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- Author:
- Misbah, Ibrahim; Zhao, Fusheng; Shih, Wei-Chuan
- Source:
- ACS applied materials & interfaces 2018 v.11 no.2 pp. 2273-2281
- ISSN:
- 1944-8252
- Subject:
- refractive index, etc ; alloys; cameras; color; colorimetry; electric field; energy; hybridization; mobile telephones; nanogold; nanosilver; nanospheres; point-of-care systems; surface plasmon resonance; wavelengths; white light; Show all 16 Subjects
- Abstract:
- ... We report the first observation of symmetry breaking-induced mode splitting in coupled gold–silver alloy nanodisk array (ANA). According to the plasmonic hybridization picture, the original localized surface plasmon resonance (LSPR) of individual nanodisk is split into a pair of high and low energy modes when placed in between a superstrate and a substrate. Although well studied in single silver n ...
- DOI:
- 10.1021/acsami.8b17876
-
http://dx.doi.org/10.1021/acsami.8b17876
- Author:
- Sas, Olalla G.; Domínguez, Irene; González, Begoña; Domínguez, Ángeles
- Source:
- Journal of environmental management 2018 v.228 pp. 475-482
- ISSN:
- 0301-4797
- Subject:
- refractive index, etc ; 2-chlorophenol; atmospheric pressure; compressibility; hydrophobicity; ionic liquids; liquid-liquid extraction; o-cresol; resorcinol; solubility; temperature; thermal expansion; viscosity; Show all 13 Subjects
- Abstract:
- ... In this work, the capability of the ionic liquid, 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide, [C2mim]FSI, to extract o-cresol, 2-chlorophenol, resorcinol and phenol from water, reaching the legal limit of 1 mg L⁻¹ was analyzed. The extraction process was carried out for each one of these phenolic compounds varying the initial concentration in water from 3 mg L⁻¹ to 1000 mg L⁻¹, and for a ...
- DOI:
- 10.1016/j.jenvman.2018.09.042
-
http://dx.doi.org/10.1016/j.jenvman.2018.09.042
- Author:
- Avcı, Davut; Altürk, Sümeyye; Sönmez, Fatih; Tamer, Ömer; Başoğlu, Adil; Atalay, Yusuf; Kurt, Belma Zengin; Dege, Necmi
- Source:
- Tetrahedron 2018 v.74 no.50 pp. 7198-7208
- ISSN:
- 0040-4020
- Subject:
- refractive index, etc ; Fourier transform infrared spectroscopy; X-ray diffraction; alpha-glucosidase; binding sites; cadmium; carboxylic acids; chemical reactions; chromium; computer simulation; copper; crystal structure; enzyme inhibition; genistein; geometry; models; spectral analysis; thiocyanates; ultraviolet-visible spectroscopy; Show all 19 Subjects
- Abstract:
- ... Novel complexes of 6−methylpyridine−2−carboxylic acid and thiocyanate {[Cu(NCS)(6-mpa)2], (1); [Cd(NCS)(6-mpa)]n, (2); [Cr(NCS)(6-mpa)2·H2O], (3)} were synthesized, and their structures were characterized by XRD analysis, FT–IR and UV–Vis spectroscopic techniques. The inhibitory activities of the synthesized complexes (1–3) on α-glucosidase were determined by using genistein reference compound. Fu ...
- DOI:
- 10.1016/j.tet.2018.10.054
-
http://dx.doi.org/10.1016/j.tet.2018.10.054
- Author:
- Muroga, Shun; Hikima, Yuta; Ohshima, Masahiro
- Source:
- Analytical chemistry 2018 v.91 no.3 pp. 1887-1893
- ISSN:
- 1520-6882
- Subject:
- refractive index, etc ; absorbance; absorption; angle of incidence; chemical structure; image analysis; near-infrared spectroscopy; nondestructive methods; polymers; Show all 9 Subjects
- Abstract:
- ... This paper proposes a nondestructive method of evaluating polymer composites using near-infrared (NIR) diffuse reflection spectroscopy with multiple ground plates. Wavelength-dependent absorption and reduced scattering coefficients were acquired to evaluate the chemical structure and the concentration of the substances from absorption and to determine the size and the dispersity of filler in the p ...
- DOI:
- 10.1021/acs.analchem.8b03723
-
http://dx.doi.org/10.1021/acs.analchem.8b03723
- Author:
- Skopak, T.; Kroeker, S.; Levin, K.; Dussauze, M.; Méreau, R.; Ledemi, Y.; Cardinal, T.; Fargin, E.; Messaddeq, Y.
- Source:
- Journal of physical chemistry 2018 v.123 no.2 pp. 1370-1378
- ISSN:
- 1932-7455
- Subject:
- refractive index, etc ; Raman spectroscopy; cations; density functional theory; gallium; glass; glass transition temperature; nuclear magnetic resonance spectroscopy; physical chemistry; sodium; Show all 10 Subjects
- Abstract:
- ... Glass compositions in the gallium-rich region of the ternary GaO₃/₂–GeO₂–NaO₁/₂ vitreous system are studied as a function of the Na/Ga cationic ratio (ranging from 1.30 to 1.61) for a fixed GeO₂ content. Glass structures are investigated by ⁷¹Ga magic angle spinning nuclear magnetic resonance, infrared, and Raman spectroscopies, and the thermal, optical, and physical properties are characterized. ...
- DOI:
- 10.1021/acs.jpcc.8b08632
-
http://dx.doi.org/10.1021/acs.jpcc.8b08632
- Author:
- Fung, Han Wai Millie; So, Seulgi; Kartub, Kellen; Corn, Robert M.
- Source:
- Journal of physical chemistry 2018 v.123 no.1 pp. 762-769
- ISSN:
- 1932-7455
- Subject:
- refractive index, etc ; electrochemistry; glass; nanopores; physical chemistry; scanning electron microscopy; surface area; tin dioxide; tungsten oxide; zinc oxide; Show all 10 Subjects
- Abstract:
- ... To quantitatively characterize the optical coupling between ZnO (a high refractive index but nonabsorptive material) and an electrochromic material (either tungsten oxide (WO₃) or poly(3,4-ethylenedioxythiophene) (PEDOT)), electrodiffractive and electrochromic properties were investigated from a novel two-component composite nanostructured electrodeposited grating that incorporated both ZnO and ei ...
- DOI:
- 10.1021/acs.jpcc.8b08072
-
http://dx.doi.org/10.1021/acs.jpcc.8b08072
- Author:
- Taguchi, Marie; Ogami, Tasuku; Ando, Jun; Fukuda, Takashi; Emoto, Akira
- Source:
- Colloids and surfaces 2018 v.558 pp. 171-178
- ISSN:
- 0927-7757
- Subject:
- refractive index, etc ; colloids; glass; glucose; molecular weight; polystyrenes; wavelengths; Show all 7 Subjects
- Abstract:
- ... The formation of submicron polystyrene (PS) particles based on dewetting process during spin-coating was investigated. The surface morphologies on glass substrates were analyzed. The formation of particles was achieved using PS with relatively high molecular weight (Mw ≥ 3250). In addition, it was observed that the particle formation proceeded through sequential morphological changes in the order ...
- DOI:
- 10.1016/j.colsurfa.2018.07.007
-
https://dx.doi.org/10.1016/j.colsurfa.2018.07.007
- Author:
- Xie, Juan; Duan, Ming; Bai, Penghui; Lei, Kai; Yang, Chen; Liu, Biao; Zhang, Lei; Tang, Junlei; Wang, Yingying; Wang, Hu
- Source:
- Analytical chemistry 2018 v.91 no.1 pp. 1133-1139
- ISSN:
- 1520-6882
- Subject:
- refractive index, etc ; crystals; photons; physical models; silica; vapors; volatile organic compounds; Show all 7 Subjects
- Abstract:
- ... Two physical models, the replacing model and the filling model, have been proposed to explain the mechanism of the effective-refractive-index change of photonic crystals (PCs). Theoretically, the photonic bandgap (PBG) would shift when PCs are exposed to different environments, which leads to a change of the effective refractive index of PCs. However, the mechanism of effective-refractive-index ch ...
- DOI:
- 10.1021/acs.analchem.8b04874
-
http://dx.doi.org/10.1021/acs.analchem.8b04874
- Author:
- Banerjee, Sourish; Onnink, Arnoud J.; Dutta, Satadal; Aarnink, Antonius A. I.; Gravesteijn, Dirk J.; Kovalgin, Alexey Y.
- Source:
- Journal of physical chemistry 2018 v.122 no.51 pp. 29567-29576
- ISSN:
- 1932-7455
- Subject:
- refractive index, etc ; ammonia; carbon; crystals; gallium; nitrogen; physical chemistry; silicon; temperature; thermal degradation; Show all 10 Subjects
- Abstract:
- ... This article describes novel composite thin films consisting of GaN, C, and Ga (termed “GaCN”, as an analogue to BCN and other carbonitrides) as a prospective material for future optical applications. This is due to their tunable refractive index that depends on the carbon content. The composites are prepared by introducing alternating pulses of trimethylgallium (TMG) and ammonia (NH₃) on silicon ...
- DOI:
- 10.1021/acs.jpcc.8b09142
-
http://dx.doi.org/10.1021/acs.jpcc.8b09142
- Author:
- Sarma, Dominik; Carl, Peter; Climent, Estela; Schneider, Rudolf J.; Rurack, Knut
- Source:
- ACS applied materials & interfaces 2018 v.11 no.1 pp. 1321-1334
- ISSN:
- 1944-8252
- Subject:
- refractive index, etc ; additives; adsorption; antibodies; antifouling activities; beverages; caffeine; dyes; fluorescent antibody technique; haptens; hydrophobicity; microparticles; moieties; polyethylene glycol; polymerization; polystyrenes; quantitative analysis; silane; silica; washing; Show all 20 Subjects
- Abstract:
- ... Commercial bead-based assays are commonly built upon polystyrene particles. The polymeric carrier can be encoded with organic dyes and has ideal material properties for cytometric applications such as low density and high refractive index. However, functional groups are conventionally integrated during polymerization and subsequent modification is limited to the reactivity of those groups. Additio ...
- DOI:
- 10.1021/acsami.8b10306
-
https://dx.doi.org/10.1021/acsami.8b10306
- Author:
- Seyfang, Kelsey E.; Kobus, Hilton J.; Popelka-Filcoff, Rachel S.; Plummer, Andrew; Magee, Charles W.; Redman, Kahlee E.; Kirkbride, K. Paul
- Source:
- Forensic science international 2018 v.293 pp. 47-62
- ISSN:
- 0379-0738
- Subject:
- refractive index, etc ; antimony; energy-dispersive X-ray analysis; forensic sciences; glass; mass spectrometry; scanning electron microscopy; Australia; Show all 8 Subjects
- Abstract:
- ... The majority of 0.22 calibre rimfire ammunition available in Australia, and overseas, tends to use glass powder rather than antimony sulfide frictionator in the primer. This glass can be the nucleus of a GSR particle, with other primer components condensing around and onto the glass structure. As the composition of glass frictionator remains largely unaltered during ammunition discharge [1] there ...
- DOI:
- 10.1016/j.forsciint.2018.10.017
-
https://dx.doi.org/10.1016/j.forsciint.2018.10.017
- Author:
- Malacrida, Cassia Roberta; Moraes, Izabel Cristina Freitas; de Rosso, Veridiana Vera; Rodrigues, Christianne Elisabete da Costa; de Souza, Allan Chiea
- Source:
- Journal of food processing and preservation 2018 v.42 no.12 pp. e13828
- ISSN:
- 0145-8892
- Subject:
- refractive index, etc ; Caryocar brasiliense; acid value; antioxidant activity; bioactive compounds; cold; cooking fats and oils; food industry; nutritive value; oleic acid; pharmaceutical industry; phenolic compounds; pressing; pulp; solvents; zeaxanthin; Show all 16 Subjects
- Abstract:
- ... This study aimed to evaluate the application of an enzymatic pretreatment in obtaining pequi pulp oil by cold pressing. It was evaluated the yield and quality of the oil obtained mainly in relation to the bioactive compounds. There was an increase of approximately 22% in the process yield compared to the cold pressing without enzymatic pretreatment. Comparing the physicochemical characteristics of ...
- DOI:
- 10.1111/jfpp.13828
-
http://dx.doi.org/10.1111/jfpp.13828
- Author:
- Giraldo, Marco A.; Parra, Juan L.; Stavenga, Doekele G.
- Source:
- Journal of comparative physiology 2018 v.204 no.12 pp. 965-975
- ISSN:
- 0340-7594
- Subject:
- refractive index, etc ; absorbance; color; courtship; hummingbirds; keratin; males; plumage; reflectance; reflectance spectroscopy; Show all 10 Subjects
- Abstract:
- ... The male Anna’s hummingbird features a brightly reddish-pink reflecting gorget, due to large stacks of melanosomes in the feather barbules, arranged in layers separated by keratin. Direct observations together with detailed scatterometry demonstrated that the barbules reflect incident light in an approximately specular manner. The structural colouration is iridescent, i.e. varies with a changing a ...
- DOI:
- 10.1007/s00359-018-1295-8
-
http://dx.doi.org/10.1007/s00359-018-1295-8
- Author:
- Jun, Sun; Yating, Li; Xiaohong, Wu; Chunxia, Dai; Yong, Chen
- Source:
- Journal of food process engineering 2018 v.41 no.8 pp. e12884
- ISSN:
- 0145-8876
- Subject:
- refractive index, etc ; algorithms; cherry tomatoes; fruits; light scattering; models; near-infrared spectroscopy; nondestructive methods; prediction; reflectance spectroscopy; regression analysis; spectral analysis; spectrometers; total soluble solids; wavelengths; Show all 15 Subjects
- Abstract:
- ... As one of the most important indexes of internal quality testing of fruit, soluble solids content (SSC) is significant for its rapid and efficient nondestructive testing by using near infrared reflectance spectroscopy (NIRS). In this article, 126 cherry tomatoes were selected as the research object. Reflectance spectra data of 228 bands in cherry tomatoes were acquired by the near infrared spectro ...
- DOI:
- 10.1111/jfpe.12884
-
http://dx.doi.org/10.1111/jfpe.12884
- Author:
- Zhang, Yunong; Ma, Kaijie; Kuang, Xiangrong; Liu, Le; Sun, Yunxu; Xi, Jingyu
- Source:
- Journal of physical chemistry 2018 v.122 no.50 pp. 28550-28555
- ISSN:
- 1932-7455
- Subject:
- refractive index, etc ; batteries; electrochemistry; electrolytes; physical chemistry; sulfates; vanadium; Show all 7 Subjects
- Abstract:
- ... Studying the disequilibrium transfer of the electrolyte in vanadium redox flow batteries is essential for the application of the batteries. Due to the lack of proper detection techniques, the real-time study of the disequilibrium transfer is difficult. In this paper, a real-time refractive index detector with high resolution is developed to study the material transfer in the positive electrolyte a ...
- DOI:
- 10.1021/acs.jpcc.8b10165
-
http://dx.doi.org/10.1021/acs.jpcc.8b10165
- Author:
- Mordan, Emily H.; Wade, James H.; Wiersma, Zach S. B.; Pearce, Eric; Pangburn, Todd O.; deGroot, A. Willem; Meunier, David M.; Bailey, Ryan C.
- Source:
- Analytical chemistry 2018 v.91 no.1 pp. 1011-1018
- ISSN:
- 1520-6882
- Subject:
- refractive index, etc ; aerosols; detectors; gel chromatography; light scattering; molecular weight; photons; polystyrenes; silicon; solvents; Show all 10 Subjects
- Abstract:
- ... Molecular weight distribution (MWD) is often the most informative analytical parameter in polymer analysis, with gel permeation chromatography (GPC) being the most common approach for determining the MWD for polymer samples. Many industrially relevant polymers lack chromogenic or fluorogenic signatures, precluding use of spectroscopy-based detection. Universal detectors, such as evaporative light ...
- DOI:
- 10.1021/acs.analchem.8b04263
-
http://dx.doi.org/10.1021/acs.analchem.8b04263
- Author:
- Arosa, Yago; Algnamat, Bilal S.; Rodríguez, Carlos Damián; Lago, Elena López; Varela, Luis Miguel; de la Fuente, Raúl
- Source:
- Journal of physical chemistry 2018 v.122 no.51 pp. 29470-29478
- ISSN:
- 1932-7455
- Subject:
- refractive index, etc ; anions; cations; interferometry; ionic liquids; models; physical chemistry; sodium; temperature; uncertainty; wavelengths; white light; Show all 12 Subjects
- Abstract:
- ... A thorough analysis of the refractive index of 11 1-alkyl-3-methylimidazolium-based ionic liquids with three different anions, tetrafluoroborate (BF₄), bis(trifluoromethylsulfonyl)imide (NTf₂), and trifluoromethanesulfonate (OTf), is reported. Refractive indices were estimated, in the temperature interval from 298.15 to 323.15 K, using an Abbe refractometer to determine the value at the sodium D l ...
- DOI:
- 10.1021/acs.jpcc.8b08971
-
http://dx.doi.org/10.1021/acs.jpcc.8b08971
- Author:
- Schulte, P.; Lehmkuhl, F.
- Source:
- Palaeogeography, palaeoclimatology, palaeoecology 2018 v.509 pp. 126-136
- ISSN:
- 0031-0182
- Subject:
- refractive index, etc ; clay; feldspar; fractionation; hydrolysis; loess; mica; mineral content; models; particle size distribution; silt; silt fraction; weathering; Show all 13 Subjects
- Abstract:
- ... Chemical and physical processes within aeolian sediments result in a reduction of the particle grain size. In loess sediments the post-depositional grain size variation is due to a reduction of the dominating coarse silt fraction in favor of the clay and fine silt fraction. Generally, there are two post-depositional fractionation processes: (1) the chemical weathering of silt sized minerals like m ...
- DOI:
- 10.1016/j.palaeo.2017.02.022
-
https://dx.doi.org/10.1016/j.palaeo.2017.02.022
- Author:
- Gorkowski, Kyle; Donahue, Neil M.; Sullivan, Ryan C.
- Source:
- Environmental science 2018 v.20 no.11 pp. 1512-1523
- ISSN:
- 2050-7895
- Subject:
- refractive index, etc ; Raman spectroscopy; aerosols; algorithms; atmospheric chemistry; chemistry; droplets; environmental science; glycerol; optical traps; particulates; separation; sodium chloride; Show all 13 Subjects
- Abstract:
- ... We present a new algorithm for the analysis of whispering gallery modes (WGMs) found in the cavity enhanced Raman spectra retrieved from optically tweezed droplets. Our algorithm improves the computational scaling when analyzing core–shell droplets (i.e. phase-separated or biphasic droplets) in the aerosol optical tweezers (AOT), making it computationally practical to analyze spectra collected at ...
- DOI:
- 10.1039/c8em00166a
-
http://dx.doi.org/10.1039/c8em00166a
- Author:
- Lim, Wei Yang; Supekar, Omkar D.; Zohrabi, Mo; Gopinath, Juliet T.; Bright, Victor M.
- Source:
- Langmuir 2018 v.34 no.48 pp. 14511-14518
- ISSN:
- 1520-5827
- Subject:
- refractive index, etc ; contact angle; electric potential; electrodes; liquids; microscopy; prediction; remote sensing; wavelengths; Show all 9 Subjects
- Abstract:
- ... Electrowetting adaptive optical devices are versatile, with applications ranging from microscopy to remote sensing. The choice of liquids in these devices governs its tuning range, temporal response, and wavelength of operation. We characterized a liquid system, consisting of 1-phenyl-1-cyclohexene and deionized water, using both lens and prism devices. The liquids have a large contact angle tunin ...
- DOI:
- 10.1021/acs.langmuir.8b02849
-
http://dx.doi.org/10.1021/acs.langmuir.8b02849