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... In high temperature annealing of carbon nanotube (CNTs) bundles for structure and thermal conductivity (κ) improvement, the statistical errors from sample-wide structure variation and sample transfer/preparation significantly overshadows the understanding of structure-κ correlation and change. In this work, the sequential process of current-induced thermal annealing (CITA) on improving the structu ...
active sites; annealing; anodes; batteries; chemical bonding; cobalt; cobalt sulfide; coordination polymers; electrolytes; energy; nanopores; nanosheets; screening; simulation models
Abstract:
... Sodium ion batteries (SIBs) for large-scale grid applications are facing great challenges in terms of development of high-performance electrode materials and screening of suitable electrolytes. Herein, a versatile and scalable protocol for synthesizing two-dimensional (2D) holey cobalt sulfide (h-Co₄S₃) nanosheets is demonstrated for high-rate and long-life SIBs in an ether-based electrolyte of 1. ...
... Metal-organic framework derived hierarchical bayberry-like Ni@carbon hollow nanosphere/reduced graphene oxide (Ni@CHS/rGO) hybrid was synthesized by combining a simple solvothermal reaction with a further annealing treatment. 3D hierarchical bayberry-like Ni@CHS/rGO hybrid not only offered a continuous highly conductive Ni metal and graphene matrix to facilitate the charge transfer, but also allow ...
active sites; annealing; catalysts; catalytic activity; durability; electrical properties; electrochemistry; hydrogen production; mass transfer; nanopores; nickel; structure-activity relationships; vanadium
Abstract:
... Nickel-based non-noble-metal materials have emerged as promising catalysts for electrochemical hydrogen production in view of their attractive intrinsic activities, electrical properties and low cost. Exploring new candidates for further improving the performances of nickel-based catalysts and understanding the structure–activity relationship are still necessary to reduce the overpotential of the ...
active sites; ammonia; annealing; argon (noble gases); electrochemistry; electrodes; electrolytes; graphene oxide; nitrides; solar cells; vanadium
Abstract:
... A three-dimensional (3D) porous architecture combining porous vanadium nitride nanoribbons with reduced graphene oxide was prepared through a hydrothermal process and subsequent thermal annealing in an ammonia/argon mixed atmosphere. Then, the obtained 3D porous vanadium nitride nanoribbon/reduced graphene oxide (PVNN/RGO) composite was explored as the counter electrode of dye-sensitized solar cel ...
... New synthetic methods are of great significance in enabling access to valuable compounds and materials. Although conjugated poly(3-hexylthiophene) (P3HT) has been widely investigated, P3HT copolymers containing functional groups (such as amino, imino, hydroxyl, etc.) are rarely reported because of inherent synthetic difficulties. Here P3HT copolymers bearing diverse functional pendants, which cann ...
... Mesoporous anatase TiO₂ nanomaterials (MATNs) with both large specific surface areas and structural coherence are highly desirable to achieve excellent physicochemical properties for photovoltaic applications, but the existing synthesis methods either need templates or cause pollution. Herein we report a simple, template-free, and green approach to synthesize MATNs consisting of interconnected nan ...
... Scalable, cost-effective synthesis and integration of graphene is imperative to realize large-area applications such as nanoporous atomically thin membranes (NATMs). Here, we report a scalable route to the production of NATMs via high-speed, continuous synthesis of large-area graphene by roll-to-roll chemical vapor deposition (CVD), combined with casting of a hierarchically porous polymer support. ...
... Nanocrystalline stannous oxide (SnO) powder has been prepared by ball-milling of micrometer-SnO in a nitrogen atmosphere. A cation deficiency of 6.5% was found in the nano-SnO sample by X-ray photoelectron spectroscopy. After annealing at 350, 450, or 550 °C under dynamic vacuum conditions, oxygen vacancies were found in the nano-SnO samples, as verified by electron paramagnetic resonance experime ...
David Kuhness; Hyun Jin Yang; Hagen W. Klemm; Mauricio Prieto; Gina Peschel; Alexander Fuhrich; Dietrich Menzel; Thomas Schmidt; Xin Yu; Shamil Shaikhutdinov; Adrian Lewandowski; Markus Heyde; Anna Kelemen; Radosław Włodarczyk; Denis Usvyat; Martin Schütz; Joachim Sauer; Hans-Joachim Freund
X-ray photoelectron spectroscopy; annealing; density functional theory; energy; models; scanning tunneling microscopy; silica; stoichiometry; temperature
Abstract:
... We present a new polymorph of the two-dimensional (2D) silica film with a characteristic ‘zigzag’ line structure and a rectangular unit cell which forms on a Ru(0001) metal substrate. This new silica polymorph may allow for important insights into growth modes and transformations of 2D silica films as a model system for the study of glass transitions. Based on scanning tunneling microscopy, low en ...
annealing; films (materials); polymers; semiconductors
Abstract:
... An issue for the morphology control of organic materials in active layer has still been in spotlight. Most research people have focused on the p-type semiconducting compounds; however, the studies on the n-type materials are rarely conducted. Thus, in this paper, we systematically controlled the morphology of the n-type semiconductor by introducing insulating polymers, PS and PAN. We analyzed the ...
... Lithiophilic Cu₂O nanoparticle decorated copper foil synthesized by a facile air annealing approach was employed as a lithium plating substrate. The Cu₂O layers can stabilize lithium nucleation and alleviate the growth of lithium dendrites, thus enhancing lithium plating and stripping performance. This simple strategy is easily scalable to achieve low-cost lithium metal anodes for commercial appli ...
... Expected for many promising applications in the field of electronics and optoelectronics, a reliable method for the characterization of graphene electrical transport properties is desired to predict its device performance or provide feedback for its synthesis. However, the commonly used methods of extracting carrier mobility from graphene field effect transistor or Hall-bar is time consuming, expe ...
annealing; chemistry; molybdenum; molybdenum disulfide; solar cells
Abstract:
... Monolayer MoS₂ has long been considered as the most promising candidate for wearable photovoltaic devices. However, its photovoltaic efficiency is restricted by its large band gap (2.0 eV). Though the band gap can be reduced by increasing the number of layers, the indirect band gap nature of the resulting multilayer MoS₂ is unfavorable. Herein, we report a theoretical discovery of the hitherto unk ...
... A high-performance aromatic co-polyimide (co-PI) fiber was prepared by thermal treating the polyamic acid (PAA) precursor fiber produced through a wet spinning technique. A gradient thermal treatment protocol, which was selected based on the thermogravimetric analysis of PAA fibers, was employed for achieving the best structure and fiber performance. The structural and morphological variations of ...
algorithms; annealing; batteries; biodiesel; energy; energy use and consumption; life cycle costing; models; system optimization; wind; wind power; wind turbines; Iran
Abstract:
... The main contribution of this research is formulating the size optimization of grid-independent hybrid wind/photovoltaic/biodiesel/battery systems and proposing a hybrid algorithm on this optimization problem. There are many investigations based on hybrid wind and PV power systems but the investigation on the hybrid wind/photovoltaic/biodiesel/battery system is rarely found. Here, the optimal desi ...
Long Bai; Zhibin Du; Jingjing Du; Wei Yao; Jiaming Zhang; Zeming Weng; Si Liu; Ya Zhao; Yanlian Liu; Xiangyu Zhang; Xiaobo Huang; Xiaohong Yao; Ross Crawford; Ruiqiang Hang; Di Huang; Bin Tang; Yin Xiao
angiogenesis; annealing; bone formation; coatings; crystal structure; endothelial cells; hydrophilicity; hydroxyapatite; in vitro studies; in vivo studies; inflammation; macrophages; nanoparticles; osteoblasts; oxidation; porous media; prostheses; temperature; tissue transplantation; titanium; titanium dioxide; wettability
Abstract:
... A multifaceted coating for hard tissue implants, with favorable osteogenesis, angiogenesis, and osteoimmunomodulation abilities, would be of great value since it could improve osseointegration and alleviate prosthesis loosening. However, to date there are few coatings that fully satisfy these criteria. Herein we describe a microporous TiO2 coating decorated with hydroxyapatite (HA) nanoparticles t ...
... Numerous modifications strategies are applied to spinel ZnFe₂O₄ nanorods with a band gap energy of ∼2.0 eV to enhance their activity as a photoanode for photoelectrochemical (PEC) water splitting. First, hybrid microwave annealing (HMA) imparts high crystallinity to ZnFe₂O₄ nanorods, while preserving the formed nanostructure and maintaining high electric conductivity of F:SnO₂ (FTO) substrate. Thi ...
... ZnMn₂O₄ and Zn₁₋ₓAlₓMn₂O₄ were synthesized by a spray drying process followed by an annealing treatment. Their structural and electrochemical characteristics were investigated by SEM, XRD, XPS, charge–discharge tests and EIS. XPS data indicate that the substitution of Al³⁺ for Zn²⁺ causes manganese to be in a mixed valence state by a charge compensation mechanism. Moreover, the presence of this ch ...
... Mechanical grinding method was employed to prepare FeCoNiSiₓAl₀.₄ high entropy alloy powders, which present a simple solid solution structure (FCC and BCC). After annealing at 673 K, a large amount of BCC phase precipitate and a small amount of CoFe₂O₄ phase generate. The change of crystal structure may lead to an increase in Mₛ (from 100.3 emu g⁻¹ to 124.2 emu g⁻¹) and a decrease in Hc (from 107 ...