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- Slutskyy, Yuriy; Overman, Larry E.
- Organic letters 2016 v.18 no.11 pp. 2564-2567
- regioselectivity, etc ; Lewis bases; alkenes; catalytic activity; chemical structure; free radicals; oxalates; redox reactions; Show all 8 Subjects
- ... Visible-light photoredox-catalyzed fragmentation of methyl N-phthalimidoyl oxalate allows the direct construction of a 1,4-dicarbonyl structural motif by a conjugate addition of the methoxycarbonyl radical to reactive Michael acceptors. The regioselectivity of the addition of this alkoxyacyl radical species to electron-deficient olefins is heavily influenced by the electronic nature of the accepto ...
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