Jump to Main Content
- Nonaka, Gen-ichiro, et al. Show all 8 Authors
- Journal of organic chemistry 2013 v.78 no.11 pp. 5410-5417
- optical isomerism; organic chemistry; spectral analysis
- ... Prompted by the outcome that the synthesized roxbin B was not identical to the natural roxbin B, the structural determination process and spectral data were re-examined, with the finding that roxbin B was very likely to be 1-O-galloyl-2,3-(R);4,6-(S)-bis-O-hexahydroxydiphenoyl-β-d-glucose (cuspinin). Because the (R)-axial chirality is rare in natural products when the hexahydroxydiphenoyl group br ...