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arsenic; arsenites; biocompatible materials; colorimetry; electrochemistry; guidelines; oligonucleotides; oxidation; risk; transportation; well water; China
Abstract:
... Approximately 94 to 220 million people worldwide are at risk of drinking well water containing arsenic > 10 µg/L, the WHO guideline value. To identify non-compliant domestic wells, assess health risks and reduce exposure, accurate and rapid on-site inorganic arsenic screening methods are desirable because all domestic wells worldwide need to be tested. Here, the principles, advantages and limitati ...
... Scorodite (FeAsO₄·H₂O) is a common arsenic-bearing (As-bearing) iron mineral in near-surface environments that could immobilize or store As in a bound state. In flooded soils, microbe induced Fe(III) or As(V) reduction can increase the mobility and bioavailability of As. Additionally, humic substances can act as electron shuttles to promote this process. The dynamics of As release and diversity of ...
Bacillus (bacteria); arsenic; genes; groundwater; oxidoreductases; prokaryotic cells; China
Abstract:
... Many investigations suggest that dissimilatory arsenate-respiring prokaryotes (DARPs) play a key role in stimulating reductive mobilization of As from solid phase into groundwater, but it is not clear how environmental Mn(II) affects the DARPs-mediated reductive mobilization of arsenic. To resolve this issue, we collected soil samples from a realgar tailings-affected area. We found that there were ...
Microcystis aeruginosa; algae; algal blooms; arsenates; arsenic; biotransformation; inorganic phosphorus; microcystins; organic phosphorus; polymers; sodium; water pollution; China
Abstract:
... Little information is available on influences of the conversion of dissolved organic phosphorus (DOP) to inorganic phosphorus (IP) on algal growth and subsequent behaviors of arsenate (As(V)) in Microcystis aeruginosa (M. aeruginosa). In this study, the influences factors on the conversion of three typical DOP types including adenosine-5-triphosphate disodium salt (ATP), β-glycerophosphate sodium ...
... Preparing materials for simultaneous remediation of anionic and cationic heavy metals contamination has always been the focus of research. Herein a biochar supported FeMnMg layered double hydroxide (LDH) composites (LB) for simultaneous remediation of copper and arsenic contamination in water and soil has been assembled by a facile co-precipitation approach. Both adsorption isotherm and kinetics s ...
Nitrosospira; ammonia; arsenic; bioavailability; community structure; genes; humans; nitrogen; oxidation; phylogeny; quantitative polymerase chain reaction; restriction fragment length polymorphism; toxicity; China
Abstract:
... Soil arsenic contamination is of great concern because of its toxicity to human, crops, and soil microorganisms. However, the impacts of arsenic on soil ammonia oxidizers communities remain unclear. Seven types of soil spiked with 0 or 100 mg arsenic per kg soil were incubated for 180 days and sampled at days 1, 15, 30, 90 and 180. The changes in the community composition and abundance of ammonia ...
... Metal smelting have brought severe metal(loid)s contamination to the soil. Spatial distribution and pollution source analysis for soil metal(loid)s in an abandoned lead/zinc smelter were studied. The results showed that soil was contaminated heavily with metal(loid)s. The mean of lead (Pb), arsenic (As), cadmium (Cd), mercury (Hg) and antimony (Sb) content in topsoil is 9.7, 8.2, 5.0, 2.3, and 1.2 ...
... Direct discharge of aquaculture wastewater may have toxic effects, due to the presence of heavy metals, antibiotics, and even resistant pathogens, but little attention has been given. Here, tanks simulating a wild ecosystem were built to study the effects of long-term exposure to duck wastewater containing oxytetracycline (OTC) and/or arsenic (As) on the growth, physiological function, and gut mic ...
... The crisis of arsenic (As) accumulation in rhizomes threatens the quality and safety of Panax notoginseng (Burk.) F.H. Chen, which is a well-known traditional Chinese herb with a long clinical history. The uptake of arsenate (AsV) could be suppressed by supplying phosphate (Pi), in which Pi transporters play important roles in the uptake of Pi and AsV. Herein, the P . notoginseng Pi transporter-en ...
... Little has been published about the interactions of metals and parasites in economically important aquaculture species, particularly shellfish. Metal bioaccumulation and parasitic diseases could vary in different species depending on temperature changes and other environmental factors. Most studies conducted on endoparasites, such as acanthocephalans, cestodes, nematodes, and trematodes, indicate ...
Jeremiah Zhe Liu; Wenying Deng; Jane Lee; Pi-i Debby Lin; Linda Valeri; David C. Christiani; David C. Bellinger; Robert O. Wright; Maitreyi M. Mazumdar; Brent A. Coull
... Gene-environment and nutrition-environment studies often involve testing of high-dimensional interactions between two sets of variables, each having potentially complex nonlinear main effects on an outcome. Construction of a valid and powerful hypothesis test for such an interaction is challenging, due to the difficulty in constructing an efficient and unbiased estimator for the complex, nonlinear ...
... Anthropogenic and climatic perturbations redistribute arsenic (As), antimony (Sb), and selenium (Se) within the environment. The speciation characteristics of these elements determine their behavior and biogeochemical cycling, but these redox-sensitive species are challenging to capture, with few methods able to harmonize measurements across the whole plant-soil-ecosystem continuum. In this study, ...
arsenic; bibliometric analysis; climate change; water; water analysis; water management; water quantity; Bangladesh
Abstract:
... This paper presents a review of water research, development, and management in Bangladesh, with examples drawn from the past and present. A bibliometric analysis is adopted here to analyze the water-related publication data of Bangladesh. Water-quality-related research is the dominating research field in Bangladesh as compared to water-quantity (floods and droughts)-related ones. The most producti ...
... Metals, many of which are potentially toxic, are present in the aquatic environment originated from both natural and anthropogenic sources. In these ecosystems, these elements are mostly deposited in the sediment, followed by water dissolution, potentially contaminating resident biota. Among several aquatic animals, crustaceans are considered excellent bioindicators, as they live in close contact ...
air temperature; arsenic; chlorides; dissolved oxygen; electrical conductivity; environment; freshwater; models; oxygen; regression analysis; river water; rivers; sulfates; water pollution; water quality; water temperature
Abstract:
... Water quality is a concern in most river basins worldwide due to the widespread release of pollutants which impacts the freshwater ecosystems. Exploring the relationships between drivers and water quality parameters at the regional scale is key in the identification of appropriate actions for the reduction of water pollution. Regional models are the appropriate tool to achieve this, though their d ...
adsorbents; adsorption; arsenates; arsenic; arsenites; chemical species; lakes; magnetism; oxidation; pH; rain; reference standards; rivers; solid phase extraction; standard deviation
Abstract:
... Mercapto- and amino-functionalized magnetic nanoparticles, Fe₃O₄@SiO₂@MPTMS (SMNPs-MPTMS) and Fe₃O₄@SiO₂@APTES (SMNPs-APTES), have been applied as magnetic solid-phase extraction (MSPE) sorbents to directly extract arsenite (As(III)) and arsenate (As(V)) respectively, followed by inductively coupled plasma-mass spectrometry (ICP-MS) detection. Various MSPE parameters were optimized including dose ...
... Arsenic is a ubiquitous element in the environment, a source of constant evolutionary pressure on organisms. The arsenic resistance machinery is thoroughly described for bacteria. Highly resistant lineages are also common in eukaryotes, but evolutionary knowledge is much more limited. While the origin of the resistance machinery in eukaryotes is loosely attributed to horizontal gene transfer (HGT) ...
... Elevated sediment-bound trace elements and iron-bearing minerals in intertidal habitats have been drawing more attention, but there is rarely a comparative study assessing these features between halophyte plants habitat and mudflats. In this paper, sediment samples were collected in S. alterniflora and the corresponding mudflat at 7 typical intertidal habitats (Chongming, Xiapu, Yueqing, Yunxiao, ...
arsenic; comparative study; geochemistry; human health; pollution load; public health; soil quality; toxicity; urban development; waste disposal; zinc; Chile
Abstract:
... Toxic metal enrichment in urban soils from natural and anthropogenic sources is a public health concern that challenges sustainable urban development. Active and legacy mining is likely a major contributor of localized metal pollution in resource-based economies, although other sources associated with industrial and transportation activities may also contribute in urban settings. In mining countri ...
... The application of biochar materials in metal(loid)s-polluted soil has been widely explored, while lesser is known about their potential threats to ecological environment. The impacts of biochar, Fe₃O₄ supported biochar, and sulfide Fe₃O₄ supported biochar both in the clean and arsenic (As)/lead (Pb) contaminated soil were systematically investigated by laboratory simulation experiments. Results s ...
anodes; arsenic; biosensors; copper; electric potential difference; electricity; environment; heavy metals; microbial fuel cells; municipal wastewater; pH; toxicity
Abstract:
... This study investigated a dual-chamber microbial fuel cell-based biosensor (DC-MFC-B) for monitoring copper and arsenic in municipal wastewater. Operational conditions, including pH, flow rate, a load of organic substrate and external resistance load, were optimized to improve the biosensor's sensitivity. The DC-MFC-B's toxicity response was established under the electroactive bacteria inhibition ...
Monte Carlo method; arsenic; carcinogenicity; databases; environment; heavy metals; meta-analysis; risk; soil; soil pollution; Australia; Oman; United Kingdom
Abstract:
... With the rapid development of the mining industry, the pollution of heavy metal(loid)s in soils near copper (Cu) mining sites is a significant concern worldwide. However, the pollution status and probabilistic health risks of heavy metal(loid)s of soils associated with Cu mines, have rarely been studied on a global scale. In this study, eight heavy metal(loid) concentrations in soil samples taken ...
arsenic; at-risk population; average daily intake; carcinogenicity; carnivores; environmental impact; fish; food guides; gold; health effects assessments; human health; methylmercury compounds; poverty; research; risk; watersheds; Colombia
Abstract:
... The Atrato River basin is one of the most biodiverse areas worldwide, and paradoxically, it is one of the sites in Colombia with the highest environmental impact from gold mining. This study assessed the distribution of Hg, As, Pb, and Cd in 47 fish species (n = 1372) and the accumulative human health risk in inhabitants (n = 2325) from 13 municipalities located along the Atrato River basin. The r ...
Daniel Beene; Philip Collender; Andres Cardenas; Charles Harvey; Linden Huhmann; Yan Lin; Johnnye Lewis; Nancy LoIacono; Ana Navas-Acien; Anne Nigra; Craig Steinmaus; Alexander van Geen
... Unless a toxicant builds up in a deep compartment, intake by the human body must on average balance the amount that is lost. We apply this idea to assess arsenic (As) exposure misclassification in three previously studied populations in rural Bangladesh (n=11,224), Navajo Nation in the Southwestern United States (n=619), and northern Chile (n=630), under varying assumptions about As sources. Relat ...
aquifers; arsenic; atmospheric precipitation; environment; geostatistics; groundwater; hydrogeochemistry; kriging; probability; probability analysis; risk management; water management; Italy
Abstract:
... The concept of natural background level (NBL) aims at distinguishing the natural and anthropogenic contributions to concentrations of specific contaminants, as groundwater management and protection tools. This is usually defined as a unique value at a regional scale, even when the hydrogeological and geochemical features of a certain territory are far from homogeneous. The concentration of target ...
... Fruit-bodies of six Thelephora species (Fungi, Basidiomycota, Thelephoraceae) were analyzed for their trace element concentrations. In Thelephora penicillata, extremely high concentrations of Cd and As were found, followed by highly elevated concentrations of Cu and Zn. The highest accumulation ability was found for Cd with a mean concentration of 1.17 ± 0.37 g kg⁻¹ (dry mass) in fruit-bodies coll ...
... Iron-manganese binary oxides (Fe-Mn oxides) have the potential to immobilize arsenite/arsenate [As(III/V)] in situ in natural environments. However, the As(III/V) immobilization performances of Fe-Mn oxides in the presence of indigenous metal-reducing bacteria in reducing groundwater systems have received limited attention. Here, As(III/V) immobilization by Fe-Mn oxides and the interactions of Fe ...
... Although the compound pollution of microplastics and arsenic (As) in paddy soil can affect the growth and quality of rice, relevant research on this phenomenon was limited. Therefore, we combined a pot experiment with computational chemistry to explore the effects and mechanism of polystyrene (PSMP) and polytetrafluoroethylene (PTFE) microplastics on As bioavailability. PSMP and PTFE interacted wi ...
United States Environmental Protection Agency; X-ray diffraction; arsenic; calcium; environment; pH; risk; transmission electron microscopy
Abstract:
... Stabilizing the hazardous calcium arsenic residues (CAR) and monitoring the subsequent fate of arsenic (As) are critical to reduce its risk to the environment. In this work, a novel in situ method has been proposed to stabilize CAR by adding Feᴵᴵᴵ solution and subsequent formation of the secondary mineral (yukonite). The experiments were conducted at pH 6–9 with different Fe/As molar ratios (0.28– ...
... Iron species that occur in natural surface water could affect the photochemical behavior of pollutants. Complexation between iron species and polycarboxylate or heavy metals has been widely reported, where the ligands could be oxidized via ligand-to-metal charge transfer (LMCT) by light inducement. Such complexation and photochemical reactions might also occur for low valance metal-containing orga ...
... Arsenic in acid mine drainage (AMD) is commonly associated with the bioleaching of arsenic sulfide minerals. Orpiment is iron free and one of the most common arsenic sulfide minerals, but no studies are involved with the relationship between the iron free bioleaching of orpiment and the generation of arsenic-containing AMD. In this study, the iron free bioleaching experiments with Acidithiobacillu ...
... Restoring homeostasis following proteostatic stress hinges on a stress-specific transcriptional signature. How these signatures are regulated is unknown. We use functional genomics to uncover how activating transcription factor 6 (ATF6), a central factor in the unfolded protein response, regulates its target genes in response to toxicant induced and physiological stress in the liver. We identified ...
... This article provides a portable x-ray fluorescence (pXRF) elemental dataset from samples collected from a Cambrian Sandstone Aquifer in West-Central Wisconsin, U.S.A. Analyses were performed on drill core samples and well cutting materials collected using a variety of drilling methods. Elements presented in this dataset include aluminum (Al), arsenic (As), calcium (Ca), cobalt (Co), chromium (Cr) ...
... Adsorption is a widely used arsenic remediation technique due to its high efficacy, economic value, ease in operation and maintenance, and other multiple factors. However, the proper management of arsenic-laden spent media is one of the major challenges, which affects the sustainability of this treatment technique in field-scale implementations. This review summarizes the various adsorbents and th ...
... Recovering harmful elements (As, Pb) and metals (Cu, Bi, Zn) from copper smelting flue dust (CSFD) is a critical subject and task for arsenic contamination control and resource sustainability. In this work, a two-step pyrometallurgical process was developed to preferentially separate arsenic and recover metals from CSFD. During the low-temperature roasting, arsenic-bearing waste acid (AWA) from co ...
... High-quality products in sustainable agriculture require both limited health risks and sufficient dietary nutrients. Phosphorus (P) as a finite and non-renewable resource is widely used in agriculture, usually exerting influence on the accumulation of heavy metals (HMs) in soil and crops. The present research explores, for the first time, the combined effects of long-term P fertilizer and repeated ...
World Health Organization; adults; animal proteins; arsenic; average daily intake; cadmium; fish consumption; health effects assessments; ingestion; lead; marine fish; mercury; oral exposure; people; risk; systematic review; toxicity; toxicology; Persian Gulf
Abstract:
... Fish as a critical food source is responsible for supplying nearly 20% of the average per capita animal protein for 3.2 billion people worldwide. However, oral exposure to potentially toxic elements (PTE) such as mercury (Hg), cadmium (Cd), lead (Pb), and arsenic (As) through marine fish consumption can cause health risks in consumers. This study aimed to collect information among databases (2000– ...
... Arsenic (As) considered as one of the hazardous metalloid that hampers various physiological activities in rice. To study the mechanism of As tolerance in rice, one differentially expressed tau class glutathione-S-transferase (OsGSTU5) has been selected and transgenic rice plants with knockdown (KD) and overexpressing (OE) OsGSTU5 were generated. Our results suggested that KD lines became less tol ...
adsorption; ambient temperature; arsenic; desorption; energy; tin
Abstract:
... The sensing performance of tin arsenic (SnAs) monolayer with adsorption of different gas molecules at room temperature was systematically investigated by the first-principle calculations. The interaction of all studied gas molecules with SnAs monolayer shows physisorption nature. The moderate adsorption energy (− 0.76 eV) and large charge transfer (0.21 e) results demonstrated that the SnAs monola ...
... Cropland contamination by toxic trace metal (loid)s (TTMs) has attracted increasing attention due to the serious consequential threat to crop quality and human health. Mitigation of plant TTM stress by silica amendment has been proposed recently. However, the relationship between the siliceous structure of phytoliths and TTMs in plants, and the environmental implications of phytolith-occluded trac ...
... Up to now, information about biogeochemistry of many trace elements is scarce. Meanwhile, all the elements are always present in soil and plants. It may be suggested that the trace elements also play certain role in the biogeochemical processes. The aim of the research was to study bioaccumulation of poorly investigated trace elements (scandium, cerium, europium, hafnium, and tantalum) and well-kn ...
acidity; adsorption; antimony; arsenic; iron oxyhydroxides; spectroscopy
Abstract:
... Coexisting antimony (Sb) and arsenic (As) have raised worldwide concerns, but the factors controlling the mobilization of Sb and As in sediments near mining areas are not fully understood. Herein, multiple leaching methods and complementary spectroscopic analyses were used to investigate the mobility of Sb and As and its controlling factors in sediments around the Xikuangshan tailings pond over a ...
Titus Chinedu Egbosiuba; Michael Chika Egwunyenga; Jimoh Oladejo Tijani; Saheed Mustapha; Ambali Saka Abdulkareem; Abdulsalami Sanni Kovo; Vida Krikstolaityte; Andrei Veksha; Michal Wagner; Grzegorz Lisak
... Nickel nanoparticles (NiNPs) supported on activated multi-walled carbon nanotubes (MWCNTs) were used as an adsorbent applied towards Pb(II), As(V) and Cd(II) remediation from industrial wastewater. The result revealed the hydrophilic surface of MWCNTs-KOH was enhanced with the incorporation of NiNPs enabling higher surface area, functional groups and pore distribution. Comparatively, the removal o ...
Danio rerio; Daphnia magna; Japan; acute toxicity; aluminum; arsenic; drainage; ecotoxicology; hot springs; iron; river water
Abstract:
... We investigated the lethal toxicity of Shibukuro and Tama river water near the inflow of Tamagawa hot-spring water in Akita Prefecture, Japan. We first measured metal concentrations in both rivers. We detected iron, arsenic, and aluminum; the concentrations of each tended to decrease from upstream to downstream. We next examined the influence of river water on zebrafish Danio rerio and water flea ...
... In order to explore the utilization of Eucalyptus sawdust (C) and develop its remediation potential in cadmium and arsenic contaminated soil, Eucalyptus sawdust were modified by FeCl₃ and NaOH coprecipitation (MC). Characterization technology and pot experiment were used to explore the adsorption mechanism of cadmium and arsenic by MC and the effect of soil remediation. The results showed that iro ...
... The adsorption of inorganic arsenic (As) plays an important role in the mobility and transport of As in the river environment. In this work, the adsorption and desorption of arsenite [As(III)] and arsenate [As(V)] on river sediment were conducted under different pH, initial As concentrations, river water and sediment composition to assess As adsorption behavior and mechanism. Both adsorption kinet ...
... The preparation of easily synthesized and cheap composite materials for the efficient removal of toxic oxoanions still remains challenging in sewage treatment. Herein, a new carbonized manganese-crosslinked sodium alginate (Mn/SA-C) was fabricated for the removal of arsenite (As(III)), arsenate (As(V)) and hexavalent chromium (Cr(VI)) in water. The results indicated that the Mn/SA-C pretreated wit ...
... The purpose of this research was to investigate the adsorption of arsenic (As) from aqueous solutions using MPAC-500 and MPAC-600 (magnetic-activated carbons synthesized from the peel of Pisum sativum (pea) pyrolyzed at 500 °C and 600 °C temperatures, respectively). The potential of both biosorbents for As adsorption was determined in batch and column mode. The characterization of both biosorbents ...
... Arsenic is a highly toxic pollutant and exists in inorganic and organic forms in groundwater and industrial wastewater. It is of great importance to reduce the arsenic content to lower levels in the water (e.g., <10 ppb for drinking) in order to minimize risk to humans. In this study, a Fe–Mn–Zr ternary magnetic sorbent was fabricated via precipitation for removal of inorganic and organic arsenate ...
... Fe–Mn binary oxide (FMBO) is a promising adsorbent for As(III) removal through combined adsorption and oxidation. The calcined oyster shell‐supported Fe–Mn binary oxide (FMBO/OS) adsorbent was synthesized by the co‐precipitation method. Results indicated that the calcined oyster shell, as a carrier, improved the stability of FMBO and its adsorption capacity for As(III). The maximum adsorption capa ...