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- Levitskiy, Oleg A., et al. Show all 5 Authors
- Tetrahedron letters 2018 v.59 no.29 pp. 2831-2834
- benzophenones; chemical reactions; electrochemistry; moieties; nickel; stereoselectivity; thiocyanates
- ... One-pot method for direct stereoselective (S)-α-thioalkylation of glycine in Ni(II) coordination environment was elaborated. The reaction of electrochemically deprotonated Ni(II) glycine/Schiff-base complex containing (S)-o-[N-(N′-benzylprolyl)amino]benzophenone as an auxiliary chiral moiety with alkyl thiocyanates leads to the α-thioalkylated derivatives in a practical ca.70% chemical yield and s ...