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- Roberts, John A. S., et al. Show all 4 Authors
- Proceedings of the National Academy of Sciences of the United States of America 2014 v.111 no.46 pp. 16286-16291
- active sites; arginine; catalysts; catalytic activity; ferredoxin hydrogenase; hydrogen; nickel; oxidation; pH; scaffolding proteins; temperature
- ... Hydrogenases interconvert H ₂ and protons at high rates and with high energy efficiencies, providing inspiration for the development of molecular catalysts. Studies designed to determine how the protein scaffold can influence a catalytically active site have led to the synthesis of amino acid derivatives of [Formula] complexes, [Formula] (CyAA). It is shown that these CyAA derivatives can catalyze ...
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