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- Breitfeld, S.; Scholz, G.; Emmerling, F.; Kemnitz, E.
- Journal of materials science 2018 v.53 no.19 pp. 13682-13689
- intermediate product, etc ; Fourier transform infrared spectroscopy; X-ray diffraction; acetates; ammonium; barium; carboxylic acids; chemical bonding; coordination polymers; differential thermal analysis; dimethyl sulfoxide; fluorides; fluorine; hydrogen; mechanochemistry; metal ions; milling; nuclear magnetic resonance spectroscopy; thermogravimetry; washing; Show all 20 Subjects
- ... A new barium coordination polymer, BaF-benzenedicarboxylate (BaF(p-BDC)₀.₅), with fluorine directly coordinated to the metal cation, was prepared by mechanochemical synthesis routes. Phase-pure BaF-benzenedicarboxylate was synthesized by milling starting either from barium hydroxide or from barium acetate as sources for barium cations. In both cases, the second reactant was 1,4-benzenedicarboxylic ...