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... Selenium (Se) contamination due to industrial activities has received increasing concerns. Phytoremediation has been suggested to be an efficient and feasible way to remove Se from Se-contaminated environment. Recently, an arsenic (As) hyperaccumulator Pteris vittata L. (Chinese Brake fern) was found to be a Se accumulator. This study was carried out to investigate Se accumulation mechanisms conce ...
... The effects of 'alperujo' compost on trace element availability and on microbial activity of two contaminated soils, a calcareous soil (S1) with high contents of Pb and Zn, and an acidic soil (S2) with a substantial amount of Al, As, Pb and Zn, were assessed. Additionally, the growth and capacity for contaminant phytoextraction of five Brassica species were studied. Compost amendment did not affec ...
antioxidant activity; apoptosis; arsenic; calcium; drinking water; green tea; in vivo studies; medicinal properties; myocardium; oxidative stress; polyphenols; rats; toxicology; ultrastructure
Abstract:
... Chronic arsenic exposure in drinking water is associated with the abnormalities of cardiac tissue. Excessive generation of ROS induced by arsenic has a central role in arsenic-induced cardiotoxicity. (-)-Epigallocatechin-3-gallate (EGCG), the most abundant polyphenol in green tea, possesses a potent antioxidant capacity and exhibits extensive pharmacological activities. This study was aim to evalu ...
Citrus; arsenic; cytotoxicity; enzyme inhibitors; epithelial cells; genes; human diseases; lungs; mitogen-activated protein kinase; oxidative stress; pathogenesis; phosphatidylinositol 3-kinase; polymethoxyflavones; protein kinase C; sodium; toxic substances; ubiquitination
Abstract:
... Exogenous toxicants (e.g. arsenic, cigarette smoke), trigger oxidative stress, and initiate the pathogenesis of many human diseases. Induction of nuclear factor E2-related factor 2 (Nrf2) counteract exogenous toxicant-induced oxidative insults. Using a high-throughput screen, we firstly identified a citrus polymethoxyflavone, (2S)-5,6,7,3',4'-pentamethoxyflavanone (PMF), to be an Nrf2 activator, a ...
arsenic; chemical bonding; fluorine; germanium; hydrobromic acid; phosphine; polar compounds; polymers; silicon; tin
Abstract:
... Transphosphination reactions of (Me₃M)₃P and Me₃MPH₂ compounds (M = Si, Ge, Sn; Me = CH₃) using HE(CF₃)₂ or H₂ECF₃ (E = P, As) yield derivatives of the types Me₃ME(CF₃)₂, Me₃ME(H)CF₃, and (Me₃M)₂ECF₃, respectively. The reactivity of the different systems depends on M (Si < Ge < Sn), E (P < As), and the phosphine [Me₃MPH₂ < (Me₃M)₂PH < (Me₃M)₃P]. Me₃ME(H)CF₃ compounds undergo dismutation forming (M ...
... A series of paramagnetic (S = 3/2) chromium half-sandwiches of the type CpCrX₂D (D = donor) were synthesized by starting from [CpCrX₂]₂, Cp₂Cr, CpCrCl₂(THF), and Cp*Cr(CH₃)₂[P(CH₃)₃]. Besides the parent cyclopentadienyl (Cp) the alkylated derivatives CH₃C₅H₄, (CH₃)₅C₅ (Cp*), and C₂H₅(CH₃)₄C₅ were bound to chromium. The electronegative substituent was X = F, Cl, Br, I, and triflate, while the donor ...
... Biochar is a promising immobilizing agent of trace elements (TEs) in contaminated soils. However, several contradictory results have been reported regarding the potential of biochar to immobilize arsenic (As), chromium (Cr), and nickel (Ni) in contaminated soils. We conducted a meta-analysis on the published papers since 2006 until 2019 to examine the effects of biochar on the chemical (im)mobiliz ...
... In the Mezquital valley, untreated wastewater (45 m³ s⁻¹) from Mexico City is used for the irrigation of around 900 km²of agricultural soil. High concentrations of metals including methylmercury (3.8 ± 2.5 ng l⁻¹) and lead (0.16 ± 0.05 mg l⁻¹) were measured in anoxic wastewater canals. Downstream, dissolved, and particulate polymetallic (Hg, Pb, Cr…) concentrations decreased by factors 10 to 1,000 ...
arsenic; bioavailability; chemical analysis; chemical speciation; ferrihydrite; fluorescence; goethite; iron; iron hydroxides; mine tailings; mining; particle size; prediction; sorption; spectral analysis; spectroscopy; toxicity; weathering; California
Abstract:
... The chemical speciation and distribution of potentially toxic metal(loid)s in mine wastes is critical to assessing the risks posed by these wastes and predicting the potential bioavailability of the metal(loid)s present. Of additional potential importance is the role of particle size in the fate, transport, and toxicity of contaminated mining materials. Spectroscopic analyses of size-separated min ...
arsenic; chemical communication; chemical compounds; chemical reactions; materials; phosphorus
Abstract:
... The complexes [Cp*E{W(CO)₅}₂] (E = P, As; Cp* = C₅Me₅) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds. ...
... Lead slags from two different metallurgical technologies (primary slag from Pb-ore processing and secondary slag from car battery recycling) were submitted to 12-year batch leaching at a L/S ratio of 10 and the leaching data were compared with the previously obtained results from a ⩽1-year leaching test. In the long-term, the Pb release is efficiently controlled by the precipitation of cerussite ( ...
air; aluminum; arsenic; coal; environmental law; governance; hydrochemistry; nickel; pH; rivers; soil pollution; total nitrogen; water; water pollution; water quality; zinc
Abstract:
... Ineffective environmental regulation of effluent discharged from an underground coal mine operation has enabled water pollution within two highly valued Australian rivers. This study investigated the impacts on water chemistry of the Bargo and Nepean rivers as a result of the continuous disposal of mine effluent from Tahmoor Colliery over a 14-month period. Coal mine effluent was saline (2180 μS/c ...
... To gain an in-depth insight into the diversity and the distribution of genes under the particular evolutionary pressure of an arsenic-rich acid mine drainage (AMD), the genes involved in bacterial arsenic detoxification (arsB, ACR3) and arsenite oxidation (aioA) were investigated in sediment from Carnoulès (France), in parallel to the diversity and global distribution of the metabolically active b ...
... Concentrations of aluminium, arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, tin and zinc were determined in samples from the 1997 UK Total Diet Study and used to estimate dietary exposures of the general UK population. Population average dietary exposures to aluminium (3.4 mg/day), arsenic (0.065 mg/day), cadmium (0.012 mg/day), chromium (0.10 mg/day), copper (1.2 mg/day), me ...
arsenic; nuclear magnetic resonance spectroscopy; protons; spectral analysis
Abstract:
... ¹H NMR spectral data of 2-diphenylamino-[1,3,2]oxathiaarsolane are presented and discussed. The protons of the CH₂-groups form an AKPX-spin system. The vicinal H-C-C-H coupling constants indicate a twist-envelope conformation. A rapid inversion at arsenic does not take place. ...
arsenic; cesium; coastal sediments; coasts; copper; highlands; hydrology; lead; mining; models; plutonium; radionuclides; salt marshes; upland soils; watersheds; zinc; Irish Sea; Isle of Man
Abstract:
... The Isle of Man, situated in the central Irish Sea, was a significant centre for Pb and Zn mineral extraction during the Industrial Revolution. Comminuted mining debris from the East Snaefell and North Laxey mining areas was transported, through hydrological action, from upland catchments to the coast. This study focuses on an eastern coastal sediment sink and a salt marsh sediment sequence from P ...
air quality; antimony; arsenic; bismuth; carbon; combustion; copper; emissions; filters; human health; lead; mining; models; particulates; pyrite; toxicity; traffic; water solubility; zinc; Spain
Abstract:
... This study is the first to perform a chemical characterization and source contribution of particulate matter (PM₁₀) occurring through the abandonment and reopening of a historical sulphide mine. This long-range analysis covers the period 2009–2017 in the Riotinto mining district (Iberian Pyrite Belt, Southwestern Spain), which is a mining district of world-class importance. This mine represents a ...
aerosols; air; air pollution; aluminum; arsenic; biomass; burning; cadmium; calcium; chromium; cobalt; copper; fractionation; humans; iron; lead; magnesium; manganese; models; nickel; potassium; respiratory system; risk; risk estimate; selenium; smoke; toxicity; zinc; South East Asia
Abstract:
... Recurring biomass burning-induced smoke haze is a serious regional air pollution problem in Southeast Asia (SEA). The June 2013 haze episode was one of the worst air pollution events in SEA. Size segregated particulate samples (2.5–1.0 μm; 1.0–0.5 μm; 0.5– 0.2 μm; and <0.2 μm) were collected during the June 2013 haze episode. PM₂.₅ concentrations were elevated (up to 329 μg/m³) during the haze epi ...
... In this study, the effect of 24-Epibrassinolide (EBL) on antioxidant system in Arabidopsis thaliana were investigated under arsenate [As(V)] stress. The enzyme activity of superoxide dismutase (SOD) and catalase (CAT), total antioxidant status, malondialdehyde (MDA) level and free proline content, as well as the expression levels of SOD isoforms (Cu-ZnSODs, FeSODs and MnSOD), CAT isoforms (CAT1, C ...
... There is an increasing demand for efficient energy storage systems in our modern mobile society for a wide range of applications such as smart grids, portable electronic devices, and electric vehicles. The performance of advanced batteries in terms of energy density, power density, cyclability, and safety is mainly determined by the primary functional components, particularly by the electrode mate ...