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... The extent of protein adsorption is an important consideration in the biocompatibility of biomaterials. Various experimental methods can be used to determine the quantity of protein adsorbed, but the results usually differ. In the present work, self-assembled monolayers (SAMs) were used to prepare a series of model gold surfaces varying systematically in water wettability, from hydrophilic to hydr ...
equations; heat; hydraulic conductivity; models; saturated flow; surveys; temperature profiles; user interface; United States
Abstract:
... A new computer program, 1DTempPro, is presented for the analysis of vertical one‐dimensional (1D) temperature profiles under saturated flow conditions. 1DTempPro is a graphical user interface to the U.S. Geological Survey code Variably Saturated 2‐Dimensional Heat Transport (VS2DH), which numerically solves the flow and heat‐transport equations. Pre‐ and postprocessor features allow the user to ca ...
biochar; biomass; energy; equations; gasification; heat; mass transfer; models; momentum; reaction kinetics; renewable energy sources; synthesis gas; temperature
Abstract:
... A two dimensional modeling is developed in the reduction zone of a fixed bed downdraft biomass gasifier based on mass, energy and momentum conservation equations written for the solid and fluid phases and coupled with chemical kinetics. Kinetics parameters are derived from previous works and an effectiveness factor was used in the reaction rate correlation to quantify the mass transfer resistance ...
adverse effects; bags; emulsions; energy; enteral feeding; equations; fatty liver; glutamine; hyperglycemia; inflammation; lipids; malnutrition; mortality; overfeeding; patients; sepsis (infection); total parenteral nutrition; Australia; Belgium; Israel; United States
Abstract:
... Fifty years after the clinical introduction of total parenteral nutrition (TPN) the Arvid Wretlind lecture is an opportunity to critically analyse the evolution and changes that have marked its development and clinical use. The standard crystalline amino acid solutions, while devoid of side effects, remain incomplete regarding their composition (e.g. glutamine). Lipid emulsions have evolved tremen ...
... Previous efforts to estimate the daily energy expenditure of American Black Ducks (Anas rubripes) have relied upon diurnal behavior observations or predictive allometric equations. American Black Duck behavior was quantified during morning crepuscular, diurnal, evening crepuscular and nocturnal periods to create a 24-hr time-energy budget. Behaviors and energy expenditure differed between periods ...
cooling; cryosurgery; equations; freezing; heat transfer; heat transfer coefficient; hydrocolloids; stainless steel; surface temperature
Abstract:
... This paper describes the development of a novel cryoprobe with the same size as a 24-gauge injection needle and the evaluation of its cooling performance. This ultrafine cryoprobe was designed to reduce the invasiveness and extend application areas of cryosurgery. The ultrafine cryoprobe has a double-tube structure and consists of two stainless steel microtubes. The outer diameter of the cryoprobe ...
... A depth-averaged finite difference two-dimensional hydrodynamic-morphological and sediment transport model is presented in the orthogonal curvilinear grid system. The sediment submodel considers the influence of selective sorting by modifying the sediment transport capacity and incorporates a simple simulation method to describe changes in the grain size distribution of the bed surface by solving ...
bedload; case studies; equations; mathematical models; prediction; sediments; space and time; water resources
Abstract:
... Recent advances in the simulation of free surface flows over mobile bed have shown that accurate and stable results in realistic problems can be provided if an appropriate coupling between the shallow water equations (SWE) and the Exner equation is performed. This coupling can be done if using a suitable Jacobian matrix. As a result, faithful numerical predictions are available for a wide range of ...
... Induction of endonucleolytic DNA cleavage is an essential event that links the initiating stimuli to the final effects of cells. The cleavage efficiency and thus the final yield could be affected by many factors, including structures of DNA substrates, composite structures of enzymes–substrates or enzymes–nucleic analogs and so on. However, it is not clear whether a nucleotide derivative-substitut ...
... A 3-D numerical model has been developed to simulate dam-break flow over uneven beds in irregular domains. The model solves the Reynolds-Averaged Navier–Stokes equations (RANS) using a finite-volume method based on collocated mesh that fits the solid boundaries such as bed and walls. The velocity and pressure coupling is achieved using the PISO algorithm and the Rhie and Chow’s momentum interpolat ...
... The current work is aimed to simulate the production of high quality fatty acid methyl ester (biodiesel) production from palm oil in a micro porous ceramic membrane reactor. The TiO2/Al2O3 ceramic membrane was used as the separator and catalytic bed. It was packed with potassium hydroxide catalyst supported on palm shell activated carbon. The investigation of component distribution within the syst ...
... A 3D virtual fruit tissue generator is presented that can distinctly define the microstructural components of a fruit tissue and that can be used to model important physical processes such as gas transport during controlled atmosphere storage. The model is based on the biomechanics of plant cells in tissues. The main merit of this algorithm is that it can account for typical differences in interce ...
algorithms; anisotropy; computers; electric field; electromagnetic field; equations; finite element analysis; isotropy; mathematical models
Abstract:
... This paper presents a linear edge-based finite element method for numerical modeling of 3D controlled-source electromagnetic data in an anisotropic conductive medium. We use a nonuniform rectangular mesh in order to capture the rapid change of diffusive electromagnetic field within the regions of anomalous conductivity and close to the location of the source. In order to avoid the source singulari ...
basins; case studies; computers; equations; finite element analysis; glaciation; groundwater; groundwater flow; ice; models
Abstract:
... Pleistocene glaciation led to temporal and spatial variations of sub-surface pore fluid pressure. In basins covered by ice sheets, fluid flow and recharge rates are strongly elevated during glaciations as compared to inter-glacial periods. Present-day hydrogeological conditions across formerly glaciated areas are likely to still reflect the impact of glaciations that ended locally more than 10 tho ...
... The extremely strong Wenchuan earthquake triggered thousands of landslides in Sichuan Province, China. Flow-like landslides, such as the Tangjiashan, Wangjiayan, and Donghekou landslides were among the most destructive, causing many casualties and serious economic damage. It is therefore important to identify the flow mechanisms and investigate the specific characteristics of these flow-like lands ...
... Vibratory harvest is the most appropriate and efficient way to harvest Chinese hickory (Carya cathayensis Sarg.) nuts because of the hilly growth environment and scattered shooting architecture. To develop a mechanical harvester that can be adapted to different Chinese hickory trees, a three-dimensional (3D) model of the tree should be obtained and its dynamics parameters identified. This paper in ...
... For the first time, a kinetic model considering four-dimensional Smith–Ewart equations is presented to simultaneously calculate the time evolution of the conversion, number-average chain length, dispersity, end-group functionality (EGF), and short chain branching (SCB) content for the miniemulsion NMP of n-butyl acrylate (nBuA), initiated by poly(nBuA)-(N-tert-butyl-N-(1-diethylphosphono-2,2-dimet ...
... We introduce a version of the DICE-2007 model designed for uncertainty analysis. DICE is a wide-spread deterministic integrated assessment model of climate change. Climate change, long-term economic development, and their interactions are highly uncertain. The quantitative analysis of optimal mitigation policy under uncertainty requires a recursive dynamic programming implementation of integrated ...
... Identification and quantification of groundwater and surface-water interactions provide important scientific insights for managing groundwater and surface-water conjunctively. This is especially relevant in semi-arid areas where groundwater is often the main source to feed river discharge and to maintain groundwater dependent ecosystems. Multiple field measurements were taken in the semi-arid Bula ...
equations; latitude; longitude; meteorological data; models; prediction; regression analysis; renewable energy sources; sea level; solar radiation; time series analysis
Abstract:
... Hourly and daily measurements of total and diffuse solar radiation and sunshine duration are analyzed. Three-year measurements of the available meteorological data in Mosul (latitude 36° 19′ N, longitude 43° 09′ E and 223 m above mean sea level) are used in this study. The present work involves two parts; in the first one, monthly mean daily and hourly of total and diffuse solar radiation are anal ...
chemical compounds; chemical reactions; chemical structure; equations
Abstract:
... Algebraic equations for transition frequencies and intensities are derived for the AXX′₂ spin system. In favourable cases the resonance frequency νA and all coupling parameters JAX, JAX′ and JXX′ can be extracted from the A-part of the AXX′₂ spectrum. Examples of deceptively simple spectra are discussed. ...
... The effect of abamectin was evaluated on the functional response of green lacewing, Chrysoperla carnea (Stephens) (Neuroptera: Chrysopidae), at seven egg densities of tobacco budworm, Heliothis virescens (Fabricius), and fall armyworm, Spodoptera frugiperda (J. E. Smith) (Lepidoptera: Noctuidae), using Holling s disc equation. Functional response of green lacewing was Type II, indicating that as p ...
convection; energy conservation; equations; finite element analysis; geothermal energy; groundwater flow; heat exchangers; heat pumps; insulating materials; mass flow; mathematical models; petroleum; temperature; thermal conductivity; wells; Persian Gulf
Abstract:
... A reliable heat transfer model was developed to determine the performance of a double pipe heat exchanger retrofitted to an abandoned petroleum well. The proposed model is compared against an analytical heat transfer model and two numerical models, in order to determine the reliability and accuracy of the proposed model. Rock mass properties and well dimensions are based on realistic averages, wit ...
... The photodegradation of indoxacarb, a broad spectrum foliar insecticide and spinosad, a natural insecticide containing two active ingredients, spinosyn A (major component) and spinosyn D (minor component), was studied in aqueous suspensions of binary (ZnO and TiO₂) and ternary (Zn₂TiO₄ and ZnTiO₃) oxides under artificial light (300–460 nm) irradiation. As expected, the influence of the semiconduct ...
... The calculation of the photochemical yield of simple reactions in viscous media was discussed earlier in a rather formal way. In this paper the basic equation will be derived in a more convenient way and the numeric results of an application to photoisomerization are given. The main purpose is to demonstrate the possibility to handle even complicated reactions. ...
X-radiation; algorithms; confidence interval; detection limit; equations; fluorescence; normal distribution
Abstract:
... Blank experiment in X-ray fluorescence analysis is actually a measurement of the background at the analytical line of an element to be determined. Numerous factors affecting the appearance and registration of the background signal are responsible for its normal distribution. In this work, the possibility of using real samples with low analyte concentrations as blank samples is substantiated. A cri ...
... The woodlands in the south-west of the Argentinean pampas are dominated by Prosopis Caldenia Burkart (calden). The current deforestation rate of this woodlands is 0.82% per year. Different compensation initiatives have begun that recognize the role of forests as environmental service providers. The financial incentives they offer make it necessary to quantify the amount of carbon stored in the for ...
equations; interphase; mathematical models; water waves
Abstract:
... In this paper, for both the sharp front surface quasi-geostrophic equation and the Muskat problem, we rule out the “splash singularity” blow-up scenario; in other words, we prove that the contours evolving from either of these systems cannot intersect at a single point while the free boundary remains smooth. Splash singularities have been shown to hold for the free boundary incompressible Euler eq ...
... In a gas–particle mixture particles of different makes and sizes may have different local temperatures and are, therefore, modeled with separate energy equations. If the important radiative heat transfer contributions are determined with sophisticated spectral models such as k-distributions, spectral information is lost during the reordering process, making it difficult to separate the resulting r ...
absorbents; absorption; alkalinity; ammonia; desulfurization; engineering; equations; liquids; mass transfer; salt concentration; silicon carbide; solutions; sulfur dioxide
Abstract:
... The emission of SO₂ leads to serious environmental problems, which has attracted increasing attention. In this work, a cocurrent rotating packed bed (CO-RPB) with a novel SiC structured packing was employed as a process intensification candidate to upgrade existing desulfurization systems. The effects of rotating speed, gas flow rate, liquid flow rate, SO₂ inlet concentration, total salt concentra ...
deformation; root systems; stems; equations; heat; leaf area; sap flow; soil; trees; Picea pungens; water content; Pseudotsuga menziesii; air flow; forests
Abstract:
... AIMS: The study was focused on comparing the results of the three instrumental methods applied simultaneously for root studies in several tree species representing contrasting situations: root systems of different structure and stems of a wide range of diameters (especially when considering their resistivity). We want to learn properties of the methods, make some improvements and test their validi ...
... Triclosan, an antimicrobial agent commonly used in down‐the‐drain consumer products, is toxic to freshwater microalgae. However, the rapid photolysis and pH‐dependent dissociation of this compound may give rise to uncertainty in growth inhibition tests with freshwater microalgae, if these are not well characterized. Methods are presented to minimize these uncertainties by stabilizing pH with an or ...
... The effect of small-scale surface roughness on measurements with PI-SWERL (The Portable In-Situ Wind Erosion Laboratory) was investigated using a viscometer-type device. The relationship between shear stress at the soil surface and PI-SWERL rate of rotation (RPM) was determined empirically with test surfaces of varying roughness including fine to coarse sandpaper, small domed structures (H=2.5–2.9 ...
... Previous methods for analyzing protein–ligand binding events using the quartz crystal microbalance with dissipation monitoring (QCM-D) fail to account for unintended binding that inevitably occurs during surface measurements and obscure kinetic information. In this article, we present a system of differential equations that accounts for both reversible and irreversible unintended interactions. Thi ...
Angus; Brahman; Hereford; Santa Gertrudis; Shorthorn; beef cattle; body composition; breeding value; carcass characteristics; cattle breeding; crossing; equations; genetic correlation; marker-assisted selection; models; phenotypic correlation; prediction; sires; slaughterhouses; young animals
Abstract:
... BACKGROUND: The major obstacles for the implementation of genomic selection in Australian beef cattle are the variety of breeds and in general, small numbers of genotyped and phenotyped individuals per breed. The Australian Beef Cooperative Research Center (Beef CRC) investigated these issues by deriving genomic prediction equations (PE) from a training set of animals that covers a range of breeds ...
... Changes related to chronological age are seen in both hard and soft tissue. A number of methods for age estimation have been proposed which can be classified in four categories, namely, clinical, radiological, histological and chemical analysis. In forensic odontology, age estimation based on tooth development is universally accepted method. The panoramic radiographs of 500 healthy Goan, Indian ch ...
body water; equations; fasting; men; metabolism; mineral content; models; obesity; very low calorie diet; weight loss; women
Abstract:
... The 4-component (4-C) model is the reference method to measure fat mass (FM). Simpler 2-component (2-C) models are widely used to assess FM. We hypothesised that an aggregate 2-C model may improve accuracy of FM assessment during weight loss (WL). One hundred and six overweight and obese men and women were enrolled in different WL programs (fasting, very low energy diet, low energy diet). Body den ...
... Background: Serum osmolality is an accurate indicator of hydration status in older adults. Glucose, urea, and electrolyte concentrations are used to calculate serum osmolarity, which is an indirect estimate of serum osmolality, but which serum osmolarity equations best predict serum osmolality in the elderly is unclear.Objective: We assessed the agreement of measured serum osmolality with calculat ...
algorithms; body mass index; calorimetry; energy requirements; equations; models; prediction; resting energy expenditure; t-test
Abstract:
... The measurement of resting energy expenditure (REE) is important to assess individual total energy requirements in older subjects. The validity of REE prediction equations in this population has not been thoroughly evaluated and therefore the main aim of this analysis was to assess the accuracy of REE prediction equations in older subjects.Weight, height and body mass index (BMI) were measured. RE ...
... An accurate computational method for the classical simulation of the two-dimensional vibrational spectra is presented. The method refines our previous computational method for the third order vibrational response function in the classical limit, and it enables capturing the diagonal elongation and its waiting time (T) dependence widely observed in experimental two-dimensional infrared (2D IR) spec ...
Holstein; corpus luteum; dairy cows; equations; lactation; prediction; progesterone; ultrasonography
Abstract:
... To develop an ultrasonographic assay for determining plasma progesterone concentration (P₄) as < 1 ng/ml or ≥ 1 ng/ml, the corpus luteum (CL) area and P₄were measured in 1094 multiparous Holstein cows. The area‐measuring function and frozen images were used to outline and measure CL imaged via ultrasonography, and CL area was estimated as a polygon of a continuation straight line. A significant co ...
... This research examines the acid hydrolysis of Curcuma longa waste, to obtain the hydrolysate containing lactic acid and ethanol fermentative sugars. A central composite design for describing regression equations of variables was used. The selected optimum condition was 4.91% sulphuric acid, 122.68°C and 50min using the desirability function under the following conditions: the maximum reducing suga ...
aqueous solutions; binding capacity; calcium; cations; chelating agents; chemical speciation; equations; glass electrodes; industrial applications; ionic strength; ligands; magnesium; metal ions; potassium; potassium chloride; protons; sodium; sodium chloride; specific ion electrodes; temperature; thermodynamics
Abstract:
... Diethylenetriamine-N,N,N′,N″,N″-pentakis(methylenephosphonic acid) (DTPMPA) is used in a wide range of industrial applications, mainly because of its binding ability toward several metal cations. Because of difficulties in its synthesis and purification, very little reliable data have been reported in the literature about the coordination chemistry of this ligand in aqueous solution. For these rea ...
aquatic environment; cesium; clay; data collection; electrolytes; equations; hydrochloric acid; mica; models; pH; soil erosion; sorption; sorption isotherms; surface area
Abstract:
... Sericite is mica-based natural clay that is annealed at 800 °C for 4 h, followed by acid activation using 3.0 mol L−1 HCl at 100 °C. The interaction of cesium (I), Cs(I), with sericite could provide useful data for the study of soil erosion or mass water movement utilizing the natural radioactive Cs. In this study sericite and activated sericite were used to assess their suitability in the attenua ...
Tristachya; canopy; dry season; ecophysiology; equations; evapotranspiration; field capacity; heat transfer; humidity; savannas; soil water; soil water content; teams; temperature; volatilization; wet season; Republic of the Congo
Abstract:
... The aim of this work is to study the actual evapotranspiration and surface resistance of the savannah using the Bowen-ratio method for two contrasted periods, dry and rainy season. The reliability of this method has been assessed by comparison with the Monteith equation and the soil-water balance method in a 90% Loudetia arundinacea dominated savannah (Pointe Noire, Congo). Our results relate to t ...
Bacillariophyta; Chlorophyta; Salmo; algae; algorithms; biomass; case studies; climate change; data collection; ecosystems; equations; eutrophication; lakes; mortality; nitrate nitrogen; nutrients; pollution load; sediments; simulation models; water temperature; zooplankton
Abstract:
... SALMO (Simulation by means of an Analytical Lake Model) describes the seasonal dynamics of PO4-P, NO3-N, detritus, chlorophyta, bacillariophyta, cyanophyta and cladocerans of the epilimnion and hypolimnion of stratified lakes by complex ordinary differential equations. This study adapted the model for shallow polymictic lakes and developed a real-coded genetic algorithm to optimize key parameters ...
data analysis; equations; linear models; regression analysis
Abstract:
... This article studies global testing of the slope function in functional linear regression models. A major challenge in functional global testing is to choose the dimension of projection when approximating the functional regression model by a finite dimensional multivariate linear regression model. We develop a new method that simultaneously tests the slope vectors in a sequence of functional princ ...
data analysis; electroencephalography; equations; models
Abstract:
... We present a methodology for dealing with recent challenges in testing global hypotheses using multivariate observations. The proposed tests target situations, often arising in emerging applications of neuroimaging, where the sample size n is relatively small compared with the observations’ dimension K . We employ adaptive designs allowing for sequential modifications of the test statistics adapti ...
... Environmental variation along geographic gradients determines the distribution of animals and plants trough both direct and indirect effects. We analyze the relative contribution of climate and vegetation structure variations along a Mediterranean altitude gradient on the patterns of abundance and occurrence of the greater white-toothed shrew Crocidura russula, a generalist small mammal whose dist ...
... Adiabatic processes in the liquid–vapor two-phase region were studied with several equations of state. The comparison of the resulting isentropes, particularly their patterns in quality (fraction of vapor phase) vs temperature diagrams, indicates that there are two different classes of fluids: One class shows a simple pattern where isentropes entering the two-phase region never leave it again; the ...
... In order to investigate the mechanism of adsorption of reactive dyes from the textile industry on ash from heating plant produced by brown coal combustion, some characteristic sorption constants are determined using Langergren adsorption equations for pseudo-fi rst and pseudo-second order. Combined kinetic models of pseudo-first order and pseudo-second order can provide a simple but satisfactory exp ...
... In the present study a novel biomass, derived from the pulp of Saccharum bengalense , was used as an adsorbent material for the removal of Pb (II) ions from aqueous solution. After 50 minutes contact time, almost 92% lead removal was possible at pH 6.0 under batch test conditions. The experimental data was analyzed using Langmuir, Freundlich, Timken and Dubinin-Radushkevich two parameters isotherm ...
adsorbents; adsorption; carbon dioxide; carbon monoxide; coordination polymers; engineering; enthalpy; equations; gases; methane; models; nitrogen; normal distribution; sorption isotherms; temperature
Abstract:
... In this work, we report adsorption isotherms of various industrially important gases, viz. CO₂, CO, CH₄, and N₂ on MIL-53(Al) metal organic framework (MOF). The isotherms were measured in the range of 0–25 bar over a wide temperature range (294–350 K). The structural transformation of the adsorbent and the resulting breathing phenomenon were observed only in the case of CO₂ adsorption at 294 and 3 ...
... Manganese (II,III) oxide (Mn ₃O ₄) crystalline powder was evaluated as a potential sorbent for removal of arsenic (V) from water. Adsorption isotherm experiments were carried out to determine the adsorption capacity using de-ionized (DI) water, a synthetic solution containing bicarbonate alkalinity, and two natual groundwater samples. Adsorption isotherm data followed the Langmuir and Freundlich e ...
... Adsorption isotherm data of some alkyl aromatic hydrocarbons (benzene, toluene, ethylbenzene, o-xylene, m-xylene and p-xylene) measured in the temperature range of 423–523K on a partially dealuminated faujasite type DAY F20 zeolite by inverse gas chromatography are presented in this work. The temperature dependent form of Tóth's equation has been fitted to the multiple temperature adsorption isoth ...
... In recent decades, 2-butyl-2-ethyl-1,3-propanediol (BEPD) has been extensively evaluated as an efficient extractant for the recovery of boron from brine solutions commonly present in magnesium chloride. The BEPD leaked into the raffinate must be recovered in order to make the process of solvent extraction cost-efficient. The present study examined the feasibility of a commercialized coal-based act ...
... The adsorption behavior of benzoate, citrate, tartrate and glutamate on calcite dispersed in water was studied. At r. t. and pH = 9, the molar amount of substrate adsorbed decreases with increasing number of carboxylic groups in the molecule. Thus, monofunctional benzoate adsorbs in significantly higher molar amounts than trifunctional citrate. A more alkaline environment (pH = 12.5) has almost no ...
... Graphene oxide (GO) nanosheets were used as adsorbent material for the removal of clofibric acid (CA) which was difficult to be removed from wastewater by traditional wastewater treatment technique. Adsorption kinetics, adsorption equilibrium, and effect of pH, ionic strength, and humic acid (HA) of the adsorption of CA onto the GO nanosheets in aqueous solution were investigated in detail. Adsorp ...
... Novel chelating sponge (PVA-M-H) was prepared with polyvinyl alcohol by graft polymerization and nucleophilic substitution. E.A, SEM, FT-IR, 13CNMR, and XPS analyses were used to characterize PVA-M-H. The equilibrium adsorption capacities of PVA-M-H for Ni(II) and Cd(II) were 65.39 and 125.11mgg−1, respectively. Within the range of 278–308K, the adsorption enthalpy changes of Ni(II) and Cd(II) on ...
... The aim of the present study was to investigate the adsorption properties of aminopropyltriethoxysilane (APS) modified microfibrillated cellulose (MFC) in aqueous solutions containing Ni(II), Cu(II) and Cd(II) ions. The modified adsorbents were characterized using elemental analysis, Fourier transform infrared spectroscopy, SEM and zeta potential analysis. The adsorption and regeneration studies w ...
... Nano zirconia was used for the adsorption of Orange G dye from aqueous solutions. The best fit linear and nonlinear equations for the two adsorption isotherms and kinetic models, namely the Langmuir and Freundlich adsorption isotherms and pseudo-first-order and pseudo-second-order equations, were compared. The sum of the normalized errors and the coefficient of determination were used to determine ...
... The influence of the addition of the nonionic surfactants dodecyl dimethyl phosphine oxide (C₁₂DMPO), tetradecyl dimethyl phosphine oxide (C₁₄DMPO), decyl alcohol (C₁₀OH), and C₁₀EO₅ at concentrations between 10–⁵ and 10–¹ mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10–⁵ mmol/L on the surface tension is studied. It is shown that a significant decreas ...
... Triphenyl Phosphine Oxide (TPO) which is known as a strong inhibitor of electrode processes in aqueous solutions is progressively adsorbed at the dme from methanol in the potential range -0.5 to -1.3 volts as compared with water, -0.15 to -1.6 volts (Ag/AgCl), for the concentrations studied. Adsorption activity as well as the sharpness of the desorption peak of TPO decrease in the order: water > 5 ...
... Bone char has been used as a low-cost adsorbent for the removal of As(V) from waste water. The batch experiments show that the Langmuir isotherm describes well the adsorption behavior. The adsorption process follows a pseudo-second-order kinetic model. The column experiments were conducted at pH = 4 and 10 mg/L an initial concentration of As(V). The breakthrough curves were investigated for variou ...
... The adsorption behaviour of benzyldimethyldodecylammonium chloride (C12BDMAC) corrosion inhibitor from aqueous solutions onto a stainless steel surface has been investigated using the quartz crystal microbalance (QCM) technique and the depletion-HPLC method. Three different experimental procedures were used to carry out the adsorption measurements using the QCM. The results revealed that the emplo ...
... The porous ceramic filter media (PCFM) was applied to reduce the release of P in lake sediment and we wondered if the nano-TiO2 coating could enhance the P adsorption by PCFM alone in lake sediments. The nano-TiO2 film coated on PCFM in this study was prepared by sol–gel process, and the adsorption properties of sediment P in all fractions by the nano-TiO2 film coated PCFM were investigated throug ...
... The adsorption performance of the MIL-101@GO composite for a series of linear long chain alkanes (from n-pentane to n-octane) was investigated for the first time. The MIL-101@GO composite based on MIL-101(Cr) and graphite oxide (GO) was prepared, characterized and tested for adsorption and desorption of n-alkanes. Isotherms of a series of n-alkanes on MIL-101@GO were measured. Temperature-programm ...
... The main aim of the study presented was to determine and characterize the adsorption properties of catanionic mixtures with quaternary derivatives oflysosomotropic substances (QDLS). The surfactants investigated were quaternary ammonium salts belonging to the group of esterquats: fatty acids N,N-dimethylaminoethylesters methobromides (DMM-n), fatty acids N,N-dimethyl-aminopropylesters methobromide ...
... Adsorption, desorption, and precipitation reactions at environmental interfaces impact the bioavailability, mobility, and fate of organic phosphates in terrestrial and aquatic environments. Myo-inositol hexakisphosphate (IHP) is the most abundant organic phosphate in soils. The adsorption/desorption characteristics of IHP on/from hematite were studied using batch adsorption and desorption experime ...
... Chemically prepared activated carbon derived from durian seed (DSAC) was used as adsorbent to adsorb Malachite green (MG) dye. The prepared DSAC was characterized using Brunauer–Emmet–Teller (BET), Fourier transform infrared (FTIR), scanning electron microscope (SEM), and proximate analysis, respectively. Batch adsorption studies were carried out for the removal of MG dye from aqueous solutions by ...
... Modified talcum powder prepared by physical purification and 50% (w/w) HNO₃ acid activation was characterised by X-ray diffraction, scanning electron microscopy and energy dispersive spectrometry. The modified talcum powder was used for the methylene blue adsorption in wastewater. Adsorption contact time, pH, adsorption temperature, initial mass concentration, and solid content were investigated. ...
... The use of macroporous polymeric adsorption resins for the recovery and purification of prodigiosin from fermentation broth of Serratia marcescens SMDR was systematically studied, in which the broth was pretreated by coagulation with alum and the resulting precipitate was leached by methanol/water solution. Of the seven resins tested, Diaion HP-20 resin was selected considering the adsorption and ...
... Exergy analysis and exergoeconomics are often used to evaluate industrial energy systems performance from the thermodynamic and economic points of view. While the classical exergy analysis can be used to recognize the sources of inefficiency and irreversibilities, so called advanced exergy analysis is convenient for identifying real potential for thermodynamic improvements of the system by splitti ...
... Membrane emulsification is a promising process for formulating emulsions and particulates. It offers many advantages over conventional ‘high‐shear’ processes with narrower size distribution products, higher batch repeatability and lower energy consumption commonly demonstrated at a small scale. Since the process was first introduced around 25 years ago, understanding of the underlying mechanisms i ...
... Accurate and rapid protein quantitation is essential for screening biomarkers for disease stratification and monitoring, and to validate the hundreds of putative markers in human biofluids, including blood plasma. An analytical method that utilizes stable isotope-labeled standard (SIS) peptides and selected/multiple reaction monitoring-mass spectrometry (SRM/MRM-MS) has emerged as a promising tech ...
Acacia mearnsii; Corymbia maculata; Eucalyptus camaldulensis; Eucalyptus cladocalyx; Pinus pinaster; adverse effects; arid lands; climatic factors; clones; drought; dry environmental conditions; equations; hybrids; logit analysis; planting; rain; survival rate; temperature; topographic slope; tree and stand measurements; trees; New South Wales
Abstract:
... In order to search for suitable tree species for commercial environmental forestry over the vast semiarid and drought prone areas across the western slopes of New South Wales, Australia, a large species trial involving nine selected potential species was established at 45 sites over three broad regions in 2000. A year later, the “Millennium Drought”, the longest uninterrupted series of years with ...
... For conventional HAWT (horizontal axis wind turbines), the rotor speed is maintained constant while the blade tip speed changes continuously. This reduces considerably the power performance of the wind turbine particularly at high wind speeds where the tip speed ratio is small. With growth of variable speed generators, a compact BEM (blade element momentum) analysis is derived to design optimal bl ...
acetates; ammonia; aqueous solutions; chemical bonding; crystallography; dielectric properties; equations; indium; ligands; metal ions; methodology; perchlorates; polyamines
Abstract:
... The affinity of In(III) for N-donor ligands was investigated by differential pulse voltammetry, DFT calculations, and crystallography. The structure of [In(tpen)(CH₃COO)](ClO₄)₂ ・ 0.5H₂O (1) is reported (tpen = N,N,N´ ,N´-tetrakis(2-pyridylmethyl)ethylenediamine): Monoclinic, P2₁/n, a = 8.687(4), b = 7.767(8), c = 20.432(10) Å , β = 93.372(8)°, Z = 4, R = 0.0518. The In(III) center is 7-coordinate ...
... Age estimation in living subjects is primarily achieved through assessment of a hand–wrist radiograph and comparison with a standard reference atlas. Recently, maturation of other regions of the skeleton has also been assessed in an attempt to refine the age estimates. The current study presents a method to predict bone age directly from the knee in a modern Irish sample. Ten maturity indicators ( ...
Robinia pseudoacacia; bark; biomass; carbon; carbon sequestration; ecosystems; equations; forage; forest soils; forest types; leaves; long term effects; planning; plant litter; planting; reforestation; shrubs; soil conservation; topsoil; tree mortality; trees; China
Abstract:
... The effects of reforestation on carbon (C) sequestration in China’s Loess Plateau ecosystem have attracted much research attention in recent years. Black locust trees (Robinia pseudoacacia L.) are valued for their important use in reforestation and water and soil conservation efforts. This forest type is widespread across the Loess Plateau, and must be an essential component of any planning for C ...
... Aging is an enological technique usually employed with Vitis vinifera wines for improving and stabilizing wine sensory attributes like red wine color. However, red wines made from non-vinifera grape cultivars are considered not suitable for classic wine aging because they are prone to color loss during processing and storage, mainly due to the major occurrence of non-acylated anthocyanidin 3,5-dig ...
... Phosphorus (P) deficiency is one of the most yield-limiting factors in lowland rice production on Brazilian Inceptisol. The objective of this study was to evaluate eight P sources for lowland rice production. The P sources were simple superphosphate (SSP), polymer-coated simple superphosphate (PSSP), ammoniated simple superphosphate (ASSP), polymer-coated ammoniated simple superphosphate (PASSP), ...
air; air flow; equations; greenhouses; microclimate; mixing; models; wind speed
Abstract:
... Until about a decade ago, greenhouse microclimates were analysed using a simplified approach assuming a perfectly stirred enclosure. Demands for efficient and sustainable greenhouse operations, stimulated intensive research that focused into the distributed microclimate within greenhouses. Since the distributed microclimate and the air-exchange rate are interconnected the latter is important. Thre ...
... Beginning with harvesting, seeds are usually subjected to a series of processes which include drying for immediate or future use. Seed quality can be influenced by several factors during drying. This article presents a review of the seed air-drying process, including mathematical models based on differential equations derived from mass and energy balances for seeds and air in fixed and moving bed ...
... Accurate numerical simulations of airflow around buildings is challenging due to the dynamic characteristics of the wind. A time-dependent model has been applied for the prediction of the turbulent airflow around scale model buildings with different roof geometry in a wind tunnel. The model is based on the direct solution of transient Navier-Stokes and continuity equations using the Galerkin finit ...
albumins; blood serum; dialysis; diet; equations; hemodialysis; patients; protein content; protein energy malnutrition; renal failure; saltiness; taste; zinc
Abstract:
... Patients with renal failure often experience decreased serum zinc that remains uncorrected after dialysis. A complication of this depletion is taste impairment, which can detrimentally influence diet and nutrition. However, because more than half of all serum zinc is bound to albumin, we hypothesized that normalizing serum zinc to albumin levels may be associated with taste impairment. A total of ...
algorithms; computer science; entropy; equations; games; genes; natural selection; population genetics; students
Abstract:
... Even the most seasoned students of evolution, starting with Darwin himself, have occasionally expressed amazement that the mechanism of natural selection has produced the whole of Life as we see it around us. There is a computational way to articulate the same amazement: “What algorithm could possibly achieve all this in a mere three and a half billion years?” In this paper we propose an answer: W ...
Fourier transform infrared spectroscopy; adsorbents; adsorption; aqueous solutions; biomass; endothermy; equations; ion exchange; mass transfer; methylene blue; nitrogen; reaction kinetics; scanning electron microscopy; sorption isotherms; tea; temperature; wastes
Abstract:
... The adsorption of methylene blue (MB) from aqueous solution by alkali treated Foumanat tea waste (ATFTW) from agriculture biomass was investigated. The adsorbent was characterized by Scanning Electron Microscopy (SEM), Fourier Transform-Infrared Spectroscopy (FT-IR) and nitrogen physisorption. FTIR results showed complexation and ion exchange appear to be the principle mechanism for MB adsorption. ...
... The high-spin d⁵ complexes M₂Mn(1,2-C₆H₄(C≡C)₂)₂ (M = K, Na) are prepared in liquid ammonia according to equation (1). The magnetic moment and the position of the IR-active υC ≡ C of the potassium salt are discussed with respect to the structure of the solid compounds. ...
equations; nuclear magnetic resonance spectroscopy; phosphorus; stable isotopes; transition elements
Abstract:
... The diamagnetic trans-planar complexes [Pd(C≡CR)₂(Pet₃)₂] (R = 1,2-C₆H₄C≡CH, 1,4-C₆H₄C≡CH; et = C₂H₅) are prepared according to the equation (1). The constitution and the structure of these compounds are demonstrated by their IR, ¹H and ³¹P NMR spectra ...
... This paper presents the fundamental principles and recent advances in the field of linearity enhancement of Mach–Zehnder modulators in microwave photonic systems using all-optical signal processing. A review of the fundamentals and applications that implement the linearity improvement is also provided. ...
equations; inventories; least squares; life cycle inventory; linear models
Abstract:
... BACKGROUND, AIM, AND SCOPE: The primary aim of this paper is to indicate that partitioning allocation methods yields only a small subset of solutions to an ill-posed problem that has potentially infinitely many exact solutions. It will be shown that each of the existing partitioning methods arrives at just one particular solution from among infinitely many solutions of an underdetermined system of ...
European Union; ecological footprint; environmental assessment; equations; issues and policy; models
Abstract:
... This paper aims at analysing how secondary materials production and end of life recovery processes are modelled in life cycle-based environmental assessment methods in order to discuss their suitability in product policy-support contexts, with a focus on Sustainable Consumption and Production (SCP) policies. The equations prescribed in three published, widely recognised standards are evaluated. In ...
Guillermo Blanco; Luis M. Bautista; Dámaso Hornero‐Méndez; Sergio A. Lambertucci; Guillermo Wiemeyer; José A. Sanchez‐Zapata; Fernando Hiraldo; José A. Donázar; Dan Chamberlain
birds of prey; blood flow; blood volume; captive animals; carotenoids; dietary nutrient sources; equations; Andes region
Abstract:
... Because large species ingest proportionally less food than small ones, it may be predicted that they should incorporate relatively fewer carotenoids to a proportionally equal volume of blood. However, some species may increase their levels of circulating carotenoids by ingesting unusual food. We tested whether the plasma concentration of carotenoids scales to the three‐quarter power of mass in nin ...
... The relationship between body dry weight (W) and shell length (L) of blue mussels, Mytilus edulis, can be expressed by the condition index (CI = W/L ³) which varies from population to population and during the year. Here, we examine the influence of CI on the relationships between maximum filtration rate (F, l h⁻¹), W (g), and L (mm) as described by the equations: F W = aW ᵇ and F L = cL ᵈ , respe ...
... Tree growth equations are an important and common tool used to effectively assess the yield and determine management practices in forest plantations. Increasingly, they are being developed for urban forests, providing tools to assist urban forest managers with species selection, placement, and estimation of management costs and ecosystem services. This study describes the development of allometric ...
Gustavo Calderucio Duque Estrada; Mário Luiz Gomes Soares; Daniel Medina Corrêa Santos; Viviane Fernandez; Paula Maria Moura de Almeida; Marciel Rocha de Medeiros Estevam; Maria Rita Olyntho Machado
Avicennia; aboveground biomass; branches; carbon; equations; inventories; leaves; linear models; regression analysis; trees; uncertainty; Brazil
Abstract:
... As mangroves become recognized as important carbon storages, the need for reducing the uncertainty of carbon inventories becomes increasingly emphasized. Accordingly, the objective of this study was to develop allometric models to estimate the total aboveground biomass (AGB) and the biomass per compartment of Avicennia schaueriana and to compare them with other models previously published for the ...
... The association between physiologically dependent pharmacokinetic parameters (CLB, T₁/₂ᵦ, Vdₛₛ) of marbofloxacin and body weight was studied in eight animal species based on allometric equation Y = aWᵇ, where ‘Y’ is the pharmacokinetic parameter, ‘W’ is body weight, ‘a’ is allometric coefficient (intercept) and ‘b’ is the exponent that describes relation between pharmacokinetic parameter and body ...
... This paper deals with the technical feasibility of calcium oxide as a sorbent for CO2 (carbon dioxide) in syngas for air–steam gasification of lignocellulosic biomass. The process is simulated through a kinetic approach incorporating rate equations for the component reactions. Using the kinetic simulation data, parametric performance analysis is carried out highlighting the significance of SBR (st ...
... As anaerobic batch tests are easy to conduct, they are commonly used to assess the effects of different operational factors on the anaerobic digestion process. Hydrolysis of particulate material is often assumed to be the rate limiting step in anaerobic digestion. Its velocity is often estimated by data fitting from batch tests. In this study, a Monod-type alternative to the commonly used first-or ...