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- Author:
- Maia, Joaquim; Cruz, Jose Manuel; Sendón, Raquel; Bustos, Juana; Cirugeda, Maria Eugenia; Sanchez, José Juan; Paseiro, Perfecto
- Source:
- Food research international 2010 v.43 no.5 pp. 1283-1288
- ISSN:
- 0963-9969
- Subject:
- amines; aminolysis; bisphenol A; bottles; depolymerization; fluorescence; foods; gas chromatography; high performance liquid chromatography; human health; mass spectrometry; milk; protein degradation
- Abstract:
- ... The key block for the production of polycarbonate (PC) is bisphenol A (BPA). Recent studies have proven that this monomer is able to migrate from PC baby bottles into food simulants and, although this is a polemical subject, numerous investigations indicate that BPA may have an effect on the human health. For these reasons, BPA safety regarding human exposure has recently become an alarming issue. ...
- DOI:
- 10.1016/j.foodres.2010.03.014
-
http://dx.doi.org/10.1016/j.foodres.2010.03.014
- Author:
- Yang, Ying; Kluger, Ronald
- Source:
- Chemical communications 2010 v.46 no.40 pp. 7557-7559
- ISSN:
- 1364-548X
- Subject:
- aminolysis; azides; crosslinking; hemoglobin
- Abstract:
- ... A cross-linked hemoglobin bis-tetramer with oxygenation properties appropriate for a red cell substitute is produced by CuAAC conjugation of a dialkyne and two equivalents of an azide of β,β-cross-linked hemoglobin. The latter is formed efficiently by the aminolysis of the 3,5-dibromosalicylate ester of the β-82-β′-82-bis trimesyl amide of human hemoglobin A with (4-aminomethyl)benzyl azide. ...
- DOI:
- 10.1039/c0cc02023k
-
https://dx.doi.org/10.1039/c0cc02023k
- Author:
- Usuki, Hirokazu; Uesugi, Yoshiko; Arima, Jiro; Yamamoto, Yukihiro; Iwabuchi, Masaki; Hatanaka, Tadashi
- Source:
- Chemical communications 2010 v.46 no.4 pp. 580-582
- ISSN:
- 1364-548X
- Subject:
- Streptomyces thermocyaneoviolaceus; amino acids; aminolysis; aminopeptidases; catalytic activity; chemical communication; chemical compounds; cost effectiveness; dipeptides
- Abstract:
- ... Aminopeptidase from Streptomyces thermocyaneoviolaceus NBRC14271 was engineered into transaminopeptidase and used to catalyze an aminolysis reaction to give linear and cyclic dipeptides from cost-effective substrates such as the ester derivatives of amino acids. ...
- DOI:
- 10.1039/b914320c
-
https://dx.doi.org/10.1039/b914320c
- Author:
- Wiss, Kerstin T.; Theato, Patrick
- Source:
- Journal of polymer science 2010 v.48 no.21 pp. 4758-4767
- ISSN:
- 0887-624X
- Subject:
- alkynes; aminolysis; composite polymers; nuclear magnetic resonance spectroscopy; polymerization; polymethylmethacrylate; stable isotopes
- Abstract:
- ... The synthesis of block copolymers via polymer conjugation of well-defined building blocks offers excellent control over the structures obtained, but often several coupling strategies need to be explored to find an efficient one depending on the building blocks. To facilitate the synthesis of polymers with adjustable functional end-groups for polymer conjugation, we report on the combination of act ...
- DOI:
- 10.1002/pola.24267
-
http://dx.doi.org/10.1002/pola.24267
- Author:
- Varman, Mahendra; Miyafuji, Hisashi; Saka, Shiro
- Source:
- Journal of wood science 2010 v.56 no.6 pp. 488-494
- ISSN:
- 1435-0211
- Subject:
- Elaeis guineensis; aminolysis; fractionation; fronds; lignin; mesocarp; oilseed cakes; oxidation; water treatment
- Abstract:
- ... In order to investigate the potential for efficient utilization of oil palm (Elaeis guineensis), supercritical water treatment (at 380°C and 100 MPa for 8 s) was applied to fractionate extractives-free samples into water-soluble portion and water-insoluble portion. The water-insoluble portion was further fractionated into methanol-soluble portion and methanol-insoluble residue. Samples were prepar ...
- DOI:
- 10.1007/s10086-010-1124-3
-
https://dx.doi.org/10.1007/s10086-010-1124-3
- Author:
- Sinha, Vijaykumar; Patel, Mayank R.; Patel, Jigar V.
- Source:
- Journal of polymers and the environment 2010 v.18 no.1 pp. 8-25
- ISSN:
- 1566-2543
- Subject:
- aminolysis; glycolysis; hydrolysis; methanolysis; pollution; polymers; recycling; socioeconomics; waste disposal
- Abstract:
- ... The paper reviews the problem due to the use and disposal of synthetic polymers to the environment and its solutions; in particular poly (ethylene terphthalate). Wide spread application and non-biodegradability of the PET creates huge amounts of waste and disposal, tend to a serious problem. The most important cause for recycling and reprocessing the waste PET has arisen from the awareness and con ...
- DOI:
- 10.1007/s10924-008-0106-7
-
http://dx.doi.org/10.1007/s10924-008-0106-7
- Author:
- Avadanei, Mihaela; Drobota, Mioara; Stoica, Iuliana; Rusu, Elena; Barboiu, Virgil
- Source:
- Journal of polymer science 2010 v.48 no.23 pp. 5456-5467
- ISSN:
- 0887-624X
- Subject:
- Fourier transform infrared spectroscopy; absorption; amines; aminolysis; atomic force microscopy; delamination; polyethylene terephthalates; scanning electron microscopy; weight loss
- Abstract:
- ... Surface of biaxially oriented poly(ethylene terephthalate) films was chemically modified by exposure to ethylenediamine (EDA), triethylenetetramine (TETA), and tetraethylenepentamine (TEPA) for different treatment times. Variable angle attenuated total reflection Fourier transform infrared (ATR‐FTIR) spectroscopy was used in conjunction with weight loss measurements, scanning electron microscopy ( ...
- DOI:
- 10.1002/pola.24354
-
http://dx.doi.org/10.1002/pola.24354
- Author:
- Min, Eun Hee; Ting, S.R. Simon; Billon, Laurent; Stenzel, Martina H.
- Source:
- Journal of polymer science 2010 v.48 no.15 pp. 3440-3455
- ISSN:
- 0887-624X
- Subject:
- acrylamides; aminolysis; concanavalin A; contact angle; crosslinking; fluorescence microscopy; glucosamine; glucose; molecular weight; polymerization; polymers; solvents; temperature
- Abstract:
- ... Stable and surface-modified films with regular porous arrays were created by crosslinking honeycomb structured porous films prepared via breath figures from poly(styrene-co-maleic anhydride). The formation of open or closed pores of the films was controlled by the addition of a polyion complex. Subsequent crosslinking of the films with 1,8-diaminooctane led to films, which maintain their structure ...
- DOI:
- 10.1002/pola.24129
-
http://dx.doi.org/10.1002/pola.24129
- Author:
- Weiß, Markus; Brinkmann, Tobias; Gröger, Harald
- Source:
- Green chemistry 2010 v.12 no.9 pp. 1580-1588
- ISSN:
- 1463-9270
- Subject:
- Pseudozyma antarctica; aminolysis; carboxylic ester hydrolases; chromatography; enantioselectivity; environmental assessment; environmental impact; green chemistry; hydrogenation; hydrolysis; moieties; solvents
- Abstract:
- ... An improved, greener process for the enantioselective chemoenzymatic synthesis of (S)-3-aminobutanoic acid has been developed. Reaction steps comprise an initial aza-Michael addition starting from cheap prochiral compounds, subsequent enzymatic resolution via aminolysis using commercially available Candida antarctica lipase B in a solvent-free one-pot process, hydrolysis of the resulting ester and ...
- DOI:
- 10.1039/c002721a
-
http://dx.doi.org/10.1039/c002721a