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Karina M. Borges; W. Rodney Cooper; Stephen F. Garczynski; Jenita Thinakaran; Andy S. Jensen; David R. Horton; Joseph E. Munyaneza; Isabel Cueva; Nina M. Barcenas
... The psyllid Bactericera maculipennis (Crawford) (Hemiptera: Triozidae) often cohabits field bindweed (Convolvulus arvensis, Solanales: Convolvulaceae) and other plants with the congeneric psyllid, Bactericera cockerelli (Sulc), in the Pacific Northwestern United States. Bactericera cockerelli is a vector of “Candidatus Liberibacter solanacearum,” the pathogen associated with zebra chip disease of ...
alternative medicine; consciousness; focus groups; interviews; musculoskeletal system; patients; placebos
Abstract:
... BACKGROUND: Complementary therapists spend considerable time with their patients, especially in the first consultation. The communication between patients and their therapists is important for raising consciousness and activation of the patient’s self-healing power. Thus, the aims in this study were to delineate what complementary therapists regard as essential in patient consultations, their view ...
electricity; embodied energy; energy costs; infrastructure
Abstract:
... Attempts to assess the possibility of deriving all energy from renewable sources typically deal only with the aggregate amount of energy required, and do not consider the implications and difficulties arising from the need for differing forms of energy. In a 100% renewable system some of these forms will have to be provided by conversion from others, mostly from electricity. Conversion involves in ...
... On the vine, phosphorus deficiency causes a reduction in the development of the root system and growth retardation. This study aimed to define the best option in phosphorus fertilization of vines 'Chardonnay' as well of the quality of grape must. The experiments it was carried out by for the Core for Study, Research and Extension in Enology (NEPE2)/UNIPAMPA - Campus Dom Pedrito, RS, Brazil, with g ...
... In spring 2006 sweet cherry cultivar ʻReginaʼ was planted on Gisela 3, Gisela 5 and Weiroot 72 at three tree spacings 1.5, 2.0 and 2.5 m in several locations of Alpe Adria region in Europe. After the sixth leaf results for tree vigour, productivity and fruit weight were evaluated. Tree vigour was affected by location, rootstock and rootstock × location combination. Trees in Maribor and Sondrio wer ...
Garcinia atroviridis; Garcinia gummi-guta; active ingredients; body weight; common names; cultivars; dried fruit; flavor; fruits; growers; home gardens; income; leaves; mountains; orchards; seedlings; soups; taste; villages; Thailand
Abstract:
... 'Som Kandarn', the local name of a cultivar of Garcinia atroviridis Griff., was found many years ago in Kiriwong village, Nakhon Si Thammarat province, southern Thailand. Growers have planted a few 'Som Kandarn' seedlings in mixed-fruit-cropping orchards in the mountains, especially in low-fertility areas. 'Som Kandarn' has been known in the village as an easy-to-grow fruit tree. Mainly the fruit ...
... Over the last 30 years, (±)-1-(9-fluorenyl)ethyl chloroformate ((±)-FLEC) was used as a chiral derivatizing agent in various analytical applications involving a wide range of endogenous, pharmaceutical and environmentally relevant molecules.This comprehensive review aims to present all the significant aspects related to the state of the art in FLEC labeling and subsequent chiral separation of the ...
... (+)-Meyeniins A–C (1–3), a novel class of sulfur-containing hexahydroimidazo[1,5-c]thiazole derivatives, were isolated from the tubers of Lepidium meyenii (maca) cultivated in Lijiang, Yunnan province, China. Guided by their biosynthetic hypothesis, a stereocontrolled biomimetic synthesis of meyeniins A–C and their individual enantiomers was efficiently accomplished by a combination of a condensat ...
Arabidopsis thaliana; X-ray diffraction; biosynthesis; chemical structure; derivatization; genes; nuclear magnetic resonance spectroscopy; organic compounds
Abstract:
... Two GFPPS linked (+)-thalianatriene (1) and (−)-retigeranin B (2) sesterterpene synthase genes were identified from the genome of Arabidopsis thaliana. 1 possesses an unprecedented 11–6–5 tricyclic ring system, while 2 contains a characteristic 5–5–5–6–5 pentacyclic ring system. Their structures were determined by extensive NMR spectroscopy, chemical derivatization, and X-ray crystallography. The ...
... Endothelial inflammation is an increasingly prevalent condition in the pathogenesis of many cardiovascular diseases. (-)-7(S)-hydroxymatairesinol (7-HMR), a naturally occurring plant lignan, possesses both antioxidant and anti-cancer properties and therefore would be a good strategy to suppress tumor necrosis factor-α (TNF-α)-mediated inflammation in vascular endothelial cells (VECs).: The objecti ...
hydrogen production; irradiation; photocatalysis; polymers; solar radiation
Abstract:
... A two-dimensional imide-based conjugated polymer with a preferred (001) orientation was constructed by solvent-induced assembly. A high performance of 1640 μmol h⁻¹ g⁻¹ for solar-driven photocatalytic hydrogen evolution and an excellent stability were achieved due to tunnelling charge transport between the neighbouring molecular sheets. ...
... Tin disulfide is considered to be a promising anode material for Li ion batteries because of its high theoretical capacity as well as its natural abundance of sulfur and tin. Practical implementation of tin disulfide is, however, strongly hindered by inferior rate performance and poor cycling stability of unoptimized material. In this work, carbon-encapsulated tin disulfide nanoplates with a (101) ...
Ferrisia virgata; adults; alcohols; arthropods; bioassays; carboxylic esters; enantiomers; gas chromatography-mass spectrometry; greenhouses; high performance liquid chromatography; insecticidal properties; insects; males; nuclear magnetic resonance spectroscopy; pyrethrins; sex pheromones; trapping
Abstract:
... Derivatives of 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid (chrysanthemic acid) are classic natural pyrethroids discovered in pyrethrum plants and show insecticidal activity. Chrysanthemic acid, with two asymmetric carbons, has four possible stereoisomers, and most natural pyrethroids have the (1R,3R)-trans configuration. Interestingly, chrysanthemic acid–related structures are ...
... An increasing body of evidence suggests that the volatile pheromones of cerambycid beetles are much more diverse in structure than previously hypothesized. Here, we describe the identification, synthesis, and field testing of (2E,6Z,9Z)-2,6,9-pentadecatrienal as a male-produced aggregation-sex pheromone of the cerambycid Elaphidion mucronatum (Say) (subfamily Cerambycinae, tribe Elaphidiini). This ...
Acharya Suresh; Stark Timo D.; Oh Seung Tack; Jeon Songhee; Pak Sok Cheon; Kim Mina; Hur Jinyoung; Matsutomo Toshiaki; Hofmann Thomas; Hill Rodney A.; Balemba Onesmo B.
... We investigated the antioxidative properties of (2R,3S,2″R,3″R)-manniflavanone (MF) using in vitro assays and examined its effects on myogenesis and lactate-induced oxidative stress in C2C12 cells. MF was purified from Garcinia buchananii stem bark. H₂O₂ and oxygen radical absorbance capacity assays demonstrated that MF is a powerful antioxidant. This finding was supported by diphenylpicrylhydrazi ...
... Three prenylflavanones, (2S)-5,7-dihydroxy-4′-methoxy-8-(3″,3″-dimethylallyl)flavanone (3), (2S)-5,4′-dihydroxy-7-methoxy-6-(3″,3″-dimethylallyl)flavanone (6), 8-prenylnaringenin (11), and a new epimeric pair (2″S/2″R)-(2S)-5,7-dihydroxy-4′-methoxy-6-(2″-hydroxy-3″-methylbut-3″-enyl)flavanones (4a/4b) were isolated together with taraxerone, taraxerol, epitaraxerol, β-sitosterol, oleanolic acid, 1- ...
catalysts; chemical elements; chemical reactions; chemical structure; organic compounds; solvents; stereochemistry
Abstract:
... Four novel chiral imidazolium tagged molecules derived from dipeptide (2S,4R)-Hyp-(S)-Phe-OMe were prepared and evaluated as organocatalysts in the asymmetric aldol reaction using water as solvent. It was found that catalysts incorporating the hexanoyl linker are active down to 5 mol% and afford aldol products with up to 94% yield, up to 98:2 dr and up to 97:3 er. This chiral imidazolium catalyst ...
carbon; chemical reactions; chemical structure; organic compounds
Abstract:
... A strategy for the synthesis of multisubstituted hydrocarbazoles has been developed through (3 + 2)-annulation of p-quinamines and arynes. In this way, new analogs of hydrocarbazoles with quaternary carbon center can be synthesized in satisfactory yield under mild conditions. Furthermore, this (3 + 2)-annulation can be easily scaled-up, and the products can be modified through simple transformatio ...
... Many uncommon non‐methylene‐interrupted fatty acids (NMI FA) are present in limpet gonads, but their biological properties remain unknown. To investigate new biological effects of naturally occurring NMI FA in eukaryotic cells, the biological activities of structurally analogous (4Z,15Z)‐octadecadienoic acid (1), (9Z,20Z)‐tricosadienoic acid (2), and (12Z,23Z)‐hexacosadienoic acid (3) were examine ...
chemistry; composite polymers; electric potential difference; solar cells; solar energy
Abstract:
... We synthesized two types of novel poly(3-alkylthiophene)-free (D)ₙ-b-(A)ₘ conjugated block copolymers: PTQI-block-PNDISs. PTQI-b-PNDIS is the fully conjugated block copolymer, in which the donor block is connected to the acceptor block via a π-conjugated unit. In addition, the donor block was connected to an acceptor block through a non-conjugated alkylene spacer, yielding PTQI-b-PNDISL, which is ...