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... This study was carried out to determine the effect of intermittent frying of French fries using four different types of frying media on the media quality as well as 3-monochloropropane-1,2-diol esters (3-MCPDE) and glycidyl esters (GE) in frying oils and acrylamide contents in finished product. A total of 80 h of heating (control) and frying experiments at 180 °C was conducted, from which the heat ...
Acrocomia; Helianthus annuus; Jatropha; biodiesel; castor beans; cotton; crops; esters; fatty acids; feedstocks; fuel production; multi-criteria decision making; peanuts; research and development; soybean oil; soybeans; Brazil
Abstract:
... This work establishes a ranking of the potential oleaginous feedstocks for HEFA biojet production in southeast Brazil, and consolidates their advantages and limitations, in order to assist in prioritizing strategic actions, such as research, R&D investment, and incentives for the most promising regional oilseeds. The oilseeds and the criteria considered were determined from a bibliographical revie ...
2,2-diphenyl-1-picrylhydrazyl; Helianthus annuus; aerial parts; antioxidant activity; caffeic acid; emulsions; esters; in vitro studies; isomers; late flowering; oxidation; quinic acid; tandem mass spectrometry
Abstract:
... The aim of this study was to evaluate the differences in the antioxidant activity and phenolic profile of sunflower (Helianthus annuus L.) extracts obtained from the aerial parts of plants harvested at five growth stages. In vitro assays were used to determine the antioxidant activity, i.e., ABTS•⁺ and DPPH• scavenging activity, the ferric-reducing antioxidant power (FRAP) and the ability to inhib ...
Helianthus annuus; alpha-tocopherol; beta-tocotrienol; carbon; esters; hexane; phospholipids; scanning electron microscopy; sunflower oil; water activity; water content
Abstract:
... The aim of this work is to analyze the effect of moisture content of sunflower expanded material on the quality of the extracted oil by determining its wax, phospholipids, and tocopherol content and composition. Sunflower oil extraction is carried out in a batch extractor at 50 °C using hexane and three moisture levels (5.65, 12.40, and 18.92% dry basis). The increasing moisture content causes an ...
... The spray combustion characteristics of sunflower (Helianthus annuus) biodiesel/methyl esters (SFME) and 50% SFME/diesel blend and diesel were investigated via a liquid swirl flame burner. The swirl flame was established at atmospheric condition by using a combined twin-fluid atomiser-swirler configuration at varied atomising air-to-liquid ratios (ALR) of 2.0–2.5. Diesel flame showed a sooty flame ...
... A biobased approach was taken to endow microcrystalline cellulose (MCC) with surface hydrophobicity using sunflower oil biodiesel (sunflower oil fatty acid ethyl esters, SFEEs) and thereby improve the compatibility with a hydrophobic polypropylene (PP) matrix. This environmentally friendly green chemistry approach introduces a monomolecular long-chain fatty acid layer on the MCC surface, making th ...
... Biodiesel is the main substitute for petrodiesel being constituted by several alkyl esters including unsaturated compounds. It can undergo partial oxidation when stored for long periods and transported over long distances. The aims of this study were to analyze the impact of the oxidation process on the physicochemical properties of biodiesel and its remediation through distillation and esterifica ...
Helianthus annuus; alpha-chlorohydrin; cooking fats and oils; corn; detection limit; esters; mass spectrometry; peanuts; seeds; supermarkets; vegetable oil
Abstract:
... A series of refined edible oils derived from mixed seeds, peanuts, corn, sunflower and palm obtained from the local supermarket were analyzed for their content of 3-MCPD esters. A direct analytical method for the determination of 3-monochloropropane-1,2-diol esters (3-MCPD esters) was applied to investigate the major MCPD esters found in common edible oils; in particular seven types of monoesters ...
... Acyl-CoA-binding proteins (ACBPs) bind to acyl-CoA esters and promote their interaction with other proteins, lipids and cell structures. Small class I ACBPs have been identified in different plants, such as Arabidopsis thaliana (AtACBP6), Brassica napus (BnACBP) and Oryza sativa (OsACBP1, OsACBP2, OsACBP3), and they are capable of binding to different acyl-CoA esters and phospholipids. Here we cha ...
... The fatty acid composition and volatile compounds of selected traditional Macedonian edible oils of several varieties, including sunflower seeds, pumpkin seeds, flax seed, rapeseed and sesame seeds, were analysed. The fatty acid (FA) composition was determined by GC-FID analysis after transesterification into the corresponding methyl esters. α-Linolenic acid (C18:3) was the main unsaturated fatty ...
... The aim of this study was to investigate the physicochemical properties (moisture content, conductivity, 5-HMF, fructose, glucose, L*, a* and b* color parameters) and volatile compounds of Romanian honeys. According to the melissopalynological analysis, the honey samples were of the following botanical origins: acacia, sunflower and tilia. Liquid–liquid extraction followed by GC-MS analysis was us ...
... The antioxidant activity of ethyl and octyl hydroxytyrosyl ethers toward lipids was determined using the Rancimat and open cup methods at high temperatures and 50 °C, respectively. The effect of the unsaturation of the matrix was evaluated using sunflower, soya, and fish refined oils. The antioxidant activities of alkyl hydroxytyrosyl ethers (HTy ethers), hydroxytyrosyl esters, and free hydroxytyr ...
... In order to discriminate premium quality from inexpensive edible oils, the fatty acid profiles of tea, rapeseed, corn, sunflower and sesame oil were compared with the ones from extra virgin olive oil (EVOO). Fatty acid methyl esters were quantified by GC/MS. Principal component analysis (PCA) and random forests (RF) were applied to cluster the samples. RF showed a better ability of discrimination ...
... In this study, a novel experimental approach was used to overcome the lack of phase equilibrium information to obtain data that is more applicable to industrial situations. Liquid–liquid equilibrium (LLE) data, tie-lines, and phase boundaries were carried out for two systems of canola oil methyl esters (containing 1 wt % KOH) + glycerol + methanol and sunflower oil methyl esters (containing 1 wt % ...
... The present work is concerned with the performance, emission, and combustion characteristics of vegetable oil esters with varying saturated and unsaturated fatty acid composition tested in a stationary direct injection compression ignition engine. Saturated fatty acids (SFAs) are long-chain carboxylic acids that usually have between 12 and 24 carbon atoms and have no double bonds. Unsaturated fatt ...
... BACKGROUND: Oilseed germination is characterized by the degradation of storage lipids. It may proceed either via the direct action of a triacylglycerol lipase, or in certain plant species via a specific lipid body 13-lipoxygenase. For the involvement of a lipoxygenase previous results suggested that the hydroxy- or oxo-group that is being introduced into the fatty acid backbone by this lipoxygenas ...
... In this work, the quality of biodiesel produced by basic transesterification from several vegetable oils (soybean, rapeseed, sunflower, high oleic sunflower, Cynara Cardunculus L., Brassica Carinata and Jatropha Curca) cultivated in Extremadura has been studied in detail. The influence of raw material composition on properties such as density, viscosity, cetane number, higher heating value, iodine ...
... New renewable fuels are urgently needed due to increasing fossil fuel pollution. Biodiesel, which contains alkyl esters produced by transesterification of oils, is an alternative fuel. Nevertheless, the main problem of biodiesel is its high price. Costs can be reduced by replacement of the current homogeneous catalysts by heterogeneous catalysts; however, research for new catalysts is actually slo ...
... This study evaluated the capabilities of a handheld mid-infrared (MIR) spectrometer combined with multivariate analysis to characterize oils, monitor chemical processes occurring during oxidation, and to determine fatty acid composition. Vegetable oils (corn, peanut, sunflower, safflower, cottonseed, and canola) were stored at 65 °C for 30 days to accelerate oxidation reactions. Aliquots were draw ...
... In this study, fatty acid ethyl esters (FAEE) were produced from four different vegetable oils (sunflower, cotton seed, olive oil, and used frying oil) using calcium ethoxide as a heterogeneous solid base catalyst. The ester preparation involved a two-step transesterification reaction, followed by purification. The effects of the mass ratio of catalyst to oil, the molar ratio of ethanol to oil, an ...