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Citrus; arsenic; cytotoxicity; enzyme inhibitors; epithelial cells; genes; human diseases; lungs; mitogen-activated protein kinase; oxidative stress; pathogenesis; phosphatidylinositol 3-kinase; polymethoxyflavones; protein kinase C; sodium; toxic substances; ubiquitination
Abstract:
... Exogenous toxicants (e.g. arsenic, cigarette smoke), trigger oxidative stress, and initiate the pathogenesis of many human diseases. Induction of nuclear factor E2-related factor 2 (Nrf2) counteract exogenous toxicant-induced oxidative insults. Using a high-throughput screen, we firstly identified a citrus polymethoxyflavone, (2S)-5,6,7,3',4'-pentamethoxyflavanone (PMF), to be an Nrf2 activator, a ...
arsenic; cesium; coastal sediments; coasts; copper; highlands; hydrology; lead; mining; models; plutonium; radionuclides; salt marshes; upland soils; watersheds; zinc; Irish Sea; Isle of Man
Abstract:
... The Isle of Man, situated in the central Irish Sea, was a significant centre for Pb and Zn mineral extraction during the Industrial Revolution. Comminuted mining debris from the East Snaefell and North Laxey mining areas was transported, through hydrological action, from upland catchments to the coast. This study focuses on an eastern coastal sediment sink and a salt marsh sediment sequence from P ...
... In this study, the effect of 24-Epibrassinolide (EBL) on antioxidant system in Arabidopsis thaliana were investigated under arsenate [As(V)] stress. The enzyme activity of superoxide dismutase (SOD) and catalase (CAT), total antioxidant status, malondialdehyde (MDA) level and free proline content, as well as the expression levels of SOD isoforms (Cu-ZnSODs, FeSODs and MnSOD), CAT isoforms (CAT1, C ...
... Recently indoor air quality (IAQ) has become a key issue, especially in schools, where children spend most of the day. Only in a few cases IAQ was investigated using lichens as biomonitors. During autumn 2017, lichens (Evernia prunastri) were exposed for two months indoors and outdoors in public (schools) and private (dwellings) environments, in both rural and urban areas of Slovakia. The bioaccum ...
Khanghyun Lee; Changhee Han; Sang-Bum Hong; Seong-Joon Jun; Yeongcheol Han; Cunde Xiao; Zhiheng Du; Soon Do Hur; Jong Ik Lee; Claude F. Boutron; Sungmin Hong
air pollution; arsenic; coal; combustion; ice; snow; technology; toxicity; China; Europe; Greenland; North America
Abstract:
... We report the first high-resolution record of arsenic (As) observed in Greenland snow and ice for the periods 1711–1970 and 2003–2009 AD. The results show well-defined large-scale atmospheric pollution by this toxic element in the northern hemisphere, beginning as early as the 18th century. The most striking feature is an abrupt, unprecedented enrichment factor (EF) peak in the late 1890s, with an ...
... The area of Ponce Enríquez, Southern Ecuador, is one of the most important artisanal and small scale gold mining (ASGM) areas in the country, where informal mining operations can be found using amalgamation technique, even though it has been prohibited since 2010. Considering the potential impact of these mining operations, the present research focused on heavy metal pollutants in subsurfac ...
... Soil heavy metal pollution has become a worldwide environmental issue that has attracted considerable public attention, largely from the increasing concern for the security of agricultural products. Heavy metals refer to some metals and metalloids possessing biological toxicity, such as cadmium, mercury, arsenic, lead, and chromium. These elements enter the soil agro-ecosystem through natural proc ...
active sites; adsorbents; adsorption; arsenic; biomimetics; chitosan; drinking water; heavy metals; mercury; metal ions; moieties; nanoparticles; silica; water purification
Abstract:
... Highly efficient adsorbents for drinking water purification are demanded since the contaminants are generally in a low concentration which makes it difficult for conventional adsorbents. Herein, we present a novel biomimetic SiO₂@chitosan composite as adsorbent with a high adsorption capability towards heavy metal ions including As(V) and Hg(II). The hollow leaf-like SiO₂ scaffold within the adsor ...
Pawel Dabrowski; Michal Jerzy Kulus; Agata Cieslik; Zygmunt Domagala; Rafał J. Wiglusz; Piotr Kuropka; Jan Kuryszko; Agata Thannhauser; Lukasz Szleszkowski; Piotr Marian Wojtulek; Daniel Solinski; Piotr Dziegiel
... Venereal syphilis is a sexually transmitted disease caused by Treponema pallidum – Gram-negative, slowly growing bacteria. The spread of the disease in the Old World was due to increased birth rate, urban population growth, migration and lack of knowledge concerning the epidemiology. In the past, the treatment was mainly symptomatic and included application of mercury compounds. The goal of the st ...
... 1. The consumption of arsenic is toxic to most biota. However, a noctuid caterpillar was recently reported feeding on a plant known to hyperaccumulate arsenic. 2. The aim of this study was to investigate the effects of arsenic‐rich Pteris vittata L. consumption by Callopistria floridensis G., and measure differences in arsenic concentrations at various stages of development (larval and adult), and ...
... An analytical method for the biomonitoring of arsenic, benzene and polycyclic aromatic hydrocarbons (PAHs) in human urine was developed using liquid chromatography tandem mass spectrometry (LC-MS/MS). The urinary metabolites of monomethylarsonic acid (MMAA), dimethylarsonic acid (DMAA), s-phenylmercapturic acid (S-PMA), and 1-hydroxypyrene (1-OHP) were selected as the corresponding marker compound ...
... Production of acid mine drainage (AMD) and acid sulfate soils is one of the most concerning environmental consequences associated with mining activities. Implementation of appropriate post-mining AMD management practices is very important to minimize environmental impacts such as high soil acidity, soil erosion, and metal leachability. The objective of this study was to develop a cost-effective an ...
... We studied the size distribution of ions (Cl⁻, NO₃⁻, SO₄⁼, Na⁺, NH₄⁺, K⁺, Mg⁺⁺, Ca⁺⁺) and elements (As, Ba, Cd, Co, Cs, Cu, Fe, Li, Mn, Ni, Pb, Rb, Sb, Se, Sn, Sr, Ti, Tl, V, Zn) during the winter and summer seasons of seven consecutive years (2008–2014) in an area of the Po Valley (Northern Italy) characterised by industrial, agricultural and urban settings. The study included the collection and ...
arsenic; biomarkers; creatinine; data collection; drinking water; environmental exposure; osmolality; specific gravity; urine; United Kingdom
Abstract:
... Spot urinary concentrations of environmental exposure biomarkers require correction for dilution. There is no consensus on the most appropriate method, with creatinine used by default despite lacking theoretical robustness. We comparatively assessed the efficacy of creatinine; specific gravity (SG); osmolality and modifications of all three for dilution correcting urinary arsenic. For 202 particip ...
arsenic; bioavailability; carcinogenicity; comparative study; particle size; particulates; risk; China
Abstract:
... The distribution and bioavailability of arsenic (As) in indoor/outdoor total suspended particulates (TSP), inhalable particulate matters (PM₁₀), and fine particulate matters (PM₂.₅) in Baoding, China were investigated. The average I/O ratios for TSP, PM₁₀, and PM₂.₅ were 0.52, 0.66, and 0.96, respectively. There was no significant correlation between indoor/outdoor TSP, PM₁₀, and PM₂.₅. The indoor ...
... PURPOSE: River sediment pollution by heavy metals/metalloids has attracted widespread attention due to a serious threat to the ecosystem and human health. As an effective and economical alternative, the stabilization method was considered by previous studies for the remediation of sediments polluted by metals/metalloids. However, a comprehensive study is required for an extensive comparison on the ...
... Arsenic(As)-mediated contamination of groundwater resources in different parts of the world is a consequence of natural or anthropogenic sources, leading to adverse effects on the environment and human health. Millions of people from different countries are unfortunately consuming groundwater contaminated with alarming levels of As. Exposure to the high concentration of As for an extended period o ...
... The impact of mining activities on the environment is vast. In this regard, many mines were operating well before the introduction of environmental law. This is particularly true of cinnabar mines, whose activity has declined for decades due to growing public concern regarding Hg high toxicity.Here we present the exemplary case study of an abandoned Hg mine located in the Somiedo Natural Reserve ( ...
arsenic; cadmium; copper; drinking water; food plants; health effects assessments; human health; humans; laws and regulations; lead; nickel; risk; soil properties; synergism; toxicity; zinc
Abstract:
... Trace elements (TEs) may have toxic effects to plants and humans; thus, countries and organizations impose maximum allowable regulation limits of their concentrations in soils. Usually such limits are placed in different categories according to soil use, soil properties or based on both attributes. However, some countries have regulation limits irrespective of differentiation in soil properties. I ...
Monte Carlo method; arsenic; carcinogenicity; ingestion; potatoes; risk; soil; tomatoes; wheat; Turkey (country)
Abstract:
... Natural arsenic contamination is a critical problem for various places around the world. Simav Plain (Kutahya, Turkey) is one such area that was shown to have natural arsenic contamination in its waters and soils. Arsenic exposure through ingestion of edible crops cultivated in Simav Plain and associated health risks were assessed in this study. To achieve this objective, arsenic levels in 18 crop ...
... There is a lack of field compatible analytical methods for the speciation of As(iii) to characterize groundwater pollution at anthropogenic sites. To address this issue, an inhibition-based acetylcholine esterase (AchE) sensor was developed to determine As(iii) in groundwater. 4-Acetoxyphenol was employed to develop an amperometric assay for AchE activity. This assay was used to guide the fabricat ...
... Bauxite residue, the by-product of the alumina industry, is mainly stored in land-based bauxite residue disposal areas (BRDAs). Environmental concern has been raised due to the large volumes in stockpile, the high alkalinity of the material, as well as the presence of elevated concentrations of trace elements. If not adequately managed, BRDAs can act as a source of pollution. In order to minimize ...
L. Fernandez-Rojo; C. Casiot; E. Laroche; V. Tardy; O. Bruneel; S. Delpoux; A. Desoeuvre; G. Grapin; J. Savignac; J. Boisson; G. Morin; F. Battaglia-Brunet; C. Joulian; M. Héry
... A field-pilot bioreactor exploiting microbial iron (Fe) oxidation and subsequent arsenic (As) and Fe co-precipitation was monitored during 6 months for the passive treatment of As-rich acid mine drainage (AMD). It was implemented at the Carnoulès mining site (southern France) where AMD contained 790–1315 mg L⁻¹ Fe(II) and 84–152 mg L⁻¹ As, mainly as As(III) (78–83%). The bioreactor consisted in fi ...
... The sea water serves as a source for desalination and shelter for dependent biota. To understand the sources of metal in Kuwait Bay and the open sea, samples were collected and analyzed for metals like B, Li, Sr, Hg, Pb, Ba, Fe, Zn, Mn, Be, Cd, Co, Cr, Ni, Se, V, Al, Mo, and As. The comparison of Bay and Seawater shows that most of the metals were higher in sea water. Samples were collected in two ...
arsenic; biochar; boreal forests; cadmium; composts; copper; diammonium phosphate; field capacity; forest soils; human health; lead; organic matter; remediation; toxicity; water content; zinc
Abstract:
... Metal-contaminated soils present a great threat to natural ecosystems and human health. Remediation studies focusing on metal-polluted soils with high organic matter (OM > 20%) are limited. This study evaluated the effectiveness of biochar, compost, diammonium phosphate (DAP), and iron oxides (Fe-O), in immobilizing metals from an OM-rich boreal forest soil contaminated with arsenic (As), cadmium ...
... This paper presents the results of laboratory investigations conducted on gold mine tailings (GMT) to assess their chemical, mineralogical and geotechnical characteristics in view of assessing its suitability as an alternative backfilling solution in mine reclamation. Chemical characterization revealed that GMT is dominated by Si, Al, and Fe with notable amounts of Cr, Zr, Zn, Pb, Ce, As, Ba, Ni, ...
... Agaricus brasiliensis, an edible mushroom with medicinal properties, has a tendency to accumulate high concentrations of heavy metals, especially cadmium. To address this issue, strains with low Cd accumulation must be developed. To breed a low-Cd-accumulating, high yield, and high-quality strain, mycelial fragments of A. brasiliensis were mutagenized with different doses of 60Co-γ-irradiation. Th ...
... Driven by the significant need for characterization of the chemical speciation of arsenic in food, this work developed a method for rapid determination of four common arsenic species, namely, arsenite, arsenate, monomethyl arsenic acid, and dimethyl arsenic acid, in vegetables using microwave‐assisted extraction, followed by detection with high‐performance liquid chromatography hyphenated to induc ...
aquifers; arsenic; case studies; data collection; groundwater; humans; iron; manganese; nitrates; pollution; statistical analysis; water management; Italy
Abstract:
... The assessment of geochemical Natural Background Levels (NBLs) in groundwater, aims at distinguishing the naturally high levels of geogenic compounds from anthropogenic pollution. This is a fundamental issue in groundwater management, in particular when the concentration of inorganic compounds exceeds the threshold values set for the evaluation of the groundwater chemical status, as requested by e ...
aluminum; arsenic; cadmium; chemometrics; chromium; copper; estuaries; heavy metals; iron; lead; nickel; sediments; vanadium; water pollution; zinc; Brazil
Abstract:
... Current studies use indices and chemometric approaches to assess the health quality of estuarine systems to support estuarine management. This study aims to use a multivariate approach and a set of indices to evaluate sediment health quality. Levels of Al, As, Cd, Cr, Cu, Fe, Ni, Pb, Sc, V, and Zn were quantified by ICP-OES, and nine indices were applied and evaluated individually. Most of the ind ...
... The inorganic content of the well-preserved 3.2-m record of Las Conchas bog (NW Spain), covering 8000 cal yr BP., was analysed. To study natural vs. human contributions, we applied an innovative approach, namely the sequential study of multivariate statistics (factor analysis followed by clustering of the factor score matrix) and enrichment factors (EFs). The increasing weight of potentially toxic ...
... A sensitive and selective fluorimetric method for the rapid determination of trace amounts of As(III)/As(V) species in certain tea samples forms the basis of the study. 3′,6′-bis(diethylamino)-2-{[(1E)-(4,5-dimethyl-2-furyl)methylene]amino}spiro[isoindole-1,9′-xanthen]-3(2H)-one (DMBD), was synthesized and characterized as a new fluorescence reagent for the speciation of As(III)/As(V) species. As( ...
adsorbents; adsorption; arsenates; arsenic; arsenites; coprecipitation; halloysite; iron; iron oxides; nanocomposites; nanotubes; water pollution
Abstract:
... In this paper, Fe3O4 was loaded on the surface of halloysite nanotubes (HNTs) by a simple one-pot coprecipitation method to prepare Fe3O4/HNTs nanocomposites (Fe3O4/HNTs) for arsenic removal from water. The growth mechanism and the arsenic removal performance of the nanocomposites were investigated. The morphology of Fe3O4/HNTs varied as the mass ratio of the total iron salts (Fe3+: Fe 2+ = 2:1) t ...
... In this study, a novel bioflocculant QZ-7 was produced from Bacillus salmalaya 139SI for industrial wastewater treatment. Biochemical analysis, FTIR, scanning electron microscopy-energy dispersive X-ray spectroscopy, and thermogravimetric analysis were performed. A synthetic wastewater sample was used to validate the performance of the prepared OZ-7 for the adsorption efficiency of As, Zn²⁺ Pb²⁺, ...
... A novel direct sampling (DS-HG) system consisting of an enlarged gas liquid separator (GLS) coupled with a foam breaker was firstly utilized for the in-situ dielectric barrier discharge atomic fluorescence spectrometer (DBD-AFS). After direct dilution using 5% HCl (v:v), a prepared blood sample was introduced into the DS-HG with a UV digestion unit, of which arsenic hydrides directly generated fro ...
adsorbents; adsorption; aquatic environment; arsenates; arsenic; arsenites; bicarbonates; calcium; chlorides; colloids; coprecipitation; endothermy; fluorides; magnesium; nanoparticles; oxidation; pH; phosphates; river water; silicates; social welfare; sulfates; surface area; toxicity; water pollution; water treatment
Abstract:
... Co-existing of arsenate (As(V)) and arsenite (As(III)) in aquatic environment have posed a great threat to humans due to the high mobility and toxicity. Developing practical methods for the removal of arsenic contamination in water source is vital for improving human wellbeing. Here, a novel nanostructured Fe-Ti-Mn composite oxide (FTMO) for the efficient removal of arsenic was synthesized using a ...
aluminum; ammonia; arsenic; cadmium; chromium; cobalt; copper; detection limit; fruit quality; fruit wines; gases; hydrogen; iron; lead; manganese; mercury; nickel; nitric acid; oxygen; tandem mass spectrometry; vanadium; zinc
Abstract:
... The composition of inorganic elements is a key factor in determining the quality of fruit wines. However, the use of direct sample injection is challenging for multi-elemental analysis of fruit wine samples. In this paper, an analytical method using inductively coupled plasma tandem mass spectrometry (ICP-MS/MS) was established for determining multiple elements (Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, ...
... A pH-responsive, charge switchable piperazine derivative, 1,4-bis(3-propane- sulphonate sodium)-piperazinediethanesulfonic acid disodium-sulfate (4), has been designed via a stepwise synthesis and proposed as a draw solute to remove arsenics (Asᴵᴵᴵ, Asⱽ) from water through forward osmosis (FO). Having multiple sulfonic groups, 4 generates a high osmotic pressure and produces a water flux as high a ...
... Under flooded conditions in paddy soil, the mobility of As increases while the mobility of Cd decreases. The opposite geochemical behavior of As and Cd makes it difficult to reduce their mobilities simultaneously. Our recent study found that combined applications of biochar and zero-valent iron successfully reduced the mobilities of As and Cd simultaneously. On this basis, in the present study, an ...
absorption; arsenic; binding capacity; breast feeding; breast milk; cadmium; environmental monitoring; feces; lactation; lead; lifestyle; maternal nutrition; mercury; mothers; neonates; nutrients; pregnancy; probiotics; public health; risk; risk assessment; toxic substances
Abstract:
... Potential exposure to toxic elements initially occurs during gestation and after birth via breast milk, which is the principal source of nutrients for infants during the first months of life. In this study, we evaluated whether maternal oral supplementation with a multi-strain probiotic product can protect infants from exposure to arsenic (As), cadmium (Cd), mercury (Hg), and lead (Pb) via breast ...
adverse effects; aluminum; arsenic; bromine; case studies; geology; human health; iron; nickel; Turkey (country)
Abstract:
... Public fountains are very common and everyday people appreciate the benefits a water fountain can bring. However, consumption of public fountain water in some country has decreased because of growing concerns that constituents in fountain water may have adverse effects on health. A few studies have examined the safety of public fountains, proposing only limited evidence of fountain‐related health ...
... A rapid on-line non-chromatographic hydride generation atomic fluorescence spectrometry is described and determination of inorganic arsenic (iAs (III) and iAs (V)) species is achieved within a single run. Thioglycolic acid (TGA) was used for on-line pre-reduction of iAs (V) and quantification of arsenic species was accomplished via calibration with one As form; as iAs (III). Samples and calibratio ...
... Arsenic (As) is a carcinogenic element threatening the health of millions of people around the world. The sources for human exposure include drinking water, crops, processed food items, vegetables, mushrooms, animal products etc. The people at most risk are those living in hotspots of As contamination viz., Bangladesh and West Bengal, India. However, it has been found that rice growing in other un ...
... A simple and novel method was developed at first time to enhance As (V) removal by zero valent iron (ZVI) and activated ZVI/Fe3O4 media (AIM) through air injection at intervals. Fe (II) was essential to trigger As (V) removal by ZVI and AIM, and magnetite did not improve As (V) removal. In presence of 0.5 mM Fe (II) under anaerobic condition, 10 g L−1 ZVI and AIM showed same As (V) removal efficie ...
... p-Arsanilic acid (p-ASA) and roxarsone (ROX) are two major phenylarsenic feed additives that are still widely used in many countries, and the land application of animal waste containing these compounds could introduce large quantities of arsenic into the environment. In this study, we proposed a treatment scheme for animal waste that involves leaching of p-ASA/ROX out of the manure first by water, ...
... This study evaluates a simultaneous assessment of organic matter (OM) and trace elements (TE) bio-accessibility in substrate and digestate from a full-scale anaerobic digester by a sequential OM extraction method. Simultaneous release of TE was determined along with the extraction of different OM fractions and the effects of extracting reagents on characteristics of OM were evaluated by nuclear ma ...
... Arsenic is prevalent in contaminated drinking water and affects more than 140 million people in 50 countries. While the wide-ranging effects of arsenic on neurological development and cancer draw the majority of concern, arsenic's effects on the gut mucosa-associated immune system are often overlooked. In this study, we show that 24 h after a single dose [low dose (50 μg/kg bw), medium dose (100 μ ...
arsenic; cluster analysis; heat; models; mortality; regression analysis; risk factors; urinary bladder neoplasms; United States
Abstract:
... Bladder cancer is a significant health issue across the United States of America (USA). Evidence of unequal distribution of a disease or condition's incidence and mortality would suggest that important geographically-defined variables may play a role. In this study, a spatial cluster analysis of bladder cancer mortality identified significant hot spots in some parts of the USA. Regression analysis ...
... A dendrochemical study of cottonwood trees (Populus deltoides) was conducted across a childhood cancer cluster in eastern Sandusky County (Ohio, USA). The justification for this study was that no satisfactory explanation has yet been put forward, despite extensive local surveys of aerosols, groundwater, and soil. Concentrations of eight trace metals were measured by ICP-MS in microwave-digested 5- ...
Internet; adult literacy; arsenic; cadmium; cosmetics; developed countries; developing countries; heavy metals; income; lead; mercury; systematic review
Abstract:
... There is an urgent need to address the safety problems caused by the use of skin lightening cosmetics. Evidence suggests that some of them may contain heavy metals.We conducted a systematic review of global legal regulations regarding the permissible level of mercury, lead, arsenic, and cadmium in cosmetic products, with particular emphasis on skin lightening preparations.The systematic search of ...
Quercus virginiana; arsenic; best management practices; chlorophyll; leaf area; leaf water potential; models; monitoring; root pruning; roots; sapwood; stomatal conductance; trees
Abstract:
... A suite of best management practice documents (BMPs) providing procedures to protect trees are available around the world. An underpinning component of these texts is the provision of a tree protection zone (TPZ), the purpose of which is to define an area of ground surrounding the tree to be excluded from development activities. TPZs 12 times the trunk diameter are common in BMPs, however, the pri ...
... Cadmium (Cd) and arsenic (As) are nonessential and toxic elements in rice that often occur together in contaminated paddy field soils. To understand whether rice has a common molecular response mechanism against Cd and As toxicity, 30-day seedlings (Oryza sativa L. indica) were exposed separately to Cd and As3+ in hydroponic cultures for up to 7 days. Root transcriptomic analysis of plants exposed ...
arsenic; models; monitoring; prediction; reflectance; reflectance spectroscopy; soil; China
Abstract:
... Visible and near-infrared reflectance (VNIR) spectroscopy is considered to be a potential and efficient means for monitoring soil arsenic (As) contamination. While current studies mainly focus on the evaluation of models' performance when training and verification samples are collected from the same region, whether the model developed at a specific region can be transferred to other regions is sti ...
... Arsenic is one of the most widespread global environmental toxicants associated with endemic poisoning. ATP-binding cassette (ABC) proteins are transmembrane channels that transport and dispose of lipids and metabolic products across the plasma membrane. The majority of ABC family members (including ABCB1 and ABCC1) are reported to play a role in the development of arsenic and drug resistance in m ...
... This study aimed to investigate nine heavy metal concentrations (As, Cd, Cr, Pb, Cu, Fe, Zn, Mn and Ni) in water, sediment and snakehead fish (Channa striata) and to identify abnormal chromosomes in C. striata from a reservoir near an industrial factory and a reference area. Heavy metal concentrations were measured by inductively coupled plasma optical emission spectrometry (ICP-OES). The metal co ...
... Arsenic (As) and cadmium (Cd) are known to be toxic to humans, and elevated concentrations have been documented in food crops worldwide. However, little is known regarding their uptake, translocation, and distribution in wheat plants during plant development. A series of experiments were conducted to investigate the spatial distribution and dynamics of As and Cd in two wheat cultivars (cv. JN12 an ...
arsenic; cadmium; chromium; cobalt; copper; heavy metals; humic substances; hydroxides; iron; lead; manganese; molybdenum; nickel; rivers; sediments; sorption; vanadium; zinc; Sea of Japan
Abstract:
... The average concentrations of elements Fe, Mn, Zn, Pb, Cu, Cr, V, Co, Cd, Ni, As, and Mo in the subcolloidal fraction of bottom sediments were determined in the northern and central parts of the Amur Bay. The concentrations of metals Pb, Co, Ni, Zn, Cr, V, and As in bottom sediments subject to direct influence of the Razdol’naya River were shown to increase by 5–17% because of their sorption on Fe ...
... A non-invasive study of trace element accumulation in tail feathers of the Kentish plover (Charadrius alexandrinus) was performed along the coastline of the northern littoral strip of the Venice Lagoon, with the aim to verify whether contamination may be a factor affecting conservation status of Kentish plover populations.Body burdens in feathers of 11 trace elements including toxic metals/metallo ...
... Plants that have grown for many years in the special environmental conditions prevailing in mining areas are naturally screened and show strong capacity to adapt to their environment. The present study investigated the enrichment characteristics of U and other heavy metals (As, Cu, Pb, Mn, Mo, Zn, Cd, Co, and Ni) in the soil–plant system in Xiazhuang uranium mine. Four dominant plants (Castanopsis ...
... The heavy metals Al, Cr, Cu, Ni, Pb, Zn, Fe, Mn, As, and Cd in the rainfall-driven supratidal wetlands along the west coast of the Bohai Sea (the areas are named site 1, site 2, site 3, and site 4 from south to north in the gradient in this study) are tested for their accumulation risks and sources. Results show that the distribution and enrichment of the heavy metals in the supratidal wetlands ar ...
agricultural soils; arsenic; basins; cadmium; case studies; coal; combustion; copper; ecosystems; environmental health; fertilizers; food security; heavy metals; human health; irrigation water; lead; mercury; paddy soils; pollution; rice; risk; risk assessment; soil sampling; transportation; zinc; China
Abstract:
... Contamination of agricultural soil by heavy metals has become a global issue concerning food security and human health risk. In this study, a soil investigation was conducted to evaluate metals accumulation, potential ecological and health risks as well as to identify sources of metals in paddy soils in Hanzhong City, which is located in a sedimentary basin. Ninety-two (92) surface soil samples (b ...
anthropogenic activities; arsenic; chromium; copper; heavy metals; industrialization; industry; lead; multivariate analysis; nickel; pollution; principal component analysis; river deltas; sand; zinc; China; Yellow River
Abstract:
... In 2014, three sediment cores were collected from the northern [Xinyanggang (XYG)], middle [Chuandonggang (CDG)], and southern [Xiaoyangkou (XYK)] parts of the coastal tidal flats of the North Jiangsu radial sand ridges (NJRSR), East China. The grain size and contents of heavy metals (Cu, Zn, Cr, Ni, Pb and As) in the cores were detected. The features of sediments and the accumulation of heavy met ...
... The Fenhe River basin is the main agricultural and industrial developed area in Shanxi province, China. In recent years, agricultural non-point source pollution in the Fenhe River basin intensified, threatening soil quality and safety in the area. Accumulation of eight heavy metals (HMs) including chromium (Cr), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), cadmium (Cd), lead (Pb) and mercury ...
advection; anthropogenic activities; arsenic; belowground biomass; bioaccumulation; coasts; dust; ecosystems; ecotoxicology; estuaries; metals; models; plant litter; pollution; sediments; toxicity; Bay of Bengal; India
Abstract:
... Arsenic (As), a toxic element is a concern for the habitants in and around the coastal areas of West Bengal (India) where world's largest Sundarbans mangrove is situated. Little is known about the potential of these mangroves in storing As within their biomass and transporting to the Bay of Bengal. A comprehensive yearly data of above ground and below ground biomass (AGB, BGB), and exchange fluxes ...
T. L. Tasker; W. D. Burgos; M. A. Ajemigbitse; N. E. Lauer; A. V. Gusa; M. Kuatbek; D. May; J. D. Landis; D. S. Alessi; A. M. Johnsen; J. M. Kaste; K. L. Headrick; F. D. H. Wilke; M. McNeal; M. Engle; A. M. Jubb; R. D. Vidic; A. Vengosh; N. R. Warner
arsenic; atomic absorption spectrometry; basins; calibration; cations; chromium; copper; data quality; environmental protection; lead; monitoring; nickel; oils; radioactivity; radium; radon; sediments; sludge; wastewater; zinc; United States
Abstract:
... Accurate and precise analyses of oil and gas (O&G) wastewaters and solids (e.g., sediments and sludge) are important for the regulatory monitoring of O&G development and tracing potential O&G contamination in the environment. In this study, 15 laboratories participated in an inter-laboratory comparison on the chemical characterization of three O&G wastewaters from the Appalachian Basin and four so ...
World Health Organization; X-ray absorption spectroscopy; arsenic; electrocoagulation; electrolysis; magnetite; pH; research; sorption; water; water treatment; water utilities; Netherlands
Abstract:
... Consumption of drinking water containing arsenic at concentrations even below the World Health Organization provisional limit of 10 μg/L can still lead to unacceptable health risks. Consequently, the drinking water sector in the Netherlands has recently agreed to target 1 μg/L of arsenic in treated water. Unfortunately, in many poor, arsenic-affected countries, the costs and complexity of current ...
Xiaohui Zhang; Song Tang; Mao Wang; Weimin Sun; Yuwei Xie; Hui Peng; Aimin Zhong; Hongling Liu; Xiaowei Zhang; Hongxia Yu; John P. Giesy; Markus Hecker
... Acid mine drainage (AMD) is one of the most hazardous byproducts of some types of mining. However, research on how AMD affects the bacterial community structure of downstream riverine ecosystems and the distribution of metal resistance genes (MRGs) along pollution gradient is limited. Comprehensive geochemical and high-throughput next-generation sequencing analyses can be integrated to characteriz ...
... To investigate the acid-extractable heavy metals in fine particulate matter (PM₂.₅) over Xi’an, China, 24-h PM₂.₅ samples were collected every 3 days from December 2015 through November 2016. The bioavailable fraction, termed here the bioavailability index (BI), of PM₂.₅-bound metal (As, Ba, Cd, Co, Cu, Mn, Ni, Pb, Ti, V, and Zn) and potential influencing factors, including relative humidity, temp ...
... A highly lead(II) resistant (up to 2200 mg/l) bacterium PbRPSD202 was selected among 210 lead resistant bacteria isolated from marine environment of Paradeep Port, Odisha for possible biosoption of toxic Pb (II) ions from metals polluted environments. The bacterium was identified as Bacillus xiamenensis following the phenotypic as well as 16S rRNA gene sequence analysis. In addition to Pb(II), it ...
arsenic; artificial intelligence; automation; bias; case studies; cost effectiveness; data collection; experts; health effects assessments; human health; model validation; models; prediction; risk assessment; toxicology
Abstract:
... Machine learning has emerged as a cost-effective innovation to support systematic literature reviews in human health risk assessments and other contexts. Supervised machine learning approaches rely on a training dataset, a relatively small set of documents with human-annotated labels indicating their topic, to build models that automatically classify a larger set of unclassified documents. “Active ...
... Field monitoring was conducted to evaluate the effects of active mine water treatment on improving the water quality of receiving river in a densely populated catchment. Microcosm experiment was also performed to assess the effects of treated mine water on the growth of the vegetable and the uptake of trace elements by the vegetable. The results show that the treatment process was very effective i ...
... The surrounding of the poorly maintained tailing ponds is endangered by the toxic substances and represents a serious risk for the health of the local population. The aim of the study was to determine the soil pollution by the hazardous elements (As, Cr, Cd, Cu, Fe, Mn, Ni, Pb, Zn) around the tailing pond using contamination factor (Cf), degree of contamination (Cd) and pollution load index (PLI). ...
... We describe and illustrate lesions in an outbreak of lead arsenate poisoning in beef cattle that ingested pesticide residues stored in an abandoned building of a former orange orchard. Of 70 exposed cattle, 14 had diarrhea, paresis, ataxia, recumbency, and/or seizures. Ten of the affected animals died after a clinical course of 12–18 h. Pathologic findings in 3 steers included extensive necrohemor ...
... MnO₂ is one of the most widespread and cheapest materials in nature that can both adsorb arsenic and oxidize arsenite [As(III)] to arsenate [As(V)]. In this study, column β-MnO₂ [CM] with the main facet of {110} and pincer β-MnO₂ [PM] with the facets of {110} and {101} are synthesized and used to remove arsenic in water under different conditions. For the adsorption process, the experimental data ...
... The adsorption behavior of thioarsenite (TAsIII) on the surface of hematite (α-Fe2O3) is unknown at present. In the present study, we have investigated the transformation and reactions of TAsIII [monothioarsenite (MTAsIII) and dithioarsneite (DTAsIII)] on the surface of α-Fe2O3 in the presence of sulfide at S/As = 1 and 3 by X-ray absorption spectroscopy (XAS) and Raman spectroscopy. The adsorptio ...
... Arsenic-containing water poses a serious threat to human health. In this study, two types of Fe-modified rice straw biochars [(Fe-impregnated biochar (FeIm char) and pre-modified rice straw biochar (PMRS char)] were prepared, in which three ratios [1, 5, and 10% (w/w)] of Fe modification were evaluated, resulting in six different Fe-modified biochars. Then, a series of adsorption experiments, usin ...
... Arsenic species are regarded as typical water pollutants due to their toxicity. The chemical structures of arsenic species greatly influence their migration and transformation in the environment. Metal-organic frameworks (MOFs) are used as reliable adsorbents to control arsenic contamination, so it is urgently needed to study the effect of chemical structure of arsenic species during adsorption pr ...
... In the present paper, used cigarette filter ash was prepared and used as an active adsorbent to remove As(III) ions from aqueous solutions. The prepared adsorbent structure was identified by scanning electron microscopy analysis, Brunauer–Emmett–Teller method and energy-dispersive X-ray spectroscopy analysis. The influence of contact time, pH, adsorbent dose and initial concentration of As(III) on ...
... Microplastics exhibit active environmental behavior and unique surface characteristics, and act as carriers for the migration of trivalent arsenic (As(III)) in the environment. Herein, the mechanism by which polytetrafluoroethylene (PTFE) microplastic particles adsorb As(III) is systematically determined. The larger the size of PTFE particles, the smaller the specific surface area, the higher the ...
adsorption; arsenic; arsenites; chemical bonding; chemical treatment; endothermy; ferrous chloride; fly ash; groundwater; ions; pH; temperature; toxicity; water treatment; zeolites
Abstract:
... The high toxicity of arsenite and the difficulty to remove it is one of the main challenges for water treatment. In the present work the surface of a low cost zeolite was modified by chemical treatment with a ferrous chloride to enhance its arsenite adsorption capacity. The effect of pH, ions coexistence, concentration, temperature and dosage was studied on the adsorption process. Additionally, th ...
... Gold nanoparticles (AuNPs) have been extensively used for detecting arsenite, As(III). Many methods rely on a DNA aptamer that claimed to bind specifically to inorganic arsenic. In these cases, the focus was on arsenic binding to the aptamer, while the potential interactions between As(III) and the AuNP surface were ignored. Herein, a set of spectroscopic and isothermal titration calorimetry (ITC) ...
... Arsenic (As) is considered as one of the most hazardous elements found in the groundwater. It is present in water in both arsenate (As(V)) and arsenite (As(III)) forms. On exposure for a considerable length of time to water having As concentration above the maximum permissible limit of 10 μg/L, there is a serious threat of developing various health problems including cancer. There is frequent repo ...
... The characteristic of adsorption of As(V) onto ferric oxide-impregnated anion resin Dowex marathon MSA (FO-Dowex) was investigated. Batch adsorption experiment was studied as a function of pH, contact time, initial As(V) concentration, and temperature. The results revealed that the adsorption of As(V) onto FO-Dowex was highly pH-dependent and that the equilibrium time was attained within 360 min. ...
... Recently, arsenic-contaminated water has become a big concern. Therefore, the present study aimed to absorb arsenic from the aqueous solution using modified saxaul tree ash. Arsenic adsorption process was performed in vitro by investigating the effect of various parameters such as pH, contact time, arsenic concentrations, temperature and adsorbent dosage on the adsorption efficiency. Isotherms, ki ...
... The magnetite-enriched particles (MEP) were separated from the mill scale on low magnetic intensity ranging from 300 to 500 gauss. The characterization of the MEP was done with scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). The adsorption efficiency of MEP was investigated with batch tests and column operation. The maximum adsorption cap ...
... As(III) is more toxic and harder to remove than As(V) though they are always co-exist in water. In order to effectively eliminate pollution of arsenic and explore the adsorption mechanism, a novel-innovative hydrated zirconium oxide (ZrO(OH)₂) and manganese dioxide (MnO₂) coated modified activated charcoal (Zr/Mn/C) prepared via a co-precipitation-hydrothermal method. Results showed that As(III) c ...
... Chitosan-magnetic-graphene oxide (CMGO) nanocomposite was prepared for arsenic adsorption. The nanocomposite was characterized through BET, FTIR, FESEM, EDX, and VSM analyses. These characterizations confirmed the formation of CMGO nanocomposites with high specific surface area (152.38 m2/g) and excellent saturation magnetization (49.30 emu/g). Batch adsorption experiments were conducted to evalua ...
X-ray absorption spectroscopy; adsorption; arsenic; binding capacity; ferrihydrite; goethite; iron oxides; models; nanosheets; pH; sorbents; sorption isotherms; surface area
Abstract:
... Adsorption onto two-dimensional nanosheet materials offers new possibilities for fast and efficient removal of contaminants from waters. Here, the adsorption of As(V) to a new type of iron oxides – single sheet iron oxide (SSI) – has been studied as a function of time, loading and pH. Adsorption of As(V) onto SSI was very fast compared to other iron oxides, with 80% of total As(V) adsorbed within ...
arsenic; arsenites; asymmetric membranes; carbon nanotubes; copper; copper nanoparticles; decontamination; drinking water; drinking water treatment; ferrimagnetic materials; hot water treatment; microfiltration; organic matter; phosphates; sodium hydroxide
Abstract:
... BACKGROUND: For effective removal of arsenite [As(III)] from drinking water, copper ferrite (CuFe₂O₄) particles were prepared by using a hydrothermal method and incorporated into layered carbon nanotube (CNT) membranes. The prepared composite membranes were used in the filtration of As(III) under conditions representative of drinking water treatment. RESULTS: The results demonstrated that the CNT ...
... Developing affordable and efficient materials for the removal of arsenic from drinking water is crucial for human and environmental safety. In the present study, the adsorptive performance of magnetic GO/ZnFe₂O₄ nanocomposite and ZnFe₂O₄ nanospinel for arsenic removal from aqueous water was analyzed. The adsorbents were characterized using Fourier-transform infrared spectroscopy, X-ray powder diff ...
... The study of aerosol dispersion characteristics in wastewater treatment plants (WWTPs) has attracted extensive attention. Oxidation ditch (OD) is a commonly implemented process during biological wastewater treatment. This study assessed the component characteristics, source apportionment, and exposure risks of aerosols generated from a WWTP using the OD process (AWO). The results indicated that th ...
adsorbents; adsorption; arsenic; carbon; carbon dioxide; ferric chloride; fly ash; iodine value; iron; kinetics; models; raw materials; rural water supply; sorption isotherms; steam; temperature
Abstract:
... The fly ash from the Corner Brook Pulp and Paper (CBPP) mill was used in this study as the raw material for the preparation of a low-cost adsorbent for arsenic removal from the well water of Bell Island. The CBPP fly ash was physically activated in two different ways: (a) activation with pure CO2 (CAC) with the iodine number and methylene value of 704.53 mg/g and 292.32 mg/g, respectively; and (b) ...
... Clean drinking water is a basic need of human beings around the world. In the past few decades, many research groups have been trying different methods to exploit quantum dots (QDs) to decontaminate water but, due to either cost or cumbersome steps, they have been unsuccessful. We have tried exploiting graphene quantum dots (GQDs) for heavy metal ion detection, particularly for arsenic ions in con ...
... The study was aimed to evaluate the ability of native lichen Xanthoria (X.) parietina to biomonitor and bioaccumulate some heavy metals (As, Cd, Co, Cr, Ni, Pb), PAHs, PCDDs, PCDFs, PCBs and PBDEs and to evaluate the use of the native X. parietina as a multi-tracer tool for scenarios characterized by different anthropogenic pressures. Samples of native X. parietina were collected in six different ...
... Arsenic (As) contamination in soils has posed a severe threat to safe crop production. The previous studies showed the antagonism between phosphorus (P) and As in plant growth and As uptake, while the mechanisms of alleviating As toxicity by P is not completely clear. Due to the limiting P condition, it is imperative to understand how low P addition can be used to suppress arsenate As (V) uptake a ...
... Abiotic stresses enhance the cellular level of reactive oxygen species (ROS) which consequently leads to toxic methylglyoxal (MG) production. Glyoxalases (GlyI & GlyII) catalyze the conversion of toxic MG into non-toxic lactic acid but their properties and functions have been overlooked in cyanobacteria. This is the first attempt to conduct a genome-wide analysis of GlyI protein (PF00903) from Ana ...
... Currently, most arsenic (As) studies in populations are concerned with water-borne arsenicosis. However, residents in Xingren County of Guizhou Province, Southwest of China, represent a unique case of arsenicosis which is related to indoor combustion of high As-containing coal. This study aimed to assess the alterations of As levels and its risk factors in coal-borne arsenicosis residents during t ...
... Arsenic is an important toxic chemical affecting millions of people around the world. Exposure to inorganic arsenic results in various health problems including skin lesions, hypertension, hematological disturbance, cardiovascular disease, spleen enlargement and cancer. Gallic acid (GA) is an important phenolic compound possessing various pharmacological properties including anti-inflammatory, ant ...
... Highly efficient decontamination of naturally occurring As(iii) from aqueous media remains a rigorous task for public health and ecosystem protection. As its increasingly acute toxicity and mobile characteristics than those of As(v), it is imperative to exploit a technique for the simultaneous removal and detoxication of As(iii). Herein, a novel strategy involving outer and inner structural engine ...
... Millions of people worldwide are at risk of arsenic poisoning from their drinking water. In Bangladesh the problem extends to rural drinking water wells, where non-biological solutions are not feasible. In serial enrichment cultures of water from various Bangladesh drinking water wells, we found transfer-persistent arsenite oxidation activity under four conditions (aerobic/anaerobic; heterotrophic ...