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- Seemann, J., et al. Show all 2 Author
- Zeitschrift für Naturforschung 2014 v.53 no.1 pp. 13-16
- Raman spectroscopy; X-radiation; aqueous solutions; crystal structure; temperature; thiocyanates
- ... By treatment of [PtCl₆]²⁻ with an excess of SCN– in aqueous solution [Pt(SCN)₆]²⁻ is formed. The X-ray structure determination on a single crystal of [Py₂CH₂][Pt(SCN)₆] (orthor-hombic, space group Pna2₁, a = 15.5084(9), b = 11.8444(11), c = 13.2830(9)Å, Z = 4) shows, that the thiocyanate groups are exclusively S-coordinated with average Pt-S distances of 2.378 Å and Pt-S-C angles in the range from ...