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natural resource management; agricultural education; alternative crops; alternative farming; marketing strategies; decision support systems; decision making; buckwheat; Fagopyrum esculentum; Minnesota
Abstract:
... Decision cases have been used in the USA for both classroom and extension education within agriculture and natural resources. Use of cases has sometimes been limited by the extensive amount of time that may be required to assign and analyze conventional, text-based cases. Availability of video decision cases, which are visual and do not necessarily require reading, could foster the use of cases on ...
fluorescence in situ hybridization; messenger RNA; alternative splicing; humans; complementary DNA; sequence alignment; dogs; single nucleotide polymorphism; amino acid sequences; gene expression; genes; nucleotide sequences; chromatin; sequence homology; physical chromosome mapping; dog breeds
Abstract:
... HMGA1 nonhistone proteins are reported to participate in various cellular processes including regulation of inducible gene transcription, integration of retroviruses into chromosomes, and the induction of neoplastic transformation and promotion of metastatic progression of cancer cells. Overexpression of HMGA1 was shown to be characteristic for various malignant tumors, suggesting a relation betwe ...
intestinal microorganisms; ribosomal RNA; hindgut; symbionts; Protozoa; genes; nucleotide sequences; molecular systematics; Reticulitermes santonensis; new species
Abstract:
... Lignocellulose digestion by wood-feeding termites depends on the mutualistic interaction of unusual, flagellate protists located in their hindgut. Most of the flagellates harbor numerous prokaryotic endosymbionts of so-far-unknown identity and function. Using a full-cycle molecular approach, we show here that the endosymbionts of the larger gut flagellates of Reticulitermes santonensis belong to t ...
... Greater Prairie Chickens started their range expansion from Wisconsin about 1900. They reached Sault Ste. Marie, Ontario, by 1925 and completed colonization of Manitoulin Island by 1945. In the fall of 1932, an irruption of Northern Sharp-tailed Grouse from the Hudson Bay Lowlands occurred. Residents of Manitoulin distinguished the two species and reported the presence of “square-tails” and “sharp ...
diabetes; peripheral nervous system diseases; walking
Abstract:
... OBJECTIVE:--Peak plantar pressures (PPPs) have been studied extensively as a contributing factor to skin breakdown, especially in the forefoot where most plantar neuropathic ulcers occur. The purposes of this article were to 1) describe an additional pressure variable, the peak pressure gradient (PPG), 2) determine whether the PPG is higher in the forefoot than in the rearfoot (even when compared ...
agromedicine; agricultural health and safety; agricultural education; high schools; program evaluation; Northeastern United States; Mid-Atlantic region
... Blackberry cv. Thornless, selected from the cross Kotata × NZ 8610L-163 (E90 × N-71), is a thornless, high-yielding cultivar with good disease resistance and large, uniformly shaped and firm fruits with good processing quality and excellent adaptation to machine harvesting. ...
... Blackberry cv. Black Pearl, selected from the cross of ORUS 1117-11 × ORUS 1122-1, is a thornless cultivar with good plant disease resistance and large fruits with excellent processing quality and adaptation to machine harvesting. ...
... A bacterial artificial chromosome (BAC) library was constructed from the bread wheat (Triticum aestivum L.) genotype 'Chinese Spring' ('CS'). The library consists of 395,136 clones with an estimated average insert size of 157 kb. This library provides an estimated 3.4-fold genome coverage for this hexaploid species. The genome coverage was confirmed by RFLP analysis of single-copy RFLP clones. The ...
celiac disease; steatorrhea; women; men; dietary restriction; food choices; dietary surveys; quality of life; psychological stress; life events
Abstract:
... Aim: The aim of this study was to explore the dilemmas experienced by women and men in their everyday lives in relation to their coeliac disease, and to explore the qualities of these dilemmas in relation to specific situations and living conditions. Methods: We interviewed 43 informants, aged 20-40 years, using 'The Critical Incident Technique'. Interviews focused on situations that gave rise to ...
germplasm releases; harvest date; raspberries; insect pests; plant viruses; plant pests; fruit quality; crop yield; Rubus idaeus; Amphorophora; firmness; agronomic traits; fruit crops; high-yielding varieties; British Columbia
Abstract:
... Raspberry cv. Esquimalt, derived from the cross Comox × Glen Ample, is a vigorous cultivar with spineless canes and upright growth habit and large, firm fruits with excellent fresh flavour. The cultivar is suitable for hand-picking and can be used to extend fresh raspberry market season due to its delayed ripening. ...
... To verify the compatibility behaviour of the almond cultivar 'Francoli' and to clarify its S genotype a combination of pollination tests, stylar ribonuclease and allele specific PCR analysis was used. 'Francoli' was released from IRTA's breeding programme in 1994, having been putatively raised from the cross 'Cristomorto' (S1S2) x 'Gabaix' (S10S25). This cultivar was also reported to be self-incom ...
germplasm releases; harvest date; cultivars; Vaccinium; fruit quality; firmness; fruit crops; blueberries; sweetness; New Jersey
Abstract:
... 'Hannah's Choice' is an early-ripening, tetraploid, highbush blueberry (Vaccinium corymbosum L.) that was developed by the cooperative breeding program of the Agricultural Research Service of the U.S. Department of Agriculture (USDA) and the New Jersey Agricultural Experiment Station (NJAES). It was named because it represents an improvement in sweetness, firmness, and flavor over currently grown ...
... Blackberry cv. Metolius, selected from the cross Douglas × Kotata, is a medium-yielding cultivar with vigorous plants and early-ripening, uniformly sized and shaped, glossy, firm fruits with excellent colour and flavour. ...
... Blackberry cv. Nightfall, derived from the cross Marion × Waldo, is a thornless cultivar with good plant disease resistance, yield similar to that of the well-established cultivar, Marion, and large fruits with excellent processing quality and adaptation to machine harvesting. ...
germplasm releases; vigor; Rubus; plant architecture; fruit quality; crop yield; firmness; fruit crops; high-yielding varieties; blackberries; mechanical harvesting; Oregon
Abstract:
... Blackberry cv. Obsidian, selected from the cross ORUS 828-43 and ORUS 1122-1, is a high-yielding cultivar with outstanding plant vigour and early ripening, large and firm fruits with excellent colour and flavour. ...
... Prime-Jan (APF-8) and Prime-Jim (APF-12) are the first commercial cultivars of primocane-fruiting blackberry (Rubus subgenus Rubus). Prime-Jan resulted from a cross of Ark. 1836 × Arapaho, whereas Prime-Jim was obtained from Arapaho × Ark. 830, and both were developed in Arkansas, USA. This unique type of blackberry fruit on current-season canes (primocanes) and second-season canes (floricanes). A ...
... Application of growth promoters or inhibitors and mowing height adjustment are potential means of improving the growth and performance of TifEagle bermudagrass [Cynodon dactylon (L.) Pers. x C. transvaalensis Burtt-Davy] in a reduced light environment (RLE). A study was conducted in June to August 2001 and 2002 to examine the effects of growth factors and two mowing heights on TifEagle bermudagras ...
... 'White Rock' and 'White County' are the second and third white-flesh peach releases from the University of Arkansas peach breeding programme aiming to develop adapted white-flesh peach cultivar for on-farm, local and shipping sales. 'White Rock' resulted from a cross of Ark. 371 × Ark. 367, and 'White County' resulted from a cross of Ark. 392 × Ark. 433N made at the University of Arkansas Fruit Su ...
... An artificial aphid was developed by making parafilm® bubbles filled with aphid haemolymph and its suitability for parasitoid oviposition was tested. Aphidius ervi accepted the parafilm® aphid and laid eggs on it. By stretching, the thickness of the parafilm could be changed. The thicker the parafilm, the higher was the mean number of ovipositional stings and the lower the mean number of eggs rele ...
... BACKGROUND: The uptake of nutrients, expulsion of metabolic wastes and maintenance of ion homeostasis by the intraerythrocytic malaria parasite is mediated by membrane transport proteins. Proteins of this type are also implicated in the phenomenon of antimalarial drug resistance. However, the initial annotation of the genome of the human malaria parasite Plasmodium falciparum identified only a lim ...
acetaldehyde; glyoxylic acid; chemical reactions; catechin; model food systems; wines; winemaking; food chemistry
Abstract:
... (+)-Catechin reaction with two aldehydes (acetaldehyde and glyoxylic acid) was studied in winelike model solution. The two aldehydes were reacted either individually or together with (+)-catechin and in molar excess. The reactions were followed by HLPC-UV and HPLC-ESI/MS to monitor (+)-catechin disappearance as well as dimer and polymer appearance. In all reactions a reaction order of close to 1 f ...
... (1[rightwards arrow]3),(1[rightwards arrow]4)-ss-Glucans had previously been detected in nonlignified cell wall preparations of only the Poaceae and five other families in the graminoid clade of the Poales (s.l.). Cell walls of vegetative organs of 12 species in nine families of the Poales (s.l.) were examined by immunogold labeling using a monoclonal antibody to (1[rightwards arrow]3),(1[rightwar ...
insect pests; Pseudococcus viburni; sex pheromones; chemical composition; monoterpenoids; field experimentation
Abstract:
... The sex pheromone of the obscure mealybug, Pseudococcus viburni, consists of (1R*,2R*,3S*)-(2,3,4,4-tetramethylcyclopentyl)methyl acetate, the first example of a new monoterpenoid structural motif in which the two isoprene units forming the carbon skeleton are joined by 2'-2 and 3'-4 connections rather than the usual 1'-4, head-to-tail connections. This highly irregular terpenoid structure, and th ...
Dioryctria abietivorella; insect pests; sex pheromones; chemical composition; field experimentation; insect traps; Abies
Abstract:
... The sex pheromone of the fir coneworm moth consists of a blend of (3Z,6Z,9Z,12Z,15Z)-pentacosapentaene and (9Z,11E)-tetradecadienyl acetate. Analogous blends of polyunsaturated, long-chain hydrocarbons with much shorter chain aldehydes or alcohols recently have been discovered in three other moth species in the superfamily Pyraloidea. These combinations of components from two distinct structural c ...
chemical reactions; enzyme activity; kinetics; models; moieties; pH; thymine
Abstract:
... A model compound containing a thymine oxetane moiety linked to a flavin chromophore was investigated regarding (6-4)-photolyase activity. The need for a charge shift reaction was demonstrated by a detailed pH-dependent kinetic analysis. ...
... Reported here is a technique to use the (7)Be/(210)Pb(xs) ratio as a measure of suspended sediment age or as an indicator of the fraction of the suspended sediment that is recently eroded from the landscape. Although both (7)Be and (210)Pb(xs) are delivered seasonally and stochastically to the landscape by precipitation, the ratio of the two radionuclides varies substantially less. The (7)Be/(210) ...
sex pheromones; chemical composition; field experimentation
Abstract:
... Considering the vast Eurasian distribution of gypsy moth, Lymantria dispar (Lepidoptera: Lymantriidae), the many subspecies, and their presence in different lymantriid communities, we tested the hypothesis that L. dispar populations in eastern Asia employ one or more pheromone components in addition to the previously known single component pheromone (7R,8S)-cis-7,8-epoxy-2-methyloctadecane [= (+)- ...
insect pests; sex pheromones; chemical composition; synthesis; field experimentation; insect traps
Abstract:
... Our objective was to identify the sex pheromone of Lymantria bantaizana (Lepidoptera: Lymantriidae) whose larvae feed exclusively on walnut, Juglans spp., in China, and Japan. Coupled gas chromatographic-electroantennographic detection (GC-EAD) analyses of pheromone gland extracts revealed a single EAD-active component. Retention index calculations of this compound on four GC columns suggested tha ...
insect pests; sex pheromones; chemical composition; stereoisomers; field experimentation; insect traps; pest monitoring; insect control
Abstract:
... We identified, synthesized, and field-tested the sex pheromone of female red cedar cone midge Mayetiola thujae (Hedlin) (Diptera: Cecidomyiidae), a pest insect in red cedar Thuja plicata seed orchards. Coupled gas chromatographic (GC)-electroantennographic detection analyses of pheromone extract revealed three components (A, B, C) that elicited responses from antennae of males, all of which occurr ...
... In response to insect feeding, corn plants (Zea mays cv. Delprim) release elevated levels of volatile organic compounds (VOCs), including the C6-volatile (Z)-3-hexenol. The level of mRNA accumulation for a series of defense genes was monitored in response to application of (Z)-3-hexenol (50 nmol) to undamaged plants. The induction of transcripts for hpl (hydroperoxide lyase), fps (farnesyl pyropho ...
catalysts; catalytic activity; chemical reactions; ligands; phosphine
Abstract:
... The vinylideneruthenium(ii) complexes bearing bulky and basic tertiary phosphine ligands, RuCl₂(CCHPh)L₂ (L = PPrⁱ₃, PCy₃), serve as good catalyst precursors for (Z)-selective cross-dimerization between arylacetylenes and silylacetylenes in the presence of N-methylpyrrolidine. ...
sex pheromones; chemical composition; field experimentation; wind tunnels; insect pests
Abstract:
... (Z, Z)-6,9-Heneicosadien-11-one (Z6Z9-11-one-21Hy) was identified as the major sex pheromone component of the painted apple moth (PAM), Teia anartoides (Lepidoptera: Lymantriidae), on the basis of (1) comparative gas chromatographic-electroantennographic detection (GC-EAD) analyses, GC-mass spectrometry (MS), high-performance liquid chromatography (HPLC)-MS, and HPLC-UV/visible spectroscopy of phe ...
... (−)-Menthol is the most familiar of the monoterpenes as both a pure natural product and as the principal and characteristic constituent of the essential oil of peppermint (Mentha x piperita). In this paper, we review the biosynthesis and molecular genetics of (−)-menthol production in peppermint. In Mentha species, essential oil biosynthesis and storage is restricted to the peltate glandular trich ...
aerosols; atmospheric circulation; ice; salt concentration; surface temperature; Greenland
Abstract:
... Interannual to multidecadal modes in ocean/atmosphere dynamics in the North Atlantic region have been identified using sea salt aerosol proxy records from northern Greenland ice cores over the last 1,000 years. Sea salt concentrations show a consistent relationship with anomalies in the meridional pressure gradient over the North Atlantic region over all considered time scales. These pressure anom ...
... Dppf is one of the most useful and popular ligands in coordination chemistry. Its overwhelming success has overshadowed and arguably even delayed the development and use of closely related ferrocene-based ligands with two ligating N, O or S atoms. Recently, however, dynamic progress concerning such homo-donor ligands can be noted. This tutorial review describes the main results obtained over the p ...
... The organometallic tetraradical 1,2,4,5-[(η⁷-C₇H₇)V̇(η⁵-C₅H₄)]₄C₆H₂ has been prepared and structurally characterized. The isotropic EPR spectrum displays 29 a(⁵¹V) hyperfine lines, the intensity distribution slightly deviating from binomial. Exchange coupling therefore approaches the strong exchange limit, Jₒᵣₜₕₒ ≠ Jₘₑₜₐ ≠ Jₚₐᵣₐ ≳50 a(⁵¹V) with a(⁵¹V) = 0.0067 cm⁻¹. According to magnetic susceptom ...
... 1,3-Dipolar cycloaddition reactions of nitrones with alkenes and alkynes are well-studied reactions in solution-phase organic chemistry. However, the number of studies concerned with their application in solid-phase organic synthesis is rather low compared to other 1,3-dipoles, e.g. azides or nitrile oxides. This tutorial review aims to summarise the main approaches towards the application of nitr ...
chemical compounds; epoxidation reactions; oxidation
Abstract:
... 1,4-Cyclohexadienes allow a direct comparison of epoxidation and C–H oxidation within the same molecule and give evidence for radical pathways during the Jacobsen epoxidation. ...
... Many bees are oligolectic and collect pollen for their larvae only from one particular plant family or genus. Here, we identified flower scent compounds of two Salix species important for the attraction of the oligolectic bee Andrena vaga, which collects pollen only from Salix. Flower scent was collected by using dynamic-headspace methods from Salix caprea and S. atrocinerea, and the samples were ...
... The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 °C) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction. ...
chemical compounds; chemical reactions; nanomaterials; synthesis
Abstract:
... The chemical synthesis of 1-dimensional (1-D) PEDOT nanostructures in the form of tubes, rods, thimbles, and belts has been successfully accomplished through the use of a “hard template”. ...
... Chinese cabbages cv 'Yuki' (Brassica campestris L ssp pekinensis (Lour) Olsson) were treated with air containing 1-methylcyclopropene (1-MCP) at concentrations ranging from 0 to 1 microliter l(-1) for 12 h at 22 degrees C before storage for 9 weeks at 3 degrees C. Quality, weight loss and trimming loss were measured before treatment, and before and after storage, but were not influenced by 1-MCP. ...
... 1-Methylcyclopropene (1-MCP) is a new technology that is applied commercially to inhibit ethylene action in apple fruit, but its interactions with existing technologies such as diphenylamine (DPA) for control of superficial scald development in fruit during and after storage is unknown. To investigate possible interactions between 1-MCP and DPA, Delicious apples were untreated or treated with 2 g ...
... 1-Triflylpyrroles bearing acetyl group(s) on position 3, or 2 and 4, are efficient dienophiles in normal electron demand Diels–Alder reactions activated by high pressures and Lewis acids. ...
... Lactococcus lactis is a Gram-positive lactic acid bacterium that, in addition to its traditional use in food fermentations, is increasingly used in modern biotechnological applications. In the last 25 years great progress has been made in the development of genetic engineering tools and the molecular characterization of this species. A new versatile and tightly controlled gene expression system, b ...
... A June-August Alpine temperature proxy series is developed back to AD 951 using 1,527 ring-width measurements from living trees and relict wood. The reconstruction is composed of larch data from four Alpine valleys in Switzerland and pine data from the western Austrian Alps. These regions are situated in high elevation Alpine environments where a spatially homogenous summer temperature signal exis ...
... Five compounds of iridoids, lignan and phenylpropanoid glycosides were isolated from the roots ofValeriana jatamansi by column chromatography. Their structures were elucidated as 11-methoxyviburtinal (1), baldrinal (2), prinsepiol-4-O-β-D-glucoside (3), coniferin (4), and hexacosanic acid (5) by spectroscopic analysis. 11-Methoxyviburtinal was a new compound, and others were isolated from the plan ...
... Total globulins extracted with 0.4 M NaCl in buffer from coconut endosperm separated into two peaks on gel filtration: peak I corresponding to 11S globulin or cocosin and peak II to 7S globulin with native molecular weights of 326 000 and 156 000, respectively. The percent composition of total globulins was estimated to be 11S, 86% and 7S, 14%. On SDS-PAGE, cocosin resolved into two closely migrat ...
... Jasmonic acid (JA) and methyl jasmonate (MeJA), collectively known as JAs, regulate diverse physiological processes in plants, including the response to wounding. Recent reports suggest that a cyclopentenone precursor of JA, 12-oxo-phytodienoic acid (OPDA), can also induce gene expression. However, little is known about the physiological significance of OPDA-dependent gene expression. We used micr ...
... The detailed analysis of peach seed oil was performed using 1H and 13C NMR spectroscopy. From the 13C NMR solution spectra it was possible to detect the content of saturated, mostly palmitic fatty acids (approximately 100 g kg(-1)), the oleic-linoleic ratio in sn-1,3 and sn-2 positions was (2:1 and 1:2) and the positional distribution of glycerol esters on triacylglycerol chains, which is a mixtur ...
... It is difficult to quantify the mechanism(s) responsible for competition-induced yield loss using traditional experimental techniques. A technique using yield and ¹³C discrimination (ΔΔ) for wheat, a C₃ plant, has been developed to separate total yield loss (TYL) into yield loss due to N (YLNS) and water (YLWS) stresses. The objective of this research was to determine whether the ΔΔ approach could ...
... Genomic clone coding for the 16R isoform of 14-3-3 proteins from potato plants has recently been described. This paper reports on 20R-gene isolation and analysis, and compares two isoforms. The northern blot analysis of mRNA of the 20R 14-3-3 isoform suggests its similarity to 16R. Vascular tissue-specific expression and age-dependent synthesis in potato leaves has been detected in both promoters. ...
... The 14-3-3 protein is one of the best candidates for coordinating all plant metabolic pathways. To verify this suggestion transgenic potato plants with repression of one (J4 and J5 plants), two (G1 plants), and six (G3 plants) constitutive 14-3-3 protein isoforms as well as plants overexpressing the 14-3-3 protein were studied. Reduction in the 14-3-3 protein level in the J4 and J5 transformants, ...
... CLAVATA3 (CLV3), CLV3/ESR19 (CLE19), and CLE40 belong to a family of 26 genes in Arabidopsis thaliana that encode putative peptide ligands with unknown identity. It has been shown previously that ectopic expression of any of these three genes leads to a consumption of the root meristem. Here, we show that in vitro application of synthetic 14-amino acid peptides, CLV3p, CLE19p, and CLE40p, correspo ...
... Lipoxygenases (LOXs) are a family of enzymes capable of peroxidizing phospholipids. A member of the LOX family of enzymes, 15-LOX, participates in the degradation of mitochondria and other organelles within differentiating red blood cells, the reticulocytes. The present study provides biochemical and immunocytochemical evidence for the presence of 15-LOX in the sperm cytoplasmic droplet (CD). Test ...
Antonios M. Douvas; Panagiota S. Petrou; Sotirios E. Kakabakos; Konstantinos Misiakos; Panagiotis Argitis; Evagelia Sarantopoulou; Zoe Kollia; Alkiviadis C. Cefalas
... A new methodology for protein microarray fabrication is proposed based on the ablation of polymer film using laser at 157 nm (F₂). The polymer has been selected among others with the criterion of negligible protein adsorption. Improved results have been obtained by pretreatment of the polymer surface with an inert protein. The use of 157-nm laser radiation allowed very good depth control during th ...
... Field-collected mosquitoes of the two main malaria vectors in Africa, Anopheles gambiae sensu lato and Anopheles funestus, were screened for their midgut bacterial contents. The midgut from each blood-fed mosquito was screened with two different detection pathways, one culture independent and one culture dependent. Bacterial species determination was achieved by sequence analysis of 16S rRNA genes ...
... For simultaneous identification of members of the betaproteobacterial order "Rhodocyclales" in environmental samples, a 16S rRNA gene-targeted oligonucleotide microarray (RHC-PhyloChip) consisting of 79 probes was developed. Probe design was based on phylogenetic analysis of available 16S rRNA sequences from all cultured and as yet uncultured members of the "RHODOCYCLALES:" The multiple nested pro ...
... Phylogenetic analyses of 16S rRNA sequences of sponge-associated cyanobacteria showed them to be polyphyletic, implying that they derived from multiple independent symbiotic events. Most of the symbiont sequences were affiliated to a group of Synechococcus and Prochlorococcus species. However, other symbionts were related to different groups, such as the OSCILLATORIALES: ...
... Small subunit 16S rRNA sequences, growth temperatures, and phylogenetic relationships have been established for 129 bacterial isolates recovered under aerobic growth conditions from different regions of a 22-m ice core from the Muztag Ata Mountain glacier on the Pamirs Plateau (China). Only 11% were psychrophiles (grew at 2°C or -2°C up to ~20°C), although the majority (82%) were psychrotolerant ( ...
General Circulation Models; evaporation; surface temperature; troposphere; wind; Mexico; South America; United States
Abstract:
... Most major features of the interdecadal shift in boreal winter-spring precipitation over the American continents associated with the 1976-1977 transition are reproduced in atmospheric general circulation model (GCM) simulations forced with observed sea surface temperature (SST). The GCM runs forced with global and tropical Pacific SSTs produce similar multidecadal changes in precipitation, indicat ...
El Nino; climate; ecological restoration; flood control; floods; global change; planning; water pollution; water resources; watersheds; weather forecasting; China; Yangtze River
Abstract:
... This paper reviews changes in the use of short-term climate information for water management in China after the 1998 Great Flood in the Yangtze River basin. This devastating flood is now believed to have been caused mainly by the 1997–98 El Niño event. Although the short-term climate forecasts and weather forecasts are considered to be useful in planning for flood prevention activities and for mak ...
catalytic activity; chemical reactions; sesquiterpenoids
Abstract:
... 2,2-Dimethyl cyclopentanones are readily prepared by acid catalyzed ring expansion of isopropenylcyclobutanols; the method allows ready access to the family of sesquiterpenes cuparanes and herbertanes, as demonstrated by the synthesis of (±)-α-cuparenone and the direct precursor of (±)-herbertene. ...
alcohols; amides; amines; chemical reactions; ethers; moieties
Abstract:
... Amines, amides and ethers containing 2-arylallyl groups are selectively and easily deprotected with tert-butyllithium. This transformation probably involves a carbolithiation reaction of the styrenyl moiety followed by a β-elimination process. ...
... The hadBC and hadI genes from Clostridium difficile were functionally expressed in Escherichia coli and shown to encode the novel 2-hydroxyisocaproyl-CoA dehydratase HadBC and its activator HadI. The activated enzyme catalyses the dehydration of (R)-2-hydroxyisocaproyl-CoA to isocaprenoyl-CoA in the pathway of leucine fermentation. The extremely oxygen-sensitive homodimeric activator as well as th ...
Lewis bases; catalytic activity; chemical reactions; palladium; primary amines
Abstract:
... 2-Phenallyl was found to be a versatile protecting group of primary amines for the asymmetric one-pot three-component synthesis of propargylamines which leads to enantiomeric excess of up to 96%; it can be easily removed with a palladium(0)-catalyzed allylic substitution using 1,3-dimethylbarbituric acid as a nucleophile. ...
... The review summarises natural products containing the 2-pyrone moiety. An emphasis has been placed upon the biological activity associated with 2-pyrones, particularly with respect to potential therapeutic or anti-microbial agents. Where appropriate, non-natural 2-pyrone analogues are discussed, particularly those derived from natural product lead compounds. ...
medical entomology; vector-borne diseases; vector control; disease control programs; insect vectors; mosquito control; risk assessment; veterinary entomology; pesticides; research support
... This study content analyzed the 2004 Illinois U.S. Senate debates between Alan Keyes and Barak Obama. As is the case in presidential debates, acclaims (positive statements) were more common than attacks, which in turn were employed more frequently than defenses. Also consistent with presidential debates, these candidates discussed policy more than character. Both general goals and ideals were empl ...
... Applications of biotechnological tools, including genetic modification aimed at combating Dutch elm disease, are described. In vitro shoot cultures of Ulmus procera (English elm) SR4, U. glabra, U. americana, and U. parvifolia have been established and used as source material in genetic transfer experiments. Biolistic transformation of U. procera leaf material with cauliflower mosaic virus 35S-pro ...
... Root epidermis development in Arabidopsis provides a simple and powerful model for studying cell fate specification. Cellular, molecular, and genetic approaches have been used to define many genes, and their corresponding proteins, that are essential for the position-dependent specification of the two root epidermal cell types. These studies have led to a working model in which a network of transc ...
... Various aspects of somatic embryogenesis in carrot suspension cultures were reviewed on the basis of results obtained in our laboratory. We have established high-frequency and synchronous somatic embryogenesis systems needed for biochemical and molecular analysis. Using these systems, four phases of somatic embryogenesis were identified. The importance of expression of polarities in these phases, ...
... Current methods for creating transgenic varieties are labor and time intensive, comprised of the generation of hundreds of plants with random DNA insertions, screening for the few individuals with appropriate transgene expression and simple integration structure, and followed by a lengthy breeding process to introgress the engineered trait into cultivated varieties. Various modifications of existi ...