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1. Determination of formaldehyde and acetaldehyde in air by HPLC with fluorescence detection

Author:
M. Possanzini; V. Di Palo
Source:
Chromatographia 1997 v.46 no.5-6 pp. 235-240
ISSN:
0009-5893
Subject:
acetaldehyde; acetonitrile; air; detection limit; fluorescence; fluorometry; formaldehyde; ozone; reversed-phase high performance liquid chromatography; silica gel; storage quality
Abstract:
... Sensitive detection of atmospheric formaldehyde and acetaldehyde can be achieved by use of silica-gel cartridges impregnated with 2-diphenylacetyl-1,3-indandione-1-hydrazone (DAIH) to form fluorescent DAI hydrazones. The hydrazones are extracted with acetonitrile and separated by reversed-phase HPLC with fluorimetric detection. The low detection limits achieved (0.25 ppb CH₂O or CH₃CHO for samplin ...
DOI:
10.1007/BF02496312

2. Effect of application solvents on heterotrophic and nitrifying populations in soil microcosms

Author:
Miller, J.L.; Sardo, M.A.; Thompson, T.L.; Miller, R.M.
Source:
Environmental toxicology and chemistry 1997 v.16 no.3 pp. 447-451
ISSN:
0730-7268
Subject:
acetonitrile; air; ammonia; carbon; fuels; groundwater; methanol; methylene chloride; mineralization; naphthalene; nitrification; nitrogen fertilizers; pesticides; soil; soil ecology; soil pollution; solvents
Abstract:
... Agricultural practices may cause contamination of soil and ground water with a combination of organic compounds (pesticides and fuel) and nitrogen fertilizers. In coupled microcosm studies that monitored the mineralization of naphthalene and the nitrification of ammonia, it was observed that the solvent (dichloromethane) used to apply naphthalene to the soil inhibited nitrification, although there ...
DOI:
10.1897/1551-5028(1997)016<0447:EOASOH>2.3.CO;2

3. Air monitoring of aldehydes by use of hydrazine reagents with a triazine backbone

Author:
C. Kempter; T. Berkhoudt; Greve C. Tolbøl; K. Egmose; U. Karst
Source:
Analytical and bioanalytical chemistry 2002 v.372 no.5-6 pp. 639-643
ISSN:
1618-2642
Subject:
acetonitrile; air; aldehydes; detection limit; fluorescence; fluorescence emission spectroscopy; hydrazine; monitoring; nitrogen dioxide; ozone; reversed-phase liquid chromatography; silica gel; triazines
Abstract:
... Two hydrazine reagents, 4-N,N-dimethylamino-6-(4′-methoxy-1′-naphthyl)-1,3,5-triazine-2-hydrazine (DMNTH) and N-methyl-4-N′,N′-dimethylamino-6-(4′-methoxy-1′-naphthyl)-1,3,5-triazine-2-hydrazine (MDMNTH) have been synthesized and used for the determination of aldehydes in air samples. Test tubes with the reagents coated on silica gel were prepared and used for monitoring of carbonyls in air. After ...
DOI:
10.1007/s00216-002-1247-5

4. Development of a LC-MS/MS method for the analysis of volatile primary and secondary amines as NIT (naphthylisothiocyanate) derivatives

Author:
Anna-Sara Claeson; Anders Östin; Anna-Lena Sunesson
Source:
Analytical and bioanalytical chemistry 2004 v.378 no.4 pp. 932-939
ISSN:
1618-2642
Subject:
acetonitrile; air; ammonia; detection limit; high performance liquid chromatography; mass spectrometry; microbial culture; monitoring; screening; secondary amines; tires
Abstract:
... High-performance liquid chromatography with mass spectrometric detection was used for the structure elucidation of eighteen primary and secondary amines and ammonia derivatised with naphthylisothiocyanate (NIT). A fragmentation scheme was established using reference compounds and the scheme was applied to real air samples from a tyre repair shop and from the air above a bacterial culture. The samp ...
DOI:
10.1007/s00216-003-2205-6

5. Development of a Passive Sampler for Long-Term Measurements of Formaldehyde and Total Oxidants in Air

Author:
G. Bertoni; C. Ciuchini; V. Di. Palo; M. Possanzini
Source:
Chromatographia 2005 v.61 no.7-8 pp. 385-389
ISSN:
0009-5893
Subject:
acetonitrile; air; formaldehyde; high performance liquid chromatography; hydrazine; nitrogen dioxide; oxidants; ozone; phosphoric acid; samplers; silica gel
Abstract:
... A diffusive sampling device is described that is capable of reliable measurements of formaldehyde and total oxidants (Ox = ozone + nitrogen dioxide) at sub-ppbv concentration levels in ambient air. These species are collected on silica gel particles coated with 1-methyl-1-(2,4-dinitrophenyl)hydrazine (MDNPH) and phosphoric acid. The formaldehyde hydrazone (HCHO-MDNPh) and the N-methyl-2,4-dinitroa ...
DOI:
10.1365/s10337-005-0525-8

6. Ultra high pressure liquid chromatography

Author:
Gritti, Fabrice; Guiochon, Georges
Source:
Journal of chromatography 2008 v.1187 no.1-2 pp. 165-179
ISSN:
0021-9673
Subject:
acetonitrile; air; equations; heat; high performance liquid chromatography; permeability; silica; stainless steel; surface area; temperature profiles; viscosity
Abstract:
... The behavior of four similar liquid chromatography columns (2.1mm i.d. x 30, 50, 100, and 150mm, all packed with fine particles, average [formula removed]m, of bridged ethylsiloxane/silica hybrid-C₁₈, named BEH-C₁₈) was studied in wide ranges of temperature and pressure. The pressure and the temperature dependencies of the viscosity and the density of the eluent (pure acetonitrile) along the colum ...
DOI:
10.1016/j.chroma.2008.02.036

7. Aerobic oxidative iodination of ketones catalysed by sodium nitrite “on water” or in a micelle-based aqueous system

Author:
Gaj Stavber; Jernej Iskra; Marko Zupan; Stojan Stavber
Source:
Green chemistry 2009 v.11 no.8 pp. 1262-1267
ISSN:
1463-9270
Subject:
acetonitrile; air; aqueous solutions; aromatic compounds; catalysts; catalytic activity; green chemistry; iodination; iodine; ketones; moieties; organoiodine compounds; oxidants; regioselectivity; sodium dodecyl sulfate; sodium nitrite; sulfuric acid; surfactants
Abstract:
... Selective and efficient aerobic oxidative iodination of ketones in aqueous media was achieved by using molecular iodine as the source of iodine atoms, air as the terminal oxidant, sodium nitrite (NaNO₂) as the catalyst and H₂SO₄ as the activator of the overall catalytic process. The efficiency of the reaction, resulting in α-iodo ketones, was significantly improved in an aqueous solution of the an ...
DOI:
10.1039/b902230a

8. Development and validation of an automated monitoring system for oxygenated volatile organic compounds and nitrile compounds in ambient air

Author:
Roukos, J.; Plaisance, H.; Leonardis, T.; Bates, M.; Locoge, N.
Source:
Journal of chromatography 2009 v.1216 no.49 pp. 8642-8651
ISSN:
0021-9673
Subject:
acetaldehyde; acetone; acetonitrile; air; detection limit; emissions; esters; ethanol; ethers; flame ionization; helium; hydrophobicity; monitoring; polar compounds; relative humidity; temperature; vehicles (equipment); volatile organic compounds
Abstract:
... Few studies were conducted on oxygenated volatile organic compounds (OVOC) because of problems encountered during the sampling/analyzing steps induced by water in sampled air. Consequently, there is a lack of knowledge of their spatial and temporal trends and their origins in ambient air. In this study, an analyzer consisted of a thermal desorber (TD) interfaced with a gas chromatograph (GC) and a ...
DOI:
10.1016/j.chroma.2009.10.018

9. Optimization of the thermal environment of columns packed with very fine particles

Author:
Gritti, Fabrice; Guiochon, Georges
Source:
Journal of chromatography 2009 v.1216 no.9 pp. 1353-1362
ISSN:
0021-9673
Subject:
acetonitrile; air; chromatography; friction; heat; streams; temperature
Abstract:
... The apparent reduced HETP (height equivalent to a theoretical plate) of columns packed with very fine 1.7 μm BEH-C₁₈particles were measured under isocratic conditions, for different thermal conditions applied to the surface wall (column left in still-air at laboratory temperature, column placed in the oven of the Acquity UPLC chromatograph heated at different temperatures, or column immersed in a ...
DOI:
10.1016/j.chroma.2008.12.072

10. Electrocatalytic CO₂ Conversion to Oxalate by a Copper Complex

Author:
Angamuthu, Raja; Byers, Philip; Lutz, Martin; Spek, Anthony L.; Bouwman, Elisabeth
Source:
Science 2010 v.327 no.5963 pp. 313-315
ISSN:
0036-8075
Subject:
acetonitrile; air; carbon dioxide; catalytic activity; copper; electrochemistry; electrodes; feedstocks; global warming; hydrogen; lithium; oxalates; oxygen; superoxide anion; value added
Abstract:
... Global warming concern has dramatically increased interest in using CO₂ as a feedstock for preparation of value-added compounds, thereby helping to reduce its atmospheric concentration. Here, we describe a dinuclear copper(I) complex that is oxidized in air by CO₂ rather than O₂; the product is a tetranuclear copper(II) complex containing two bridging CO₂-derived oxalate groups. Treatment of the c ...
DOI:
10.1126/science.1177981

11. Surface grafting on poly(ethylene terephthalate) track-etched microporous membrane by activation with trifluorotriazine: Application to the biofunctionalization with GRGDS peptide

Author:
Rerat, Vincent; Pourcelle, Vincent; Devouge, Sabrina; Nysten, Bernard; Marchand-Brynaert, Jacqueline
Source:
Journal of polymer science 2010 v.48 no.1 pp. 195-208
ISSN:
0887-624X
Subject:
X-ray photoelectron spectroscopy; acetonitrile; air; atomic force microscopy; autoclaves; biocompatible materials; cell culture; contact angle; derivatization; gamma radiation; heat; hydrophilicity; ionization; polyethylene terephthalates; steam
Abstract:
... A two-step wet chemistry protocol has been developed for the surface derivatization of poly(ethylene terephthalate) (PET) track-etched membrane used as cell culturing support, that is, (a) activation by trifluorotriazine (1 M in acetonitrile (ACN), 30 °C, 3 h); (b) coupling to amine-terminated molecules, namely 3,5-bis(trifluoromethyl)benzylamine ((F)Tag), (L)-4,5-[³H]-lysine, and Gly-Arg-Gly-Asp- ...
DOI:
10.1002/pola.23778

12. Analysis of phthalic, isophthalic and long-chain (C₄–C₁₂) dicarboxylic acids in atmospheric aerosols by UPLC/ESI/ToF-MS

Author:
Giovanni Mirivel; Véronique Riffault; Jean-Claude Galloo
Source:
Analytical methods 2011 v.3 no.5 pp. 1172-1179
ISSN:
1759-9679
Subject:
acetonitrile; aerosols; air; dicarboxylic acids; experimental design; filters; formic acid; ionization; liquids; mass spectrometry; methanol; solvents; ultra-performance liquid chromatography
Abstract:
... A new analytical method for the simultaneous determination of phthalic, isophthalic and 14 long-chain dicarboxylic acids in ambient aerosols by ultra-performance liquid chromatography/time-of-flight mass spectrometry with negative-ion electrospray ionization was developed and validated. A fast and quantitative pressurized fluid extraction procedure with water as solvent was optimized using samplin ...
DOI:
10.1039/c0ay00677g

13. Nano Pd(0) supported on cellulose: A highly efficient and recyclable heterogeneous catalyst for the Suzuki coupling and aerobic oxidation of benzyl alcohols under liquid phase catalysis

Author:
Navjot Jamwal; Ravinderpal Kour Sodhi; Princy Gupta; Satya Paul
Source:
International journal of biological macromolecules 2011 v.49 no.5 pp. 930-935
ISSN:
0141-8130
Subject:
X-ray diffraction; acetonitrile; air; benzaldehyde; bromides; catalysts; catalytic activity; cellulose; ethanol; hydrazine; mixing; oxidation; oxygen; palladium; scanning electron microscopes; scanning electron microscopy; thermal analysis; transmission electron microscopes; transmission electron microscopy
Abstract:
... Nano palladium(0) supported on cellulose was found to be highly efficient recyclable heterogeneous catalyst for the Suzuki coupling between aryl bromides and phenyl boronic acid in water and aerobic oxidation of benzyl alcohols using air as the source of molecular oxygen in acetonitrile. The Cell-Pd(0) was prepared by stirring commercially available cellulose with Pd(OAc)₂ in ethanol at 25°C follo ...
DOI:
10.1016/j.ijbiomac.2011.08.013

14. Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring

Author:
Kasper Kristensen; Marianne Glasius
Source:
Atmospheric environment 2011 v.45 no.27 pp. 4546-4556
ISSN:
1352-2310
Subject:
high performance liquid chromatography; volatile organic compounds; adipic acid; sulfonic acids; mass spectrometry; forests; detection limit; atmospheric chemistry; aerosols; camphor; air; oxidation; conifers; isoprene; acetonitrile; filters; methanol; quartz; spring; solvents; air pollution; Denmark
Abstract:
... Organosulfates of monoterpenes and isoprene, as well as their oxidation products have been identified in biogenic secondary organic aerosols (BSOA) from both laboratory and field studies. Organosulfates provide an interesting coupling between air pollution and formation of low-volatility BSOA. HPLC quadrupole time-of-flight mass spectrometry was used to study polar acidic monoterpene and isoprene ...
DOI:
10.1016/j.atmosenv.2011.05.063

15. Oxidative desulfurization of diesel with TBHP/isobutyl aldehyde/air oxidation system

Author:
Wei Guo; Chengyong Wang; Peng Lin; Xiaoping Lu
Source:
Applied energy 2011 v.88 no.1 pp. 175-179
ISSN:
0306-2619
Subject:
acetonitrile; air; aldehydes; diesel fuel; hydrogenation; oxidants; oxidation; peroxidation; sulfur; synergism; temperature
Abstract:
... Oxidative desulfurization of hydrogenation diesel (40mL) was studied using air as oxidant, tert-butyl hydroperoxide (TBHP) as radical initiator at ambient pressure and moderate temperature in the presence of isobutyl aldehyde. TBHP could accelerate the production of carbonyl radical and its peroxidation. When the molar fraction of TBHP was 5mmol, the conversion of DBT could reach 96.1% in the pres ...
DOI:
10.1016/j.apenergy.2010.08.003

16. Synthesis and catalytic application of monometallic molybdenum(IV) nitrile complexes

Author:
Bernd E. Diebl; Hui Yee Yeong; Mirza Cokoja; Eberhardt Herdtweck; Brigitte Voit; Fritz E. Kühn
Source:
Tetrahedron letters 2011 v.52 no.9 pp. 955-959
ISSN:
0040-4039
Subject:
acetonitrile; air; chemical structure; molecular weight; molybdenum; oils; oxidation; synthesis; temperature
Abstract:
... The novel molybdenum(IV) compound [MoO(NCMe)₅][B(C₆F₅)₄]₂ (1a) has been prepared by air oxidation of [Mo(CO)₃(NCMe)₃] in the presence of [H(OEt₂)₂][B(C₆F₅)₄] at room temperature. The [MoO(NCMe)₅]²⁺ cation shows a distorted octahedral configuration with two different acetonitrile-metal bond lengths due to a trans effect of the oxo-ligand. The trans-acetonitrile ligand is easily abstracted under oil ...
DOI:
10.1016/j.tetlet.2010.12.059

17. Biomass burning in Siberia as a source of BrO to the Arctic free troposphere

Author:
M. Pommier; C.A. McLinden; J.A. Neuman; J.B. Nowak
Source:
Atmospheric environment 2012 v.62 no. pp. 416-423
ISSN:
1352-2310
Subject:
acetonitrile; aerosols; air; aircraft; atmospheric chemistry; biomass; bromine; burning; carbon monoxide; climate; forest fires; ozone; stratosphere; troposphere; water; water vapor; Alaska; Arctic region; Siberia
Abstract:
... During the ARCPAC (Aerosol, Radiation, and Cloud Processes affecting Arctic Climate) campaign in April 2008, several flights of the WP-3D research aircraft over the Arctic Ocean and Alaska sampled relatively rich bromine monoxide (BrO > 5 pptv) air masses in the free troposphere. In most cases air masses were identified as either stratospheric intrusions or as being recently in contact with sea-ic ...
DOI:
10.1016/j.atmosenv.2012.08.070

18. Corona Discharge Ion Mobility Spectrometry with Orthogonal Acceleration Time of Flight Mass Spectrometry for Monitoring of Volatile Organic Compounds

Author:
Sabo Martin; Matejčík Štefan
Source:
Analytical chemistry 2012 v.84 no.12 pp. 5327-5334
ISSN:
1520-6882
Subject:
1-propanol; acetone; acetonitrile; air; atmospheric pressure; benzene; butanol; ethanol; formaldehyde; ionization; mass spectrometry; methanol; models; monitoring; nitrogen; tetrahydrofuran; toluene; triethylamine; volatile organic compounds; xylene
Abstract:
... We demonstrate the application of corona discharge ion mobility spectrometry with orthogonal acceleration time of flight mass spectrometry (CD IMS-oaTOF) for volatile organic compounds (VOCs) monitoring. Two-dimensional (2D) IMS-oaTOF spectra of VOCs were recorded in nearly real time. The corona discharge atmospheric pressure chemical ionization (APCI) source was operated in positive mode in nitro ...
DOI:
10.1021/ac300722s

19. Efficient and Highly Aldehyde Selective Wacker Oxidation

Author:
Teo Peili; Wickens Zachary K.; Dong Guangbin; Grubbs Robert H.
Source:
Organic letters 2012 v.14 no.13 pp. 3237-3239
ISSN:
1523-7052
Subject:
acetonitrile; air; aldehydes; alkenes; benzoquinones; chemical structure; oxidation
Abstract:
... A method for efficient and aldehyde-selective Wacker oxidation of aryl-substituted olefins using PdCl₂(MeCN)₂, 1,4-benzoquinone, and t-BuOH in air is described. Up to a 96% yield of aldehyde can be obtained, and up to 99% selectivity can be achieved with styrene-related substrates. ...
DOI:
10.1021/ol301240g

20. Oxygen-Initiated Chain Mechanism for Hydride Transfer Between NADH and NAD+ Models. Reaction of 1-Benzyl-3-Cyanoquinolinium Ion with N-Methyl-9,10-Dihydroacridine in Acetonitrile

Author:
Hao Weifang; Parker Vernon D.
Source:
Journal of organic chemistry 2012 v.77 no.20 pp. 9286-9297
ISSN:
1520-6904
Subject:
NAD (coenzyme); acetonitrile; aerobic conditions; air; hydrides; isotopes; organic chemistry; oxygen
Abstract:
... A reinvestigation of the formal hydride transfer reaction of 1-benzyl-3-cyanoquinolinium ion (BQCN⁺) with N-methyl-9,10-dihydroacridine (MAH) in acetonitrile (AN) confirmed that the reaction takes place in more than one step and revealed a new mechanism that had not previously been considered. These facts are unequivocally established on the basis of conventional pseudo-first-order kinetics. It wa ...
DOI:
10.1021/jo301874q

21. Radical-Involved Photosynthesis of AuCN Oligomers from Au Nanoparticles and Acetonitrile

Author:
Li Renhong; Kobayashi Hisayoshi; Tong Jiawei; Yan Xiaoqing; Tang Yu; Zou Shihui; Jin Jiabin; Yi Wuzhong; Fan Jie
Source:
Journal of the American Chemical Society 2012 v.134 no.44 pp. 18286-18294
ISSN:
1520-5126
Subject:
acetonitrile; air; catalytic activity; chemical bonding; cyanides; dissociation; gas chromatography-mass spectrometry; gold; hydroxybenzaldehyde; irradiation; nanogold; nuclear magnetic resonance spectroscopy; photosynthesis; porous media; silica; transmission electron microscopy; trapping; ultraviolet radiation
Abstract:
... We show here the first radical route for the direct photosynthesis of AuCN oligomers with different sizes and shapes, as evidenced by TEM observations, from an Au nanoparticle/benzaldehyde/CH₃CN ternary system in air under UV-light irradiation. This photochemical route is green, mild, and universal, which makes itself distinguishable from the common cyanidation process. Several elementary reaction ...
DOI:
10.1021/ja305198p

22. Reaction of a copper(ii)–nitrosyl complex with hydrogen peroxide: putative formation of a copper(i)–peroxynitrite intermediate

Author:
Apurba Kalita; Pankaj Kumar; Biplab Mondal
Source:
Chemical communications 2012 v.48 no.38 pp. 4636-4638
ISSN:
1364-548X
Subject:
acetonitrile; air; chemical communication; copper; hydrogen peroxide; nitric oxide; oxidation; phenol; spectral analysis; ultraviolet-visible spectroscopy
Abstract:
... The reaction of a Cu(ii)–nitrosyl complex (1) with hydrogen peroxide at −20 °C in acetonitrile results in the formation of the corresponding Cu(i)–peroxynitrite intermediate. The reduction of the Cu(ii) center was monitored by UV-visible spectroscopic studies. Formation of the peroxynitrite intermediate has been confirmed by its characteristic phenol ring nitration reaction as well as isolation of ...
DOI:
10.1039/c2cc31117h

23. Surface Tension Measurement at the Microscale by Passive Resonance of Capillary Waves

Author:
Pigot Christian; Hibara Akihide
Source:
Analytical chemistry 2012 v.84 no.5 pp. 2557-2561
ISSN:
1520-6882
Subject:
acetonitrile; air; light scattering; methanol; methodology; surface tension
Abstract:
... The properties of fluid interfaces increase in importance as the physical scale decreases and, hence, characterization of surface tension becomes all the more critical. However, there is to date no method to characterize this parameter on microscale surfaces. We propose here a simple method based on the resonance of capillary waves, which are naturally excited by thermal fluctuations, under one-di ...
DOI:
10.1021/ac3000804

24. Analisis kromatografi cair kinerja tinggi untuk penetapan kadar asam galat, kafein dan epigalokatekin galat pada beberapa produk teh celup

Author:
Yohanes Martono; Sudibyo Martono
Source:
Agritech 2013 v.32 no.04 pp. -
ISSN:
2527-3825
Subject:
acetonitrile; air; black tea; detection limit; epigallocatechin gallate; gallic acid; green tea; high performance liquid chromatography; methanol; pH; tea bags
Abstract:
... A rapid and accurate High Performance Liquid Chromatography (HPLC) method for determination of gallic acid, caffein, and epigallocatechin gallate (EGCG) with an isocratic mobile phase elution was developed. HPLC parameters consisted of a C18 reversed-phase column (Eurosphere C18, 250 × 4.6 mm i.d., 5μm), mobile phase composed of 0.1% ortho phosporic acid : water : acetonitrile : methanol (14 : 7 : ...
DOI:
10.22146/agritech.9578

25. Degradation of VX Surrogate Profenofos on Surfaces via in Situ Photo-oxidation

Author:
Petrick Lauren M.; Sabach Sara; Dubowski Yael
Source:
Environmental Science & Technology 2013 v.47 no.15 pp. 8751-8758
ISSN:
1520-5851
Subject:
acetonitrile; air; hydrophilicity; instrumentation; nerve tissue; oxygen; ozone; phosphoric acid; photooxidation; profenofos; relative humidity; superoxide anion; ultraviolet radiation
Abstract:
... Surface degradation of profenofos (PF), a VX nerve gas surrogate, was investigated using in situ photo-oxidation that combines simple instrumentation and ambient gases (O₂ and H₂O) as a function of exposure conditions ([O₃], [OH], UV light λ = 185 and/or 254 nm, relative humidity) and PF film surface density (0.38–3.8 g m–²). PF film 0.38 g m–² fully degraded after 60 min of exposure to both 254 a ...
DOI:
10.1021/es4016537

26. Simultaneous Determination of Pyridine-Triphenylborane Anti-Fouling Agent and Its Degradation Products in Artificial Seawater by CZE

Author:
Netnapit Kaewchuay; Keiichi Fukushi; Takanari Hattori
Source:
Chromatographia 2013 v.76 no.15-16 pp. 1049-1053
ISSN:
0009-5893
Subject:
acetonitrile; air; chromatography; electrolytes; hydrolysis; pH; phenol; photolysis; seawater; sodium
Abstract:
... We developed a CZE method for simultaneous determination of pyridine-triphenylborane (PTPB) anti-fouling agent and its degradation products such as diphenylborinic acid (DPB), phenylboronic acid (MPB), and phenol in artificial seawater (ASW) with no extraction procedure. The ASW samples, in which 20 % (v/v) acetonitrile was added, were injected directly into the capillary using vacuum injection. A ...
DOI:
10.1007/s10337-013-2506-7

27. A modular approach toward the synthesis of 2,4-disubstituted pyridines

Author:
Raju Singha; Shubhendu Dhara; Jayanta K. Ray
Source:
Tetrahedron letters 2013 v.54 no.36 pp. 4841-4843
ISSN:
0040-4039
Subject:
acetonitrile; air; aldehydes; ammonium chloride; chemical reactions; chemical structure; pyridines; solvents; synthesis; triethylamine
Abstract:
... A number of 2,4-disubstituted pyridines have been synthesized using α,β,γ,δ-unsaturated aldehydes and ammonium chloride in the presence of triethylamine in acetonitrile solvent at 80°C under air balloon. ...
DOI:
10.1016/j.tetlet.2013.06.092

28. Coupling ASE, sylilation and SPME–GC/MS for the analysis of current-used pesticides in atmosphere

Author:
Caroline Raeppel; Marie Fabritius; Marie Nief; Brice M.R. Appenzeller; Maurice Millet
Source:
Talanta 2014 v.121 pp. 24-29
ISSN:
0039-9140
Subject:
acetonitrile; acids; air; derivatization; desorption; filters; gas chromatography-mass spectrometry; glass fibers; ions; pesticides; sodium chloride; solid phase microextraction; solvents; spring; summer; traps; uncertainty; urea; France
Abstract:
... An analytical methodology using Accelerated Solvent Extraction (ASE) and a sylilation procedure coupled to Solid Phase Micro-Extraction (SPME) and GC/MS was developed for the determination of 31 pesticides of different chemical classes (urea, phenoxy acids, pyrethrenoïds, etc.) commonly used in non-agricultural areas in atmospheric samples. This methodology was developed to evaluate the outdoor at ...
DOI:
10.1016/j.talanta.2013.12.040

29. Determination of methylamine, dimethylamine, and trimethylamine in air by high-performance liquid chromatography with derivatization using 9-fluorenylmethylchloroformate

Author:
Mohammad Asif Iqbal; Jan E. Szulejko; Ki-Hyun Kim
Source:
Analytical methods 2014 v.6 no.15 pp. 5697-5707
ISSN:
1759-9679
Subject:
Raja clavata; acetonitrile; air; biodegradation; derivatization; detection limit; dimethylamine; fish; headspace analysis; high performance liquid chromatography; liquids; methylamine; methylation; spoilage; total volatile basic nitrogen; trimethylamine
Abstract:
... An HPLC-UV method coupled with 9-fluorenylmethylchloroformate (FMOC) derivatization was developed for the determination of short chained amines in an environmental matrix. The basic reaction conditions among different target compounds (three methylated amines: mono- (MA), di- (DMA), and tri-methylamine (TMA)) with the reagent (FMOC) have been investigated. Comparative calibration of TMA as an indi ...
DOI:
10.1039/c4ay00740a

30. The Development and Validation of a Stability-Indicating UHPLC-DAD Method for Determination of Perindopril L-Arginine in Bulk Substance and Pharmaceutical Dosage Form

Author:
Magdalena Paczkowska; Przemysław Zalewski; Piotr Garbacki; Alicja Talaczyńska; Anna Krause; Judyta Cielecka-Piontek
Source:
Chromatographia 2014 v.77 no.21-22 pp. 1497-1501
ISSN:
0009-5893
Subject:
acetonitrile; air; angiotensin-converting enzyme inhibitors; arginine; cis-trans isomers; detection limit; drug formulations; formic acid; humidity; hydrolysis; oxidation; ultra-performance liquid chromatography; wavelengths
Abstract:
... A stability-indicating ultra-high-performance liquid chromatography (UHPLC) method with a diode array detector was developed and validated for the determination of cis/trans isomers of perindopril L-arginine in bulk substance and pharmaceutical dosage form. The separation was achieved on a Poroshell 120 Hilic (4.6 × 150 mm, 2.7 µm) column using a mobile phase composed of acetonitrile–0.1 % formic ...
DOI:
10.1007/s10337-014-2724-7
PubMed:
25400289
PubMed Central:
PMC4224746

31. Dispersed-Nanoparticle Loading Synthesis for Monodisperse Au-Titania Composite Particles and Their Crystallization for Highly Active UV and Visible Photocatalysts

Author:
Sakamoto Takeshi; Nagao Daisuke; Noba Masahiro; Ishii Haruyuki; Konno Mikio
Source:
Langmuir 2014 v.30 no.24 pp. 7244-7250
ISSN:
1520-5827
Subject:
acetonitrile; air; crystallization; ethanol; gold; hot water treatment; irradiation; nanogold; photocatalysis; photocatalysts; solvents; titanium dioxide; ultraviolet radiation
Abstract:
... Submicrometer-sized amorphous titania spheres incorporating Au nanoparticles (NPs) were prepared in a one-pot synthesis consisting of a sol–gel reaction of titanium(IV) isopropoxide in the presence of chloroauric acid and a successive reduction with sodium borohydride in a mixed solvent of ethanol/acetonitrile. The synthesis was allowed to prepare monodisperse titania spheres that homogeneously in ...
DOI:
10.1021/la5012499

32. Epoxidation of styrene over Fe(Cr)-MIL-101 metal–organic frameworks

Author:
Jian Sun; Guangli Yu; Qisheng Huo; Qiubin Kan; Jingqi Guan
Source:
RSC advances 2014 v.4 no.72 pp. 38048-38054
ISSN:
2046-2069
Subject:
acetonitrile; air; catalysts; catalytic activity; coordination polymers; epoxidation reactions; hydrogen peroxide; iron; metal ions; oxidants; solvents; styrene
Abstract:
... Epoxidation of styrene is one of the key reactions in organic synthesis. In this paper, we investigated the effect of different metal ions in MIL-101 metal–organic framework on styrene epoxidation using various oxidants such as air, H₂O₂ and TBHP. For the aerobic epoxidation of styrene, Fe-MIL-101 and Cr-MIL-101 presented good styrene conversion (87.2 vs. 65.5%) and epoxide selectivity (54.4% vs. ...
DOI:
10.1039/c4ra05402d

33. Inhalable Constituents of Thirdhand Tobacco Smoke: Chemical Characterization and Health Impact Considerations

Author:
Sleiman Mohamad; Logue Jennifer M.; Luo Wentai; Pankow James F.; Gundel Lara A.; Destaillats Hugo
Source:
Environmental Science & Technology 2014 v.48 no.22 pp. 13093-13101
ISSN:
1520-5851
Subject:
acetonitrile; acrolein; air; chronic exposure; cigarettes; disability-adjusted life year; furans; inhalation exposure; nicotine; particulates; pollutants; smoke; smoking (habit); sorption; tracer techniques; volatile organic compounds; California
Abstract:
... Tobacco smoke residues lingering in the indoor environment, also termed thirdhand smoke (THS), can be a source of long-term exposure to harmful pollutants. THS composition is affected by chemical transformations and by air–surface partitioning over time scales of minutes to months. This study identified and quantified airborne THS pollutants available for respiratory exposure, identified potential ...
DOI:
10.1021/es5036333

34. Long-Term Air-Stable n-Channel Organic Thin-Film Transistors Using 2,5-Difluoro-1,4-phenylene-bis{2-[4-(trifluoromethyl)phenyl]acrylonitrile}

Author:
Nagamatsu Shuichi; Oku Shinya; Kuramoto Kouji; Moriguchi Tetsuji; Takashima Wataru; Okauchi Tatsuo; Hayase Shuzi
Source:
ACS applied materials 2014 v.6 no.6 pp. 3847-3852
ISSN:
1944-8252
Subject:
acetonitrile; air; aldehydes; condensation reactions; semiconductors
Abstract:
... A long-term air-stable n-type organic semiconductor, 2,5-difluoro-1,4-phenylene-bis{2-[4-(trifluoromethyl)phenyl]acrylonitrile}, was synthesized by a high-yield simple procedure of Knoevenagel condensation with aldehyde and acetonitrile derivatives. A fabricated organic thin-film transistor (OTFT) using this compound exhibited good n-channel OTFT properties with a high electron mobility of 0.17 cm ...
DOI:
10.1021/am404549e

35. Metal-Free Azaphosphaannulation of Phosphonamides through Intramolecular Oxidative C–N Bond Formation

Author:
Kim Yea Rin; Cho Seungyoon; Lee Phil Ho
Source:
Organic letters 2014 v.16 no.11 pp. 3098-3101
ISSN:
1523-7052
Subject:
acetonitrile; air; chemical bonding; chemical reactions; chemical structure; iodine; phosphorus
Abstract:
... We report an efficient metal-free azaphosphaannulation of a myriad of phosphonamides through intramolecular oxidative C–N bond formation using PhI(OAc)₂ and iodine in acetonitrile under air, thus leading to the formation of benzazaphosphol-3-one 1-oxides, which are novel phosphorus heterocyclic privileged structures. ...
DOI:
10.1021/ol501207w

36. Molecular Characterization of Organosulfates in Organic Aerosols from Shanghai and Los Angeles Urban Areas by Nanospray-Desorption Electrospray Ionization High-Resolution Mass Spectrometry

Author:
Tao Shikang; Lu Xiaohui; Levac Nicole; Bateman Adam P.; Nguyen Tran B.; Bones David L.; Nizkorodov Sergey A.; Laskin Julia; Laskin Alexander; Yang Xin
Source:
Environmental Science & Technology 2014 v.48 no.18 pp. 10993-11001
ISSN:
1520-5851
Subject:
acetonitrile; aerosols; air; alkanes; electrospray ionization mass spectrometry; emissions; esterification; hygroscopicity; ionization; molecular weight; nitrogen; non-polar compounds; organic sulfur compounds; solvents; sulfates; sulfuric acid; surface tension; surfactants; toluene; urban areas; California; China
Abstract:
... Fine aerosol particles in the urban areas of Shanghai and Los Angeles were collected on days that were characterized by their stagnant air and high organic aerosol concentrations. They were analyzed by nanospray-desorption electrospray ionization mass spectrometry with high mass resolution (m/Δm = 100,000). Solvent mixtures of acetonitrile and water and acetonitrile and toluene were used to extrac ...
DOI:
10.1021/es5024674

37. Nitrogen-Doped Carbon Nanoparticles by Flame Synthesis as Anode Material for Rechargeable Lithium-Ion Batteries

Author:
Bhattacharjya Dhrubajyoti; Park Hyean-Yeol; Kim Min-Sik; Choi Hyuck-Soo; Inamdar Shaukatali N.; Yu Jong-Sung
Source:
Langmuir 2014 v.30 no.1 pp. 318-324
ISSN:
1520-5827
Subject:
acetone; acetonitrile; air; anodes; burning; carbon nanoparticles; dielectric spectroscopy; energy efficiency; graphene; ions; lithium batteries
Abstract:
... Nitrogen-doped turbostratic carbon nanoparticles (NPs) are prepared using fast single-step flame synthesis by directly burning acetonitrile in air atmosphere and investigated as an anode material for lithium-ion batteries. The as-prepared N-doped carbon NPs show excellent Li-ion stoarage properties with initial discharge capacity of 596 mA h g–¹, which is 17% more than that shown by the correspond ...
DOI:
10.1021/la403366e

38. Notizen: 3-Diethylamino-5-phenyl-1,2,4-dithiazolium-hexachlorodicuprat(II) und -tetrachlorocuprat(II), (dpd)2Cu2Cl6 und (dpd)2CuCl4 / 3-Diethylamino-5-phenyl-1,2,4-dithiazolium Hexachlorodicuprates(II) and Tetrachlorocuprates(II), (dpd)2Cu2Cl6 and (dpd)2CuCl4

Author:
Jürgen Hartung; Lothar Beyer; Vicente Fernández; David Tudela; Enrique Gutiérrez-Puebla
Source:
Zeitschrift für Naturforschung 2014 v.46 no.8 pp. 1113-1116
ISSN:
0932-0776
Subject:
X-radiation; acetonitrile; air; crystals
Abstract:
... (dpd)₂Cu₂Cl₆ has been prepared by the reaction of bis(1,1-diethyl-3-benzoyl-thioureato)-copper(II) with SOCl₂ in nitromethane. The brown air stable crystals were characterized by X-ray structure determination. Space group P2₁/n, Z = 4, 4222 observed unique reflexions, R = 0.053, Lattice dimensions (22 °C): a = 1336.4(2), b = 1677.2(9), c = 749.3(2) pm; β = 92.46(2)°. Similar reaction in acetonitri ...
DOI:
10.1515/znb-1991-0823

39. Palladium(ii) complexes bearing the 1,2,3-triazole based organosulfur/ selenium ligand: synthesis, structure and applications in Heck and Suzuki–Miyaura coupling as a catalyst via palladium nanoparticles

Author:
Fariha Saleem; G. K. Rao; Arun Kumar; Satyendra Kumar; Mahabir P. Singh; Ajai K. Singh
Source:
RSC advances 2014 v.4 no.99 pp. 56102-56111
ISSN:
2046-2069
Subject:
Suzuki reaction; X-ray diffraction; acetonitrile; air; catalysts; catalytic activity; chemical bonding; energy; energy-dispersive X-ray analysis; geometry; ligands; nanoparticles; organobromine compounds; palladium; phenylboronic acids; selenium; sulfur; transmission electron microscopy; triazoles
Abstract:
... Air and moisture insensitive palladium complexes, [Pd(L)Cl₂] (1/2), in which L = 1-benzyl-4-phenylthiomethyl or 1-benzyl-4-phenylselenomethyl-1H-1,2,3-triazole (L1 or L2) catalyze Heck (HC) and Suzuki–Miyaura coupling (SMC) reactions between a series of aryl bromides including deactivated bromides and n-butyl acrylate and phenylboronic acid, respectively. The optimal catalytic loading was found to ...
DOI:
10.1039/c4ra09574j

40. Pollution patterns in the upper troposphere over Europe and Asia observed by CARIBIC

Author:
Angela K. Baker; Sebastian Traud; Carl A.M. Brenninkmeijer; Peter Hoor; Marco Neumaier; David E. Oram; Armin Rauthe-Schöch; Detlev Sprung; Sebastian Schloegl; Franz Slemr; Peter F.J. van Velthoven; Heini Wernli; Andreas Zahn; Helmut Ziereis
Source:
Atmospheric environment 2014 v.96 pp. 245-256
ISSN:
1352-2310
Subject:
acetonitrile; air; aircraft; atmospheric chemistry; biofuels; biomass; burning; carbon monoxide; case studies; convection; emissions; fossil fuels; pollutants; propane; summer; troposphere; Central Asia; Eastern European region; Germany; India; Middle East; North America; Philippines; West Asia; Western European region
Abstract:
... Between May 2005 and March 2008 the CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) observatory was deployed to make atmospheric observations on 42 flights between Frankfurt, Germany and Manila, the Philippines. This nearly 3 year flight series provides information about atmospheric composition in the upper troposphere over Europe and Asia ...
DOI:
10.1016/j.atmosenv.2014.06.010

41. Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct

Author:
Elena A. Vinogradova; Olga Yu. Vassilyeva; Volodymyr N. Kokozay; Brian W. Skelton
Source:
Zeitschrift für Naturforschung 2014 v.57 no.3 pp. 319-322
ISSN:
0932-0776
Subject:
X-radiation; acetonitrile; air; ammonium thiocyanate; cadmium; coordination polymers; copper; crystal structure; crystallization; crystals; dimethyl sulfoxide
Abstract:
... A new polymorph of the copper(II) thiocyanate complex with 2-dimethylaminoethanol, [Cu₂(Me₂Ea)₂(NCS)₂]∞ (HMe₂Ea = 2-dimethylaminoethanol, HL) 1, was isolated in the attempted synthesis of a mixed-metal complex from zerovalent copper, cadmium oxide and ammonium thiocyanate in CH₃CN solution of HL in air. [Cu₂(Me₂Ea)₂(NCS)₂(DMSO)₂] ₂ is a product of recrystallization of 1 from DMSO. X-ray analysis c ...
DOI:
10.1515/znb-2002-0310

42. Practical Cu(OAc)2/TEMPO-catalyzed selective aerobic alcohol oxidation under ambient conditions in aqueous acetonitrile

Author:
Jian-An Jiang; Jia-Lei Du; Zhan-Guo Wang; Zhong-Nan Zhang; Xi Xu; Gan-Lin Zheng; Ya-Fei Ji
Source:
Tetrahedron letters 2014 v.55 pp. 1677-1681
ISSN:
0040-4039
Subject:
acetonitrile; air; alcohols; aldehydes; ambient temperature; catalysts; chemical structure; copper; ketones; oxidants; oxidation; solvents
Abstract:
... We reported a ligand- and additive-free Cu(OAc)2/TEMPO catalyst system that enables efficient and selective aerobic oxidation of a broad range of primary and secondary benzylic alcohols, primary and secondary 1-heteroaryl alcohols, cinnamyl alcohols, and aliphatic alcohols to the corresponding aldehydes and ketones. This ambient temperature oxidation protocol is of practical features like aqueous ...
DOI:
10.1016/j.tetlet.2013.09.050

43. Preparation and characterization of MTiX for the catalytic oxidation of cyclohexane

Author:
A. Bellifa; A. Choukchou-Braham; C. Kappenstein; L. Pirault-Roy
Source:
RSC advances 2014 v.4 no.43 pp. 22374-22379
ISSN:
2046-2069
Subject:
Fourier transform infrared spectroscopy; Lewis acids; X-ray diffraction; acetic acid; acetonitrile; adsorption; air; catalysts; catalytic activity; chromium; crystal structure; cyclohexanes; energy-dispersive X-ray analysis; liquids; oxidants; oxidation; pyridines; sol-gel processing; solvents; surface area; titanium dioxide; vanadium
Abstract:
... MTiX (M = Cr and V) samples, with 0, 5, 10 and 20 atomic percent, were synthesised by a sol–gel method and calcined at 400 °C in air. The XRD analysis results indicated that the materials presented a crystalline structure with the presence of TiO₂ anatase forms. BET analysis showed that the surface area varied with the variation of metal content. EDX analysis showed a heterogeneous distribution of ...
DOI:
10.1039/c4ra02241f

44. Sulfurization and Selenization of the Halfsandwich Nitrosylmetal Complexes Cp*M(CO)2NO (M = Cr, Mo) and Cp*M(NO)I2 (M = Mo, W)

Author:
Max Herberhold; Guo-Xin Jin; Arnold L. Rheingold
Source:
Zeitschrift für Naturforschung 2014 v.48 no.11 pp. 1488-1498
ISSN:
0932-0776
Subject:
X-radiation; acetonitrile; air; argon (noble gases); chromium; hydrogen sulfide; iodine; ligands; mass spectrometry; molybdenum; nitric oxide; nuclear magnetic resonance spectroscopy; selenium; sulfur; tungsten
Abstract:
... The photo-induced decarbonylation of Cp*Cr(CO)₂NO in acetonitrile solution in the presence of excess sulfur leads to the cyclo-pentasulfido complex Cp*Cr(NO)(S₅) (1 a), while in the case of limited sulfur supply the binuclear bis(µ-disulfido) complex Cp*₂Cr₂(NO)₂(µ-S₂)₂ (4a) is formed preferentially. The corresponding reaction with elemental selenium produces Cp*₂Cr₂(NO)₂(µ-Se₂)₂ (4b), irrespectiv ...
DOI:
10.1515/znb-1993-1106

45. Synthese und Kristallstruktur von Tris(2,2'-bipyridin)eisen(II) μOxo-bis(trichloroeisen(III)), ein Salz mit dem Anion Fe2OCl62-

Author:
Herbert Weiss; Joachim Strähle
Source:
Zeitschrift für Naturforschung 2014 v.39 no.11 pp. 1453-1455
ISSN:
0932-0776
Subject:
acetonitrile; air; chlorine; crystal structure; crystals; ions; iron; oxidation; oxygen
Abstract:
... [Fe(2,2'-bpy)₃][Fe₂OCl₆] is obtained in form of red, air stable crystals by oxidation of Fe(bpy)Cl₂ with O₂ in acetonitrile. It crystallizes in the monoclinic space group P2₁/c with Z = 4. The crystal structure contains Fe(bpy)₃²⁺ and Fe₂OCl₆²⁻ ions. The anion exhibits a bent oxobridge with Fe-O-Fe = 148,1° and Fe-O distances of equal length (176,5 pm). In the IR spectrum νₐₛ Fe-O-Fe is observed a ...
DOI:
10.1515/znb-1984-1101

46. Tetrakis(Triphenylphosphine Oxide)Lithium Di(Iodo)Aurate(I)

Author:
Oliver Schuster; Hubert Schmidbaur
Source:
Zeitschrift für Naturforschung 2014 v.61 no.8 pp. 956-960
ISSN:
0932-0776
Subject:
acetonitrile; air; anions; cations; crystals; gold; iodides; ligands; lithium; oxidation
Abstract:
... The title compound, [(Ph₃PO)₄Li]⁺ AuI₂ ⁻, crystallized from a reaction mixture obtained from Ph₃PAuC≡CPh, LiMe and MeI (molar ratio 1 : 1 : 2) in diethylether upon subsequent oxidation in air. The triclinic crystals, space group P1̅, are isomorphous with those of the corresponding di(bromo)cuprate(I). The gold atoms of the two independent [AuI2]− anions reside on centers of inversion and have no c ...
DOI:
10.1515/znb-2006-0805

47. [Cu(CN)en2]I – Copper Amine Propellers

Author:
Michael F. Bräu; Arno Pfitzner
Source:
Zeitschrift für Naturforschung B 2014 v.61 no.7 pp. 775-778
ISSN:
1865-7117
Subject:
acetonitrile; air; anions; cations; copper; crystal structure; direct contact; iodides; iodine; potassium cyanide; propellers
Abstract:
... Light blue [Cu(CN)en₂]I was prepared by reaction of copper iodide with ethylenediamine (en) and potassium cyanide in acetonitrile in air. It crystallizes in the space group C2 (No. 5) with a = 11.082(6), b = 7.155(2), c = 9.017(3) Å , β = 127.00(3)°, and Z = 2. The structure was refined from 1069 unique reflections and 90 parameters. The refinement converged to R1=0.018 and wR2=0.041 (all reflecti ...
DOI:
10.1515/znb-2006-0701

48. A sensitive LC-MS/MS method for measurement of organophosphorus pesticides and their oxygen analogs in air sampling matrices

Author:
Jenna L. Armstrong; Russell L. Dills; Jianbo Yu; Michael G. Yost; Richard A. Fenske
Source:
Journal of environmental science and health 2014 v.49 no.2 pp. 102-108
ISSN:
1532-4109
Subject:
acetonitrile; air; chlorpyrifos; correlation; detection limit; environmental health; foams; gas chromatography-mass spectrometry; liquid chromatography; monitoring; oxygen; polyurethanes; spray drift; stable isotopes; storage quality; tandem mass spectrometry
Abstract:
... A rapid liquid chromatography tandem mass spectrometry (LC-MS/MS) method has been developed for determination of levels of the organophosphorus (OP) pesticides chlorpyrifos (CPF), azinphos methyl (AZM), and their oxygen analogs chlorpyrifos-oxon (CPF-O) and azinphos methyl-oxon (AZM-O) on common active air sampling matrices. XAD-2 resin and polyurethane foam (PUF) matrices were extracted with acet ...
DOI:
10.1080/03601234.2014.846744
PubMed:
24328542
PubMed Central:
PMC5953420

49. A simple QuEChERS-like extraction approach for molecular chemical characterization of organic aerosols: application to nitrated and oxygenated PAH derivatives (NPAH and OPAH) quantified by GC–NICIMS

Author:
A. Albinet; F. Nalin; S. Tomaz; J. Beaumont; F. Lestremau
Source:
Analytical and bioanalytical chemistry 2014 v.406 no.13 pp. 3131-3148
ISSN:
1618-2642
Subject:
Lampris guttatus; acetonitrile; aerosols; agitation; air; mixing; particulates; photooxidation; solid phase extraction; solvents; temperature
Abstract:
... An extraction procedure based on the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) approach has been developed and used for analysis of particle-bound nitrated and oxygenated PAH derivatives (NPAH and OPAH, respectively). Several analytical conditions, for example GC injection temperature and MS detection settings, were optimized. This analytical procedure enabled simultaneous GC–NICIMS qu ...
DOI:
10.1007/s00216-014-7760-5

50. AC electric field for rapid assembly of nanostructured polyaniline onto microsized gap for sensor devices

Author:
Vera La Ferrara; Gabriella Rametta; Antonella Maria
Source:
Electrophoresis 2015 v.36 no.13 pp. 1459-1465
ISSN:
0173-0835
Subject:
acetonitrile; air; ammonia; dielectrophoresis; electric current; electric field; electrodes; electrophoresis; nanomaterials; prototypes; temperature
Abstract:
... Interconnected network of nanostructured polyaniline (PANI) is giving strong potential for enhancing device performances than bulk PANI counterparts. For nanostructured device processing, the main challenge is to get prototypes on large area by requiring precision, low cost and high rate assembly. Among processes meeting these requests, the alternate current electric fields are often used for nano ...
DOI:
10.1002/elps.201400550