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... Flocculent sludge system usually shows a low treatment efficiency and bad resistance to the feeding shock in the hydrolysis acidification. Integrated floating-film and activated sludge (IFFAS) is a favored system to resist shock, and zero-valent iron (ZVI) is an attractive material to enhance hydrolysis acidification. In this study, an IFFAS equipped with ZVI composite carriers was used to stably ...
... The application of anaerobic digestion (AD) to treat waste activated sludge (WAS) still exhibits some limitations, such as low methane production. In this study, cation exchange resin (CER) pretreatment was explored to enhance the efficiency of the AD of WAS. Based on the response surface methodology, the optimal conditions for CER pretreatment were reaction time of 7.4 h, 33.8 g CER (wet weight) ...
... It is desirable to control volatile fatty acids (VFAs) recovery from waste activated sludge (WAS) while avoiding the release of N and P. Structural extracellular polymeric substances (St-EPS), with typical components of alginate and polygalacturonic acid, resist the biodegradation of extracellular polymeric substances (EPS) in WAS. Previously, we purposely enriched an alginate-degrading consortium ...
... Integrated microbial electrolysis cell-anaerobic digestion (MEC-AD) systems have demonstrated potential advantages for methane production in the presence of small amounts of residual inhibitors. In this study, a series of tests were conducted to analyse the acidification and methanogenesis performance of pretreated rice straw (RS) in anaerobic digestion (AD) and MEC-AD systems after the addition o ...
... Antibacterial agents are frequently used to ensure public hygiene. Most of the massively consumed chemicals are discarded and accumulated in waste activated sludge (WAS), which might influence the subsequent anaerobic fermentation process for WAS treatment. This study mainly investigated the impacts of polyhexamethylene guanidine (PHMG, considered as a safe and efficient broad-spectrum antibacteri ...
... Cyclodextrin-based technologies have drawn worldwide attention for wastewater and sludge treatment due to its extraordinary solubilization of hydrophobic organics. β-cyclodextrin (β-CD) has been applied for enhancing sludge solubilization for production of volatile fatty acids. However, the impact of β-CD on methane production in the anaerobic digestion seemingly was unnoticed in the past, which w ...
... The long-term effects of copper nanoparticles (Cu NPs) on volatile fatty acids (VFAs) production during the waste activated sludge (WAS) fermentation, and the underlying mechanisms regarding copper species distribution and bacterial community evolution were explored. The yield of VFAs in the control was 1086 mg COD/L, whereas those were inhibited by 11.1%, 56.0% and 83.1%, with 25, 50, and 100 mg/ ...
... Surfactants were expected to exhibit positive effects on the waste activated sludge (WAS) disposal. However, the systematic comparison of different categories of surfactants on the WAS fermentation and the functional mechanisms, especially microbial metabolic traits, have not yet been precisely explored. This study revealed the positive effects of different surfactants on the volatile fatty acid ( ...
... The need of developing a new growth model based on circular economy has led to an increasing interest in the revalorization of urban and industrial wastewaters in order to use the resources efficiently. The most stablished way of valorising these residues implies the energy production in the form of biomethane. However, urban and industrial wastewaters can also be considered promising raw sources ...
... Recovery resources from waste active sludge (WAS) is an effective way to alleviate the predicament of WAS disposal, and it is also conducive to the carbon neutralization of wastewater treatment systems. This study discussed the strategy of WAS anaerobic fermentation after pre-oxidation with potassium ferrate (K₂FeO₄, PF), which can simultaneously recover vivianite and enhance SCFAs production. The ...
... High solids anaerobic digestion (AD) of chicken manure (CM) is often challenging due to ammonia-N inhibition and accumulation of volatile fatty acids (VFAs). This study evaluated the effect of adding biochars from different feedstock to ameliorate semi-dry AD of fresh CM during batch fermentation. Experiments were performed in 300 mL at two total solid (TS) levels (12% and 15%) under mesophilic (3 ...
acidification; activated sludge; calcium phosphates; cation exchange resins; chemical speciation; orthophosphates; phosphorus; polymers; research; solubility; total phosphorus; water
Abstract:
... Waste activated sludge (WAS) is an important source of non-renewable phosphorus (P) recovery. Given the factor that the occurrence states of phosphorus in WAS determines its recovery efficiency, the spatial distribution and chemical speciation of phosphorus were comprehensively and simultaneously analyzed by in-situ and step-by-step extraction methods for the first time. It was confirmed that the ...
... In this study, the roles of chitosan (CTS) in anaerobic digestion of Waste activated sludge (WAS) were investigated. The results show that the methane production potential of WAS is positively correlated with the CTS content. The presence of 30 g/kg total suspended solids CTS increased the cumulative methane production from 215 ± 1.52 to 272 ± 1.83 mL/g volatile suspended solids. The positively ch ...
... The green and low-cost surfactant Alkylethoxyglucoside (AEG) was used to enhance VFAs production from waste activated sludge (WAS). VFAs production (436.27 ± 14.88 mg COD/g VSS) was improved by ∼6.15 times than the blank under the optimal dosage 0.4 g/g TSS, exceeding most of current enhancement strategies. Thereinto, AEG degradation contributed to ∼15% of total VFAs production, and its primary de ...
... Biocidal agents (BAs) are widely used in environmentally safe toilet complexes (ESTC) of passenger railcars to suppress microbial activity in fecal sludge (FS). The subsequent disposal of BA-containing FS at municipal sewage treatment facilities adversely affects their work due to the loss of activated sludge. The antimicrobial properties of BAs based on quaternary ammonium compounds (QAC) and pol ...
... The enrichment of zinc oxide nanoparticles (ZnO NPs) in waste activated sludge (WAS) has raised concerns about their potential impact on anaerobic digestion of WAS. To date, there is no information regarding how to attenuate the negative effects of ZnO NPs on WAS anaerobic digestion. In this study, it was found that the appropriate amount of cationic polyacrylamide (cPAM) could mitigate the toxici ...
... Electro-dewatering (ED) is an attractive technology for enhancing dewaterability of waste activated sludge (WAS), and the distribution and composition of EPS and secondary structure of extracellular protein in sludge has a great influence on the sludge dewaterability. Therefore, in order to optimize and regulate sludge ED process, it is necessary to study the influence of EPS components and compos ...
... Microplastics in wastewater inevitably accumulate in waste activated sludge (WAS) via wastewater biological treatment, potentially affecting the subsequent sludge treatment unit. Nevertheless, all previous research studies focused on the impacts of the direct addition of one type of model microplastics on the sludge anaerobic treatment process. This approach actually cannot reflect the real situat ...
... Sodium dodecylbenzene sulfonate (SDBS), a typical surfactant being widely used in various applications, was highly accumulated in waste activated sludge. To date, however, its effect on hydrogen production from dark fermentation of sludge has not been documented. The work therefore aimed to explore whether and how SDBS affects hydrogen production. Experimental results showed that with an increase ...
acetates; acidification; activated sludge; butyrates; molecular weight; nitrogen content; organic nitrogen; phosphorus; propionic acid; sewage; total organic carbon; China
Abstract:
... Effects of sludge age on volatile fatty acids (VFAs) production and Phosphorus (P) release during anaerobic acidification of waste activated sludge (WAS) were investigated. Sequencing batch reactors (SBR) fed with simulating domestic sewage were applied to produce WAS of different sludge ages, and batch tests were used for anaerobic acidification. The maximum dissolved total organic carbon, releas ...
... Waste activated sludge (WAS) and animal manure are two significant reservoirs of glucocorticoids (GCs) in the environment. However, GC degradation during anaerobic digestion (AD) of WAS or animal manure has rarely been investigated. In this study, co-fermentation of WAS and animal manure was conducted to investigate the performance of AD in controlling GC dissemination. Effects of manure type on G ...
... Methane recovery from waste activated sludge (WAS) through anaerobic digestion is generally restricted by the poor degradability of WAS. Herein, a novel sludge pretreatment technology by using the calcium hypochlorite (Ca(ClO)₂) in enhancing the methane production from WAS anaerobic digestion was reported. The solubilization of WAS was significantly increased after 10–240 mg Ca(ClO)₂/g VS (VS: vol ...
... Persulfates ((peroxymonosulfate (PMS) and peroxydisulfate (PDS)) can disintegrate waste activated sludge (WAS), but their influence on volatile fatty acid (VFA) production during anaerobic fermentation is largely unclear. Particularly, it is unknown whether persulfates can improve fermentation without any preactivation. This study investigated how the direct addition of PMS and PDS into the fermen ...
... The usefulness of waste activated sludge (WAS) as an energy source is limited by the poor generation efficiency of methane from WAS, which is mainly due to the complex nature of sludge and low abundance of functional microbes. In this study, the interfacial thermodynamics, electron transfer and microbial community of sludge were investigated to reveal the enhancing effects of isoelectric-point (pI ...
... Anaerobic digestion (AD) of waste activated sludge (WAS) has been widely used, while it poses problems including low methane yield and production rate. Hydrochar is produced by hydrothermal liquefaction of biomass; however, little is known about the role of hydrochar in promoting AD of WAS. The present study showed that hydrochar increased the methane production rate by 30.8% and yield by 31.4% of ...
... Anaerobic digestion (AD) is a promising technology for stabilization of waste activated sludge (WAS) and energy recovery. Choline as a kind of alkaloid performed well in enhancing methane production from AD for WAS according to our previous research. This study furtherly investigated the influences of choline on the methanogenetic pathway and microbial community during AD process. Results showed t ...
acidification; activated sludge; anaerobic digestion; electron transfer; environmental management; food waste; hydrolysis; methane production; methanogens; microbial activity; polysaccharides; China
Abstract:
... A large amount of waste activated sludge (WAS) and food waste (FW) are produced every year in China. Anaerobic co-digestion is considered to be an effective way to solve this problem. This study applied FW/WAS mixture as co-substrate to create different digestive environment, aiming to understand the mechanism of Fe₃O₄ particles in promoting AD performance. The results showed that the addition of ...
... Ferric chloride (FC) is widely used in sewage treatment in practice and would influence anaerobic digestion by remaining in waste-activated sludge (WAS). However, the effects and mechanisms of FC involved in the WAS anaerobic digestion system have yet to be thoroughly elucidated. This study revealed the different effects and underlying mechanism of FC addition on each key stage of WAS anaerobic di ...
acidification; activated sludge; chemical oxygen demand; energy; energy density; ethanol; fermentation; hydrolysis; medium chain fatty acids; methane; microbial communities; short chain fatty acids; solubilization
Abstract:
... The utilization of waste activated sludge (WAS) to recover energy in the form of methane or short-chain fatty acids (SCFAs) is generally restricted by the low energy density of products and poor degradability of WAS. Herein, this study reported a novel alternative WAS fermentation technology to produce high-energy medium-chain fatty acids (MCFAs) from WAS in a one-stage anaerobic fermentation syst ...
... In wastewater treatment plants, most of the pathogens and antibiotic resistant genes (ARGs) transferred into and concentrated in waste activated sludge (WAS), which would cause severe public health risks. In this study, the capabilities of several WAS pre-treatment approaches to inactivate coliforms/E. coli and ARGs, as well as the subsequent regrowth of coliforms/E. coli and ARGs/intI1 in treated ...
... Tetramethylammonium Hydroxide (TMAH) is widely used as a developer in the thin-film transistor liquid crystal display (TFT-LCD) industry, which is a corrosive alkaline and neuronal toxic compound. In this study, the performances of combined hydrolysis acidification-aerobic and anaerobic batch reactors for synthetic TMAH wastewater treatment were evaluated. It also investigated the real TMAH wastew ...
... Acidogenic fermentation of wastes produces volatile fatty acid (VFA)-rich streams that can be used as low-cost carbon sources for polyhydroxyalkanoate (PHA) production. In this study, an inoculum collected from an anaerobic reactor of a municipal WWTP was conditioned to suppress methanogenic activity. The heat-shock conditioning method of the inoculum proved to be more efficient than acid and alka ...
... The emergence of triclosan (TCS) in the environment has caused extensive concern, but its role in waste activated sludge (WAS) anaerobic fermentation (AF) is still uncertain. This work investigated the impact of TCS on volatile fatty acids (VFAs) recycling from WAS. The results showed that TCS of 200 mg/kg TSS increased the maximum VFA accumulation from 7284 to 15,083 mg COD/L. The increase in tot ...
... Perfluorooctanoic acid (PFOA) is a type of persistent organic pollutant that has been detected in wastewater treatment systems, subsequently entering the waste activated sludge (WAS) anaerobic digesters. Nevertheless, how PFOA affects the anaerobic digestion of WAS has never been reported till now. In this study, a series of batch digesters were set up to assess the performance of the anaerobic sl ...
... One of the key challenges of wastewater treatment today is to understand the potential effect of residual pollutants on the management of waste activated sludge (WAS). This study aims to clarify the effect of chlortetracycline (CTC) as a residual antibiotic on the anaerobic fermentation of WAS to produce volatile fatty acids (VFAs). The results show that CTC with a concentration of 10 mg/kg total ...
... This study proposed a novel polyoxometalates (POMs)-based pretreatment technology to improve methane production from waste activated sludge (WAS) for the first time. Experimental results indicated methane production from WAS pretreated with 0.25 g POMs/g TSS increased by 43.7%. Mechanism analysis revealed POMs pretreatment promoted WAS disintegration and improved the biodegradability of the releas ...
... Superfine sand in waste activated sludge (WAS) increased the uncertainty of anaerobic fermentation. Experiments showed that VFAs production from WAS was positively affected by superfine sand, with an increase from 2513 mg COD/L in the control (without superfine sand) to 3002 mg COD/L with superfine sand. A mechanism study demonstrated that the main factor responsible for the improved VFAs accumula ...
... The development of anaerobic digestion (AD) for volatile fatty acids (VFAs) production from waste activated sludge (WAS) is arrested due to low hydrolysis and acidification efficiency. This study proposed to enhance WAS reduction and VFAs accumulation during AD process via bioaugmentation of acetate-producing bacteria. Four acetogens were firstly isolated from a temperature-phased anaerobic digest ...
... BACKGROUND: This study investigates a novel, efficient and green pretreatment approach using ferrous iron catalyzed peracetic acid oxidation (Fe²⁺/PAA) on anaerobic fermentation of waste activated sludge. The underlying mechanisms are also studied for both the chemical and microbial effects. RESULTS: The results indicate that Fe²⁺/PAA exhibit significant positive synergistic effect on short‐chain ...
... Adding alkaline into an anaerobic waste activated sludge (WAS) fermentation with thermophilic bacteria pretreatment could efficiently improve short-chain fatty acids (SCFAs) accumulation to 3550 ± 120 mg COD/L. The acidification rate in combined test was 21.2%, while that was 15.6% and 10.7% in sole thermophilic bacteria pretreatment and control tests respectively. Four distinct groups of microbes ...
... The efficiency of petrochemical wastewater biological treatment is dependent upon complex bacterial communities. A well understanding of the structure and function of bacterial community and their association with environmental variables is essential for the elucidation of contaminant removal mechanisms and optimization of wastewater treatment processes. In this study, the bacterial communities an ...
... Investigating the impact of hydrothermal pretreatment (HTP) on organic solubilization and anaerobic acidification of thickened waste activated sludge (TWAS) was the objective of this study. For this purpose, 15 different hydrothermal pretreatment scenarios were investigated. The HTP temperature, retention time, and pressure for this study extended from 150 to 240 °C, 5 to 30 min, and 69 to 488 psi ...
acidification; activated sludge; fermentation; hydrolysis; methane; methane production; pH; phosphates; pollution; research; short chain fatty acids; solid wastes; temperature
Abstract:
... The efficiency of anaerobic fermentation of waste activated sludge (WAS) under low-temperature condition is usually low. This work reported a new strategy to enhance the low-temperature fermentation of WAS by using aged refuse (AR), and explored the effect of initial pH 4 till pH 12 on the production of short-chain fatty acid (SCFA) from AR-enhanced sludge fermentation. The results showed that AR ...
... To simultaneously achieve biological denitrification and bio-energy recovery from sludge, the effects of nitrite on the two-phase anaerobic digestion (AD) of waste activated sludge were explored. Herein, effects of nitrite on the acidogenic phase are optimized, and the corresponding influence mechanisms are investigated. The experimental results show that the optimal nitrite treatment conditions f ...
... The effects of different hypochlorite types (namely Ca(OCl)₂ and NaOCl) on the waste activated sludge (WAS) anaerobic fermentation, and microbial community and activity were investigated. The results indicated that both Ca(OCl)₂ and NaOCl contributed to volatile fatty acids (VFAs) production by simultaneously enhancing the solubilization, hydrolysis and acidification processes. The maximal VFAs wa ...
acetates; acidification; activated sludge; anaerobic digesters; anaerobic digestion; butyrates; fermentation; hydrolysis; iron; iron oxides; methanogens; pH; short chain fatty acids
Abstract:
... Anaerobic digestion of waste activated sludge (WAS) to produce acetate has recently attracted growing interest, while the slow hydrolytic acidification of sludge and the consumption of acetate by methanogens both decrease the yield of acetate. In this study, Fe₃O₄ was added to a WAS anaerobic digester under alkaline conditions (pH = 10). The concentration of short-chain fatty acids (SCFA) during W ...
... Zinc oxide nanoparticles (ZnO NPs) production and usage might lead to a large discharge of ZnO NPs into the natural environment, raising concerns of pollution and ecological security. The effects of ZnO NPs on waste activated sludge hydrolytic acidification and microbial communities were studied in semi-continuous fermentation systems. The fermentation performance of eight ZnO NPs concentrations i ...
... The poor biodegradability of waste activated sludge (WAS) is widely regarded as one of the main bottlenecks in the fermentation of sludge and is attributed mainly to the complex nature of sludge. In this study, the physical structure and interfacial thermodynamics of sludge, which reflect its complex nature, were explored to reveal the effects of isoelectric-point (pI) pretreatment on enhancing th ...
... Triclocarban (TCC), as the most typical antibacterial agent, is widely discovered in many ecological environment, especially in sludge. However, so far, no studies have reported the effect of TCC exposure on the properties of excess sludge. Therefore, in this study, TCC’s toxicities to waste activated sludge (WAS) were analyzed by investigating the variation of physicochemical properties of sludge ...
... In this study the environmental impact of the anaerobic digestion (AD) of sewage sludge within an activated sludge wastewater treatment plant (WWTP) was investigated. Three alternative AD systems (mesophilic, thermophilic, and temperature-phased anaerobic digestion (TPAD)) were compared to determine which system may have the best environmental performance. Two life cycle assessments (LCA) were per ...