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1. Dehydration of the nanoporous coordination framework Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆]·4(H₂O): single crystal to single crystal transformation and negative thermal expansion in Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆]

Author:
Halder, Gregory J.,   et al.   ; Pretsch, Thorsten; Chapman, Karena W.; Kepert, Cameron J.;     Show all 4 Authors
Source:
Chemical communications 2006 no.17 pp. 1857-1859
ISSN:
1364-548X
Subject:
cations; chemical reactions; desorption; erbium; nanopores; thermal expansion
Abstract:
... Desorption of bound and unbound water molecules from the nanoporous coordination framework Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆]·4H₂O to form the apohost, Erⁱⁱⁱ[Coⁱⁱⁱ(CN)₆], proceeds via a single crystal to single crystal transformation in which the Er(iii) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties. ...
DOI:
10.1039/b601344a