as one of the subtlest environmental hazards in all compartments of the total environment. Enhanced by activities in the anthroposphere, they accumulate in the atmosphere, lithosphere, and hydrosphere. Eventually, trace elements can bioaccumulate or biomagnifiy in the biosphere, with harmful effects on animals occupying higher trophic levels, including humans. ...
... Whole blood, serum, and feather samples from 29 Humboldt Penguins (Spheniscus humboldti) at the Punta San Juan Marine Protected Area, Peru, were analyzed for 55 toxic and essential elements by using inductively coupled plasma mass spectrometry. Mercury (Hg) was analyzed by cold vapor atomic fluorescence. Maximum Hg concentrations in serum (0.0056 mg/g), whole blood (0.297 mg/kg), and feathers (1.8 ...
... Crop productivity and yield are adversely affected by abiotic and biotic stresses. Therefore, finding out the genes responsible for stress tolerance is a significant stride towards crop improvement. A gene co-expression network is a powerful tool to detect the most connected genes during heavy metal (HM) stress in plants. The most connected genes may be responsible for HM tolerance by altering the ...
absorption; arsenic; dietary exposure; human food chain; humans; hydrides; parboiling; rice; risk; spectroscopy; staple foods; Andes region; Ecuador
Abstract:
... Natural and anthropogenic sources contribute to arsenic contamination in water and human food chain in Andean countries. Human exposure to arsenic via rice consumption is of great concern in countries where this crop is the dominant staple food, and limited information is available on the arsenic contamination on rice in Ecuador. This work was to contribute to the lack of knowledge analysing total ...
... 659 water samples from springs and wells in the Sabatini and Vicano-Cimino Volcanic Districts (central Italy) were analyzed for arsenic (As), fluoride (F⁻) and radon (²²²Rn) concentrations. Waters mostly sourced from a shallow and cold aquifer hosted within volcanic rocks, which represents the main public drinking water supply. Cold waters from perched aquifers within sedimentary formations and th ...
... The current research focuses on anaerobic respiration of arsenic and other toxic metals by purple nonsulfur bacteria (PNSB). Among the optimization assays performed were carbon utilization, cross metal resistance, and metal respiration, along with a comparison of each assay in photoheterotrophic and chemoheterotrophic growth. The bacteria were identified by the classification of 16S ribosomal RNA ...
... Soils are often co-contaminated with As, Pb, and Cd. To what extent ingested metal(loid)s interact with each other in the gastrointestinal tract and influence their RBA (relative bioavailability) is largely unknown. Three soils predominantly contaminated with As (MS, mining/smelting impacted), Pb (WR, wire rope production impacted), and Cd (EP, enamel pottery production impacted) were administered ...
adverse effects; arsenic; batteries; bioavailability; cadmium; cement; chromium; coal; combustion; emissions; emissions factor; factories; fluorescent lamps; gasoline; human health; humans; inventories; iron; issues and policy; lead; mercury; particulates; risk; river deltas; steel; toxicity; uncertainty; China
Abstract:
... Atmospheric toxic metals (TMs) may cause adverse effects on the environment and human health due to their bioavailability and toxicity. High-resolution TMs emission inventory is important input data for assessing human exposure risks, especially synergistic toxicity of multiple toxic metals. By using the latest city- and enterprise-level environment statistical data, an emission inventory of five ...
... In this study we report silica rich anthropogenic spherules from the marine environment. We found spherical, dumbbell, teardrop and fused spherules in Zuari estuary (near the Dona paula jetty), south west coast of India. The spherules were composed of SiO2 (69.8%), Na2O (13.2%), CaO (8.8%), MgO (3.8%), and traces of Al2O3, and FeO. Their high Na and Ca contents rules out the possibility of being a ...
antimony; arsenic; basins; cadmium; chromium; copper; eutrophication; fabrics; freshwater; lead; nickel; risk; river valleys; sediments; statistical analysis; toxic substances; toxicity; water pollution; water treatment; wetlands; zinc; China; Yangtze River
Abstract:
... Increasing attention is being paid to Sb as a primary hazardous substance, and further systematic studies of Sb behavior in freshwater wetlands are required. The plain wetlands in Lake Taihu basin located in lower Yangtze River valley, are heavily populated and economically developed area in China. The plain wetlands receive polluted water from point sources (textile and printing plants). In this ...
... AIMS: Antimony (Sb) is locally found at potentially toxic concentrations in mineralized soils, usually together with arsenic (As). However, local adaptation of plant populations to Sb toxicity has never been shown thus far. Here we compared Sb tolerance and accumulation between a non-metallicolous (NM) population of Salvia spinosa, and a con-specific metallicolous (M) population from a strongly Sb ...
... A fraction with molecular weight of 0.2–1.0 kDa was prepared from abalone viscera hydrolysate by ultrafiltration and nanofiltration. The contents of protein, carbohydrate, and fat in abalone viscera were 45.75%, 18.19%, and 13.60%, respectively. The protein in abalone viscera hydrolysate faction (AVHF) reached up to 75.73%, while carbohydrate and fat fell to 1.80% and 0.20%, respectively. The leuc ...
arsenic; pollution control; rivers; standard deviation; water pollution; China
Abstract:
... Water samples were collected from the Pu River in 2017 to research the distribution and accumulation characteristics of dissolved arsenic. We mainly built three types of expectation and standard deviation calculations corresponding to discrete, weighted and continuous random variables. The continuous expectation and standard deviation calculations are defined based on the concentration function an ...
... Arsenic pollution in groundwater has been identified as a major hazard in developing countries. In this purview, Karanja or Pongamia pinnata seed cake, a biodiesel residue has been proposed to being utilized to curb the arsenic menace using an agro-industrial waste. The study investigates the biosorption of As (III) onto thermally activated de-oiled karanja seed cake (TAKB) with a surface area of ...
... Heavy metal(loid) extraction from soils in overlapped areas of farmland and coal resources (OAFCR) is crucial in understanding heavy metal bioavailability in soil and the subsequent risks to crops and consumers. However, limited attention has been paid to the extraction procedure of heavy metal(loid)s in OAFCR soils in the research. This study therefore explored different single and mixed extracti ...
United States Environmental Protection Agency; adsorbents; adsorption; arsenic; boron; experimental design; pH; pollutants; pollution control; response surface methodology; scanning electron microscopes; slags; toxicity; wastewater; wastewater irrigation
Abstract:
... The reuse of geothermal wastewater for irrigation is an attractive alternative for supplying water demand in agriculture, due to the high volumes generated in geothermal plants. This application is limited by the presence of toxic semimetals such as arsenic and boron, which generally require high-cost commercial adsorbents for removal. This work studies the removal mechanism and process optimizati ...
agricultural land; arsenic; cadmium; case studies; chromium; copper; heavy metals; lead; mercury; models; nickel; pollution; soil types; traffic; zinc; China
Abstract:
... As we all know, geochemical data usually contain outliers and they are heterogeneous, which will severely affect the use of receptor models based on classical estimates. In this paper, an advanced modified RAPCS-RGWR (robust absolute principal component scores-robust geographically weighted regression) receptor model was introduced to analyze the pollution sources of eight heavy metals (Cd, Hg, As ...
... Recovery of heavy metals in acid mine drainage (AMD) such as Mn, Fe, Cu, Zn, As, Cd and Pb was evaluated using volume retarded osmosis and low-pressure membrane (VRO-LPM) process. In VRO-LPM process, the draw solution (DS) is regenerated by the naturally generated pressure, giving its economic value. Ethylenediaminetetraacetic acid tetrasodium salt (EDTA-4Na) and Poly (sodium-4-styrenesulfonate, P ...
... Various genesis of epithermal veins as well as host rock cause complication in the modeling process. Thus LINEST and controlling function were applied to improve the accuracy and the quality of the model. The LINEST is a model which is based on multiple linear regression and refers to a branch of applied statistics. This method concerns directly to the application of t-test (TINV and TDIST to anal ...
World Health Organization; adults; arsenic; basins; children; drinking water; geographic information systems; geostatistics; groundwater; guidelines; health effects assessments; ingestion; iron; kriging; manganese; minerals; nitrates; risk; risk characterization; rocks; spatial variation; water quality standards; weathering; Bangladesh
Abstract:
... This study aims to appraise the spatial variations and pathways of groundwater contaminations and associated health risks in the Surma basin, Bangladesh using geostatistics, Fuzzy GIS technique and health risk modelbased on ninety groundwater samples. The results show that the mean concentrations of As, Fe, Mn and NO₃ are below the Bangladesh water quality standard, whereas As, Fe and Mn concentra ...
... Arsenic (As) is a significant contaminant in the environment and its detection through macrophytes can provide a powerful tool. Myriophyllum alterniflorum constitutes a good candidate by virtue of its ability to accumulate contaminants, and moreover its biomarkers can respond to the presence of trace metals and metalloids. The objective of this study therefore is to evaluate the watermilfoil respo ...
... The present study aims to compare the contents of minerals (essential major—K, Ca, Mg, Na, P, S; essential trace—Fe, Mn, Zn, Cu, B, Mo, As, Se, Ni, V, Cr, Co; non-essential—Sn, Ga, Li, Be, Rb, Sr, Al, Pd, Cd, Hg, Pb, Ge) in strawberry (stem, leaf, and fruit) cultivated in two different cultivation systems, soil and hydroponic. The concentrations of 30 minerals in the acid-digested strawberry sampl ...
adults; arsanilic acid; arsenic; bladder; chicken meat; cities; dietary exposure; geographical variation; health effects assessments; lung neoplasms; poultry production; roxarsone; world markets; China
Abstract:
... Organoarsenicals have been used in poultry production for years, however, studies focused on roxarsone (ROX), with little attention to p-arsanilic acid (ASA). We assessed As concentration and speciation in chicken meat collected from 10 cities in China. The geometric mean for total As in 249 paired raw and cooked samples was 4.85 and 7.27 μg kg–1 fw, respectively. Among 81 paired raw and cooked sa ...
... Biologically toxic arsenate is physicochemically similar to biologically essential phosphate. Because arsenate and phosphate are indiscriminately incorporated by microbes, their ambient concentration ratios can be an important factor controlling microbial growth and metabolism. This study investigated the spatial distributions of arsenate and phosphate and the associated biogeochemical dynamics in ...
... The aim of the study was to evaluate the As phytoextraction potential of four tree species: Acer pseudoplatanus L., Betula pendula Roth., Quercus robur L., and Ulmus laevis Pall. in light of their prospective use in the phytoremediation of arsenate [As(V)] contaminated soils. The content of nutritional elements: B, Ca, K, Mg, Na, Si, P, and S was also analyzed. The trees were grown for 1 month in ...
... The elevation of arsenic (As) content in soils is of considerable concern with respect to its uptake by plant and subsequent entry into wildlife and human food chains. The treatment of sorghum seedlings with As as NaH₂As₄O. 7H₂O at various concentrations (A₁ = 0, A₂ = 20, A₃ = 40 and A₄ = 60 mg As kg⁻¹ soil) and salinity at four different levels (S₁ = 0, S₂ = 3, S₃ = 6 and S₃ = 9 dS m⁻¹) reduced f ...
... High arsenic (As) concentrations are found in marine clams, usually as less-toxic arsenobetaine (AsB). However, when clams were exposed to elevated As concentrations in the environments, As species distribution within them may be altered. This study aimed to determine As bioaccumulation and biotransformation in marine clams (Asaphis violascens) along As concentration gradients for 10 days. Nine tr ...
... Arsenic (As) concentrations in fine (2) and coarse (3) rice varieties belonging to Hafizabad, Gujranwala and Sheikhupura districts was assessed initially by means of field survey, followed by pot experiments. Bulk soil samples collected from same rice districts (Hafizabad and Gujtanwala) were spiked with As (0, 10, 20 mg kg⁻¹) and each was amended with iron sulphate (0, 25, 50 g kg⁻¹) to investiga ...
United States Environmental Protection Agency; arsenic; carcinogenicity; environmental science; information systems; maximum contaminant level; public health
Abstract:
... Arsenic poses a threat to public health due to widespread environmental prevalence and known carcinogenic effects. In 2001, the US EPA published the Final Arsenic Rule (FAR) for public drinking water, reducing the maximum contaminant level (MCL) from 50 to 10 μg/L. We investigated impacts of the FAR on drinking water violations temporally and geographically using the Safe Drinking Water Informatio ...
... Flavins are ubiquitous redox-active compounds capable of producing reactive oxygen (O₂•–, •OH, and H₂O₂) and flavin radical species in natural environments, yet their roles in the redox transformations of environmental contaminants, such as arsenic (As), remain to be investigated. Here, we show that reduced flavins can be a source of effective oxidants for As(III) under both oxic and anoxic condit ...
... Using the computation method of thermodynamic equilibrium, effects of sewage sludge (SS) co-combustion conditions and interactions with Fe₂O₃, SiO₂, CaO and Al₂O₃ on migration and transformation of arsenic (As) were simulated in oxy-fuel (CO₂/O₂) and air (N₂/O₂) atmospheres. Arsenic mainly existed as As(s), As₄(g), As₂O₅(s), As₄O₆(g) and AsO(g) and volatilized more easily in reducing than oxidizin ...
... A temperature-controlled ash deposition probe was applied to collect temporally resolved deposit samples in a 100 kW rated down-fired pilot-scale combustor under two atmospheres: (1) air condition and (2) 70% O₂ as inlet gas (named as OXY70). The mineral compositions, particle size distributions, and partitioning of arsenic in the inside and outside deposits were measured. The properties of the as ...
... The aim of the present experimental study was to perform a technical-economic evaluation of a combined treatment system, consisting of coagulation-flocculation or rapid sand filtration as pre-treatment followed by column adsorption, for reducing the arsenic concentration from approximately 1 mg/L to below the limit set for groundwater remediation and drinking water, i.e., 0.01 mg/L, according to t ...
... This research has been carried out for assessing phytoremediation of contaminated soils with 4 concentrations of arsenic by three plants, namely Vetiver grass (Vetiveria zizanioides), Chara algae (Chara vulgaris) and Water hyacinth (Hyacintus orientalis). The experimental results showed that at least two sampling times were significantly different. In addition, at least two plants were also signif ...
... Surface-enhanced Raman spectroscopy (SERS), as a nondestructive and fast detection technique, is a promising alternative approach for arsenic detection, particularly for in situ applications. SERS-based speciation analysis according to the fingerprint SERS signals of different arsenicals has the potential to provide a superior technique in species preservation over the conventional chromatographic ...
... The present investigation was premeditated to explore the toxic effects of arsenic (As) on an essential oil-bearing plant, the menthol mint (Mentha arvensis L.). Arsenic was applied in the form of sodium arsenate (Na₂HAsO₄.7H₂O) to the soil. Different concentrations of As (20, 40, 60, 80, and 100 mg kg⁻¹of soil) were applied and one set of plants was kept as control. The response of plants towards ...
... Three Canna cultivars namely Canna red dazzler (CR), Canna flaccida (CF) and Canna cala lillies (CL) were selected to examine the uptake of arsenic and antioxidative response at four different arsenic concentrations (10, 20, 30 and 50 mg kg¯1). The study consisted of three harvestings at an interval of 45 days each, and at each harvest arsenic uptake and antioxidant activity were examined. The ars ...
... The heavy metals transfer from the soil, where they accumulate, to the edible parts of the plants, and then, their entrance in the food chain can represent a source of concern for human health. Among heavy metals, arsenic is one of the most widespread in the soil of Lazio (central region of Italy), where the phytoavailable geogenic arsenic enters the food chain, with a dangerous exposition of the ...
... A new starch stabilized ferromanganese binary oxide (starch-FMBO) with an Fe/Mn ratio of 1.00–2.00 and a synthetic pH of 2 was prepared using an organic polymer (starch) as the stabilizing dispersant. The maximum arsenic adsorption capacity of starch-FMBO was 161.29 mg/g. Adsorption optimization was also conducted, which revealed that starch-FMBO had a high adsorption capacity over a wide pH range ...
... Granular activated carbon (GAC) was modified with Fe–Mn binary oxide to produce a novel effective hybrid adsorbent (GAC–FeMn) for simultaneous removal of As(III) and As(V) from water. After characterization (including BET, SEM/EDS and XRD analyses) of the raw and modified GAC, FTIR analysis before and after As removal showed that ligand exchange was the major mechanism for As removal on GAC–FeMn. ...
... Combinations of metal(loid) contamination and antibiotics are considered to increase the abundance of resistance genes in the environment, whereas the combined effect of metal(loid)s and antibiotics on microbial communities and antibiotic resistance genes (ARGs) in the gut of soil fauna remains unknown. We investigated herein the alteration of ARGs and the gut microbial communities after the earth ...
arsenic; cadmium; cultivars; highlands; infants; laws and regulations; production technology; rice; Brazil
Abstract:
... Brazil is a major producer of rice, but there is not enough information about As and Cd in rice grown under different conditions in this country. Here, As and Cd were determined by ICP-MS and species of As by HPLC-ICP-MS in Brazilian husked rice, covering diverse cultivars and regions, as well as upland and flooded production systems. Significant differences were observed for contents of both elem ...
United States Environmental Protection Agency; World Health Organization; arsenic; autumn; cadmium; carcinogenicity; chromium; drinking water; exposure pathways; factor analysis; guidelines; human health; ingestion; lead; manganese; principal component analysis; receptors; risk; risk assessment; rivers; seasonal variation; summer; Turkey (country)
Abstract:
... The Keban Dam Reservoir in Turkey is an internationally important reservoir, because it is located on the Euphrates River, which is an important transboundary river. Water samples were seasonally collected from 11 sampling sites on the reservoir between autumn 2014 and summer 2015. Spatial and seasonal variations, possible sources and health risks of dissolved trace metals (TMs) were investigated. ...
aquifers; arsenic; bedrock; chronic exposure; drilling; drinking water; geochemistry; gravel; pH; public health; sand; water quality; wells; United States
Abstract:
... Chronic exposure to geogenic arsenic via drinking water is a worldwide health concern. However, effects of well installation and operation on arsenic concentrations and mobilization are not well understood. This knowledge gap impacts both reliable detection of arsenic in drinking water and effective public health recommendations to reduce exposure to arsenic. This study examines changes in arsenic ...
... Arsenic exposure route for humans is through the drinking of contaminated water and intake of arsenic-contaminated foods, particularly in arsenic-exposed areas of Bengal delta. Transport of the arsenic-contaminated crops and vegetables grown using arsenic-contaminated groundwater and soil in arsenic-exposed areas to the uncontaminated sites and consequent dietary intakes leads to great threats for ...
... Iron (Fe) plaque on rice roots contains a unique microbiota that connects the root and rhizosphere environments. However, the factors controlling the microbial community structure and function in Fe plaque are unknown. We performed Illumina sequencing of 16S rRNA gene amplicons and of total community DNA to compare the microbial community structure and metabolic potential of Fe plaques derived fro ...
... Several surveys have been conducted in Nicaragua between 1996 and 2015 confirming the presence of high levels of arsenic (>10 μg/L). In this paper, these peer-reviewed (n = 2) and non-peer reviewed sources (n = 14) have been combined to provide an extensive overview of the arsenic contamination of drinking water sources in Nicaragua. So far, arsenic contamination has been detected in over 80 rural ...
... Arsenic (As) contamination in drinking water is a global public health risk. The present study highlighted the geological and anthropogenic causes of As contamination in groundwater (GW) and surface water (SW) and assessment of their potential health risks in Sindh province of Pakistan. Upon analyzing 720 GW and SW samples from 18 different sites, the estimates of As in groundwater and surface wat ...
... This work describes a novel system for arsenic detection in water using leucomalachite green dye in a microfluidic platform. A simplified leucomalachite green method was integrated into a microfluidic detection system. In acidic medium arsenic is reacted with potassium iodate to liberate iodine, which in turn oxidises leucomalachite green to malachite green forming a green colour associated with a ...
... The Eucalyptus cultivation acreage was large in Guangxi provinces. Guanglin 9 (Eucalyptus grandis × Eucalyptus urophylla) is a widely cultivated Eucalyptus species and has been found to grow normally in soils contaminated by heavy metals such as arsenic (As), but the detoxification mechanisms are not clear yet. Through hydroponic experiment, the adsorption and detoxification of As in Eucalyptus we ...
Barrett M. Welch; Adam Branscum; Sharia M. Ahmed; Perry Hystad; Ellen Smit; Sakila Afroz; Meghan Megowan; Mostofa Golam; Md Omar Sharif Ibne Hasan; Mohammad L. Rahman; Quazi Quamruzzaman; David C. Christiani; Molly L. Kile
... Arsenic can impair immune function. Timing of exposure can influence potential immunotoxicity of arsenic exposure. We examined the association between drinking water arsenic concentrations (W-As) measured repeatedly during different exposure windows in early life and serum concentrations of IgG antibodies against diphtheria and tetanus toxoids (diphtheria and tetanus antibody).A prospective cohort ...
... Widespread arsenic contamination in underground water is a well-documented public health concern that threatens millions of lives worldwide. We investigated the risk of young-adult mortality due to high chronic exposure to arsenic through years of drinking arsenic contaminated water.A prospective cohort study of 58,406 individuals was enrolled who were 4–18 years at baseline. Since Matlab HDSS (He ...
Marta Calatayud; Silvia Sara Farias; Gladys Soria de Paredes; Mónica Olivera; Natalia Ávila Carreras; Maria Cecilia Giménez; Vicenta Devesa; Dinoraz Vélez
DNA damage; adverse effects; arsenic; biomarkers; cacodylic acid; children; chronic exposure; creatinine; drinking water; metabolites; normal values; urine; Argentina
Abstract:
... Chronic exposure to inorganic arsenic (As) is associated with numerous adverse effects. Argentina is one of the countries affected by arsenicism; however, there are few studies that evaluate inorganic As exposure and its effects on child population. The aim of this study is to evaluate exposure to As through water and food in child populations living in the provinces of Santiago del Estero and Cha ...
... The influence of aquifer sediments provenance and geochemical processes on groundwater solute chemistry, including the fate of groundwater arsenic (As) in aquifers for three distinct tectono-morphic zones (north-western, northern, and southern [NW, N, and S] in the basin of Himalayan Mega Rivers, i.e., Brahmaputra river basin (BRB), and adjoining the Himalayas and Indo-Burmese ranges, have been de ...
... The rice consumption behaviors of Thai citizens vary among regions. However, the influence of different consumption patterns on arsenic (As) exposure has never been reported. This study was conducted to investigate the effects of rice consumption behavior on As exposure levels. White rice (n = 96) and sticky rice (n = 63) samples were collected from local households in northern Thailand. The actua ...
... Iron minerals are important for arsenic immobilization in paddy fields; however, intensive ferrolysis causes arsenic (As) release. Bismuth-impregnated biochar derived from wheat straw (BiBC) was synthesized to immobilize arsenic by regulating the ferrolysis process in a paddy field. Further X-ray based analysis (XRD and XPS) results demonstrated that crystal particles of bismuth oxide and bismuth ...
Marta I. Litter; Ana M. Ingallinella; Valentina Olmos; Marianela Savio; Gonzalo Difeo; Lía Botto; Elsa Mónica Farfán Torres; Sergio Taylor; Sofía Frangie; Jorge Herkovits; Isidoro Schalamuk; María José González; Eliana Berardozzi; Fernando S. García Einschlag; Prosun Bhattacharya; Arslan Ahmad
United States Environmental Protection Agency; World Health Organization; analytical methods; arsenic; at-risk population; bottled water; drinking water; equipment; groundwater; guidelines; human health; laws and regulations; metabolism; surveys; valleys; watersheds; Argentina
Abstract:
... An overview about the presence of arsenic (As) in groundwaters of Argentina, made by a transdisciplinary group of experts is presented. Aspects on As occurrence, effects of As on human health, regulations regarding the maximum allowable amount of As in drinking water as well as bottled water, and analytical techniques for As determination are presented. The most affected region in Argentina is the ...
... Health effects of arsenic in adults have been studied and documented more extensively than in infants and children, despite the fact that the younger population is more sensitive and is more exposed. Although rice has the highest concentrations of inorganic arsenic among foods, it is widely consumed by infants and children. The present article discusses the latest global literature on the presence ...
... Human exposure to arsenic (As) through the consumption of rice (Oryza sativa L.) is a worldwide health concern. In this paper, we evaluated the major causes for high inorganic As levels in cooked rice foods, and the potential of post-harvesting and cooking options for decreasing inorganic As content in cooked rice, focusing particularly on As endemic areas. The key factors for high As concentratio ...
World Health Organization; adverse effects; arsenic; cardiovascular diseases; chronic exposure; diabetes; drinking; drinking water; guidelines; neoplasms; people; public health; risk; Bangladesh; Cambodia; China; India; Myanmar; Nepal; Pakistan; Vietnam
Abstract:
... Arsenic affects hundreds of millions of people around the world, with majority of the arsenic-affected populations living in Southeast Asia. Recent reports estimated that population exposed to water arsenic at concentrations higher than the World Health Organization guideline level of 10 μg/L or higher than 50 μg/L included 70–80 million people living in India, 28–60 million in Bangladesh, 47–60 m ...
Martha Powers; Joseph Yracheta; David Harvey; Marcia O’Leary; Lyle G. Best; Annabelle Black Bear; Luke MacDonald; Jolie Susan; Khaled Hasan; Elizabeth Thomas; Camille Morgan; Pablo Olmedo; Rui Chen; Ana Rule; Kellogg Schwab; Ana Navas-Acien; Christine Marie George
United States Environmental Protection Agency; arsenic; atomic absorption spectrometry; filtration; groundwater; households; private ownership; randomized clinical trials; screening; silica; water quality; wells; North Dakota; South Dakota
Abstract:
... Elevated exposure to arsenic disproportionately affects populations relying on private well water in the United States (US). This includes many American Indian (AI) communities where naturally occurring arsenic is often above 10 µg/L, the current US Environmental Protection Agency safety standard. The Strong Heart Water Study is a randomized controlled trial aiming to reduce arsenic exposure to pr ...
... Arsenic (As) concentration in the Humboldt River (HR) water ranges from 0.012 to 0.06 mg/L, with an average of 0.032 mg/L. The river water is alkaline with pH 8.4–9.3 and oxic with average 12 mg/L of dissolved O₂ and + 139 mV of oxidation–reduction potential (ORP). The river water contains an average specific electrical conductivity of 1000 µS/cm with elevated B (average 0.77 mg/L), Li (average 0. ...
aquifers; arsenic; chemical reduction; coastal plains; desorption; drinking; drinking water; eolian sands; freshwater marshes; groundwater; groundwater contamination; hydroxides; iron; manganese; organic carbon; pH; principal component analysis; Brazil
Abstract:
... Excessive concentrations of arsenic in aquifers have been presented for the first time in the southern Brazilian coastal plain. In this region, the shallow aquifers are mainly constituted by a mosaic distribution of marsh sediment lenses formed in the interdune depressions in past times and subsequently covered by eolian sands. The stratigraphic descriptions and analytical determinations in water ...
... This batch and column kinetics study of arsenic removal utilized copper-impregnated natural mineral tufa (T–Cu(A–C)) under three ranges of particle size. Non-competitive kinetic data fitted by the Weber–Morris model and the single resistance mass transfer model, i.e., mass transfer coefficient kfa and diffusion coefficient (Dₑff) determination, defined intra-particle diffusion as the dominating ra ...
... The alkaline leaching solution from arsenic-containing gold concentrate contains a large amount of arsenate ions, which should be removed because it is harmful to the production process and to the environment. In this study, conventional Fe (III) precipitation was used to remove arsenic from the leaching solution. The precipitation reaction was carried out at the normal temperature, and the effect ...
... In this study, column-scale laboratory experiments were performed to evaluate the arsenic (As) removal efficiency of different agricultural biowastes-derived biosorbents (orange peel, banana peel, rice husk) and biochar, using As-containing solutions and As-contaminated groundwater. All the biosorbents and biochar efficiently removed (50–100%) As from groundwater (drinking well water). Arsenic rem ...
... China ranks the top in global annual rice output. However, extensive mining and smelting has led to elevated arsenic (As) in paddy soils, potentially imperiling local population health and sustainable rice production in the country. Under flooded condition, reductive As mobilization generally occurs, providing a unique advantage for soil As removal. In this study, we explore the depletion magnitud ...
Gibbs free energy; World Health Organization; anions; arsenic; drinking water; electricity; groundwater; guidelines; laundry; nanofiltration; rural areas; rural communities; solar collectors; temperature; Nicaragua
Abstract:
... This research evaluated the effect of different fluxes (16, 23 & 30 L/m2 h) and temperatures (31,35 & 43 °C) on the rejection of As(V) during nanofiltration (NF) of natural geothermal influenced groundwater in Nicaragua. A NF pilot plant powered by solar panels was built and operated in rural community Telica, exposed to As-rich drinking water sources due to geothermal influences. The results show ...
Angélica E. Ramírez-Rodríguez; Bernardo Bañuelos-Hernández; Mariano J. García-Soto; Dania G. Govea-Alonso; Sergio Rosales-Mendoza; M. Catalina Alfaro de la Torre; Elizabeth Monreal-Escalante; Luz M. T. Paz-Maldonado
... Arsenic contamination of groundwater is a significant problem in countries like Mexico, where San Luis Potosi is among the regions registering severe levels of it. Bioremediation with microalgae capable to absorb and metabolize metals or metalloids like arsenic reduces their toxicity and is a cost-effective approach compared to physical–chemical processes. We evaluated the capability of Chlamydomo ...
... Two arsenic-resistant purple non-sulphur bacteria (PNSB), Q3B and Q3C, were isolated (from industrial contaminated site and paddy fields) and identified by SSU rRNA gene sequencing as Rhodospirillum and Rhodospirillaceae species, respectively. Maximum arsenic reduction by these PNSB was observed in anaerobic conditions. Rhodospirillum sp. Q3B showed 74.92% (v/v) arsenic reduction while Rhodospiril ...
aerosols; air; arsenic; arsenicals; human health; nanoparticles; therapeutics; toxicity
Abstract:
... Arsenic is ubiquitous in the environment and of special concern due to its varying toxicity depending on the chemical form present. Less is known about arsenic in air, especially about organoarsenicals, their sources and fate. There is also a lack of knowledge regarding arsenic in airborne nanoparticles that are critical for understanding with respect to human health effects due to their size. Her ...