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- Chowdhury, Abhishek Dutta, et al. Show all 4 Authors
- RSC advances 2012 v.2 no.8 pp. 3437-3446
- X-radiation; electron paramagnetic resonance spectroscopy; geometry; nitric oxide; nitrogen dioxide; oxygen; pH; ruthenium; solvents
- ... The nitrosyl complexes, [Ruᴵᴵ(trpy)(L)(NO⁺)Cl]BF₄, BF₄, and [Ruᴵᴵ(trpy)(L)(NO⁺)](BF₄)₂, (BF₄)₂, (trpy = 2,2′:6′,2′′-terpyridine, L⁻ = deprotonated form of unsymmetrical quinaldic acid) have been synthesized. Single crystal X-ray structures of BF₄ and (BF₄)₂ reveal that in the former L⁻ binds to the ruthenium ion selectively in a monodentate fashion through the O⁻ donor whereas the usua ...