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1. Construction of Ag2CO3/BiOBr/CdS ternary composite photocatalyst with improved visible-light photocatalytic activity on tetracycline molecule degradation

Author:
Kaliyappan Perumal; Shajahan Shanavas; Tansir Ahamad; Annamalai Karthigeyan; Padmanabhan Murugakoothan
Source:
Journal of environmental sciences (China) 2023 v.125 pp. 47-60
ISSN:
1001-0742
Subject:
absorption; electron paramagnetic resonance spectroscopy; irradiation; pH; photocatalysis; photocatalysts; photoluminescence; photolysis; pollution control; synergism; tetracycline; transmission electron microscopy; ultraviolet-visible spectroscopy; wastewater; China
Abstract:
... Photocatalytic degradation was considered as a best strategy for the removal of antibiotic drug pollutants from wastewater. The photocatalyst of ABC (Ag₂CO₃/BiOBr/CdS) composite synthesized by hydrothermal and precipitation method. The ABC composite used to investigate the degradation activity of tetracycline (TC) under visible light irradiation. The physicochemical characterization methods (e.g. ...
DOI:
10.1016/j.jes.2021.10.021

2. Efficient degradation of organic pollutants by S-NaTaO3/biochar under visible light and the photocatalytic performance of a permonosulfate-based dual-effect catalytic system

Author:
Yuehui Tai; Jinlong Sun; Haoran Tian; Fuyue Liu; Boyu Han; Wei Fu; Zhangpei Liu; Xiuye Yang; Qifeng Liu
Source:
Journal of environmental sciences (China) 2023 v.125 pp. 388-400
ISSN:
1001-0742
Subject:
absorption; acid orange 7; biochar; ciprofloxacin; energy efficiency; hot water treatment; irradiation; methyl orange; photocatalysis; photocatalysts; pollution; probability; rhodamines; solar energy; sulfur; tetracycline; China
Abstract:
... Removing large concentrations of organic pollutants from water efficiently and quickly under visible light is essential to developing photocatalytic technology and improving solar energy efficiency. This study used a simple hydrothermal method to prepare a non-metallic, S-doped NaTaO₃ (S-NTO) photocatalyst, which was then loaded onto biochar (BC) to form a S-NTO/BC composite photocatalyst. After u ...
DOI:
10.1016/j.jes.2022.01.028

3. Efficient removal of Cr(VI) by a 3D Z-scheme TiO2-ZnxCd1-xS graphene aerogel via synergy of adsorption and photocatalysis under visible light

Author:
Qianwei Liang; Xin Chen; Ruina Liu; Ke Xu; Hanjin Luo
Source:
Journal of environmental sciences (China) 2023 v.124 pp. 360-370
ISSN:
1001-0742
Subject:
adsorption; aerogels; graphene; graphene oxide; irradiation; light; photocatalysis; photocatalysts; synergism; virulence; wavelengths; China
Abstract:
... Efficient and robust photocatalysts for environmental pollutants removal with outstanding stability have great significance. Herein, we report a kind of three dimensional (3D) photocatalyst presented as Z-scheme heterojunction, which combining TiO₂ and ZnₓCd₁₋ₓS with graphene aerogel to contrast TiO₂-ZnₓCd₁₋ₓS graphene aerogel (TSGA, x=0.5) through a moderate hydrothermal process. The as-prepared ...
DOI:
10.1016/j.jes.2021.09.037

4. Ferroelectric polarization effect on the photocatalytic activity of Bi0.9Ca0.1FeO3/CdS S-scheme nanocomposites

Author:
Yaowen Zhang; Zifei Wang; Jiangwei Zhu; Xuemin He; Hongtao Xue; Sanlong Li; Weiwei Mao; Yong Pu; Xing'ao Li
Source:
Journal of environmental sciences (China) 2023 v.124 pp. 310-318
ISSN:
1001-0742
Subject:
absorption; irradiation; light; liquids; methyl orange; nanocomposites; nanowires; photocatalysis; photocatalysts; semiconductors; sol-gel processing; temperature; China
Abstract:
... BiFeO₃ (BFO), as a kind of narrow band-gap semiconductor material, has gradually emerged advantages in the application of photocatalysis. In this paper, Ca doped BFO nanoparticles Bi₀.₉Ca₀.₁FeO₃ (BCFO) were prepared by sol-gel method. And BCFO and CdS nanocomposites with two morphologies were obtained by controlling the time of loading CdS under a low temperature liquid phase process. It is found ...
DOI:
10.1016/j.jes.2021.09.021

5. Synergistic effects of structural, crystalline, and chemical defects on the photocatalytic performance of Y-doped ZnO for carbaryl degradation

Author:
Supphadate Sujinnapram; Sutthipoj Wongrerkdee
Source:
Journal of environmental sciences (China) 2023 v.124 pp. 667-677
ISSN:
1001-0742
Subject:
ambient pressure; carbaryl; irradiation; photocatalysis; solar radiation; surface area; yttrium; China
Abstract:
... In this study, a photocatalytic material consisting of ZnO and yttrium-doped ZnO (YZO) nanoparticles was obtained via a facile precipitation conducted under ambient pressure whereby crystalline ZnO was successfully doped with yttrium. YZO had a hexagonal wurtzite polycrystalline structure with smaller crystal and grain sizes than ZnO, which in turn meant larger specific surface area and pore volum ...
DOI:
10.1016/j.jes.2021.11.035

6. 0D/3D NiCo2O4/defected UiO-66 catalysts for enhanced degradation of tetracycline in peroxymonosulfate/simulated sunlight systems: Degradation mechanisms and pathways

Author:
Yuhan Wang; Chang Liu; Chao Wang; Qing Hu; Longzhen Ding
Source:
Chemosphere 2022 v.299 pp. 134322
ISSN:
0045-6535
Subject:
irradiation; lighting; photocatalysis; solar radiation; tetracycline; toxicity
Abstract:
... Developing synergistic systems and taking environmental risks into account are two necessary aspects of being considered to remove persistent organic pollutants efficiently. Thus, a combined catalytic system uniting the Fenton-like process and simulated solar-light photocatalysis has been constructed. Moreover, a series of NiCo₂O₄/HP-UiO-66 catalysts (yNiCo-DUx) were also fabricated to improve tet ...
DOI:
10.1016/j.chemosphere.2022.134322

7. 2D WO₃–ₓ Nanosheet with Rich Oxygen Vacancies for Efficient Visible-Light-Driven Photocatalytic Nitrogen Fixation

Author:
Zhixiong Yang; Jiquan Wang; Junting Wang; Meng Li; Qiang Cheng; Zhuangzhuang Wang; Xiaotian Wang; Jiaming Li; Yuan Li; Gaoke Zhang
Source:
Langmuir 2022 v.38 no.3 pp. 1178-1187
ISSN:
1520-5827
Subject:
ammonia; electric current; electron paramagnetic resonance spectroscopy; electron transfer; energy; irradiation; light; nanosheets; nitrogen fixation; oxygen; photocatalysis; photocatalysts
Abstract:
... Oxygen vacancy modulation holds great promise for enhancing the photocatalytic activity for efficient nitrogen fixation under mild conditions. In this work, the two-dimensional WO₃–ₓ nanosheets with rich oxygen vacancies were prepared using solvothermal synthesis. The WO₃–ₓ nanosheets (rich oxygen vacancies) display nice photocatalytic activity for N₂ reduction to ammonia with a high yield rate of ...
DOI:
10.1021/acs.langmuir.1c02862

8. 3D carbon aerogel from waste corrugated cardboard as a photothermal reservoir for solar steam generation

Author:
Hanxin Huo; Yuhui Ma; Yu Cheng; Junrui Cao
Source:
Environmental science and pollution research 2022 v.29 no.16 pp. 23936-23948
ISSN:
0944-1344
Subject:
Fourier transform infrared spectroscopy; aerogels; carbon; carbon dioxide; carbonization; cardboard; cold; energy; evaporation rate; furfural; heat; hydrophilicity; irradiation; nanopores; pollution; polymerization; pyrolysis; research; solvents; steam; surface area; surface temperature; thermogravimetry; wettability
Abstract:
... Three-dimensional carbon aerogel (CA800) was prepared from waste corrugated cardboard (WCC) by the procedure of slurrying, solvent replacement, drying, and carbonization in turn, and the product was explored as an all-in-one evaporator for solar steam generation without bulk water. Carbonization of the precursor was investigated using thermogravimetric analyzer coupled with Fourier transform infra ...
DOI:
10.1007/s11356-021-17659-0

9. 3D printing of cell-laden visible light curable glycol chitosan bioink for bone tissue engineering

Author:
Hyun Kyung Chang; Dae Hyeok Yang; Mi Yeon Ha; Hyun Joo Kim; Chun Ho Kim; Sae Hyun Kim; Jae Won Choi; Heung Jae Chun
Source:
Carbohydrate polymers 2022 v.287 pp. 119328
ISSN:
0144-8617
Subject:
adsorption; biocompatible materials; biopolymers; bone formation; bones; cell proliferation; cell viability; chitosan; hemolysis; irradiation; light; riboflavin; three-dimensional printing; water solubility
Abstract:
... Although chitosan is the second most abundant natural polymer on earth, with a wide range of biomaterial applications, its poor water solubility limits general printing process. We selected water-soluble methacrylated glycol chitosan (MeGC) as an alternative and prepared a MeGC-based MG-63 cell-laden bioink for 3D printing using a visible light curing system. Optimal cell-laden 3D printing of MeGC ...
DOI:
10.1016/j.carbpol.2022.119328

10. 4D printing induced by microwave and ultrasound for mushroom mixtures: Efficient conversion of ergosterol into vitamin D2

Author:
Jieling Chen; Min Zhang; Arun S. Mujumdar; Pattarapon Phuhongsunge
Source:
Food chemistry 2022 v.387 pp. 132840
ISSN:
0308-8146
Subject:
ergocalciferol; ergosterol; food chemistry; irradiation; least squares; mushrooms; neural networks; ultrasonic treatment; ultrasonics; ultraviolet radiation
Abstract:
... This study hoped to use microwave and ultrasound combined with 4D printing technology to promote the conversion of ergosterol into vitamin D₂ in printing model with mushroom scraps. Under the UV irradiation, the conversion was different in the printed model with different irradiation areas and different physical field pretreatment. Compared with raw materials, vitamin D2 concentrations in the prin ...
DOI:
10.1016/j.foodchem.2022.132840

11. A 3D C@TiO2 multishell nanoframe for simultaneous photothermal catalytic hydrogen generation and organic pollutant degradation

Author:
Yong Li; Huan Chang; Zhifei Wang; Qianqian Shen; Xuguang Liu; Jinbo Xue; Husheng Jia
Source:
Journal of colloid and interface science 2022 v.609 pp. 535-546
ISSN:
0021-9797
Subject:
carbon; energy; heat; hydrogen production; irradiation; lighting; photocatalysis; photocatalysts; pollutants; semiconductors; solar energy; wastewater
Abstract:
... Rapid heat loss and fast charge carrier recombination constitute two crucial issues that hinder the development of efficient solar energy utilization and conversion over the semiconductor in a photothermal catalytic system. Inspired by energy production from waste water, we designed an advanced 3D C@TiO₂ multishell nanoframe (MNF) photocatalyst. Its unique structural features of heat confinement a ...
DOI:
10.1016/j.jcis.2021.11.052

12. A Covalent Organic Framework/Graphene Dual-Region Hydrogel for Enhanced Solar-Driven Water Generation

Author:
Changxia Li; Sijia Cao; Jana Lutzki; Jin Yang; Thomas Konegger; Freddy Kleitz; Arne Thomas
Source:
Journal of the American Chemical Society 2022 v.144 no.7 pp. 3083-3090
ISSN:
1520-5126
Subject:
drinking water; energy; evaporation; graphene; hydrogels; hydrophilicity; hydrophobicity; irradiation; seawater; sewage; steam; volatilization; water content; water shortages; water treatment; wettability
Abstract:
... Solar-driven water generation is a sustainable water treatment technology, helping to relieve global water scarcity issues. However, this technology faces great challenges due to the high energy consumption of water evaporation yielding low evaporation rates. Here, a covalent organic framework (COF)/graphene dual-region hydrogel, containing hydrophilic and hydrophobic regions in one material, is d ...
DOI:
10.1021/jacs.1c11689

13. A DNA and mitochondria dual-targeted photosensitizer for two-photon-excited bioimaging and photodynamic therapy

Author:
Yuping Zhou; Weikang Xia; Chuang Liu; Sheng Ye; Lei Wang; Ruiyuan Liu
Source:
Biomaterials science 2022 v.10 no.7 pp. 1742-1751
ISSN:
2047-4849
Subject:
DNA; apoptosis; biocompatible materials; bioimaging; biosafety; blood; cancer therapy; fluorescence; fluorescent antibody technique; irradiation; mitochondria; neoplasm cells; neoplasms; photochemotherapy; photosensitizing agents; white light
Abstract:
... Biological substrates and organelle multi-targeted photosensitizers for ultra-efficient cancer treatment through photodynamic therapy (PDT) are highly desirable. Herein, a multiple pyridinium-anchored photosensitizer containing the triphenylamine unit, TPA-2PI, has been designed and utilized for DNA and mitochondria dual-targeted two-photon-excited bioimaging and PDT. TPA-2PI possesses an ultrahig ...
DOI:
10.1039/d1bm01969d

14. A New Concept of Radiation Detection Based on a Fluorochromic and Piezochromic Nanocluster

Author:
Huangjie Lu; Huiliang Hou; Yu-Chang Hou; Zhaofa Zheng; Yingying Ma; Zhengyang Zhou; Xiaofeng Guo; Qing-Jiang Pan; Yonggang Wang; Yuan Qian; Jian-Qiang Wang; Jian Lin
Source:
Journal of the American Chemical Society 2022 v.144 no.8 pp. 3449-3457
ISSN:
1520-5126
Subject:
cations; color; colorimetry; cost effectiveness; dosimetry; electronic equipment; irradiation; ligands; thorium
Abstract:
... Developing materials that possess colorimetric responses to external stimuli is a promising strategy for addressing the current challenges in radiation dosimetry. Currently, colorimetric ionizing-radiation-responsive materials remain underexplored, and those with multistimuli response are rare. Herein, the integration of thorium cation and photoresponsive terpyridine carboxylate ligand gives rise ...
DOI:
10.1021/jacs.1c11496

15. A Specific Mass-Tag Approach for Detection of Foodborne Pathogens Using MALDI-TOF Mass Spectrometry

Author:
Nan Li; Weifei Zhang; Jing Lin; Gaowa Xing; Haifang Li; Jin-Ming Lin
Source:
Analytical chemistry 2022 v.94 no.9 pp. 3963-3969
ISSN:
1520-6882
Subject:
analytical chemistry; detection limit; irradiation; matrix-assisted laser desorption-ionization mass spectrometry; microbial detection; milk; morbidity; mortality; nucleic acid hybridization; oligonucleotides
Abstract:
... Pathogen infections present a considerable threat to global health owing to the high morbidity and mortality, and usually multiple pathogens coexist in food and the environment. Consequently, it is in urgent need to develop some multiplexed and sensitive approaches for pathogen detection. Here, we presented a novel strategy using mass tag-mediated surface engineering for simultaneous detection of ...
DOI:
10.1021/acs.analchem.1c05069

16. A Triple Photoredox/Cobalt/Brønsted Acid Catalysis Enabling Markovnikov Hydroalkoxylation of Unactivated Alkenes

Author:
Masanari Nakagawa; Yuki Matsuki; Kazunori Nagao; Hirohisa Ohmiya
Source:
Journal of the American Chemical Society 2022 v.144 no.18 pp. 7953-7959
ISSN:
1520-5126
Subject:
alkenes; catalytic activity; cobalt; hydrides; hydrogen; irradiation; light; oxidation; photochemistry; protonation; reducing agents
Abstract:
... We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under visible light irradiation. The triple catalysis realizes three key elementary steps in a single catalytic cycle: (1) Co(III) hydride generation by photochemical reduction of Co(II) followed by protonation, (2) metal hydrid ...
DOI:
10.1021/jacs.2c00527

17. A Water-Stable Lanthanide-Based MOF as a Highly Sensitive Sensor for the Selective Detection of Paraquat in Agricultural Products

Author:
Theanchai Wiwasuku; Adulvit Chuaephon; Upeksha Habarakada; Jaursup Boonmak; Theerapong Puangmali; Filip Kielar; David J. Harding; Sujittra Youngme
Source:
ACS sustainable chemistry & engineering 2022 v.10 no.8 pp. 2761-2771
ISSN:
2168-0485
Subject:
absorption; agrochemicals; aqueous solutions; density functional theory; detection limit; electron transfer; energy; food contamination; green chemistry; human health; irradiation; ligands; luminescence; paraquat; rapid methods; toxicity
Abstract:
... The toxic agrochemical contamination of food and the environment is one of the most pressing concerns for human health and environmental sustainability. In this work, a water-stable 3D lanthanide-based MOF, [Tb₂(H₂btec)(btec)(H₂O)]·4H₂O (Tb-MOF) has been demonstrated as a turn-off luminescent sensor for the detection of poisonous paraquat. The ligand 1,2,4,5-benzenetetracarboxylic acid (H₄btec) wa ...
DOI:
10.1021/acssuschemeng.1c07966

18. A bioactive dextran-based hydrogel promote the healing of infected wounds via antibacterial and immunomodulatory

Author:
Lisheng Zhou; Liming Zhou; Chengxiu Wei; Rui Guo
Source:
Carbohydrate polymers 2022 pp. 119558
ISSN:
0144-8617
Subject:
angiogenesis; antibacterial properties; bacterial infections; cytokines; dextran; gelatin; hydrogels; inflammation; irradiation; macrophages; mice; nanosheets; phenotype; phosphorus; zinc; zinc oxide
Abstract:
... Bacterial infection will attack the wound and aggravate inflammation, which is the main reason for the difficulty in wound healing. Here, we reported a dextran-based hydrogel composed of methacrylated gelatin (GelMA) and oxidized dextran (oDex), which loaded with black phosphorus (BP) nanosheets and zinc oxide nanoparticles (ZnO NPs). The hydrogel exhibited synergistic antibacterial activity of ph ...
DOI:
10.1016/j.carbpol.2022.119558

19. A biocompatible bismuth based metal-organic framework as efficient light-sensitive drug carrier

Author:
Qingyan Zhang; Yuanyuan Liu; Zeyan Wang; Peng Wang; Zhaoke Zheng; Hefeng Cheng; Xiaoyan Qin; Xiaoyang Zhang; Ying Dai; Baibiao Huang
Source:
Journal of colloid and interface science 2022 v.617 pp. 578-584
ISSN:
0021-9797
Subject:
amoxicillin; bismuth; ciprofloxacin; coordination polymers; drug carriers; ellagic acid; hydrogen bonding; irradiation; lighting; norfloxacin; tetracycline; toxicity
Abstract:
... The low toxicity and good photo active property endow bismuth based metal–organic frameworks (MOFs) potential candidates for efficient light-sensitive drug carrier. In this work, SU-101, composed of Bi and ellagic acid (EA), is found to display high ciprofloxacin (CIP) loading ratio (85.8%) and controlled CIP release under light illumination (the maximum CIP release ratio is 95.56%). Further inves ...
DOI:
10.1016/j.jcis.2022.01.188

20. A bone implant with NIR-responsiveness for eliminating osteosarcoma cells and promoting osteogenic differentiation of BMSCs

Author:
Zhuangzhuang Wu; Qiaoqiao Tian; Jiani Wang; Yi Feng; Lizhi Li; Chaojian Xu; Jia Lv; Zhi Lv
Source:
Colloids and surfaces 2022 v.211 pp. 112296
ISSN:
0927-7765
Subject:
alloys; antineoplastic activity; bone formation; collagen; fever; fluorine; irradiation; osteosarcoma; photocatalysis; prostheses; reactive oxygen species; synergism; therapeutics; titanium dioxide
Abstract:
... Incomplete removal of tumor cells and insufficient osseointegration are the main causes of bone tumor recurrence and implantation failure. In the present study, a multifunctional titanium-based bioactive implant for near-infrared-triggered synergy therapy to overcome these hurdles is engineered, composed of titanium dioxide (TiO₂) nanoparticles doped with fluorine (F)/dopamine (PDA)/collagen. The ...
DOI:
10.1016/j.colsurfb.2021.112296

21. A comprehensive insight into a rapid degradation of sulfamethoxazole by peroxymonosulfate enhanced UV-A LED/g-C3N4 photocatalysis

Author:
Xiuwei Ao; Zifu Li; Hao Zhang
Source:
Journal of cleaner production 2022 v.356 pp. 131822
ISSN:
0959-6526
Subject:
aldehydes; antibiotics; antimicrobial properties; carbon nitride; graphene; hydroxylation; irradiation; organic matter; pH; photocatalysis; photoisomerization; sulfamethoxazole; toxicity
Abstract:
... In this study, a strategy combining graphitic carbon nitride (g-C₃N₄) and peroxymonosulfate (PMS) under UV-A LED irradiation was proposed to effectively degrade sulfamethoxazole (SMX), which is a frequently detected antibiotic. The presence of PMS doubled the SMX degradation efficiency by the PMS/UV-A LED/g-C₃N₄ system, which exhibited considerable reactivity for SMX removal. SMX degradation was e ...
DOI:
10.1016/j.jclepro.2022.131822

22. A cosubstantial [0D+2D] CTF membrane with enhanced perm-selectivity and solar cleaning for multiscale molecular separation

Author:
Guiliang Li; Yang Liu; Jiaping Chen; Shuting Xu; Na Lu; Haibo Lin; Fu Liu
Source:
Journal of membrane science 2022 v.654 pp. 120554
ISSN:
0376-7388
Subject:
dyes; irradiation; oils; photocatalysis; solar radiation; surfactants; triazines; wastewater
Abstract:
... Fouling is the pending issue of conspicuous two-dimensional membranes for complex wastewater treantment. Here, we first report a hybrid-dimensional cosubstantial [0D+2D] covalent triazine framework (CTF) membrane to sort out the membrane fouling via solar-cleaning strategy. The intersertal 0D CTF-0 in lamellar membrane as “pillar” offers interspacing pathways for selective separation of sub/microm ...
DOI:
10.1016/j.memsci.2022.120554

23. A critical review on ibuprofen removal from synthetic waters, natural waters, and real wastewaters by advanced oxidation processes

Author:
Enric Brillas
Source:
Chemosphere 2022 v.286 pp. 131849
ISSN:
0045-6535
Subject:
Crustacea; analgesics; carcinogenicity; chlorine; excretion; fish; fungi; hospitals; human health; hybrids; ibuprofen; iron; irradiation; oxidation; ozonation; photocatalysis; remediation; sewage sludge; ultrasonics; urine; wastewater
Abstract:
... Ibuprofen (IBP) is one ubiquitous drug prescribed as anti-inflammatory, analgesic, and antipyretic. It has been detected in effluents of wastewater plant treatments, sewage sludge, hospital wastewaters, surface waters, and drinking water due to its continuous release to the environment, mainly from the excretion in the urine of animals and humans. IBP is a carcinogenic and non-steroidal endocrine ...
DOI:
10.1016/j.chemosphere.2021.131849

24. A designed experiment for CdS-AgBr photocatalyst toward methylene blue

Author:
Seyyedeh Atefeh Mirsalari; Alireza Nezamzadeh-Ejhieh; Ahmad Reza Massah
Source:
Environmental science and pollution research 2022 v.29 no.22 pp. 33013-33032
ISSN:
0944-1344
Subject:
analysis of variance; confidence interval; experimental design; irradiation; methylene blue; models; nanocomposites; pH; photocatalysis; photocatalysts; pollution; research; response surface methodology
Abstract:
... A boosted photocatalytic activity was observed for the CdS-AgBr nanocomposite in the degradation of methylene blue (MB). The experimental design method based on the response surface methodology (RSM) approach used to study the simultaneous interaction effects between the influencing variables. Analysis of variance (ANOVA) of the results confirmed a significant model for processing the data because ...
DOI:
10.1007/s11356-021-17569-1

25. A direct Z-scheme polypyrrole/Bi2WO6 nanoparticles with boosted photogenerated charge separation for photocatalytic reduction of Cr(VI): Characteristics, performance, and mechanisms

Author:
Ningning Song; Shengyu Zhang; Shuang Zhong; Xiaosi Su; Chengyou Ma
Source:
Journal of cleaner production 2022 v.337 pp. 130577
ISSN:
0959-6526
Subject:
electric field; irradiation; light; pH; photocatalysis; pyrroles
Abstract:
... Creating specific photoinduced carriers transport pathways is an important means of improving the photocatalytic performance. Here, we report a simple modification strategy: in-situ deposition of polypyrrole (PPy) onto Bi₂WO₆ (BWO) surface. The close contact between the interface of BWO and PPy as well as the appropriate band structure made it form a bult-in electric field, thus driving the direct ...
DOI:
10.1016/j.jclepro.2022.130577

26. A dose optimization method of disinfection units and synergistic effects of combined disinfection in pilot tests

Author:
Fan-Qin Wei; Yun Lu; Qi Shi; Zhuo Chen; Kui-Xiao Li; Ting Zhang; Yu-Long Shi; Qi Xu; Hong-Ying Hu
Source:
Water research 2022 v.211 pp. 118037
ISSN:
0043-1354
Subject:
chlorine; coliform bacteria; disinfection; irradiation; ozonation; ozone; research; system optimization; wastewater treatment; water; water reuse
Abstract:
... The increasing requirement for reclaimed water has made it necessary to utilize multiple disinfection processes for efficient removal of organoleptic indicators, while guaranteeing microbial safety. However, there is not a proper way to appropriately distribute the operation load between different disinfection units. This study provides a new method to optimize doses of sequential ozonation, ultra ...
DOI:
10.1016/j.watres.2022.118037

27. A facile synthesis of Ag3PO4/BiPO4 p-n heterostructured composite as a highly efficient photocatalyst for fluoroquinolones degradation

Author:
Xin Zhu; Yu Yan; Yuting Wang; Tao Long; Jinzhong Wan; Cheng Sun; Yang Guo
Source:
Environmental research 2022 v.203 pp. 111843
ISSN:
0013-9351
Subject:
absorption; ciprofloxacin; irradiation; nanorods; norfloxacin; ofloxacin; photocatalysis; photocatalysts; remediation; research; solar radiation
Abstract:
... Ag₃PO₄/BiPO₄ heterojunction photocatalysts with an intergrowth structure composed of sphere-shaped Ag₃PO₄ and nanorod BiPO₄ were synthesized via a facile combination of solvothermal method and in-situ deposition process. They exhibit enhanced photocatalytic activities under sunlight irradiation, and the heterojunction composite with the 10 wt% loading amounts of Ag₃PO₄ presented the highest photoc ...
DOI:
10.1016/j.envres.2021.111843

28. A graphene-Ag based near-infrared defined accurate anti-scarring strategy for ocular glaucoma surgery

Author:
Yanan Wang; Zikang Xu; Wenchi Li; Wei Wei; Mengqi Qin; Qun Li; Xuexia Liu; Xu Zhang; Xiaolei Wang
Source:
Biomaterials science 2022 v.10 no.5 pp. 1281-1291
ISSN:
2047-4849
Subject:
biocompatibility; biocompatible materials; fibroblasts; fibrosis; filtration; glaucoma; irradiation; surgery
Abstract:
... Excessive fibrosis is the major factor in the failure of glaucoma filtration surgery. So far, the dominant approach for inhibiting fibrosis is the use of an antimetabolite drug, but the complications it causes, such as filtering bleb leakage, bacterial endophthalmitis and ocular hypotony, are also inevitable. Herein, a multifunctional anti-scarring platform (PVA@rGO-Ag/5-Fu) integrated with outsta ...
DOI:
10.1039/d1bm01614h

29. A high efficiency water hydrogen production method based on CdS/WN composite photocatalytic

Author:
Haowen Liu; Jie Chen; Wenyao Guo; Qunjie Xu; Yulin Min
Source:
Journal of colloid and interface science 2022 v.613 pp. 652-660
ISSN:
0021-9797
Subject:
absorption; cost effectiveness; electrical conductivity; hydrogen; hydrogen production; irradiation; light; metalloids; nanosheets; nitrides; photocatalysis; photocatalysts; photoreduction; semiconductors; sol-gel processing; tungsten
Abstract:
... Based on the strategy that electrocatalysts can be used as additives to improve the performance of photocatalysts, and the unique metalloid properties of tungsten nitride (WN), it can form a Schottky junction with the semiconductor at the heterogeneous interface to improve the photocatalytic performance of semiconductor catalysts. In this paper, WN with excellent electrical conductivity was select ...
DOI:
10.1016/j.jcis.2022.01.014

30. A high-performance microreactor integrated with chitosan/ Bi2WO6/CNT/TiO2 nanofibers for adsorptive/photocatalytic removal of cephalexin from aqueous solution

Author:
Fayazeh Rabanimehr; Mehrdad Farhadian; Ali Reza Solaimany Nazar
Source:
International journal of biological macromolecules 2022 v.208 pp. 260-274
ISSN:
0141-8130
Subject:
adsorption; aqueous solutions; cephalexin; chitosan; irradiation; light intensity; lighting; models; nanofibers; pH; photocatalysis; photocatalysts; response surface methodology; sorption isotherms; synergism
Abstract:
... A Z-scheme Bi₂WO₆/CNT/TiO₂ photocatalyst was synthesized hydrothermally and loaded on chitosan nanofibers with different mass percentages using the electrospinning process. The batch adsorption experiments for chitosan nanofibrous samples containing Bi₂WO₆/CNT/TiO₂ revealed that the adsorption process and its kinetic followed the Langmuir isotherm and pseudo-second-order model, respectively. A pla ...
DOI:
10.1016/j.ijbiomac.2022.03.108

31. A multi-color persistent luminescent phosphor β-NaYF₄:RE³⁺ (RE = Sm, Tb, Dy, Pr) for dynamic anti-counterfeiting

Author:
Bohan Wang; Zhihao Wang; Peng Mao; Yu Wang
Source:
RSC advances 2022 v.12 no.18 pp. 11534-11542
ISSN:
2046-2069
Subject:
X-radiation; irradiation; luminescence
Abstract:
... Conventional luminescent materials generally exhibit uni-color and transient emission under UV excitation, which makes them mediocre in the field of anti-counterfeiting. The high-level anti-counterfeiting techniques are always becoming more complicated and in need of multi-color and persistent luminescent materials. Herein, we report a series of β-NaYF₄:RE³⁺ (RE = Sm, Tb, Dy, Pr) persistent lumine ...
DOI:
10.1039/d2ra01425d

32. A multifunctional carbon dot-based nanoplatform for bioimaging and quaternary ammonium salt/photothermal synergistic antibacterial therapy

Author:
Xiaohong Chu; Pan Zhang; Yihan Liu; Baohong Sun; Xinrong Huang; Ninglin Zhou; Jian Shen; Na Meng
Source:
Journal of materials chemistry B 2022 v.10 no.15 pp. 2865-2874
ISSN:
2050-7518
Subject:
Escherichia coli; Staphylococcus aureus; ammonium salts; antibiotics; biocompatibility; bioimaging; death; drug resistance; fever; fluorescent dyes; irradiation; luminescence; nanocomposites; public health; quaternary ammonium compounds; therapeutics
Abstract:
... The emergence of drug resistance and superbugs poses a devastating threat to public health and can even lead to death. Thus, it is significant to develop a novel antibacterial agent to combat bacterial infections. Herein, we developed quaternary ammonium salt (QAS) modified near-infrared carbon dots (RCDs-C₃₅), which possesses synergistic antibacterial performance under 808 nm irradiation. This na ...
DOI:
10.1039/d1tb02717d

33. A mutually beneficial macrophages-mediated delivery system realizing photo/immune therapy

Author:
Xiudan Wang; Junya Lu; Yuling Mao; Qinfu Zhao; Caishun Chen; Jianan Han; Meiqi Han; Huijuan Yuan; Siling Wang
Source:
Journal of controlled release 2022 v.347 pp. 14-26
ISSN:
0168-3659
Subject:
cancer therapy; carbon; drugs; heat; immunotherapy; interleukin-12; irradiation; macrophages; nanomedicine; neoplasms; photochemotherapy; photothermotherapy; porous media; singlet oxygen; temperature
Abstract:
... The accumulation of nanomedicines in tumor tissues determines their therapeutic efficacy. We herein exploit the tropism of macrophages to improve the accumulation and retention time of nanomedicine at tumors. Interestingly, macrophages are not merely as transporters, but killers activated by nanomedicine. The system(M@C-HA/ICG) was established by decorating macrophages with hyaluronic acid-modifie ...
DOI:
10.1016/j.jconrel.2022.04.038

34. A nanohybrid of Prussian blue supported by boracic acid-modified g-C3N4 for Raman recognition of cell surface sialic acid and photothermal/photodynamic therapy

Author:
Ya-Ning Wang; Wen-Shu Zhang; Xiao-Peng Liu; Yun-Yun Wei; Zhang-Run Xu
Source:
Colloids and surfaces 2022 v.215 pp. 112490
ISSN:
0927-7765
Subject:
absorbance; carbon nitride; electron transfer; energy transfer; graphene; irradiation; nanohybrids; neoplasms; photochemotherapy; sialic acid
Abstract:
... Theranostic nanoplatforms with accurate diagnosis and effective therapy show a bright prospect for tumor treatments. Herein, a novel boracic acid-modified graphite carbon nitride and Prussian blue nanohybrid (PB@B-g-C₃N₄) was developed, which provides sialic acid-targeted Raman recognition and synergistic photothermal/photodynamic therapy in the near-infrared region. Owing to the specific interact ...
DOI:
10.1016/j.colsurfb.2022.112490

35. A near-infrared light-driven photoelectrochemical aptasensing platform for adenosine triphosphate detection based on Yb-doped Bi₂S₃ nanorods

Author:
Jie Gao; Yifan Ding; Kai Yan; Jingdong Zhang
Source:
Journal of materials chemistry B 2022 v.10 no.18 pp. 3524-3530
ISSN:
2050-7518
Subject:
aptasensors; blood serum; detection limit; electric current; electrodes; electron transfer; humans; irradiation; nanorods; oligonucleotides; photostability
Abstract:
... Due to its capability of low spectral interference, high light stability, and minimal photodamage to biological species, near-infrared (NIR) light is advantageous in biosensing and biochemical analysis. This work developed a photoelectrochemical (PEC) aptasensor for adenosine triphosphate (ATP) detection using NIR light as the irradiation source. In order to utilize NIR light, we prepared Yb-doped ...
DOI:
10.1039/d2tb00180b

36. A novel Sm doped Cr2O3 sesquioxide-decorated MWCNTs heterostructured Fenton-like with sonophotocatalytic activities under visible light irradiation

Author:
Gh. Eshaq; Amer M; Moonis Ali Khan; Zeid A. Alothman; Mika Sillanpää
Source:
Journal of hazardous materials 2022 v.426 pp. 127812
ISSN:
0304-3894
Subject:
absorbance; dissociation; durability; electron paramagnetic resonance spectroscopy; hot water treatment; irradiation; light; mineralization; nanocomposites; pH; photocatalysis; photocatalysts; reaction mechanisms; sonocatalysis; synergism; ultrasonic treatment
Abstract:
... Novel Sm doped Cr₂O₃ decorated MWCNTs nanocomposite photocatalyst was successfully prepared by a facile hydrothermal method for metoprolol (MET) degradation. A heterogeneous photo -Fenton like system was formed with the addition of H₂O₂ for ultrasonic irradiation (US), visible light irradiation (Vis) and dual irradiation (US/Vis) systems. The intrinsic characteristics of Sm doped Cr₂O₃ decorated M ...
DOI:
10.1016/j.jhazmat.2021.127812

37. A novel Y-shaped photoiniferter used for the construction of polydimethylsiloxane surfaces with antibacterial and antifouling properties

Author:
Wei Sun; Jingrui Liu; Qing Hao; Kunyan Lu; Zhaoqiang Wu; Hong Chen
Source:
Journal of materials chemistry B 2022 v.10 no.2 pp. 262-270
ISSN:
2050-7518
Subject:
Escherichia coli; bacteria; cytotoxicity; ionic liquids; irradiation; light; polydimethylsiloxane; polyhydroxyethyl methacrylates; polymerization; sulfur
Abstract:
... The simultaneous introduction of two new functionalities into the same polymeric substrate under mild reaction conditions is an interesting and important topic. Herein, dual-functional polydimethylsiloxane (PDMS) surfaces with antibacterial and antifouling properties were conveniently developed via a novel Y-shaped asymmetric dual-functional photoiniferter (Y-iniferter). The Y-iniferter was initia ...
DOI:
10.1039/d1tb01968f

38. A novel fluorescence internal filtration immunoassay for the detection of clenbuterol

Author:
Fei Peng; Beibei Li; Shijiao Sun; Fang Mi; Ying Wang; Cunming Hu; Pengfei Geng; Lin Pang; Jiutong Li; Ming Guan
Source:
European food research & technology 2022 v.248 no.2 pp. 415-426
ISSN:
1438-2377
Subject:
agonists; antibodies; antigens; bronchodilators; centrifugation; clenbuterol; detection limit; filtration; fluorescence; food research; human health; immunization; irradiation; lean meat; livestock; magnetism; rhodamines
Abstract:
... Clenbuterol is a β-adrenergic receptor agonist that can be used as a bronchodilator for the treatment of respiratory diseases or as an additive feed in livestock to improve conversion rate of lean meat. However, the residue of clenbuterol in food can be a threat to human health. Therefore, it is important to monitor clenbuterol in foods. In this paper, a fluorescence inner filtration immunoassay ( ...
DOI:
10.1007/s00217-021-03886-9

39. A novel method of co-doping TiO2 with carbon and boron for enhancing photocatalytic degradation of 4-nitrophenol

Author:
M. Azizi; T. Ebadi; F. Qaderi
Source:
International journal of environmental science and technology 2022 v.19 no.4 pp. 2619-2634
ISSN:
1735-1472
Subject:
boron; carbon; irradiation; nanocatalysts; p-nitrophenol; pH; photocatalysis; photocatalysts; pollutants; porosity; response surface methodology; surface area; titanium dioxide
Abstract:
... The carbon/boron co-doped TiO₂ (CBCT) photocatalyst was produced through the gel-hydrothermal process in this study. Its properties were then analyzed by using XRD, FE-SEM, EDX, FTIR, BET and Raman techniques, according to which the CBCT had the dominant anatase phase, whereas its specific surface area (46.1 m²/g) and porosity (0.101) made it a suitable photocatalyst. The response surface methodol ...
DOI:
10.1007/s13762-021-03386-z

40. A polydopamine-based photodynamic coating on the intraocular lens surface for safer posterior capsule opacification conquering

Author:
Jiqiao Qie; Shimin Wen; Yuemei Han; Sihao Liu; Liangliang Shen; Hao Chen; Quankui Lin
Source:
Biomaterials science 2022 v.10 no.9 pp. 2188-2197
ISSN:
2047-4849
Subject:
adhesion; apoptosis; biocompatibility; biocompatible materials; cataract; dopamine; drugs; epithelium; humans; irradiation; photochemotherapy; reactive oxygen species; refractive index; transmittance
Abstract:
... Intraocular lens (IOL) is the indispensable implant for cataract surgery. However, posterior capsular opacification (PCO) happens in high incidence after IOL implantation. PCO is caused by adhesion, proliferation, and trans-differentiation of the residual human lens epithelial cells (HLECs). Despite the great achievements in surface coating and antiproliferative drug loading on the intraocular len ...
DOI:
10.1039/d2bm00038e

41. A prominent dual heterojunction framed CuWO4/Bi2WO6/MnS ternary NCs for para-chlorophenol degradation, Cr(VI) reduction & toxicity studies

Author:
V. Subhiksha; Mohammad K. Okla; Ibrahim A. Alaraidh; Asmaa Mohebaldin; Walid Soufan; Mostafa A. Abdel-Maksoud; Ramadan F. Abdelaziz; Ajith M. Thomas; Lija L. Raju; S. Sudheer Khan
Source:
Chemosphere 2022 pp. 134802
ISSN:
0045-6535
Subject:
4-chlorophenol; Allium cepa; Escherichia coli; adsorption; chromium; computer software; coprecipitation; cytotoxicity; desorption; ecotoxicology; environmental impact; genotoxicity; irradiation; light; mineralization; nanocomposites; pH; photocatalysis; photocatalysts; photolysis; remediation
Abstract:
... In account of environmental remediation, an ideal photocatalyst was fabricated for the effective treatment of water systems. Herein, dual heterojunctions framed CuWO₄/Bi₂WO₆/MnS nanocomposite (NCs) was synthesised via simple co-precipitation method followed by ultra-sonicated-assisted route. The prepared NCs were investigated its photocatalytic degradation performance using para-chlorophenol (4-CP ...
DOI:
10.1016/j.chemosphere.2022.134802

42. A reusable visible driven N and C–N doped TiO₂ magnetic nanocomposites for photodegradation of direct red 16 azo dye in water and wastewater

Author:
Hadis Zangeneh; Mehrdad Farhadian; Ali Akbar Zinatizadeh
Source:
Environmental technology 2022 v.43 no.9 pp. 1269-1284
ISSN:
1479-487X
Subject:
asparagine; azo dyes; energy; environmental technology; irradiation; magnetism; nanocomposites; pH; photocatalysis; photocatalysts; photolysis; urea; wastewater
Abstract:
... The visible active N-doped TiO₂/ZnFe₂O₄ (urea–TiO₂/ZnFe₂O₄) and CN-codoped TiO₂/ZnFe₂O₄ (L-asparagine–TiO₂/ZnFe₂O₄) nanocomposites were successfully synthesized by the sol–gel–hydrothermal method for direct red 16 (DR16) photodegradation. Their properties of the prepared nanocomposites were analysed using XRD, FT-IR, FE-SEM, EDX, DRS and PL tests. The DRS and PL results confirmed a narrow band-gap ...
DOI:
10.1080/09593330.2020.1825530

43. A review of advances in multifunctional XTiO3 perovskite-type oxides as piezo-photocatalysts for environmental remediation and energy production

Author:
Ridha Djellabi; Marcela Frias Ordonez; Francesco Conte; Ermelinda Falletta; Claudia L. Bianchi; Ilenia Rossetti
Source:
Journal of hazardous materials 2022 v.421 pp. 126792
ISSN:
0304-3894
Subject:
crystallites; energy conversion; heat; irradiation; oxygen; photocatalysis; photocatalysts; remediation; ultrasonics; vibration
Abstract:
... Over more than three decades, the field of engineering of photocatalytic materials with unique properties and enhanced performance has received a huge attention. In this regard, different classes of materials were fabricated and used for different photocatalytic applications. Among these materials, recently multifunctional XTiO₃ perovskites have drawn outstanding interest towards environmental rem ...
DOI:
10.1016/j.jhazmat.2021.126792

44. A review of bacterial biofilm control by physical strategies

Author:
Dan Liu; Quanfeng Huang; Weiming Gu; Xin-An Zeng
Source:
Critical reviews in food science and nutrition 2022 v.62 no.13 pp. 3453-3470
ISSN:
1549-7852
Subject:
biofilm; equipment; extracellular matrix; food science; hygiene; irradiation; magnetic fields; nutrition; spoilage; ultrasonics
Abstract:
... Biofilms are multicellular communities of microorganisms held together by a self-produced extracellular matrix, which contribute to hygiene problems in the food and medical fields. Both spoilage and pathogenic bacteria that grow in the complex structure of biofilm are more resistant to harsh environmental conditions and conventional antimicrobial agents. Therefore, it is important to develop eco-f ...
DOI:
10.1080/10408398.2020.1865872

45. A review of methods to reduce the probability of the airborne spread of COVID-19 in ventilation systems and enclosed spaces

Author:
Gentry Berry; Adam Parsons; Matthew Morgan; Jaime Rickert; Heejin Cho
Source:
Environmental research 2022 v.203 pp. 111765
ISSN:
0013-9351
Subject:
COVID-19 infection; air; airborne transmission; environmental factors; filtration; heat inactivation; human population; ionization; irradiation; markets; probability; reactive oxygen species; research and development; viruses
Abstract:
... COVID-19 forced the human population to rethink its way of living. The threat posed by the potential spread of the virus via an airborne transmission mode through ventilation systems in buildings and enclosed spaces has been recognized as a major concern. To mitigate this threat, researchers have explored different technologies and methods that can remove or decrease the concentration of the virus ...
DOI:
10.1016/j.envres.2021.111765

46. A self-coated hollow mesoporous silica nanoparticle for tumor targeting and chemo-photothermal therapy

Author:
Qingni Xu; Cong Chang; Xuelian Wang; Chaohua Li; Yuqi Chen; Yueli Zhang; Mengqi Yin; Yuyang Li; Bei Xiong; Bo Lu
Source:
Journal of materials science 2022 v.57 no.10 pp. 6013-6025
ISSN:
0022-2461
Subject:
cancer therapy; carcinoma; doxorubicin; drug delivery systems; humans; hyaluronic acid; irradiation; liver; pH; photochemotherapy; photothermotherapy; porous media; silica
Abstract:
... Chemotherapy combined with photothermal therapy, a promising strategy for cancer treatment, has a high potential to control drug release and improve therapeutic efficacy. Inspired by this, a pH/NIR dual-responsive drug delivery system (DOX/HMSN@PDA-HA nanoparticles, simplified as DHPH NPs) based on hollow mesoporous silica nanoparticles (HMSNs) was designed for targeted therapy of tumor, by self-c ...
DOI:
10.1007/s10853-022-07020-2

47. A solar thermal driven ORC-VFR system employed in subtropical Mediterranean climatic building

Author:
Hooman Azad Gilani; Siamak Hoseinzadeh; Farbod Esmaeilion; Saim Memon; Davide Astiaso Garcia; Mamdouh El Haj Assad
Source:
Energy 2022 v.250 pp. 123819
ISSN:
0360-5442
Subject:
Cyprus; Mediterranean climate; capital; energy; energy use and consumption; heat; heat exchangers; irradiation; mass flow; power generation; temperature
Abstract:
... This paper investigates the configuration of solar thermal collector driven organic Rankine cycle (ORC) utilized to power air-conditioning system of the two-story office building in Paralimni, Cyprus, through a Variable-Refrigerant-Flow (VRF) system. The reason to choose this Mediterranean climate of Paralimni, Cyprus, is due to its higher dependency on fossil fuels compared to many other countrie ...
DOI:
10.1016/j.energy.2022.123819

48. A steric hindrance alleviation strategy to enhance the photo-switching efficiency of azobenzene functionalized metal–organic frameworks toward tailorable carbon dioxide capture

Author:
Qi Huang; Junju Mu; Zhen Zhan; Feng Wang; Shangbin Jin; Bien Tan; Chunfei Wu
Source:
Journal of materials chemistry A 2022 v.10 no.15 pp. 8303-8308
ISSN:
2050-7496
Subject:
adsorbents; benzene; carbon dioxide; cis-trans isomers; density functional theory; energy; energy costs; irradiation; isomerization; ultraviolet radiation
Abstract:
... Photo-switching metal–organic frameworks are widely reported for low energy CO₂ capture and release. However, owing to the steric hindrance caused by dense packing of MOF solids, the photo-switching efficiency was still severely restricted. Such an issue then further causes low CO₂ switching capacity and poor regeneration of MOF adsorbents. Herein, we present a strategy to tailor the photo-switchi ...
DOI:
10.1039/d1ta09270g

49. A sustainable valorization of industrial tomato seeds (cv Rio Grande): Sequential recovery of a valuable oil and optimized extraction of antioxidants by microwaves

Author:
Toufik Ouatmani; Hayate Haddadi‐Guemghar; Lila Boulekbache‐Makhlouf; Djamila Mehidi‐Terki; Azzedine Maouche; Khodir Madani
Source:
Journal of food processing and preservation 2022 v.46 no.1 pp. e16123
ISSN:
0145-8892
Subject:
antioxidant activity; biofuels; byproducts; fatty acid composition; feedstocks; gas chromatography; income; irradiation; microwave treatment; response surface methodology; seed oils; solid phase extraction; solvents; sustainable development; tomato paste; tomatoes; wastes
Abstract:
... Tomato seeds are a major waste of tomato paste manufacturing. In this study, an interesting yield of oil was obtained (21.69%) from the seeds of an industrial tomato byproduct (Rio Grande variety), after a Soxhlet extraction. The fatty acid profile of the extracted oil was established by gas chromatography and the tomato seed oil (TSO) was rich in unsaturated fatty acids (79.83%). After that, micr ...
DOI:
10.1111/jfpp.16123

50. A tandem process for the synthesis of β-aminoboronic acids from aziridines with haloamine intermediates

Author:
Subin Park; Jangwoo Koo; Weonjeong Kim; Hong Geun Lee
Source:
Chemical communications 2022 v.58 no.23 pp. 3767-3770
ISSN:
1364-548X
Subject:
aziridines; boron; irradiation
Abstract:
... An unprecedented synthetic strategy is devised to generate β-aminoboronic acids from aziridines via a sequential process involving 1,2-iodoamine formation and radical borylation under light irradiation. A variety of aziridines including multiply substituted aziridines have been successfully employed as synthetic precursors, expanding their synthetic utility compared to previous methods. Mechanisti ...
DOI:
10.1039/d2cc00808d