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absorption; additives; annealing; chemical interactions; photovoltaic cells; polymers; thiophene; transistors
Abstract:
... In order to investigate the effect of an (E)-1,2-di(thiophen-2-yl)ethene (TVT) unit on the hole mobility and photovoltaic properties of dithienyl-difluorobenzothiadiazole (DTBT) based polymers, two conjugated polymers PDT-DTBT-DT (thiophene backboned) and PTVT-DTBT-DT (TVT backboned) were synthesized. Compared to PDT-DTBT-DT, the backbone conformation of PTVT-DTBT-DT could be well modulated by the ...
annealing; chemical communication; crystals; electric field; geometry; iron oxides
Abstract:
... (NH₄)₃FeF₆ mesocrystalline octahedrons are formed by in situ dissolution and the reaction of anodic iron oxides, followed by a non-classical crystal growth process involving electrical polarization and subsequent alignment of primary (NH₄)₃FeF₆ particles under an external electric field. The obtained (NH₄)₃FeF₆ can be converted to nano-micro hierarchical α-Fe₂O₃ octahedrons by thermal annealing. ...
... The self-assembly of 1,3,5-benzenetribenzoic acid (BTB) molecules on both Cu(111) and epitaxial graphene grown on Cu(111) were studied by scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) under ultrahigh vacuum conditions. On Cu(111), the BTB molecules were found to mainly arrange in close-packed structures through H-bonding between the (partially) deprotonated carboxy ...
... Ice recrystallization (IR) is a process in which large ice crystals grow at the expense of smaller ones. It occurs constantly in nature and in industrial processes in conditions of moderate cooling of a partially frozen environment or at accelerated rate due to temperature fluctuations of frozen substances. IR is one of the major causes of smooth texture loss and deterioration of frozen food such ...
... Antifreeze proteins (AFPs) have evolved in cold-adapted organisms to control ice crystal growth when exposed to sub-zero temperature conditions. It has been suggested that the effect of the proteins results in small ice crystal size, thus avoiding the mechanical damage to frozen tissues and cells caused by large ice grains. The polar diatom Fragilariopsis cylindrus, a dominant species within sea-i ...
... In high temperature annealing of carbon nanotube (CNTs) bundles for structure and thermal conductivity (κ) improvement, the statistical errors from sample-wide structure variation and sample transfer/preparation significantly overshadows the understanding of structure-κ correlation and change. In this work, the sequential process of current-induced thermal annealing (CITA) on improving the structu ...
... At present, efficient and stable low-cost electromagnetic (EM) wave absorbing materials have been widely explored, but further improvement is still necessary. In this research, three types of hierarchical Co₃O₄/N-doped carbon/short carbon fiber (SCF) composites with different assembly structures were produced by annealing the ZIF-67/SCF and Co-LDHs/SCF precursors at 700 °C. The obtained Co₃O₄/N-do ...
... Banking of organs using current tissue banking practices employing conventional cryopreservation by freezing is not feasible due to the well known damage caused by intra and extra-cellular ice formation. An alternative cryopreservation approach is known as vitrification. There has been considerable success in ice-free vitrification of small tissue samples but better ice control is required for sam ...
active sites; annealing; anodes; batteries; chemical bonding; cobalt; cobalt sulfide; coordination polymers; electrolytes; energy; nanopores; nanosheets; screening; simulation models
Abstract:
... Sodium ion batteries (SIBs) for large-scale grid applications are facing great challenges in terms of development of high-performance electrode materials and screening of suitable electrolytes. Herein, a versatile and scalable protocol for synthesizing two-dimensional (2D) holey cobalt sulfide (h-Co₄S₃) nanosheets is demonstrated for high-rate and long-life SIBs in an ether-based electrolyte of 1. ...
... Since quinoidal molecules have double-bond linkages between aromatic rings, they have many advantages for efficient charge transport resulting from high planarity and extended π-conjugation length. However, they unavoidably generate some isomers, which cause difficulty in purification and characterization. In this study, sulfur–oxygen conformation locking and steric repulsion approach is introduce ...
... Efficient cesium lead halide perovskite light-emitting diodes (PeLEDs) are demonstrated using nearly 100% coverage of CsPbBr₃ film as the emitter. The PeLEDs with only a pumping away process deposited from equimolar PbBr₂–CsBr exhibit more than 30 fold electroluminescent (EL) performance improvement compared to the ones with both pumping away and annealing processes. And to further improve the EL ...
... We demonstrate an in situ synthesis for preparing a carbon-shielded three-dimensional Co–Ni nanocone array on Ni foam (CoNi NCs/NF@C) via the solvothermal and thermal annealing processes. It is found that the easily separable CoNi NCs/NF@C possesses high peroxidase/catalase dual-mimic activity and good catalytic stability. The fusion of the amorphous carbon sheath with the Co–Ni nanocones (1) effe ...
... The 3D flowerlike α-Fe₂O₃@TiO₂ core–shell nanocrystals with thorhombic, cubic, and discal morphologies are synthesized for photocatalytic application. α-Fe₂O₃ nanocrystals were prepared via a Cu²⁺, Zn²⁺, and Al³⁺ ion-mediated hydrothermal route. The α-Fe₂O₃@TiO₂ core–shell nanocrystals are obtained via a hydrothermal and annealing process. The shape-dependent photocatalytic activities of these as- ...
... Three-dimensional hierarchical nitrogen-doped graphene (3D-NG) frameworks were successfully fabricated through a feasible solution dip-coating method with commercially available sponges as the initial backbone. A spongy template can help hinder the graphene plates restacking in the period of the annealing process. The Pt/3D-NG catalyst was synthesized employing a polyol reduction process. The resu ...
... Metal-organic framework derived hierarchical bayberry-like Ni@carbon hollow nanosphere/reduced graphene oxide (Ni@CHS/rGO) hybrid was synthesized by combining a simple solvothermal reaction with a further annealing treatment. 3D hierarchical bayberry-like Ni@CHS/rGO hybrid not only offered a continuous highly conductive Ni metal and graphene matrix to facilitate the charge transfer, but also allow ...
... Hierarchical porous ZnO/ZnCo₂O₄ (denoted as ZZCO) nanosheets have been successfully synthesized by one-step thermal annealing of the as-prepared Zn–Co-MOF precursor. The ZZCO nanosheets are composed of uniform sized, interconnected primary ZnO and ZnCo₂O₄ (donated as ZCO) nanoparticles (NPs), which are homogeneously dispersed in the products. Moreover, it possesses favorable features, such as a th ...
active sites; annealing; catalysts; catalytic activity; durability; electrical properties; electrochemistry; hydrogen production; mass transfer; nanopores; nickel; structure-activity relationships; vanadium
Abstract:
... Nickel-based non-noble-metal materials have emerged as promising catalysts for electrochemical hydrogen production in view of their attractive intrinsic activities, electrical properties and low cost. Exploring new candidates for further improving the performances of nickel-based catalysts and understanding the structure–activity relationship are still necessary to reduce the overpotential of the ...
annealing; capacitance; durability; electric potential difference; electrical conductivity; electrochemistry; electrodes; foams; graphene; mobile telephones; nickel; surface area
Abstract:
... Consumer grade supercapacitors as power supply resources require outstanding electrode materials with large conductivity, high durability and retention rates, as well as large capacity. Graphene is a promising functional material as an electrical double layer capacitance electrode due to its large surface area, high chemical stability and moderate conductivity. However, the existing graphene synth ...
... Preparation of inks with proper rheology performance is the key for extrusion based 3D printing. In this work, extrusion based 3D printing graphene oxide (GO)/geopolymer (GOGP) nanocomposite was reported for the first time. The addition of GO in geopolymeric aqueous mixture (alumiosilicate and alkaline-source particles) dramatically changes its rheology properties, and enable the 3D printing that ...
... A point-of-care testing chip was developed for the colorimetric detection of inorganic mercury ion (Hg²⁺). The disposable chip fabricated by three-dimensional printing technology contains DNAzymes produced by rolling circle amplification (RCA); a color change caused by the enzymatic reaction between DNAzymes and the peroxidase substrate 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) is meas ...