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- Fu, Wenzhao, et al. Show all 6 Authors
- Industrial & engineering chemistry process design and development 2019 v.58 no.5 pp. 1888-1895
- acetylene; activation energy; active sites; byproducts; catalysts; catalytic activity; energy; ethane; hydrogenation; models; nanoparticles; palladium; particle size; process design
- ... Catalysis is a kinetics behavior, and developing the kinetics-assisted discrimination of the active sites is an important yet challenging issue in the heterogeneous catalysis. Herein, we combine the multifaceted kinetics analysis with the model calculations to discriminate the dominant active sites in Pd-catalyzed semihydrogenation of acetylene. The size-insensitive activation energy of ≥3.1 nm si ...