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1. 2D/2D Nanoarchitectured Nb₂C/Ti₃C₂ MXene Heterointerface for High-Energy Supercapacitors with Sustainable Life Cycle

Author:
Kabeer Nasrin; Vasudevan Sudharshan; Murugesan Arunkumar; Marappan Sathish
Source:
ACS applied materials & interfaces 2022 v.14 no.18 pp. 21038-21049
ISSN:
1944-8252
Subject:
capacitance; electrochemical capacitors; electrodes; energy; energy density
Abstract:
... Layered 2D/2D heterointerface composites experience interesting properties that greatly stimulate the recent surge in the attention as robust supercapacitor electrode materials, especially the MXene-based 2D/2D heterointerface for its robust energy storage compatibility. This report unveils a synergistically in situ prepared 2D/2D Nb₂C/Ti₃C₂ MXene (NCTC) heterointerface nanoarchitecture by facile ...
DOI:
10.1021/acsami.2c02871

2. 3-D printed injection system for capillary electrophoresis

Author:
Bonnie Jaskowski Huge; Kevin Young; Caitlin Kerr; Matthew M. Champion; Norman J. Dovichi
Source:
Analytical methods 2022 v.14 no.11 pp. 1163-1168
ISSN:
1759-9679
Subject:
calibration; capillary zone electrophoresis; electrodes; electrolytes; fluorescein; fluorescence
Abstract:
... Commercial systems for capillary electrophoresis are designed for the unattended analysis of several samples, and are usually large, complex, and expensive. We report a compact system for manual injection of a single sample in capillary electrophoresis, which is ideal for method development and for student training. The injector consists of two parts that are manufactured by three-dimensional prin ...
DOI:
10.1039/d2ay00075j

3. 3D Cross-linked Ti3C2Tx-Ca-SA films with expanded Ti3C2Tx interlayer spacing as freestanding electrode for all-solid-state flexible pseudocapacitor

Author:
Handan Liu; Yanyan Liu; Dan Xu; Long Chen; Wen Guo; Tiantian Gu; Feng Yu; Gang Wang
Source:
Journal of colloid and interface science 2022 v.610 pp. 295-303
ISSN:
0021-9797
Subject:
capacitance; crosslinking; electrochemical capacitors; electrodes; energy density; microstructure; nanosheets; sodium alginate
Abstract:
... Ti₃C₂Tₓ, a member of the MXene, has attracted extensive interest because of its high conductivity, unique two-dimensional (2D) structure and intrinsic pseudocapacitance for supercapacitors. Flexible and freestanding Ti₃C₂Tₓ films are promising electrodes for functioned supercapacitors used in wearable and portable electronic devices. However, the severe self-restacking of 2D Ti₃C₂Tₓ nanosheets res ...
DOI:
10.1016/j.jcis.2021.10.127

4. 3D hierarchical core–shell spiny globe shaped Co₂P@Ni₂P/NiCo₂O₄@CoO for asymmetric supercapacitors

Author:
Wen-Wei Song; Bing Wang; Chen-Ning Li; Shi-Ming Wang; Zheng-Bo Han
Source:
Journal of materials chemistry A 2022 v.10 no.7 pp. 3710-3721
ISSN:
2050-7496
Subject:
capacitance; electrochemical capacitors; electrochemistry; electrodes; electrolytes; electron transfer; energy density; foams
Abstract:
... Improving the electron transfer kinetics and optimizing the electrode morphology for efficient electrolyte diffusion are effective strategies for achieving high-performance asymmetric supercapacitors (ASCs). Herein, we construct a novel ZIF-67-derived 3D hierarchical core–shell spiny globe with flat leaves-shaped heterostructure (Co₂P@Ni₂P/NiCo₂O₄@CoO–NF, CNNCC–NF) with improved electron conductiv ...
DOI:
10.1039/d1ta10580a

5. 3D interconnected porous carbon derived from spontaneous merging of the nano-sized ZIF-8 polyhedrons for high-mass-loading supercapacitor electrodes

Author:
Di Geng; Su Zhang; Yuting Jiang; Zimu Jiang; Mengjiao Shi; Jin Chang; Shichuan Liang; Mingyi Zhang; Jing Feng; Tong Wei; Zhuangjun Fan
Source:
Journal of materials chemistry A 2022 v.10 no.4 pp. 2027-2034
ISSN:
2050-7496
Subject:
capacitance; carbon; electrochemical capacitors; electrodes; electrolytes; energy; energy density; hydrophilicity; physiological transport; pyrolysis
Abstract:
... Interconnected porous carbons show great potential for high-rate capacitive energy storage, especially at high electrode mass loadings, due to their continuous conductive network and ion migration channels. Herein, we show a simple construction of 3D interconnected porous carbon through spontaneous merging of nano-sized ZIF-8 polyhedrons (ca. 76 nm) during the pyrolysis process. The obtained porou ...
DOI:
10.1039/d1ta09501c

6. A 3D hierarchical network derived from 2D Fe-doped NiSe nanosheets/carbon nanotubes with enhanced OER performance for overall water splitting

Author:
Kai Chang; Duy Thanh Tran; Jingqiang Wang; Nam Hoon Kim; Joong Hee Lee
Source:
Journal of materials chemistry A 2022 v.10 no.6 pp. 3102-3111
ISSN:
2050-7496
Subject:
carbon; carbon nanotubes; catalysts; durability; electric potential difference; electrical conductivity; electrodes; electrolytes; hydrogen; nanosheets; nickel; oxygen production; selenides
Abstract:
... Designing an earth-abundant electrode material with high activity and durability is a major challenge for water splitting to produce clean and green hydrogen energy. In this study, we report a novel high-performance electrocatalyst derived from a unique three-dimensional hierarchical network of two-dimensional iron-doped nickel selenide nanosheets (2D Fe-doped NiSe NSs) and high-quality carbon nan ...
DOI:
10.1039/d1ta07393a

7. A 3D-ACEK/SERS system for highly efficient and selectable electrokinetic bacteria concentration/detection/ antibiotic-susceptibility-test on whole blood

Author:
Kuan-Hung Chen; Shih-Han Lee; Li-Ching Kok; Tseren-Onolt Ishdorj; Hwan-You Chang; Fan-Gang Tseng
Source:
Biosensors & bioelectronics 2022 v.197 pp. 113740
ISSN:
0956-5663
Subject:
Chryseobacterium indologenes; Escherichia coli; antibiotic resistance; antibiotics; biosensors; detection limit; dielectrophoresis; electrodes; microchip technology; multiple drug resistance
Abstract:
... This study demonstrates a novel multi-functional microfluidic system, designated three dimensional Alternative Current Electrokinetic/Surface Enhanced Raman Scattering (3D-ACEK/SERS), which can concentrate bacteria from whole blood, identify bacterial species, and determine antibiotic susceptibilities of the bacteria rapidly. The system consists of a hybrid electrokinetic mechanism, integrating AC ...
DOI:
10.1016/j.bios.2021.113740

8. A Bird Nest-like Nanostructured NiCO2O4 Modified Screen Printed Electrode for the Sensitive Determination of Mangiferin

Author:
Mohammad Rahimipour; Azar Bagheri Gh.; Seyed Jamilaldin Fatemi
Source:
Journal of analytical chemistry 2022 v.77 no.1 pp. 118-125
ISSN:
1061-9348
Subject:
analytical chemistry; birds; crystal structure; detection limit; electrodes; graphene; nests; oxidation; pH; voltammetry
Abstract:
... In this work, we have demonstrated a novel bird nest-like nanostructured NiCo₂O₄ (BNNS-NiCo₂O₄) synthesis for the first time by implementing the facile hydrothermal approach and specified via various analytical methods. Particularly, XRD technique presented the data on the crystal structure of BNNS-NiCo₂O₄. Moreover, the bird nest type three-dimensional (3D) hierarchical structure was evident via ...
DOI:
10.1134/S1061934822010117

9. A Cadmium-Selective Electrode Based on Ionophores with Nitrogen-, Sulfur-, and Oxygen-Containing Functional Groups

Author:
S. D. Tataeva; K. E. Magomedov
Source:
Journal of analytical chemistry 2022 v.77 no.1 pp. 110-117
ISSN:
1061-9348
Subject:
acidity; alloys; analytical chemistry; atomic absorption spectrometry; cadmium; detection limit; electrochemistry; electrodes; ionophores; milk; pH; poly(vinyl chloride)
Abstract:
... We assessed a possibility of using octadecylamine (ODA) as an ionophore component of the membrane of a cadmium-selective electrode (Cd-SE). The equilibria in the membrane–solution system were studied depending on the acidity of the medium and the amount of the ionophore in order to reveal the mechanism of membrane functioning. At pH 1–2, octadecylamine is in the cationic form, and cadmium ions in ...
DOI:
10.1134/S1061934821110150

10. A CdSe@CdS quantum dots based electrochemiluminescence aptasensor for sensitive detection of ochratoxin A

Author:
Mingxuan Jia; Boyu Jia; Xiaofang Liao; Linchun Shi; Zheng Zhang; Miao Liu; Lidong Zhou; Donghui Li; Weijun Kong
Source:
Chemosphere 2022 v.287 pp. 131994
ISSN:
0045-6535
Subject:
aptasensors; biocompatibility; chitosan; cross-linking reagents; detection limit; diagnostic techniques; electrochemiluminescence; electrodes; electrolytes; glutaraldehyde; ochratoxin A; oligonucleotides; rhubarb; safety assessment; viability
Abstract:
... In this work, a CdSe@CdS quantum dots (QDs) based label-free electrochemiluminescence (ECL) aptasensor was developed for the specific and sensitive detection of ochratoxin A (OTA). Chitosan (CHI) could immobilize abundant QDs on the surface of an Au electrode as the luminescent nanomaterials. Glutaraldehyde was used as the crosslinking agent for coupling a large number of OTA aptamers. Thanks to t ...
DOI:
10.1016/j.chemosphere.2021.131994

11. A Comprehensive Review on Electroanalytical Methodologies for the Determination of Carmoisine (E122)

Author:
Mohammad Reza Jalali Sarvestani; Zohreh Doroudi
Source:
Food analytical methods 2022 v.15 no.6 pp. 1565-1574
ISSN:
1936-9751
Subject:
azorubine; commercialization; cosmetics; electrochemistry; electrodes; fabrics; instrumentation; laws and regulations; prices
Abstract:
... Carmoisine (CMS) as a synthetic azo dye is extensively utilized in the pharmaceutical, cosmetics, textile, and food industries. Previous studies revealed that several serious health problems are caused by longer exposure to CMS. Thus, in most countries, the permissible quantity of CMS in pharmaceutical and food products is controlled strictly by legislation. Hence, it is essential to develop a sen ...
DOI:
10.1007/s12161-021-02217-8

12. A Critical Review on Classifications, Characteristics, and Applications of Electrically Conductive Membranes for Toxic Pollutant Removal From Water: Comparison Between Composite and Inorganic Electrically Conductive Membranes

Author:
Yinghui Mo; Lu Zhang; Xin Zhao; Jianxin Li; Liang Wang
Source:
Journal of hazardous materials 2022 pp. 129162
ISSN:
0304-3894
Subject:
chemical degradation; durability; electrical conductivity; electrodes; energy; filtration; permeability; pollution control; porosity; toxicity
Abstract:
... Research efforts have recently been directed at developing electrically conductive membranes (EMs) for pressure-driven membrane separation processes to remove effectively the highly toxic pollutants from water. EMs serve as both the filter and the electrode during filtration. With the assistance of a power supply, EMs can considerably improve the toxic pollutant removal efficiency and even realize ...
DOI:
10.1016/j.jhazmat.2022.129162

13. A Cu–CNF–rGO-functionalized carbon film indicated as a versatile electrode for sensing of biomarkers using electropolymerized recognition elements

Author:
Haider Ali; Nishith Verma
Source:
Journal of materials science 2022 v.57 no.11 pp. 6345-6360
ISSN:
0022-2461
Subject:
biomarkers; carbon; carbon nanofibers; carbonization; cholesterol; copper nanoparticles; creatinine; electrical conductivity; electrochemistry; electrodes; glucose; graphene oxide; methyl orange; methylene blue; phosphates; polymerization; spermine; vapors; voltammetry
Abstract:
... A carbon film functionalized with reduced graphene oxide (rGO) and Cu nanoparticles (NPs)-tipped carbon nanofibers (CNFs) was demonstrated to be a versatile electrode for the efficient electropolymerization of the following monomers: acryl amide, methylene blue, methyl orange, and β-cyclodextrin. These electropolymers were used as the recognition elements for the measurements of glucose, creatinin ...
DOI:
10.1007/s10853-022-07029-7

14. A First-Principles Investigation of Lithium and Sodium Ion Diffusion in C₆₀ Molecular Solids

Author:
Rachel Gorelik; Abu Asaduzzaman; Venkateswara Rao Manga; Abhishek Thakur; Krishna Muralidharan
Source:
Journal of physical chemistry 2022 v.126 no.9 pp. 4259-4266
ISSN:
1932-7455
Subject:
ambient temperature; density functional theory; electrodes; energy; lithium; physical chemistry; reaction kinetics; sodium
Abstract:
... C₆₀-based molecular solids have shown promise as important constituents in electrode materials as well as for providing interfacial stability for solid state electrolytes in alkali ion batteries. At room temperature, the solid state C₆₀ crystal is characterized by a face-centered cubic (FCC) structure, with large interstitial voids, which can accommodate and promote ion transport. In this regard, ...
DOI:
10.1021/acs.jpcc.1c09269

15. A Folding-Based Electrochemical Aptasensor for the Single-Step Detection of the SARS-CoV-2 Spike Protein

Author:
Federica Curti; Simone Fortunati; Wolfgang Knoll; Marco Giannetto; Roberto Corradini; Alessandro Bertucci; Maria Careri
Source:
ACS applied materials & interfaces 2022 v.14 no.17 pp. 19204-19211
ISSN:
1944-8252
Subject:
COVID-19 infection; DNA; Severe acute respiratory syndrome coronavirus 2; aptasensors; carbon nanotubes; cost effectiveness; cross reaction; detection limit; diagnostic techniques; dissociation; electrochemistry; electrodes; electron transfer; ligands; oligonucleotides; polymerase chain reaction
Abstract:
... Efficient and timely testing has taken center stage in the management, control, and monitoring of the current COVID-19 pandemic. Simple, rapid, cost-effective diagnostics are needed that can complement current polymerase chain reaction-based methods and lateral flow immunoassays. Here, we report the development of an electrochemical sensing platform based on single-walled carbon nanotube screen-pr ...
DOI:
10.1021/acsami.2c02405

16. A High Sensitivity Electrochemical Immunosensor Based on Monoclonal Antibody Coupled Flower-Shaped Nano-ZnO for Detection of Tenuazonic Acid

Author:
Chi Zhang; Congcong Du; Wei Liu; Ting Guo; Ying Zhou; Hongyuan Zhou; Yuhao Zhang; Xiaozhu Liu; Liang Ma
Source:
Agriculture (Basel) 2022 v.12 no.2 pp. -
ISSN:
2077-0472
Subject:
Citrus; agriculture; altenuene; detection limit; electrochemistry; electrodes; electron transfer; gold; immune response; immunosensors; monoclonal antibodies; surface area; tenuazonic acid; tomatoes
Abstract:
... In this paper, an electrochemical biosensor was established for the high-sensitivity detection of Tenuazonic acid (TeA) in fruits based on the enrichment of flower-shaped nano-ZnO and the specific recognition of immune response. Herein flower-shaped nano-ZnO (ZnO NFs) with a hexagonal wurtzite structure and diameter of 700–800 nm were demonstrated to have the optimal specific surface area and outs ...
DOI:
10.3390/agriculture12020204

17. A Light-Powered Triboelectric Nanogenerator Based on the Photothermal Marangoni Effect

Author:
Chongxian Liu; Dongjie Jiang; Guiqiang Zhu; Zengzhao Li; Xiaojie Zhang; Pan Tian; Dan Wang; Engui Wang; Han Ouyang; Meng Xiao; Zhou Li
Source:
ACS applied materials & interfaces 2022 v.14 no.19 pp. 22206-22215
ISSN:
1944-8252
Subject:
electric generators; electrodes; foams; hydrophobicity; light intensity; polytetrafluoroethylene; silicon; solar radiation
Abstract:
... The photothermal Marangoni effect enables direct light-to-work conversion, which is significant for realizing the self-propulsion of objects in a noncontact, controllable, and continuous manner. Many promising applications have been demonstrated in micro- and nanomachines, light-driven actuators, cargo transport, and gear transmission. Currently, the related studies about photothermal Marangoni ef ...
DOI:
10.1021/acsami.2c04651

18. A Low-Cost Wireless Intelligent Portable Sensor Based on Disposable Laser-Induced Porous Graphene Flexible Electrode Decorated by Gold Nanoshells for Rapid Detection of Sulfonamides in Aquatic Products

Author:
Daoyang Qiu; Xiaoqiang Wang; Yangping Wen; Yifang Zeng; Weiqiang Li; Li Zhao; Lili Chen; Jianhua Xiong; Kaijie Tang
Source:
Food analytical methods 2022 v.15 no.6 pp. 1471-1481
ISSN:
1936-9751
Subject:
detection limit; electrochemistry; electrodes; fish; food safety; gold; graphene; nanoparticles; rapid methods; shrimp; sulfanilamide; wireless technology
Abstract:
... We explored a low-cost wireless smart portable sensor based on a disposable laser-induced porous graphene (LIPG) flexible substrate electrode decorated by gold nanoshells (AuNSs) for a simple and rapid electrochemical detection of sulfonamides (SAs). The LIPG was prepared by the one-step computer-controlled laser direct-writing patterning techniques on polyimide (PI) substrate, and the AuNSs were ...
DOI:
10.1007/s12161-021-02198-8

19. A New Self-Healing Triboelectric Nanogenerator Based on Polyurethane Coating and Its Application for Self-Powered Cathodic Protection

Author:
Weixiang Sun; Ning Luo; Yubo Liu; Hao Li; Daoai Wang
Source:
ACS applied materials & interfaces 2022 v.14 no.8 pp. 10498-10507
ISSN:
1944-8252
Subject:
ambient temperature; artificial intelligence; carbon; catalytic activity; corrosion; crosslinking; electric generators; electric potential difference; electrodes; friction; hydrogen; industry; oils; polyurethanes; renewable energy sources; silicone
Abstract:
... With the increasing demand for carbon neutrality, the development of renewable and recycle green energy has attracted wide attention from researchers. A novel self-healing triboelectric nanogenerator (TENG) was constructed by applying a linear silicone-modified polyurethane (PU) coating as a triboelectric layer, which was obtained by reacting hydroxypropyl silicone oil and hexamethylene diisocyana ...
DOI:
10.1021/acsami.2c00881

20. A PCR-free genosensing platform for detection of Shigella dysenteriae in human plasma samples by porous and honeycomb-like biochar decorated with ultrathin flower-like MoS2 nanosheets incorporated with Au nanoparticles

Author:
Hessamaddin Sohrabi; Mir Reza Majidi; Karim Asadpour-Zeynali; Alireza Khataee; Mahsa Dastborhan; Ahad Mokhtarzadeh
Source:
Chemosphere 2022 v.288 pp. 132531
ISSN:
0045-6535
Subject:
DNA; Gram-negative bacteria; Salmonella Typhimurium; Shigella dysenteriae; base pair mismatch; bioassays; biochar; electrochemistry; electrodes; genes; humans; nanocomposites; nanogold; nanosheets; pyrolysis; shigellosis; standard deviation; voltammetry
Abstract:
... Shigella dysenteriae, a gram-negative bacterium, which results in the most infectious of bacterial shigellosis and dysenteries. In this study, an innovative gene detection platform based on label-free DNA sequences was developed to detect Shigella dysenteriae in human plasma samples. The porous and honeycomb-like structure of biochar (BC) was first synthesized through a pyrolysis process. Then, th ...
DOI:
10.1016/j.chemosphere.2021.132531

21. A Preliminary Study on the Use of HD-sEMG for the Functional Imaging of Equine Superficial Muscle Activation during Dynamic Mobilization Exercises

Author:
Fiorenza Gamucci; Marcello Pallante; Sybille Molle; Enrico Merlo; Andrea Bertuglia
Source:
Animals 2022 v.12 no.6 pp. -
ISSN:
2076-2615
Subject:
central nervous system; electrodes; electromyography; horses; mastication; motor neurons; muscles; skeletal muscle
Abstract:
... Superficial skeletal muscle activation is associated with an electric activity. Bidimensional High-Density Surface Electromyography (HD-sEMG) is a non-invasive technique that uses a grid of equally spaced electrodes applied on the skin surface to detect and portray superficial skeletal muscle activation. The goal of the study was to evaluate the feasibility of HD-sEMG to detect electrical activati ...
DOI:
10.3390/ani12060785

22. A SiO2@MIP electrochemical sensor based on MWCNTs and AuNPs for highly sensitive and selective recognition and detection of dibutyl phthalate

Author:
Shan Wang; Mingfei Pan; Kaixin Liu; Xiaoqian Xie; Jingying Yang; Liping Hong; Shuo Wang
Source:
Food chemistry 2022 v.381 pp. 132225
ISSN:
0308-8146
Subject:
carbon nanotubes; detection limit; dibutyl phthalate; electrochemistry; electrodes; electron transfer; food chemistry; microparticles; molecular imprinting; nanogold; polymers; sensors (equipment)
Abstract:
... A molecularly imprinted sensor for highly sensitive and selective determination of dibutyl phthalate (DBP) was fabricated by combining multi-walled carbon nanotubes (MWCNTs) and Au nanoparticles (AuNPs) with surface molecularly imprinted polymer (SMIPs). The MWCNTs and AuNPs were designed to modify the electrode surface to accelerate the electron transfer rate and enhance the chemical stability. S ...
DOI:
10.1016/j.foodchem.2022.132225

23. A Sn doped, strained CuAg film for electrochemical CO₂ reduction

Author:
Xiaoye Du; Yanyang Qin; Bo Gao; Jun Ho Jang; Chunhui Xiao; Yanhuai Li; Shujiang Ding; Zhongxiao Song; Yaqiong Su; Ki Tae Nam
Source:
Journal of materials chemistry A 2022 v.10 no.13 pp. 7082-7089
ISSN:
2050-7496
Subject:
Gibbs free energy; alloys; carbon dioxide; electricity; electrochemistry; electrodes; energy; hydrogen production; value added
Abstract:
... The electrochemical CO₂ reduction reaction (CO₂RR) using renewably generated electricity under mild conditions is a promising and sustainable approach to convert CO₂ to value-added chemicals. Cu and Cu alloys are considered to be potential catalysts for CO₂ reduction among numerous catalysts. Unfortunately, the product selectivity and conversion efficiency during the CO₂RR are severely limited by ...
DOI:
10.1039/d2ta00250g

24. A T-rich nucleic acid-enhanced electrochemical platform based on electroactive silver nanoclusters for miRNA detection

Author:
Yan Zhao; Changtong Lu; Xian-En Zhao; Weiheng Kong; Shuyun Zhu; Fengli Qu
Source:
Biosensors & bioelectronics 2022 v.208 pp. 114215
ISSN:
0956-5663
Subject:
DNA; biomarkers; biosensors; detection limit; electrochemistry; electrodes; electroplating; microRNA; nanosilver; nucleotides; oxidation
Abstract:
... DNA-templated silver nanoclusters (DNA/AgNCs) serve as a useful electrochemical sensing nanomaterial characterized by excellent electroactivity and good stability, while the effect of surrounding nucleotides on their electroactivity has not been studied. Herein, we validated a nucleotide-assisted enhancement mechanism of the DNA/AgNCs electroactivity caused by T-rich nucleic acid sequences in the ...
DOI:
10.1016/j.bios.2022.114215

25. A Transparent Semiconducting Surface for Capturing and Releasing Single Cells from a Complex Cell Mixture

Author:
Jiaxin Lian; Wenxian Tang; Ying Yang; Ramanathan Vaidyanathan; Vinicius R. Gonçales; Seyed Yousef Arman; Richard D. Tilley; J. Justin Gooding
Source:
ACS applied materials & interfaces 2022 v.14 no.16 pp. 18079-18086
ISSN:
1944-8252
Subject:
desorption; electrodes; fluorescence microscopy; models; neoplasms; semiconductors; silicon; tin dioxide
Abstract:
... Selective isolation of individual target cells from a heterogeneous population is technically challenging; however, the ability to retrieve single cells can have high significance in various aspects of biological research. Here, we present a new photoelectrochemical surface based on a transparent electrode that is compatible with high-resolution fluorescence microscopy for isolating individual rar ...
DOI:
10.1021/acsami.1c23209

26. A bifunctional electrochemical sensor for simultaneous determination of electroactive and non-electroactive analytes: A universal yet very effective platform serving therapeutic drug monitoring

Author:
Xiaoli Wang; Yujian Liu; Jiang Liu; Jieming Qu; Jingjing Huang; Ruoming Tan; Yue Yu; Jing Wu; Jiao Yang; Yingchun Li; Hongping Qu; Jialin Liu
Source:
Biosensors & bioelectronics 2022 v.208 pp. 114233
ISSN:
0956-5663
Subject:
biosensors; blood serum; ceftazidime; chemical species; detection limit; electrochemistry; electrodes; ferricyanides; humans; molecular imprinting; oxidation; polymers; rabbits; therapeutics
Abstract:
... A novel electrochemical sensor for therapeutic drug monitoring (TDM) of antibiotic Zavicefta was developed in this work. The main components of Zavicefta are ceftazidime (CFZ) and avibactam (AVI), wherein CFZ can be oxidized directly on electrode surface, while AVI is non-electroactive. In order to realize the simultaneous detection of the two analytes on one sensor, we elaborately constructed a d ...
DOI:
10.1016/j.bios.2022.114233

27. A bilayer coating as an oxygen-transfer cascade for the electrochemical ambient conversion of methane to oxygenates

Author:
Yanir Kadosh; Yeshayahu Ben-Eliyahu; Yair Bochlin; Lior Ezuz; Yacov Iflah; Shuli Halevy; Sebastian Kozuch; Eli Korin; Armand Bettelheim
Source:
Chemical communications 2022 v.58 no.19 pp. 3154-3157
ISSN:
1364-548X
Subject:
carbon dioxide; density functional theory; electrochemistry; electrodes; electron transfer; energy conversion; formates; methane; methanol; oxidation; oxygen; porphyrins
Abstract:
... Oxidation of methane at ambient conditions to useful oxygenates at a bilayer-coated electrode is demonstrated. The composition of the coating, a Mn porphyrin mediator layer on top of a N(OH)₂/NiOOH one, allows a cascade of oxygen transfer events upon applying a potential. It is shown, using (spectro)electrochemical techniques, density functional theory computations and product analytical methods, ...
DOI:
10.1039/d1cc05720k

28. A biomolecule-free electrochemical sensing approach based on a novel electrode modification technique: Detection of ultra-low concentration of Δ⁹-tetrahydrocannabinol in saliva by turning a sample analyte into a sensor analyte

Author:
Greter A. Ortega; Syed Rahin Ahmed; Satish K. Tuteja; Seshasai Srinivasan; Amin Reza Rajabzadeh
Source:
Talanta 2022 v.236 pp. 122863
ISSN:
0039-9140
Subject:
Cannabis; detection limit; drugs; electrochemistry; electrodes; electroplating; roadsides; saliva; voltammetry
Abstract:
... Cannabis is currently one of the most consumed drugs in many countries. Δ⁹-tetrahydrocannabinol (THC) is the principal psychoactive component of this drug and is present in saliva after consumption. This paper reports a novel biomolecule-free electrochemical approach to detect an ultra-low level of THC in saliva using modified electrodes with molecules of the same analyte (THC) that are detected l ...
DOI:
10.1016/j.talanta.2021.122863

29. A cloth-based electrochemiluminescence sensor for determination of salbutamol residues in pork samples

Author:
Nisachon Praoboon; Jirapatpong Senabut; Manoch Thanomwat; Tanin Tangkuaram; Pusit Pookmanee; Sirirat Phaisansuthichol; Supaporn Sangsrichan; Surasak Kuimalee; Sakchai Satienperakul
Source:
Food chemistry 2022 v.386 pp. 132786
ISSN:
0308-8146
Subject:
chitosan; cotton; detection limit; electrochemiluminescence; electrodes; food chemistry; hydrophobicity; pH; platinum; pork; ruthenium
Abstract:
... The fabrication of a cloth-based analytical device combined with electrochemiluminescence detection was established for the rapid determination of salbutamol in pork samples. A hand-coloring method to pattern the hydrophobic chamber was employed, and a three-carbon electrode system was subsequently screen printed onto the patterned cotton chamber. Further modifications of the working electrode sur ...
DOI:
10.1016/j.foodchem.2022.132786

30. A comprehensive review on the recycling of spent lithium-ion batteries: Urgent status and technology advances

Author:
Shan Jin; Deying Mu; Ziang Lu; Ruhong Li; Zhu Liu; Yue Wang; Shuang Tian; Changsong Dai
Source:
Journal of cleaner production 2022 v.340 pp. 130535
ISSN:
0959-6526
Subject:
ecology; electrodes; electrolytes; environmental hazards; greenhouse gases; lithium batteries; markets; transportation
Abstract:
... The burgeoning development of lithium-ion battery technology is imperative, not only realizing targets for reducing greenhouse gas emissions, but also changing the way of global communication and transportation. As the demand increases, the quantity of discarded lithium-ion batteries (LIBs) has been continuously rising, bringing a tough waste-management challenge for recycling service sectors at e ...
DOI:
10.1016/j.jclepro.2022.130535

31. A critical review on microbe-electrode interactions towards heavy metal ion detection using microbial fuel cell technology

Author:
Md Tabish Noori; Dayakar Thatikayala; Deepak Pant; Booki Min
Source:
Bioresource technology 2022 v.347 pp. 126589
ISSN:
0960-8524
Subject:
bioelectricity; electrodes; heavy metals; metabolism; microbial fuel cells; research and development; toxicity
Abstract:
... Implicit interaction of electroactive microbes with solid electrodes is an interesting phenomenon in nature, which supported development of bioelectrochemical systems (BESs), especially the microbial fuel cell (MFCs) for valorization of low-value waste streams into bioelectricity. Intriguingly, the metabolism of interacted microbes with electrode is affected by the microenvironment at electrodes, ...
DOI:
10.1016/j.biortech.2021.126589

32. A critical review on the electrosorption of organic compounds in aqueous effluent – Influencing factors and engineering considerations

Author:
Amina Lissaneddine; Marie-Noëlle Pons; Faissal Aziz; Naaila Ouazzani; Laila Mandi; Emmanuel Mousset
Source:
Environmental research 2022 v.204 pp. 112128
ISSN:
0013-9351
Subject:
carbon; corrosion; deionization; durability; electrodes; electrolytes; hydrogen; mass transfer; models; oxidation; research; wastewater
Abstract:
... Despite being an old process from the end of the 19ᵗʰ century, electrosorption has attracted renewed attention in recent years because of its unique properties and advantages compared to other separation technologies and due to the concomitant development of new porous electrode materials. Electrosorption offer the advantage to separate the pollutants from wastewater with the possibility of select ...
DOI:
10.1016/j.envres.2021.112128

33. A critical review on the fabrication techniques that can enable higher throughput in dielectrophoresis devices

Author:
Rodrigo Martinez‐Duarte
Source:
Electrophoresis 2022 v.43 no.1-2 pp. 232-248
ISSN:
0173-0835
Subject:
affordability; carbon; diagnostic techniques; dielectrophoresis; electric field; electrodes; electrophoresis; electroplating; health services; motivation; silicon; therapeutics
Abstract:
... The sorting of targeted cells in a sample is a cornerstone of healthcare diagnostics and therapeutics. This work focuses on the use of dielectrophoresis for the selective sorting of targeted bioparticles in a sample and how the lack of throughput has been one important practical challenge to its widespread practical implementation. Increasing the cross‐sectional area of a channel can lead to highe ...
DOI:
10.1002/elps.202100179

34. A direct and simple immobilization route for immunosensors by CNBr activation for covalent attachment of anti-leptin: obesity diagnosis point of view

Author:
İnci Uludağ; Mustafa Kemal Sezgintürk
Source:
3 Biotech 2022 v.12 no.1 pp. 33
ISSN:
2190-572X
Subject:
adipose tissue; antibodies; cost effectiveness; cyanogen; dielectric spectroscopy; electrochemistry; electrodes; energy intake; immunosensors; indium; leptin; obesity; polyethylene terephthalates; tin; voltammetry
Abstract:
... Leptin is a peptide hormone produced in adipose tissue that works as an antiobesity hormone by balancing energy intake and expenditure. We aimed to develop an ultrasensitive electrochemical immunosensor based on a novel immobilization technique for the early detection of leptin-related diseases in this work. Although several methods for immobilizing antibodies to the biosensor recognition element ...
DOI:
10.1007/s13205-021-03096-w

35. A disposable modified screen-printed electrode using egg white/ZnO rice structured composite as practical tool electrochemical sensor for formaldehyde detection and its comparative electrochemical study with Chitosan/ZnO nanocomposite

Author:
G. Padmalaya; Kilaru Harsha Vardhan; P. Senthil Kumar; M. Ajmal Ali; Tse-Wei Chen
Source:
Chemosphere 2022 v.288 pp. 132560
ISSN:
0045-6535
Subject:
albumins; chitosan; detection limit; egg albumen; electrochemistry; electrodes; formaldehyde; nanocomposites; rice; sensors (equipment); urine; voltammetry
Abstract:
... In this study, Chitosan/ZnO nanocomposite (Ch/ZnO) and egg white/ZnO rice structured composite was synthesized by simple wet chemical technique and characterised by various techniques. A comparative electrochemical analysis were carried out and determined that egg white/ZnO rice structured composite modified screen printed electrode (SPCE) showed good electrochemical behaviour. The electrochemical ...
DOI:
10.1016/j.chemosphere.2021.132560

36. A dual-amplification mode and Cu-based metal-organic frameworks mediated electrochemical biosensor for sensitive detection of microRNA

Author:
Yu Xue; Yu Wang; Sinuo Feng; Mengxia Yan; Jianshe Huang; Xiurong Yang
Source:
Biosensors & bioelectronics 2022 v.202 pp. 113992
ISSN:
0956-5663
Subject:
biosensors; electrochemistry; electrodes; hybridization chain reaction; microRNA; nanogold; single-stranded DNA; surface area
Abstract:
... In this work, we developed a novel label-free and highly sensitive electrochemical (EC) biosensor for detection of microRNA (miRNA), which was based on the target-triggered and the Cu-based metal-organic frameworks (Cu-MOFs) mediated CHA-HCR dual-amplification process. Initially, the target miRNA triggered the catalytic hairpin assembly (CHA) process of hairpin DNA 1 (H1) and hairpin DNA 2 (H2) to ...
DOI:
10.1016/j.bios.2022.113992

37. A dual-mechanism-driven electrochemiluminescence aptasensor for sensitive detection of β-amyloid peptides

Author:
Zixuan Chen; Yinan Li; Haixin Qin; Xiaoyan Yang; Wei Cao
Source:
Analytical methods 2022 v.14 no.17 pp. 1739-1746
ISSN:
1759-9679
Subject:
Alzheimer disease; aptasensors; carbon nitride; detection limit; electrochemiluminescence; electrodes; graphene; heme; nanogold; oligonucleotides; oxygen; peptides; toxicity
Abstract:
... β-Amyloid (Aβ) peptides can bind both Cu²⁺ and heme cofactors simultaneously to form heme–Cu²⁺–Aβ complexes, which are proposed to generate toxic partially reduced oxygen species (PROS, e.g., H₂O₂) and play a vital role in Alzheimer's disease (AD). In this paper, a competitive dual-mechanism-driven electrochemiluminescence (ECL) aptasensor integrating the synergistic enhancement and steric hindran ...
DOI:
10.1039/d2ay00410k

38. A dual-polymer strategy boosts hydrated vanadium oxide for ammonium-ion storage

Author:
Peng Wang; Yifu Zhang; Ziyi Feng; Yanyan Liu; Changgong Meng
Source:
Journal of colloid and interface science 2022 v.606 pp. 1322-1332
ISSN:
0021-9797
Subject:
ammonium; capacitance; carbon; electrochemical capacitors; electrochemistry; electrodes; energy; polyaniline; polyvinyl alcohol; vanadium
Abstract:
... Recently, aqueous rechargeable batteries employing ammonium-ions (NH₄⁺) as charge carriers have received increasing interest because of their merits of eco-friendly, low cost and sustainability. However, the supercapacitor based on NH₄⁺ charge carriers has rarely been reported probably owing to the lack of a suitable system to achieve acceptable capacitance and cycle performance for NH₄⁺ storage. ...
DOI:
10.1016/j.jcis.2021.08.036

39. A dual-signal output electrochemical immunosensor based on Au–MoS2/MOF catalytic cycle amplification strategy for neuron-specific enolase ultrasensitive detection

Author:
Hui Dong; Shanghua Liu; Qing Liu; Yueyuan Li; Yueyun Li; Zengdian Zhao
Source:
Biosensors & bioelectronics 2022 v.195 pp. 113648
ISSN:
0956-5663
Subject:
biomarkers; electrochemistry; electrodes; electron transfer; immunoassays; immunosensors; phosphopyruvate hydratase
Abstract:
... In this work, a dual-signal output electrochemical immunosensor based on the Au–MoS₂/MOF high-efficiency catalytic cycle amplification strategy for the sensitive detection of neuron-specific enolase (NSE). The mixed-valence structure MOF (Fe²⁺/Fe³⁺-MOF) exhibits high-speed charge mobility and excellent electrochemical performance. Notably, nanoflowers-like MoS₂ (MoS₂ NFs), as a co-catalyst, were i ...
DOI:
10.1016/j.bios.2021.113648

40. A durable high-energy implantable energy storage system with binder-free electrodes useable in body fluids

Author:
Ji Su Chae; Hoomin Lee; Sung-Hyun Kim; Nilesh R. Chodankar; Sung-Min Kang; Seonghan Lee; Jeong Han Lee; Young-Kyu Han; Wan-Seob Cho; Yun Suk Huh; Kwang Chul Roh
Source:
Journal of materials chemistry A 2022 v.10 no.9 pp. 4611-4620
ISSN:
2050-7496
Subject:
body fluids; capacitance; carbon nanotubes; cytotoxicity; electrochemical capacitors; electrodes; electrolytes; energy; inflammation; oxidation
Abstract:
... We developed a flexible supercapacitor (SC) cell with biocompatible oxidized single-walled carbon nanotubes (SWCNTs) driven by electrolytes in body fluids through integration with a wireless sensor network for use in implantable electronic medical devices (IEMDs). The SC was assembled using oxidized SWCNTs (Ox-SWCNTs) in the form of binder-free buckypaper as an electrode material, which is both bi ...
DOI:
10.1039/d1ta09427k

41. A facile method combined with electroless nickel plating and carbonization to fabricate textured Ni-coated carbon tube for flexible strain sensor

Author:
Haodong Ma; Changshun Zha; Di Sun; Zhangkai Qian; Jin Shi; Zhenming Chen; Junjun Huang; Chengmei Gui
Source:
Colloids and surfaces 2022 v.643 pp. 128729
ISSN:
0927-7757
Subject:
adsorption; carbon; carbonization; cotton; detection limit; electrodes; equations; fabrics; humans; nickel; vibration
Abstract:
... High-sensitive textile sensor acts the key component of electronic wearable products. It is a challenge to low-cost fabricate flexible sensors that possess excellent response reliability. In this regard, we employ a facile method combined with electroless nickel plating and carbonization to fabricate textured Ni-coated carbon tube (Te-CNiT) electrode, used as sensitive material for resistive senso ...
DOI:
10.1016/j.colsurfa.2022.128729

42. A facile one-pot synthesis of magnetic iron oxide nanoparticles embed N-doped graphene modified magnetic screen printed electrode for electrochemical sensing of chloramphenicol and diethylstilbestrol

Author:
Saithip Pakapongpan; Yingyot Poo-arporn; Adisorn Tuantranont; Rungtiva P. Poo-arporn
Source:
Talanta 2022 v.241 pp. 123184
ISSN:
0039-9140
Subject:
Raman spectroscopy; X-ray absorption spectroscopy; X-ray diffraction; X-ray photoelectron spectroscopy; antibiotic residues; catalytic activity; chemical structure; chloramphenicol; detection limit; diethylstilbestrol; electrochemistry; electrodes; graphene; humans; iron oxides; magnetism; milk; nanohybrids; poisoning; reducing agents; sensors (equipment); synthesis; transmission electron microscopy; voltammetry
Abstract:
... Trace determination of antibacterial agents is crucial to minimize risks of human intoxication and in the prevention of serious environmental impacts. Herein, a simple one-pot solvothermal synthesis approach for a magnetic iron oxide embed nitrogen-doped graphene (MIO@NG) nanohybrid was fabricated without the addition of any extra reductant and its application towards ultrasensitive chloramphenico ...
DOI:
10.1016/j.talanta.2021.123184

43. A fast and label-free detection of hydroxymethylated DNA using a nozzle-jet printed AuNPs@Ti3C2 MXene-based electrochemical sensor

Author:
Kiesar Sideeq Bhat; Seongjun Byun; Asrar Alam; Myunggon Ko; Jungeun An; Sooman Lim
Source:
Talanta 2022 v.244 pp. 123421
ISSN:
0039-9140
Subject:
5-methylcytosine; DNA; biomarkers; chemical composition; cost effectiveness; electrochemistry; electrodes; epigenetics; genome; genomics; mammals; nanocomposites; nanogold; polyethylene terephthalates; sensors (equipment); silver; voltammetry
Abstract:
... 5-hydroxymethylcytosine (5hmC) is a key epigenetic mark in the mammalian genome that has been proposed as a promising cancer biomarker with diagnostic and prognostic potentials. A new type of two-dimensional (2D) material called MXene includes transition metal carbides and nitrides and possesses unique physico-chemical properties suitable for diverse applications, including electrochemical sensors ...
DOI:
10.1016/j.talanta.2022.123421

44. A flexible and self-healing supercapacitor based on activated carbon cloth/MnO2 composite

Author:
Zewen Fan; Jing Ren; Fa Zhang; Tao Gu; Shaofei Zhang; Rui-Peng Ren; Yong-Kang Lv
Source:
Journal of materials science 2022 v.57 no.2 pp. 1281-1290
ISSN:
0022-2461
Subject:
activated carbon; air; capacitance; crosslinking; electrochemical capacitors; electrochemistry; electrodes; electrolytes; electronics; hydrogen; temperature
Abstract:
... Flexible and self-healing supercapacitors are urgently needed to meet the practical applications of flexible and wearable electronics. Herein, we have prepared a flexible and self-healing supercapacitor by sandwiching a self-healing physically cross-linked PVA–H₂SO₄ electrolyte separator between two activated carbon cloth (ACC)/MnO₂ electrode films. The ACC/MnO₂ electrode is prepared by activation ...
DOI:
10.1007/s10853-021-06644-0

45. A flexible electrochemical biosensor based on functionalized poly(3,4-ethylenedioxythiophene) film to detect lactate in sweat of the human body

Author:
Chonghui Zhu; Yifeng Xu; Qidai Chen; Hongran Zhao; Bingrong Gao; Tong Zhang
Source:
Journal of colloid and interface science 2022 v.617 pp. 454-462
ISSN:
0021-9797
Subject:
adhesion; adsorption; biosensors; crosslinking; detection limit; electrical conductivity; electrodes; humans; lactate 2-monooxygenase; lactic acid; liquid-air interface; sweat
Abstract:
... Conductive polymers with good flexibility, conductivity and film-forming ability attract a lot of attention. In this work, a large-area and ordered structure poly(3,4-ethylenedioxythiophene) (PEDOT) film is fabricated at the air-water interface through interface synthesis method. The PEDOT film can be directly placed on a flexible screen-printed electrode, but also has good adhesion between them. ...
DOI:
10.1016/j.jcis.2022.03.029

46. A hierarchically combined reduced graphene oxide/Nickel oxide hybrid supercapacitor device demonstrating compliable flexibility and high energy density

Author:
Bo-wen Deng; Yi Yang; Yu-xin Liu; Bo Yin; Ming-bo Yang
Source:
Journal of colloid and interface science 2022 v.618 pp. 399-410
ISSN:
0021-9797
Subject:
aerogels; capacitance; deformation; electrochemical capacitors; electrochemistry; electrodes; energy; energy density; foams; graphene oxide; hot water treatment; nickel; nickel oxide
Abstract:
... This work demonstrates a hierarchical structure design with mixed holey graphene oxide (HGO) and Ni(OH)₂ active material layer made by one-pot hydrothermal reaction clinging to Nickel foam as backbone and ice-template oriented graphene oxide (GO) aerogel as filling, aiming to create an asymmetric solid supercapacitor (ASC) device with compliable flexibility and high electrochemical performance. Th ...
DOI:
10.1016/j.jcis.2022.03.068

47. A high-capacity polyaniline-intercalated layered vanadium oxide for aqueous ammonium-ion batteries

Author:
Chunhua Han; Jiao Zhu; Kai Fu; Dan Deng; Wen Luo; Liqiang Mai
Source:
Chemical communications 2022 v.58 no.6 pp. 791-794
ISSN:
1364-548X
Subject:
batteries; chemical communication; electrodes; materials; oxides; vanadium
Abstract:
... A 1.55 nm-interlayer spacing-expanded polyaniline-intercalated vanadium oxide, as a new electrode material for NH₄⁺-ion batteries, exhibits the highest ever reported capacity of ∼307 mA h g⁻¹ at a current density of 0.5 A g⁻¹. In situ FT-IR and XPS studies confirm the reversible NH₄⁺ storage is accompanied by H bond formation/breaking within the functional group of –VO···H. ...
DOI:
10.1039/d1cc05677h

48. A highly active copper-nanoparticle-based nitrate reduction electrocatalyst prepared by in situ electrodeposition and annealing

Author:
Min Hong; Qinian Wang; Jun Sun; Chao Wu
Source:
Science of the total environment 2022 v.827 pp. 154349
ISSN:
0048-9697
Subject:
adsorption; chlorination; copper; denitrification; electrochemistry; electrodes; electroplating; environment; graphene; nitrate reduction; nitrates; oxidation; particle size; surface area
Abstract:
... In recent years, copper-based electrodes have attracted intense attention for the electrochemical reduction of nitrate (NO₃⁻), the so-called ECRN. However, these electrodes suffer from low activity and selectivity. Herein, we report a novel Cu-based electrode (IE-Cu-400) for the ECRN fabricated by loading Cu-based nanoparticles onto graphite felt using in situ electrodeposition followed by anneali ...
DOI:
10.1016/j.scitotenv.2022.154349

49. A highly durable graphene monolayer electrode under long-term hydrogen evolution cycling

Author:
Michel Wehrhold; Tilmann J. Neubert; Tobias Grosser; Martin Vondráček; Jan Honolka; Kannan Balasubramanian
Source:
Chemical communications 2022 v.58 no.23 pp. 3823-3826
ISSN:
1364-548X
Subject:
electrochemistry; electrodes; electron transfer; graphene; hydrogen production
Abstract:
... Achieving long term stability of single graphene sheets towards repeated electrochemical hydrogen evolution reaction (HER) cycling has been challenging. Here, we show through appropriate electrode preparation that it is possible to obtain highly durable isolated graphene electrodes, which can survive several hundreds of HER cycles with virtually no damage to the sp²-carbon framework and persistent ...
DOI:
10.1039/d2cc00220e

50. A highly sensitive electrochemical aptasensor for cocaine detection based on CRISPR-Cas12a and terminal deoxynucleotidyl transferase as signal amplifiers

Author:
Khalil Abnous; Ali khakshour Abdolabadi; Mohammad Ramezani; Mona Alibolandi; Morteza Alinezhad Nameghi; TaranehSadat Zavvar; Zahra Khoshbin; Parirokh Lavaee; Seyed Mohammad Taghdisi; Noor Mohammad Danesh
Source:
Talanta 2022 v.241 pp. 123276
ISSN:
0039-9140
Subject:
analytical methods; aptasensors; blood serum; chemical species; cocaine; detection limit; electrochemistry; electrodes; nucleotidyltransferases; oligonucleotides
Abstract:
... Cocaine is one of the mainly used illegal drugs in the world. Using the signal amplification elements of terminal deoxynucleotidyl transferase (TdT) and CRISPR-Cas12a, a highly sensitive and simple electrochemical aptasensor was introduced for cocaine quantification. When, no cocaine existed in the sample, the 3′-end of complementary strand of aptamer (CS) was extended by TdT, leading to the activ ...
DOI:
10.1016/j.talanta.2022.123276

51. A highly sensitive electrochemiluminescence method for abrin detection by a portable biosensor based on a screen-printed electrode with a phage display affibody as specific labeled probe

Author:
Shuai Liu; Chuan Gao; Zhaoyang Tong; Xihui Mu; Bing Liu; Jianjie Xu; Bin Du; Jiang Wang; Zhiwei Liu
Source:
Analytical and bioanalytical chemistry 2022 v.414 no.2 pp. 1095-1104
ISSN:
1618-2642
Subject:
abrin; analytical chemistry; bacteriophages; biosensors; detection limit; electrochemiluminescence; electrodes; monoclonal antibodies; toxicity
Abstract:
... Abrin is a highly toxic ribosome-inactivating protein, which could be used as a biological warfare agent and terrorist weapon, and thus needs to be detected efficiently and accurately. Affibodies are a new class of engineered affinity proteins with small size, high affinity, high stability, favorable folding and good robustness, but they have rarely played a role in biological detection. In this w ...
DOI:
10.1007/s00216-021-03735-4

52. A hybrid sensing system combining simultaneous optical and electrochemical measurements: Application to beer discrimination

Author:
Clara Pérez-Ràfols; Núria Serrano; José Manuel Díaz-Cruz
Source:
Talanta 2022 v.241 pp. 123273
ISSN:
0039-9140
Subject:
absorbance; beers; carbon; discriminant analysis; electrochemistry; electrodes; models; voltammetry
Abstract:
... A hybrid sensing system, which combines simultaneous cyclic voltammetric (CV) and UV–vis absorbance measurements using a commercial carbon screen-printed electrode and a set of optical fibres in disposable cuvettes, is proposed. The hybrid system approach was applied to 27 samples of recognized beer brands, improving the classification power as compared to only voltammetric or only spectrophotomet ...
DOI:
10.1016/j.talanta.2022.123273

53. A label-free amperometric immunosensor with improved electrocatalytic 3D braided AuPtCu-SWCNTs@MoS₂-rGO for human growth differentiation factor-15 detection

Author:
Yinghui Jiao; Zhiyu Huang; Mei Chen; Xiaojun Zhou; Hongsheng Lu; Baogang Wang; Xiaozhen Dai
Source:
Analytical methods 2022 v.14 no.14 pp. 1420-1429
ISSN:
1759-9679
Subject:
biomarkers; carbon nanotubes; detection limit; early diagnosis; electrochemistry; electrodes; graphene oxide; human growth; hydrogen peroxide; immunosensors; molybdenum disulfide; nanoflowers; nanosheets; prognosis
Abstract:
... Growth differentiation factor-15 (GDF-15) is a member of the transforming growth factor-β family. GDF-15 is overexpressed in cardiovascular diseases and has become a novel biomarker for these diseases. In this study, we fabricated a label-free electrochemical immunosensor for sensitive detection of GDF-15. Briefly, a three-dimensional braided composite of AuPtCu-SWCNTs@MoS₂-rGO (denoted A@M), whic ...
DOI:
10.1039/d1ay02198b

54. A label-free and modification-free ratiometric electrochemical strategy for enhanced natural enzyme detection using a bare electrode and nanozymes system

Author:
Honghong Rao; Jianying Li; Mingyue Luo; Kehui Zhang; Hao Gou; Haixia Liu; Zhonghua Xue
Source:
Analytical and bioanalytical chemistry 2022 v.414 no.9 pp. 2991-3003
ISSN:
1618-2642
Subject:
alkaline phosphatase; analytical chemistry; bioassays; detection limit; electrochemistry; electrodes; hydrolysis; liquids; p-nitrophenol; phosphates
Abstract:
... Ratiometric electrochemical assays have been demonstrated to be more sensitive and selective in various sensing events, mainly due to their affordable built-in correction and good self-reference capability. But it is known that complicated modification and labeling operations usually are necessary for the construction of ratiometric electrochemical assays, therefore is a hot and important issue ne ...
DOI:
10.1007/s00216-022-03932-9

55. A metal free nanosensor based on nanocellulose-polypyrrole matrix and single-walled carbon nanotube: Experimental study and electroanalytical application for determination of paracetamol and ciprofloxacin

Author:
Md Shalauddin; Shamima Akhter; Wan Jeffrey Basirun; Vannajan Sanghiran Lee; Mohammad Rafie Johan
Source:
Environmental nanotechnology, monitoring & management 2022 v.18 pp. 100691
ISSN:
2215-1532
Subject:
X-ray diffraction; acetaminophen; administrative management; carbon nanotubes; cellulose; ciprofloxacin; detection limit; dielectric spectroscopy; differential thermal analysis; electrochemistry; electrodes; energy; nanocomposites; oxidation; pyrroles; sensors (equipment); thermogravimetry; transmission electron microscopy; voltammetry
Abstract:
... In the present work, a highly selective and metal-free electrochemical sensor was fabricated from the fusion of nanocellulose and polypyrrole (NNC-PPY), incorporated with single-walled carbon nanotubes (SWCNTs) via drop-casting method for the simultaneous determination of paracetamol (PCM) and ciprofloxacin (CPR). The screen printed electrode (SPE) modified with NNC-PPY/SWCNTs shows outstanding el ...
DOI:
10.1016/j.enmm.2022.100691

56. A microfluidic biosensor for rapid simultaneous detection of waterborne pathogens

Author:
Sura A. Muhsin; Muthana Al-Amidie; Zhenyu Shen; Zahar Mlaji; Jiayu Liu; Amjed Abdullah; Majed El-Dweik; Shuping Zhang; Mahmoud Almasri
Source:
Biosensors & bioelectronics 2022 v.203 pp. 113993
ISSN:
0956-5663
Subject:
Escherichia coli O157; Legionella; Salmonella; biosensors; detection limit; dielectrophoresis; electrodes; pathogens; tap water; wastewater
Abstract:
... A microfluidic based biosensor was investigated for rapid and simultaneous detection of Salmonella, Legionella, and Escherichia coli O157:H7 in tap water and wastewater. The biosensor consisted of two sets of focusing electrodes connected in parallel and three sets of interdigitated electrodes (IDE) arrays. The electrodes enabled the biosensor to concentrate and detect bacteria at both low and hig ...
DOI:
10.1016/j.bios.2022.113993

57. A microfluidic cloth-based photoelectrochemical analytical device for the detection of glucose in saliva

Author:
Xinyuan Mao; Chunsun Zhang
Source:
Talanta 2022 v.238 pp. 123052
ISSN:
0039-9140
Subject:
ammonium; cadmium sulfide; carbon; carbon nanotubes; detection limit; electric current; electrodes; glucose; saliva
Abstract:
... Photoelectrochemical (PEC) detection is a widely used detection method that uses light to stimulate and photocurrent signals to detect the target. Due to the disengagement of the excitation unit and the detection unit, the PEC background signal is reduced, and the detection sensitivity is improved. In this work, we report the first demonstration of PEC detection for microfluidic cloth-based analyt ...
DOI:
10.1016/j.talanta.2021.123052

58. A mini review on bio-electrochemical systems for the treatment of azo dye wastewater: State-of-the-art and future prospects

Author:
Liping Sun; Yinghui Mo; Lu Zhang
Source:
Chemosphere 2022 v.294 pp. 133801
ISSN:
0045-6535
Subject:
azo dyes; electrodes; textile industry; toxicity; wastewater
Abstract:
... Azo dyes are typical toxic and refractory organic pollutants widely used in the textile industry. Bio-electrochemical systems (BESs) have great potential for the treatment of azo dyes with the help of microorganisms as biocatalysts and have advanced significantly in recent years. However, the latest and significant advancement and achievements of BESs treating azo dyes have not been reviewed since ...
DOI:
10.1016/j.chemosphere.2022.133801

59. A nanoflower-like polypyrrole-based cobalt-nickel sulfide hybrid heterostructures with electrons migration to boost overall water splitting

Author:
Youchao Song; Pengda Hong; Tongfei Li; Guoxin Ma; Qinghua Deng; Yuming Zhou; Yiwei Zhang
Source:
Journal of colloid and interface science 2022 v.618 pp. 1-10
ISSN:
0021-9797
Subject:
adsorption; cost effectiveness; dissociation; electric potential difference; electrochemistry; electrodes; electrolytes; electroplating; foams; hydrogen production; nanohybrids; nanosheets; nickel; oxygen production; pyrroles; sulfides; surface area
Abstract:
... The development of high-efficiency and cost-effective difunctional electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are highly attractive to fulfill the practical water electrolysis. Herein, a novel low-cost difunctional cobalt-nickel sulfide (Co₃S₄/Ni₃S₂) flower-like heterostructures are purposely loaded on the surface of polypyrrole (PPy) nanosheets ...
DOI:
10.1016/j.jcis.2022.03.035

60. A near-infrared light-driven photoelectrochemical aptasensing platform for adenosine triphosphate detection based on Yb-doped Bi₂S₃ nanorods

Author:
Jie Gao; Yifan Ding; Kai Yan; Jingdong Zhang
Source:
Journal of materials chemistry B 2022 v.10 no.18 pp. 3524-3530
ISSN:
2050-7518
Subject:
aptasensors; blood serum; detection limit; electric current; electrodes; electron transfer; humans; irradiation; nanorods; oligonucleotides; photostability
Abstract:
... Due to its capability of low spectral interference, high light stability, and minimal photodamage to biological species, near-infrared (NIR) light is advantageous in biosensing and biochemical analysis. This work developed a photoelectrochemical (PEC) aptasensor for adenosine triphosphate (ATP) detection using NIR light as the irradiation source. In order to utilize NIR light, we prepared Yb-doped ...
DOI:
10.1039/d2tb00180b

61. A new hybrid piezo/triboelectric SbSeI nanogenerator

Author:
Bartłomiej Toroń; Krystian Mistewicz; Marcin Jesionek; Mateusz Kozioł; Maciej Zubko; Danuta Stróż
Source:
Energy 2022 v.238 pp. 122048
ISSN:
0360-5442
Subject:
antimony; dielectric permittivity; electric generators; electric potential difference; electrodes; nanowires; surface area; surface roughness
Abstract:
... In this paper, a compressed antimony selenoiodide (SbSeI)-based hybrid piezo/triboelectric nanogenerator for mechanical energy harvesting is presented for the first time. Sonochemically-fabricated SbSeI nanowires were compressed under high pressure (120 MPa) to form a pellet for use as an experimental electrode. Kapton film was utilized as the other electrode. The basic parameters used for the tri ...
DOI:
10.1016/j.energy.2021.122048

62. A new potassium dual-ion hybrid supercapacitor based on battery-type Ni(OH)2 nanotube arrays and pseudocapacitor-type V2O5-anchored carbon nanotubes electrodes

Author:
Chenglong Shi; Junlong Sun; Youyong Pang; YongPing Liu; Bin Huang; Bo-Tian Liu
Source:
Journal of colloid and interface science 2022 v.607 pp. 462-469
ISSN:
0021-9797
Subject:
carbon nanotubes; electrochemical capacitors; electrodes; electrolytes; electronics; energy density; potassium
Abstract:
... Hybrid supercapacitors (HSCs) with the characteristics of high energy density, long cycle life and without altering their power density need to be developed urgently. Herein, a novel dual-ion hybrid supercapacitors (DHSCs) with Ni(OH)₂ nanotube arrays (NTAs) as positive electrode and V₂O₅ directly grown on freestanding carbon nanotubes (CNTs) as negative electrode is assembled. In charging mechani ...
DOI:
10.1016/j.jcis.2021.09.011

63. A new rapid synthesis of hexagonal prism Zn-MOF as a precursor at room temperature for energy storage through pre-ionization strategy

Author:
Nana Liu; Xiaoguang Liu; Junqing Pan
Source:
Journal of colloid and interface science 2022 v.606 pp. 1364-1373
ISSN:
0021-9797
Subject:
ambient temperature; capacitance; carbon; electrochemical capacitors; electrodes; energy; energy density; surface area
Abstract:
... In this paper, a new hexagonal prismatic Zn-MOF is rapidly synthesized at room temperature through a one-step precipitation method as precursor for the preparation of porous carbon. The SEM and GCD tests indicate that the pre-ionization process of BTC greatly accelerates the reaction speed between BTC and Zn ions, and only 0.5 h is required for the preparation of Zn-MOF with orderly morphology at ...
DOI:
10.1016/j.jcis.2021.08.105

64. A non-destructive detection method for evaluating beef taste quality based on electrochemical PVC membrane sensor

Author:
Xiaodan Wang; Feng Hu; Jiahui Jin; Yue Huang; Xianming Zhu; Yanli Dong; Cuilian Wang; Duo Wu
Source:
Lebensmittel-Wissenschaft + Technologie 2022 v.154 pp. 112666
ISSN:
0023-6438
Subject:
beef; cohesion; dibutyl phthalate; electrochemistry; electrodes; phosphates; poly(vinyl chloride); sensory evaluation; stearic acid; storage time; taste; texture; thermoplastics; viscosity
Abstract:
... A polyvinyl chloride (PVC) membrane sensor was developed to accurately detect beef taste quality grades. The beef taste was identified by the Fisher discriminant and verified by sensory evaluation. The PVC membrane sensor with the maximum open circuit potential (OCP) value and excellent performance was composed of 0.4 mL of dibutyl phthalate (DBP), 0.25 mL of lauryl ether phosphate, 3.6 mg of magn ...
DOI:
10.1016/j.lwt.2021.112666

65. A novel artificial peroxisome candidate based on nanozyme with excellent catalytic performance for biosensing

Author:
Tingting Zhang; Yu Liu; Jiuchan Pi; Nannan Lu; Renshuai Zhang; Wujun Chen; Zhiquan Zhang; Dongming Xing
Source:
Biosensors & bioelectronics 2022 v.196 pp. 113686
ISSN:
0956-5663
Subject:
biosensors; catalase; catalytic activity; detection limit; disease diagnosis; electrochemistry; electrodes; glutathione; graphene oxide; nanocatalysts; organelles; peroxidase; synergism; therapeutics
Abstract:
... Artificial peroxisome is of critical importance to supersede natural peroxisome in fabricating protocell system and disease treatment. Nevertheless, developing feasible artificial peroxisome with various stable functions remains a monumental challenge. Nanozyme with multiple enzyme-like activities can mimic natural enzymes in peroxisome, which make it a prospective candidate for artificial peroxis ...
DOI:
10.1016/j.bios.2021.113686

66. A novel bifunctional catalyst for overall water electrolysis: nano IrₓMn₍₁₋ₓ₎Oy hybrids with L1₂-IrMn₃ phase

Author:
Zhandong Ren; Yanyan Wang; Hucheng Jiang; Hongwei Jiang; Miaojie Tian; Ye Liu; Juanjuan Han; Hua Fang; Yuchan Zhu
Source:
Chemical communications 2022 v.58 no.5 pp. 685-688
ISSN:
1364-548X
Subject:
catalysts; electrodes; electrolysis; iridium
Abstract:
... A nano IrₓMn₍₁₋ₓ₎Oy hybrid electrode with a L1₂-IrMn₃ phase was used as a bifunctional catalyst with ultra-low iridium loading for overall water electrolysis in an acid solution for the first time. The HER activity of the IrₓMn₍₁₋ₓ₎Oy hybrid electrode not only exceeded that of IrO₂, but also exceeded that of Pt/C. The OER activity of the IrₓMn₍₁₋ₓ₎Oy hybrid electrode also exceeded that of IrO₂. ...
DOI:
10.1039/d1cc06062g

67. A novel biochar electrode for efficient electroreduction of nitrate: Selective and regulation of halogen

Author:
Zhe Zhang; Wei Ma; Jinglu Hu; Gang Xin; Zhen Chen; Chunxiang Wan; Shuang Wang; Qi Zhang
Source:
Chemosphere 2022 v.288 pp. 132400
ISSN:
0045-6535
Subject:
biochar; electrodes; nitrate reduction; nitrates; nitrogen
Abstract:
... A novel biochar electrode Bio-Fe₃O₄/CF used for electroreduction of nitrate was prepared by the hydrothermal synthesis method. The results showed that the growth of spherical Fe₃O₄ on the surface of smooth biochar can significantly increase the nitrate reduction rate. Besides, the presence of Cl and Br in the solution could promote the conversion of NH₄⁺ to N₂, thereby regulating the element nitro ...
DOI:
10.1016/j.chemosphere.2021.132400

68. A novel cell-based electrochemical biosensor based on MnO2 catalysis for antioxidant activity evaluation of anthocyanins

Author:
Yongli Ye; Xinyu Sun; Yinzhi Zhang; Xiaomin Han; Xiulan Sun
Source:
Biosensors & bioelectronics 2022 v.202 pp. 113990
ISSN:
0956-5663
Subject:
anthocyanins; antioxidant activity; biosensors; catalytic activity; cell culture; detection limit; electrodes; equations; food quality; manganese dioxide; nanowires; oxidation; paraquat
Abstract:
... The rapid, efficient, and objective evaluation of active antioxidant components is of great significance for the basic research of natural products and food quality. In this work, a three-dimensional (3D) cell culture system-based electrochemical biosensor for H₂O₂ detection based on the relationship between the H₂O₂ extracellular level and the current signal response was developed, which could be ...
DOI:
10.1016/j.bios.2022.113990

69. A novel electrochemical aptasensor based on layer-by-layer assembly of DNA-Au@Ag conjugates for rapid detection of aflatoxin M1 in milk samples

Author:
Yuanyuan Hui; Haishuai Peng; Fuxin Zhang; Lei Zhang; Liu Yufang; Aiqing Zhao; Rong Jia; Bini Wang; Yuxuan Song
Source:
Journal of dairy science 2022 v.105 no.3 pp. 1966-1977
ISSN:
0022-0302
Subject:
DNA; aflatoxin M1; aptasensors; cows; dairy science; detection limit; electrochemistry; electrodes; ewe milk; food safety; goats; gold; human health; methylene blue; milk; rapid methods; transmission electron microscopes
Abstract:
... Aflatoxin M₁ (AFM₁) is a common toxin in dairy products that causes acute and chronic human health disorders. Thus, the development of a rapid and accurate AFM₁ detection method is of vital importance for food safety monitoring. This work was to develop a novel electrochemical aptasensor for sensitive and specific determination of AFM₁. The dendritic-like nanostructure was formed on the gold elect ...
DOI:
10.3168/jds.2021-20931

70. A novel electrochemical platform based on COF/La2O3/MWCNTS for simultaneous detection of dopamine and uric acid

Author:
Zhilan Pan; Hao Guo; Lei Sun; Bingqing Liu; Yuan Chen; Tingting Zhang; Mingyue Wang; Liping Peng; Wu Yang
Source:
Colloids and surfaces 2022 v.635 pp. 128083
ISSN:
0927-7757
Subject:
adsorption; carbon nanotubes; dopamine; electrochemistry; electrodes; lanthanum oxide; medicine; schiff bases; sensors (equipment); surface area; synergism; uric acid
Abstract:
... In this present paper, a novel electrochemical sensor based on a covalent organic framework (COF) and lanthanum oxide (La₂O₃) and multi-wall carbon nanotubes (MWCNTS) was prepared for sensitive and selective detection of dopamine (DA) and uric acid (UA). The sensor demonstrated excellent analytical performance for DA and UA owing to the synergistic effect among large surface area of COF, highly co ...
DOI:
10.1016/j.colsurfa.2021.128083

71. A novel electrochemical sensing platform based on the esterase extracted from kidney bean for high-sensitivity determination of organophosphorus pesticides

Author:
Han Tao; Feng Liu; Chun Ji; Yuangen Wu; Xiao Wang; Qili Shi
Source:
RSC advances 2022 v.12 no.9 pp. 5265-5274
ISSN:
2046-2069
Subject:
acetylcholinesterase; biosensors; cabbage; carbon nanotubes; carboxylation; detection limit; electrochemistry; electrodes; electron transfer; graphene; kidney beans; nanogold; oxidation; rice; trichlorfon
Abstract:
... Similar to acetylcholinesterase, the activity of plant-derived esterase can also be inhibited by organophosphorus pesticides. Therefore, an electrochemical sensing platform using kidney bean esterase as a new detection enzyme was proposed for the highly sensitive determination of organophosphorus pesticides. Purified kidney bean esterase was obtained by an efficient and economical aqueous two-phas ...
DOI:
10.1039/d1ra08129b

72. A novel electrochemical sensor for the detection of fipronil and its toxic metabolite fipronil sulfone using TiO2-polytriazine imide submicrostructured composite as an efficient electrocatalyst

Author:
Suzan El-Akaad; Roman Morozov; Mikhail Golovin; Oleg Bol'shakov; Sarah De Saeger; Natalia Beloglazova
Source:
Talanta 2022 v.238 pp. 123025
ISSN:
0039-9140
Subject:
carbon nitride; chemical species; composite materials; crystal structure; detection limit; electrochemistry; electrodes; fipronil; hot water treatment; metabolites; oxidation; pH; sensors (equipment); titanium dioxide; toxicity; voltammetry
Abstract:
... For the first time, a simple and sensitive electrochemical sensor based on a screen printed electrode (SPE) modified with titanium dioxide (TiO₂) and polytriazine imide submicrostructured composite (TiO₂-PTI) has been developed for the simultaneous detection of fipronil (FIP) and its toxic metabolite fipronil sulfone (FIP-S). The submicrostructured composite material based on TiO₂ and PTI was obta ...
DOI:
10.1016/j.talanta.2021.123025

73. A novel l-cysteine sensor using in-situ electropolymerization of l-cysteine: Potential to simple and selective detection

Author:
Wisarut Khamcharoen; Charles S. Henry; Weena Siangproh
Source:
Talanta 2022 v.237 pp. 122983
ISSN:
0039-9140
Subject:
breads; cakes; cysteine; detection limit; electrochemistry; electrodes; polymerization; wheat flour
Abstract:
... This work presents an all-in-one origami paper-based electrochemical platform for simple and inexpensive l-cysteine (Cys) detection using Cys as a monomer for modifying electrode surfaces. The proposed method combines the steps of electropolymerization and detection into a single device to offer a highly convenient method for the end-user. In comparison, the sensitivity toward Cys detection is a s ...
DOI:
10.1016/j.talanta.2021.122983

74. A novel self-cleaning electrochemical biosensor integrating copper porphyrin-derived metal-organic framework nanofilms, G-quadruplex, and DNA nanomotors for achieving cyclic detection of lead ions

Author:
Junping Ma; Wushuang Bai; Jianbin Zheng
Source:
Biosensors & bioelectronics 2022 v.197 pp. 113801
ISSN:
0956-5663
Subject:
DNA; biosensors; coordination polymers; detection limit; electrochemistry; electrodes; lead; nanosheets; peroxidase
Abstract:
... A self-cleaning electrochemical biosensor based on two-dimensional Cu-porphyrin (Cu-TCPP) metal-organic framework nanofilms, novel super G-quadruplex (G4), and DNA nanomotors was developed for the cyclic detection of Pb²⁺ ions. The Cu-TCPP framework with inherent peroxidase activity can create an ultra-thin nanofilm that functioned as a carrier to support the metastable G4 comprising four individu ...
DOI:
10.1016/j.bios.2021.113801

75. A novel solar-powered electrochemical mineralization system for persistent remediation of uranium-contaminated groundwater

Author:
Yu Zhang; Mi Li; Yilong Hua; Xiaoyan Wu; Xiaowen Zhang; Qi Fang; Tao Cai
Source:
Journal of environmental radioactivity 2022 v.250 pp. 106909
ISSN:
0265-931X
Subject:
biodegradation; coprecipitation; electrochemistry; electrodes; groundwater; iron; long term effects; magnetite; migratory behavior; mineralization; oxidation; pH; radioactivity; raw materials; remediation; seepage; uranium; water quality
Abstract:
... Reduction of the migratory ability of uranium via reduction, co-precipitation or immobilization is a widely used technology for remediation of uranium contaminated groundwater (UCG). However, the re-released uranium due to environmental alterations such as oxidation, acid dissolution, or microbial decomposition limits the long-term effect of UCG remediation. Here, we developed a novel solar-powere ...
DOI:
10.1016/j.jenvrad.2022.106909

76. A novel triazine-based covalent organic framework combined with AuNPs and reduced graphene oxide as an electrochemical sensing platform for the simultaneous detection of uric acid, dopamine and ascorbic acid

Author:
Mingyue Wang; Hao Guo; Ning Wu; Junye Zhang; Tinging Zhang; Bingqing Liu; Zhilan Pan; Liping Peng; Wu Yang
Source:
Colloids and surfaces 2022 v.634 pp. 127928
ISSN:
0927-7757
Subject:
ascorbic acid; catalytic activity; dopamine; electrochemistry; electrodes; graphene oxide; nanocomposites; nanogold; triazines; uric acid; urine
Abstract:
... In this work, a novel triazine-based covalent organic framework (TS-COF) was constructed by the condensation of 1, 3, 5-tris-(4-aminophenyl)triazine (TAPT) and squaric acid (SA) under solvothermal condition. By in situ growth of Au nanoparticles (AuNPs) on the surface of TS-COF, the AuNPs@TS-COF composite with enhanced electroactivity was prepared successfully. After introduction of reduced graphe ...
DOI:
10.1016/j.colsurfa.2021.127928

77. A phage virus-based electrochemical biosensor for highly sensitive detection of ovomucoid

Author:
Jae Hwan Shin; Tae Jung Park; Moon Seop Hyun; Jong Pil Park
Source:
Food chemistry 2022 v.378 pp. 132061
ISSN:
0308-8146
Subject:
bacteriophages; biosensors; chemical bonding; crosslinking; detection limit; dielectric spectroscopy; eggs; electrodes; food allergens; food chemistry; gold; ovomucin; peptides; voltammetry; white wines
Abstract:
... Whole peptide-displayed phage particles are promising alternatives to antibodies in sensor development; however, greater control and functionalization of these particles are required. In this study, we aimed to identify and create highly sensitive and selective phage-based electrochemical biosensors for detecting ovomucoid, a known food allergen. Phage display was performed using two different pha ...
DOI:
10.1016/j.foodchem.2022.132061

78. A physics-based 1-D PEMFC model for simulating two-phase water transport in the electrode and gas diffusion media

Author:
Md Azimur Rahman; Mrittunjoy Sarker; Felipe Mojica; Po-Ya Abel Chuang
Source:
Applied energy 2022 v.316 pp. 119101
ISSN:
0306-2619
Subject:
carbon fibers; catalysts; diagnostic techniques; electrodes; energy; fuel cells; liquids; models; oxygen; paper; porous media; water activity
Abstract:
... While significant progress in PEMFC research has been achieved in recent years, simulation of liquid water formation and transport accurately still remains a significant challenge. Under wet operating conditions, liquid water may condense in the channel, gas diffusion layer, or electrode, which introduces complicated transport phenomena. In this work, we present a physics-based, steady-state, 1-D, ...
DOI:
10.1016/j.apenergy.2022.119101

79. A portable ascorbic acid in sweat analysis system based on highly crystalline conductive nickel-based metal-organic framework (Ni-MOF)

Author:
Lichao Wang; Liuyang Pan; Xin Han; Minh Ngoc Ha; Kerui Li; Hao Yu; Qinghong Zhang; Yaogang Li; Chengyi Hou; Hongzhi Wang
Source:
Journal of colloid and interface science 2022 v.616 pp. 326-337
ISSN:
0021-9797
Subject:
ascorbic acid; catalytic activity; coordination polymers; crystal structure; detection limit; electrochemistry; electrodes; electron transfer; ligands; mobile telephones; nanorods; oxidation; surface area; sweat; synergism
Abstract:
... Conductive metal–organic frameworks can provide unique porous structures, large pore volumes, many catalytically active sites and high crystallinity, and so are becoming increasingly important and attractive as electrocatalytic materials. The present work synthesized nanorods of the conductive compound Ni₃(2,3,6,7,10,11-hexaiminotriphenylene)₂ (Ni₃(HITP)₂) with a high degree of crystallinity from ...
DOI:
10.1016/j.jcis.2022.02.058

80. A pretreatment-free electrical capacitance biosensor for exosome detection in undiluted serum

Author:
Myoungro Lee; Seong Jun Park; Gahyeon Kim; Chulhwan Park; Min-Ho Lee; Jae-Hyuk Ahn; Taek Lee
Source:
Biosensors & bioelectronics 2022 v.199 pp. 113872
ISSN:
0956-5663
Subject:
DNA; biomarkers; biosensors; blood serum; capacitance; detection limit; early diagnosis; electrodes; exosomes; humans; molybdenum disulfide; oligonucleotides
Abstract:
... The exosome is considered a useful biomarker for the early diagnosis of cancer. However, pretreatment of samples used in diagnosis is time-consuming. Herein, we fabricated a capacitance-based electrical biosensor that requires no pretreatment of the sample; it is composed of a DNA aptamer/molybdenum disulfide (MoS₂) heterolayer on an interdigitated micro-gap electrode (IDMGE)/printed circuit board ...
DOI:
10.1016/j.bios.2021.113872

81. A quasi-solid-state supercapacitor based on waste surgical masks with high flexibility and designable shape

Author:
Wusheng Zuo; Limin Zang; Qifan Liu; Jianhui Qiu; Mingyang Lan; Chao Yang
Source:
Colloids and surfaces 2022 v.634 pp. 128020
ISSN:
0927-7757
Subject:
active ingredients; capacitance; electrochemical capacitors; electrochemistry; electrodes; electrolytes; energy density; hydrogels; polymerization; pyrroles
Abstract:
... A quasi-solid-state flexible symmetric supercapacitor (QFSSC) based on waste surgical masks (WSMs) with high electrochemical performance and high flexibility has been designed. The WSMs with three-layer construction have been fully utilized to fabricate the QFSSC. The two outer layers are served as the flexible substrate to achieve flexible electrodes by loading polypyrrole (PPy) microcones via el ...
DOI:
10.1016/j.colsurfa.2021.128020

82. A reusable and sensitive electrochemical sensor for determination of idarubicin in environmental and biological samples based on NiFe2O4 nanospheres anchored N-doped graphene quantum dots composite; an electrochemical and molecular docking investigation

Author:
Mohammad Mehmandoust; Pouran Pourhakkak; Gizem Tiris; Hassan Karimi-Maleh; Nevin Erk
Source:
Environmental research 2022 v.212 pp. 113264
ISSN:
0013-9351
Subject:
Fourier transform infrared spectroscopy; Raman spectroscopy; X-ray diffraction; detection limit; diagnostic techniques; dielectric spectroscopy; electrochemistry; electrodes; energy-dispersive X-ray analysis; graphene; high performance liquid chromatography; humans; idarubicin; nanocomposites; nanospheres; pH; point-of-care systems; research; sensors (equipment); urine; voltammetry
Abstract:
... An ultrasensitive and selective voltammetric sensor with ultra-trace level detection limit is introduced for idarubicin (IDA) determination in real samples. The as-synthesized nanocomposite was characterized by several techniques, including Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Raman spectroscopy, Energy-dispersive X-ray spectroscopy (EDX), and Field emission sc ...
DOI:
10.1016/j.envres.2022.113264

83. A review of sodium chloride-based electrolytes and materials for electrochemical energy technology

Author:
Wutao Wei; Jiaqiang Xu; Weihua Chen; Liwei Mi; Jiujun Zhang
Source:
Journal of materials chemistry A 2022 v.10 no.6 pp. 2637-2671
ISSN:
2050-7496
Subject:
batteries; desalination; electrochemical capacitors; electrochemistry; electrodes; electrolysis; energy; gels; humans; hydrogen; hydrogen production; industrialization; microstructure; sodium; sodium chloride; thermodynamics
Abstract:
... Sodium chloride (NaCl), as one of the most naturally abundant compounds, plays an irreplaceable role in industrial development and human life. In recent years, NaCl has received significant attention in the field of electrochemical energy due to its unique physicochemical properties, environmental friendliness and low cost. This paper reviews the recent progress in the utilization of NaCl in elect ...
DOI:
10.1039/d1ta09371a

84. A review of textile-based electrodes developed for electrostimulation

Author:
Luisa Euler; Li Guo; Nils-Krister Persson
Source:
Textile research journal 2022 v.92 no.7-8 pp. 1300-1320
ISSN:
1746-7748
Subject:
compliance; electrical treatment; electrodes; fabrics; hydrogels; muscle strength; muscles; nerve tissue; pain; research; skin irritation
Abstract:
... Electrical stimulation can be used for the treatment of various nerve and muscle injuries as well as acute and chronic pain conditions. An electrical pulse is applied to a muscle or nerve to activate excitable tissue using internal or external electrodes with the aim of building muscle strength, artificially creating or supporting limb movement or reducing pain. Textile electrodes offer several ad ...
DOI:
10.1177/00405175211051949

85. A review on bio-electro-Fenton systems as environmentally friendly methods for degradation of environmental organic pollutants in wastewater

Author:
Fatemeh Soltani; Nahid Navidjouy; Mostafa Rahimnejad
Source:
RSC advances 2022 v.12 no.9 pp. 5184-5213
ISSN:
2046-2069
Subject:
bioelectricity; clean energy; electrochemistry; electrodes; energy; hydrogen peroxide; pH; sludge; wastewater; wastewater treatment
Abstract:
... Bio-electro-Fenton (BEF) systems have been potentially studied as a promising technology to achieve environmental organic pollutants degradation and bioelectricity generation. The BEF systems are interesting and constantly expanding fields of science and technology. These emerging technologies, coupled with anodic microbial metabolisms and electrochemical Fenton's reactions, are considered suitabl ...
DOI:
10.1039/d1ra08825d

86. A review on optimizing potentials of high voltage pulse breakage technology based on electrical breakdown in water

Author:
Guanghui Yan; Huiwen Fu; Yuemin Zhao; Zongsheng Sun; Bo Zhang
Source:
Powder technology 2022 v.404 pp. 117293
ISSN:
0032-5910
Subject:
electric potential difference; electrodes; technology
Abstract:
... Breakage plays an important role in mineral processing, and consumes a large amount of energy. Recently, widespread attentions have been drawn into high voltage pulse breakage technology (HVPB), and good prospects in mineral processing have been reported. The existing study mainly focus on the pulse discharge parameters and ore characteristics, and the important part of HVPB - discharge in water i ...
DOI:
10.1016/j.powtec.2022.117293

87. A review on the landfill leachate treatment technologies and application prospects of three-dimensional electrode technology

Author:
Dayang Yu; Yuansheng Pei; Zehua Ji; Xudan He; Zhiliang Yao
Source:
Chemosphere 2022 v.291 pp. 132895
ISSN:
0045-6535
Subject:
electrodes; landfill leachates; municipal solid waste; oxidation; urbanization; waste disposal
Abstract:
... With the expansion of urbanisation, the total amount of solid waste produced by urban residents has been increasing, and the problem of municipal solid waste disposal has also been aggravated. Landfill leachate treatment technologies could be divided into three categories: biological, physical and advanced oxidation treatment technology. Among them, advanced oxidation treatment technology has a go ...
DOI:
10.1016/j.chemosphere.2021.132895

88. A screen printed methodology optimized by molecular dynamics simulation and Lean Six Sigma for the determination of xylometazoline in the presence of benzalkonium chloride in nasal drops

Author:
Elsayed Elgazzar; Khaled Attala; Shimaa Abdel-Atty; Ahmed M. Abdel-Raoof
Source:
Talanta 2022 v.242 pp. 123321
ISSN:
0039-9140
Subject:
benzalkonium chloride; detection limit; electrodes; manganese monoxide; molecular dynamics; nanocomposites; nose; topology; yttrium
Abstract:
... A new chemically disposable screen-printed modified electrode with yttrium doped manganese oxide (Mn2O3/Y2O3) nanocomposite at screen printed electrode was mainly constructed to quantify xylometazoline hydrochloride (XMZ). The crystallographic parameters were estimated from the XRD spectrum, suggesting that Mn₂O₃ of cubic phase with average grain size ∼ 77 nm. The SEM images revealed that Y³⁺ dopa ...
DOI:
10.1016/j.talanta.2022.123321

89. A sensitive and economical electrochemical platform for detection of food additive tert-butylhydroquinone based on porous Co3O4 nanorods embellished chemically oxidized carbon black

Author:
Deepak Balram; Kuang-Yow Lian; Neethu Sebastian; Fahad S. Al-Mubaddel; Muhammad Tayyab Noman
Source:
Food control 2022 v.136 pp. 108844
ISSN:
0956-7135
Subject:
Raman spectroscopy; acid treatment; antioxidants; cobalt oxide; coprecipitation; cost effectiveness; detection limit; electrochemistry; electrodes; food preservatives; food safety; hydroquinone; lakes; nanocomposites; nanorods; oxalic acid; oxidation; peanut oil; sensors (equipment); shelf life; soot; tallow
Abstract:
... Artificial food preservatives are widely utilized across the globe to prolong shelf life of food. In this paper, a highly sensitive and cost-effective electrochemical sensor for the nanomolar detection of synthetic antioxidant tert-butyl hydroquinone (TBHQ) commonly used as a food preservative is reported. A hybrid nanocomposite was sonochemically prepared by embedding surface functionalized carbo ...
DOI:
10.1016/j.foodcont.2022.108844

90. A sensitive cholesterol electrochemical biosensor based on biomimetic cerasome and graphene quantum dots

Author:
Shuyao Wu; Meijiao Jiang; Hui Mao; Nan Zhao; Dongqing He; Qinan Chen; Daliang Liu; Wei Zhang; Xi-Ming Song
Source:
Analytical and bioanalytical chemistry 2022 v.414 no.12 pp. 3593-3603
ISSN:
1618-2642
Subject:
Fourier transform infrared spectroscopy; analytical chemistry; bioactive properties; biocompatibility; biomimetics; biosensors; catalytic activity; ceramics; cholesterol; cholesterol oxidase; detection limit; electrochemistry; electrodes; electron transfer; enzyme kinetics; graphene; photoluminescence; transmission electron microscopy; zeta potential
Abstract:
... A simple and sensitive electrochemical cholesterol biosensor was fabricated based on ceramic-coated liposome (cerasome) and graphene quantum dots (GQDs) with good conductivity. The cerasome consists of a lipid-bilayer membrane and a ceramic surface as a soft biomimetic interface, and the mild layer-by-layer self-assembled method as the immobilization strategy on the surface of the modified electro ...
DOI:
10.1007/s00216-022-03986-9

91. A sensitive electrochemical immunosensing interface for label-free detection of aflatoxin B1 by attachment of nanobody to MWCNTs-COOH@black phosphorene

Author:
Xue Zhang; Xiaoning Liao; Yongfa Wu; Wanming Xiong; Juan Du; Zhui Tu; Wuying Yang; Dan Wang
Source:
Analytical and bioanalytical chemistry 2022 v.414 no.2 pp. 1129-1139
ISSN:
1618-2642
Subject:
aflatoxin B1; analytical chemistry; carbon nanotubes; catalytic activity; detection limit; electrochemistry; electrodes; electron transfer; ferricyanides; immunosensors; monoclonal antibodies; rapid methods; voltammetry
Abstract:
... A label-free electrochemical immunosensor has advantages of real-time and rapid detection, but it is weak in detection of small molecular toxins such as aflatoxin B₁ (AFB₁). The greatest obstacle to achieving this is that small molecules bound to a common immunosensing interface cannot interfere with electron transfer effectively and the detection signal is so weak. Therefore, a sensitive electroc ...
DOI:
10.1007/s00216-021-03738-1

92. A sensitive electrochemiluminescence biosensor for assay of cancer biomarker (MMP-2) based on NGQDs-Ru@SiO2 luminophore

Author:
Xuemei Fan; Shumin Wang; Hugang Liu; Zhejian Li; Qiangqiang Sun; Yimeng Wang; Xinhui Fan
Source:
Talanta 2022 v.236 pp. 122830
ISSN:
0039-9140
Subject:
acylation; biomarkers; biosensors; detection limit; electrochemiluminescence; electrodes; electrostatic interactions; gelatinase A; gold; graphene; nanocomposites; peptides; silica; sol-gel processing
Abstract:
... A sensitive biosensor that can be used for the determination of matrix metalloproteinase 2 (MMP-2) was proposed. The biosensor was developed by using an excellent self-enhanced nanocomposites as an illuminant and a peptide as a recognition element. For the electrostatic attraction between Ru(bpy)₃²⁺ and nitrogen-doped graphene quantum dots (NGQDs), the self-enhanced electrochemiluminescence (ECL) ...
DOI:
10.1016/j.talanta.2021.122830

93. A silver catalyst with a high-energy surface prepared by plasma spraying for the hydrogen evolution reaction

Author:
Yu-Yao Bai; Wen-Jing Kang; Cong Xi; Wen-Qi Yang; Zhe Li; Zi-Ang Ma; Cun-Ku Dong; Hui Liu; Jing Mao; Fu-Xing Ye; Xi-Wen Du
Source:
Chemical communications 2022 v.58 no.17 pp. 2878-2881
ISSN:
1364-548X
Subject:
adsorption; catalysts; catalytic activity; electrodes; foil; hydrogen; hydrogen production; silver
Abstract:
... A self-supported silver electrode was prepared by plasma spraying and used for catalysing the hydrogen evolution reaction. Thanks to the non-equilibrium synthetic conditions, the silver catalyst exposes high-energy (200) crystal planes, which enhance the adsorption of hydrogen and improve the intrinsic catalytic activity. As a result, the silver catalyst delivers an overpotential of 349 mV at 10 m ...
DOI:
10.1039/d1cc06892j

94. A simple and rapid approach for on-site analysis of nicotine in tobacco based on a screen-printed electrode as an electrochemical sensor

Author:
Yunfei Sha; Jie Yu; Junwei Xiong; Chaofan Yu; Xiaoyu Zhu; Bingqian Zhang; Ting Fei; Da Wu
Source:
Analytical methods 2022 v.14 no.16 pp. 1579-1584
ISSN:
1759-9679
Subject:
acetic acid; detection limit; electrodes; flame ionization; gold; nicotine; phosphates; sensors (equipment); tobacco
Abstract:
... In this study, we report a portable kit consisting of a portable workstation, gold screen-printed electrode (SPE), 0.45 μm filter membrane, phosphate buffer solution (PBS), and acetic acid (1%) for point-of-use (POU) analysis of nicotine in tobacco. The activated-screen-printed electrode (A-SPE) displayed superior electron transmission efficiency, and the A-SPE without modification was employed fo ...
DOI:
10.1039/d2ay00058j

95. A simple and reliable electroanalytical method employing a disposable commercial electrode for simultaneous determination of lead(II) and mercury(II) in beer

Author:
Luiz R.G. Silva; Yhan S. Mutz; Jéssica S. Stefano; Carlos A. Conte-Junior; Rafael de Q. Ferreira
Source:
Journal of food composition and analysis 2022 v.110 pp. 104564
ISSN:
0889-1575
Subject:
beers; bismuth; detection limit; electrodes; food composition; human health; lead; mercury; voltammetry
Abstract:
... Trace metals such as lead and mercury can be present in beverages by contamination during production and storage processes, or by the use of hops and brewing grains that may be contaminated with trace metals. Since these metals are harmful to human health, their presence is strictly controlled by regulatory agencies. In this aspect, the present work presents the development of a new procedure for ...
DOI:
10.1016/j.jfca.2022.104564

96. A simple electrochemical immunosensor based on a gold nanoparticle monolayer electrode for neutrophil gelatinase-associated lipocalin detection

Author:
Wei-Jhen Wang; Min-Chuan Chou; Ya-Jane Lee; Wei-Li Hsu; Gou-Jen Wang
Source:
Talanta 2022 v.246 pp. 123530
ISSN:
0039-9140
Subject:
detection limit; dielectric spectroscopy; electrochemistry; electrodes; films (materials); gold; immunosensors; kidneys; nanogold; neutrophils; nickel; polyethylene terephthalates; urine; veterinary clinics
Abstract:
... An electrochemical immunosensor for the accurate detection of cat neutrophil gelatinase-associated lipocalin (NGAL) in urine samples based on an electrode with a monolayer of gold nanoparticles (AuNPs) was proposed in this study. To fabricate the sensing electrode, a nickel mold with concave micron hemisphere array was prepared and then used to transfer the micron hemispherical structure onto a po ...
DOI:
10.1016/j.talanta.2022.123530

97. A simple electrochemical immunosensor for sensitive detection of transgenic soybean protein CP4-EPSPS in seeds

Author:
Marcos E. Farías; N. Mariano Correa; Lucas Sosa; Ana M. Niebylski; Patricia G. Molina
Source:
Talanta 2022 v.237 pp. 122910
ISSN:
0039-9140
Subject:
detection limit; electrochemistry; electrodes; glyphosate; glyphosate resistance; gold; immunosensors; polyclonal antibodies; soy protein; soybeans; Argentina
Abstract:
... Soybean is the most produced crop in Argentina, and 99 % corresponds to genetically modified soybean. One of the main produced varieties is Roundup Ready® soybean (RR), which was modified to express the enzyme CP4 5-enolpyruvylshikimate 3-phosphate synthase (CP4 EPSPS), which confers resistance to glyphosate, the main herbicide worldwide used. The possible impact of genetically modified organisms ...
DOI:
10.1016/j.talanta.2021.122910

98. A simple graphene modified electrode for the determination of antimony(III) in edible plants and beverage

Author:
Fabiana Liendo; Amaya Paz de la Vega; Maria Jesus Aguirre; Fernando Godoy; Angel A. Martí; Erick Flores; Jaime Pizarro; Rodrigo Segura
Source:
Food chemistry 2022 v.367 pp. 130676
ISSN:
0308-8146
Subject:
antimony; beverages; celery; detection limit; electrochemistry; electrodes; food chemistry; graphene; graphene oxide; lettuce; pH; sodium acetate; standard deviation; voltammetry
Abstract:
... Antimony(III) is a rare electroactive specie present on Earth, whose concentration is not typically determined. The presence of high concentrations of antimony is responsible for a variety of diseases, which makes it desirable to find convenient and reliable methods for its determination. We have developed a convenient glassy carbon modified electrode with electroreduced graphene oxide GC/rGO for ...
DOI:
10.1016/j.foodchem.2021.130676

99. A simple sensing platform based on a 1T@2H-MoS₂/cMWCNTs composite modified electrode for ultrasensitive detection of illegal Sudan I dye in food samples

Author:
Qiaoling Wu; Chun Ji; Lingli Zhang; Qili Shi; Yuangen Wu; Han Tao
Source:
Analytical methods 2022 v.14 no.5 pp. 549-559
ISSN:
1759-9679
Subject:
carbon nanotubes; carboxylation; detection limit; electrodes; electron microscopy; ketchup; nanocomposites; nanosheets; sensors (equipment); surface area; Sudan
Abstract:
... The work presented here describes a highly sensitive and simple electrochemical sensor for the detection of Sudan I dye based on a nanocomposite made of MoS₂ heterogeneous nanosheets (1T@2H-MoS₂) and carboxylated carbon nanotubes (cMWCNTs) (1T@2H-MoS₂/cMWCNTs). XPS results indicate that the content of 1T phase MoS₂ was estimated to be 72% in 1T@2H-MoS₂. Electron microscopy results show that the tu ...
DOI:
10.1039/d1ay01775f

100. A small-molecule-templated nanostructure back electrode for enhanced light absorption and photocurrent in perovskite quantum dot photovoltaics

Author:
Sanghun Han; Jigeon Kim; Dong Eon Kim; Min Jae Ko; Jongmin Choi; Se-Woong Baek; Younghoon Kim
Source:
Journal of materials chemistry A 2022 v.10 no.16 pp. 8966-8974
ISSN:
2050-7496
Subject:
absorption; electric current; electrodes; glass transition temperature; ligands; quantum dots; solar energy; solar radiation
Abstract:
... Advances in the surface ligand exchange process of all-inorganic CsPbI₃ perovskite colloidal quantum dots (PQDs) have enabled the fabrication of conductive PQD solids and their utilization as photovoltaic (PV) absorbers in next-generation solution-processed thin-film solar cells. However, PQD absorbers fabricated using the ligand exchange approach for application in high-efficiency PQD solar cells ...
DOI:
10.1039/d2ta00681b