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- Author:
- Díaz, Kenya; López-González, Mar; del Castillo, Luis F.; Riande, Evaristo
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 206-213
- ISSN:
- 0376-7388
- Subject:
- activation energy; artificial membranes; carbon dioxide; diffusivity; ethane; ethylene; gases; glass transition temperature; hydrogen; methane; nitrogen; oxygen; permeability; polymers
- Abstract:
- ... This work reports the permeability of hydrogen, nitrogen, oxygen, carbon dioxide, methane, ethane and ethylene across ZIF-8/poly(1,4-phenylen ether-ether-sulfone) hybrid membranes containing 0, 0.10, 0.20 and 0.30 weight fractions of ZIF-8. The glass transition temperature is independent on the filler content suggesting that the filler does not affect the polymer chains mobility. The study was car ...
- DOI:
- 10.1016/j.memsci.2011.08.042
-
http://dx.doi.org/10.1016/j.memsci.2011.08.042
- Author:
- Plackett, David; Siu, Ana; Li, Qingfeng; Pan, Chao; Jensen, Jens Oluf; Nielsen, Søren Fæster; Permyakova, Anastasia A.; Bjerrum, Niels J.
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 78-87
- ISSN:
- 0376-7388
- Subject:
- X-radiation; ambient temperature; artificial membranes; cations; clay; dimensional stability; electric power; fuel cells; hydrogen; hydrogen bonding; infrared spectroscopy; ion exchange; permeability; phosphoric acid; polymers; relative humidity; salts; tensile strength
- Abstract:
- ... Good dispersion of modified laponite clay was achieved in polybenzimidazole (PBI) solutions which, when cast and allowed to dry, resulted in homogeneous and transparent composite membranes containing up to 20wt% clay in the polymer. The clay was organically modified using a series of ammonium and pyridinium salts with varying polarity and hydrogen-bonding capacity. Clay modification by ion-exchang ...
- DOI:
- 10.1016/j.memsci.2011.08.038
-
http://dx.doi.org/10.1016/j.memsci.2011.08.038
- Author:
- Gorey, Colleen; Escobar, Isabel C.
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 272-279
- ISSN:
- 0376-7388
- Subject:
- adsorption; ammonium nitrate; artificial membranes; cellulose acetate; ceric ammonium nitrate; desorption; fouling; hydrophilicity; hydrophobicity; phase transition; polymers; temperature; ultrafiltration
- Abstract:
- ... A potentially low fouling membrane was developed by attaching a stimuli-responsive polymer layer on the surface, which offered the potential to collapse or expand the polymer layer with change in temperature. The phase change arose from the existence of a lower critical solution temperature (LCST) such that the polymer precipitated from solution as the temperature was increased. This capability wa ...
- DOI:
- 10.1016/j.memsci.2011.08.066
-
http://dx.doi.org/10.1016/j.memsci.2011.08.066
- Author:
- Namazi, Hassan; Ahmadi, Hossein
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 280-288
- ISSN:
- 0376-7388
- Subject:
- artificial membranes; polymers; relative humidity; solubility; solvents; temperature; tensile strength
- Abstract:
- ... Poly[2,2′-(m-pyrazolidene)-5,5′-bibenzimidazole] (PPBI) was synthesized via polycondensation reaction of pyrazole-3,5-dicarboxylic acid and 3,3′,4,4′-tetraaminobiphenyle (TAB) in polyphosphoric medium. Then the novel proton conducting polymer, butylsulfonated PPBI (BS-PPBI), was synthesized through the ring-opening reaction of 1,4-butanesultone by the reactive N–H groups of PPBI. The solubility of ...
- DOI:
- 10.1016/j.memsci.2011.08.065
-
http://dx.doi.org/10.1016/j.memsci.2011.08.065
- Author:
- Samimi, Armin; Mousavi, Seyyed Abbas; Moallemzadeh, Alireza; Roostaazad, Reza; Hesampour, Mehrdad; Pihlajamäki, Arto; Mänttäri, Mika
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 197-205
- ISSN:
- 0376-7388
- Subject:
- air; artificial membranes; energy-dispersive X-ray analysis; humidifiers; mechanical properties; nanoparticles; polymers; relative humidity; scanning electron microscopy; temperature; titanium dioxide
- Abstract:
- ... Polysulfone (PSU) and polyethersulfone (PES) porous membranes; and mixed polymer with nanoparticles TiO₂, were prepared for air humidification. The mechanical properties and morphology of these membranes were studied by Tensile tester and SEM/EDX. The effects of membrane composition and operating factors on humidifier performance were investigated. The results revealed that the membrane compositio ...
- DOI:
- 10.1016/j.memsci.2011.08.043
-
http://dx.doi.org/10.1016/j.memsci.2011.08.043
- Author:
- Bakeri, Gh.; Matsuura, T.; Ismail, A.F.
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 159-169
- ISSN:
- 0376-7388
- Subject:
- absorption; acetic acid; artificial membranes; ethanol; glycerol; methanol; molecular weight; polymers; porosity; solvents; spinning; thermodynamics; viscosity
- Abstract:
- ... Low molecular weight organic compounds were added to the spinning dope as phase inversion promoters and their effects on the structure of polyetherimide (PEI) hollow fibers as well as their performance as membrane contactor were investigated. Water, methanol, ethanol, glycerol and acetic acid were added individually to the solvent NMP to prepare a dope containing 15wt% PEI, 4wt% additive, 81wt% NM ...
- DOI:
- 10.1016/j.memsci.2011.08.048
-
http://dx.doi.org/10.1016/j.memsci.2011.08.048
- Author:
- Widjojo, Natalia; Chung, Tai-Shung; Weber, Martin; Maletzko, Christian; Warzelhan, Volker
- Source:
- Journal of membrane science 2011 v.383 no.1-2 pp. 214-223
- ISSN:
- 0376-7388
- Subject:
- artificial membranes; desalination; hydrophilicity; osmosis; polymerization; polymers; seawater; sodium chloride
- Abstract:
- ... A new approach to fabricate thin film composite (TFC) membranes via interfacial polymerization for forward osmosis (FO) applications has revealed that it is possible to design TFC-FO membranes with fully sponge-like structure and likely anti-fouling characteristics while maintaining a high water flux. Not only does the sulphonated material in the substrate of TFC-FO membranes play the key role to ...
- DOI:
- 10.1016/j.memsci.2011.08.041
-
http://dx.doi.org/10.1016/j.memsci.2011.08.041