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... This work considered the utilisation of environmentally friendly biodegradable materials instead of conventional polymeric materials, in order to prevent further environmental endangerment by accumulation of non-biodegradable materials. Thermoplastic starch (TPS) is an exemplary environmentally friendly biodegradable material. Blending TPS with other biodegradable polymers such as biodegradable po ...
additives; air pollution; atomic absorption spectrometry; binding agents; bitumen; chemical reactions; chromium; contact angle; copper; durability; environmental impact; graphs; heavy metals; hydrophilicity; hydrophobicity; iron; leaching; lead; mixing; nickel; polymers; rain; temperature; thermogravimetry; toxicity; water pollution; water quality; water resources; zinc
Abstract:
... Naturally, asphalt binder has compacting and mixing temperatures higher than 150 °C. Both temperatures can be increased by modifying the pristine penetration grade asphalt binder with polymer. However, the warm-mix asphalt (WMA) technology contributes to lowering of these temperatures even though the possibility of environmental effect cannot be neglected. Air pollution and water contamination are ...
... The removal of water-soluble organics from aqueous feeds is required in numerous practical applications, including bioresource processing, fermentation, and wastewater treatment. To this end, direct contact membrane distillation (DCMD) has been proposed as a separation technology. DCMD utilizes hydrophobic membranes – typically, comprising perfluorocarbons – which, when placed between a warm feed ...
Fourier transform infrared spectroscopy; chlorides; contact angle; electrodes; energy; fouling; iron; mixing; pollutants; sludge; temperature; wastewater; water hardness; water reuse
Abstract:
... In the present work, advanced treatment of carwash wastewater with an integrated electrocoagulation–nanofiltration (EC–NF) process to reuse the treated wastewater as rinsing water was investigated. The wastewater was pretreated by EC process under various operating parameters such as temperature (25 °C, 35 °C, 45 °C), stirring speed (150 rpm, 250 rpm, 350 rpm), and electrode connection mode (MP-P, ...
... Biodegradable, non-toxic and transparent poly (l-lactic acid) (PLLA) biopolymer is modified in order to obtain an improved material with antibacterial properties for its use as active packaging of food. For this, PLLA films were endowed with the bactericidal effect of ZnO nanoparticles by internal blending and the bacteria contact-killing properties of the biopolymer chitosan (CHI) by superficial ...
... Starch was transformed to hydrophobic starch phthalate (contact angle 109°) in order to achieve a good dispersion in LDPE matrix. Nanosilica derived from rice husk after aminopropyltrimethoxysilane functionalization was also incorporated into the blend as property-enhancing filler. The produced crystalline starch phthalate had a lower particle size of 9.87 μm and a higher surface area of 2.87 m²/g ...
Candelario Palma-Bautista; Jose G. Vazquez-Garcia; Ilias Travlos; Alexandros Tataridas; Panagiotis Kanatas; José A. Domínguez-Valenzuela; Rafael De Prado
... Glyphosate retention, absorption and translocation with and without adjuvant were examined in Lolium rigidum and Conyza canadensis in greenhouse and laboratory settings to develop an understanding of the influence of the selected adjuvant on glyphosate activity. Tests on whole plants show that the dose of herbicide needed to reduce dry weight by 50% (GR50) or plant surviva ...
X-ray diffraction; chemical precipitation; contact angle; hydrophobicity; iron oxides; lipid content; lubrication; magnetic materials; magnetism; mixing; nanoparticles; oil spills; oils; oleic acid; scanning electron microscopy; surfactants; thermogravimetry; transmission electron microscopy; ultrasonics; vibration; wastewater; wastewater treatment
Abstract:
... Magnetorheological fluids (MRFs) have the excellent comprehensive properties and have widespread applications in lubrication, sealing, vibration reduction and wastewater treatment. When MRFs are used to recover oil from water, the Fe₃O₄ magnetic nanoparticles (MPs) in MRF are coated by a surfactant which has good hydrophobic and oleophilic properties. After the surfactant fully adsorbs the oil in ...
... In this research, fabricating and modifying of polyethersulfone (PES) nanofiltration membrane were reported by using deep eutectic solvents (DESs) as a novel modifier for the membranes. The applied DES was produced by mixing ethylene glycol (EG) and choline chloride (ChCl). It is commonly known as ethaline. Ethaline was exploited as a hydrophilic additive into casting solution to formulate a novel ...
... BACKGROUND: In this work, a series of graphene oxide–polyethersulfone (GO–PES) composite flat sheet (FS) and hollow fiber (HF) membranes were fabricated by blending 0.5 and 1.0 wt% of GO into the PES matrix and utilized for oil–water separation. GO was first prepared and characterized by using Fourier‐transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), X‐ray diffraction (XR ...
... A high-flux thin film nanocomposite (TFN) nanofiltration (NF) membrane for low pressure operation (3.5 bar) was fabricated by blending purified amino-functionalized single-walled carbon nanotubes (NH₂-SWCNTs) with piperazine (PIP) as aqueous phase monomers through interfacial polymerization (IP). The surface properties and structures of the polyamide (PA) active layer were suitably tailored by int ...
... Paper-based packaging is widely employed in industries ranging from food to beverages to pharmaceuticals because of its attractive advantages of biodegradability, recyclability, good strength, low cost, and lightweight. However, paper products usually have poor water barrier resistance properties because of paper and fibers porous microstructure. In this study, an ecofriendly water-resistant (hydr ...
bamboos; biocompatibility; biodegradability; cellulose; cellulose nanofibers; chemical interactions; chitin; contact angle; food packaging; mixing; modulus of elasticity; nanocomposites; raw materials; tensile strength; thermal stability
Abstract:
... This paper reports a green nanocomposite made by simply blending chitin nanofibers and bamboo cellulose nanofibers without chemically dissolving chitin and cellulose raw materials. Good biodegradability and biocompatibility of chitin in conjunction with good mechanical properties of cellulose are beneficial for developing green nanocomposite applicable for food packaging. The bamboo cellulose nano ...
... As a new kind of green solvents for potential replacement of traditional volatile organic compounds, deep eutectic solvents (DESs) have been attracting more and more attention in various applications. In this work, three types of hydrophobic DESs were synthesized by simple mixing of trioctylmethyl ammonium chloride (used as hydrogen bond acceptor) with decanoic acid, ketoprofen and gemfibrozil (hy ...
Fourier transform infrared spectroscopy; X-ray diffraction; contact angle; emulsifiers; light scattering; mixing; montmorillonite; nanoemulsions; nonionic surfactants; oils; particle size distribution; scanning electron microscopy; transmission electron microscopy; vitamin E
Abstract:
... Nanoemulsions have been widely studied and used in food, medicine, cosmetics and other industries. However, there are few studies on nanoemulsions stabilized with solid particles. In this work, water-in-oil nanoemulsions were prepared with stearyltrimethylammoniumchloride modified montmorillonite (STAC/MMT) and nonionic surfactants using low-energy method. STAC/MMT was characterized by FT-IR, XRD, ...
... Interfacing two-dimensional graphene oxide (GO) platelets with one-dimensional zinc oxide nanorods (ZnO) would create mixed-dimensional heterostructures suitable for modern optoelectronic devices. However, there remains a lack in understanding of interfacial chemistry and wettability in GO-coated ZnO nanorods heterostructures. Here, we propose a hydroxyl-based dissociation-exchange mechanism to un ...
... A novel PVDF mixed matrix ultrafiltration membrane was prepared by blending PVDF with the deformed rebar-like Fe₃O₄–palygorskite nanocomposites (MPGS) using the chemical coprecipitation method. Fe₃O₄ nanoparticles were anchored on the surface of the palygorskite nanofibers to form deformed rebar-like structures. MPGS were then distributed uniformly on the membrane matrix. PVDF chains firmly wrappe ...
Gabriela S. Medeiros; Pablo A. R. Muñoz; Camila F. P. de Oliveira; Laura C. E. da Silva; Ritika Malhotra; Maria C. Gonçalves; Vinícius Rosa; Guilhermino J. M. Fechine
... Standard and hybrid polymer nanocomposites based on poly(ɛ-caprolactone) (PCL), hydroxyapatite (HAp) and graphene oxide (GO). The GO synthetized here is made up of multilayer graphene oxide (mGO), in which up to five layers are stacked and lateral size around of 1 µm. The nanocomposites (PCL/Hap, PCL/mGO and PCL/HAp/mGO) were prepared by melt mixing in a twin-screw extruder and characterized by me ...
... In the present study, polysulfone (PSF)-activated carbon nanocomposites were synthesized by a melt mixing technique. Here, 2 wt% activated carbon (CA, CA–Ni, and CA–Co) was used as filler, and effects on thermal, mechanical, magnetic, morphological, and carbon dioxide capture properties were studied. The pyrolysis of wood sawdust produced carbon materials activated by Co and/or Ni salt. The therma ...
adhesion; atomic force microscopy; coatings; contact angle; films (materials); hydrophobicity; mixing; polymers; roughness; weathering
Abstract:
... The use of marble in construction is limited by its susceptibility to water spill and weathering. Here, a series of poly (2,2,2-trifluoroethyl methacrylate) (PTFEMA) and poly (methacrylic acid) (PMAA) blend films have been coated on a marble surface to test their water spill and weathering protection capability. The morphologies of the coated polymer films on marble (i.e. surface defects and rough ...
... Novel design of hydrophobic membrane could improve the efficiency of membrane distillation (MD) technology. Owning to being easy to realize hydrophobic modification, fast radial heat transfer rate and limiting the passage of larger contaminants, hydrophobic graphene oxide (GO) membrane shows potential for MD process. In this work, we reported on a new type of nanoparticles intercalated GO membrane ...
... A kind of hybrid membrane with self-luminescent property was prepared by mixing rare earth nanoparticles of nano-Sr₄Al₂O₄: Eu²⁺, Dy³⁺ into the casting solution dissolved with polyvinylidene fluoride (PVDF), and then coprecipitated through non-solvent induced phase separation (NIPS) method. Membrane were characterized by luminescent intensity, scanning electron microscopy (SEM), atomic force micros ...
... Moving-bed biofilm reactor (MBBR) is a well-established technology for simultaneous nitrification and denitrification (SND). In MBBR, biofilm development and pollutant removal performance are strictly governed by the physico-chemical properties of the carriers. In this study, novel surface-modified carriers with enhanced hydrophilicity (surface contact angle of 60.2 ± 2.3°) and positively-charged ...
... A novel hybrid electrospin-electrospray process was introduced to manipulate the membrane hierarchical structure towards enhanced surface superhydrophobicity and structural integrity. In this study, the two-nozzle mode was used to simultaneously electrospin PH (polyvinylidene fluoride-co-hexafluoropropylene) fibers and electrospray PS (polystyrene) beads to prepare a PH-PS composite membrane, duri ...
... Polypropylene blends with both polybutadiene rubber (PB) and polycarboxylbuturonile rubber (xNBR) and the required amount of acrylamide (AM) was prepared by blending with water, and the crystallinity, rheological behaviour and thermal performance were analysed and compared. The results of DSC and XRD characterization showed an obvious enhancement in the crystallization of the PP matrix in PP/xNBR/ ...
... The mechanism and influencing factors of sludge de-oiling process collected from the Tahe oil field, a thickened oil field in China, were investigated using biosurfactant. The oily sludge was collected from ground sludge near the oil-well blowout and pipeline perforation, and the storage time about 3∼5 years, resulting in high content of heavy components in the sludge. The viscosity of the recover ...
... A novel ion-imprinted blend membrane was fabricated to separate selectively platinum(IV) from aqueous media. An amphiphilic copolymer poly(methyl methacrylate)-b-poly(4-vinylpyridine) (PMMA-b-P4VP) was firstly synthesized via the reversible addition fragmentation chain transfer polymerization, and characterized by 1H NMR, FT-IR and GPC. Subsequently, poly(vinylidene fluoride) (PVDF) blend membrane ...
... Magnetic actuation on digital microfluidic (DMF) platforms may provide a low-cost, less cumbersome alternative for droplet manipulation in comparison to other techniques such as electrowetting-on-dielectric. Precise control of droplets in magnetically driven DMF platforms is achieved using a low-friction surface, magnetically susceptible material/droplet(s), and an applied magnetic field. Superhyd ...
... The aim of this study is to evaluate the performance and antifouling properties of polyethersulfone (PES) membrane incorporated with dual nanofiller, zinc oxide (ZnO) and multi-walled carbon nanotube (MWCNT). The synergistic effect of the these nanofillers in PES membrane is studied by blending different ratio of ZnO/MWCNT nanofiller into the PES membrane. The fabricated membranes were characteriz ...
... Covalent organic frameworks (COFs) have attracted broad interest in a number of fields including gas access, catalysis, and ionic adsorption. However, owing to the low stability in water, the application of COFs in the field of oil/water separation is extensively impeded. In this paper, we synthesized COF-DhaTab/polyacrylonitrile (PAN) nanofibrous composite membranes with a bioinspired spindle-kno ...
... Developing biomaterials based on the natural biomacromolecule silk sericin from Bombyx mori cocoon is of great interest for biomedical application. Dialdehyde carboxymethyl cellulose (DCMC) is derived from periodate oxidation of carboxy- methyl cellulose. Here, we developed a novel strategy of cross-linking of sericin with DCMC via the Schiff’s base reaction. Fourier transform infrared spectroscop ...
... The wastewater produced from various industries like textile, paper, rubber, leather, plastics, cosmetics, pharmaceuticals contains many dyes. Most commonly found dyes in these effluents are Orange G and Methylene blue. These dyes are toxic and are harmful to the environment as well as humans. Hence they need to be removed from the wastewater. Polyethersulfone (PES) membranes are most widely used ...
... This study aims to develop environment-friendly superhydrophobic textiles forming nanoparticles of polypropylene that have intrinsically low surface energy, and thus achieving the requirements for superhydrophobicity, such as hierarchical roughness and low surface energy at once. This work mainly studies the influences of tacticity (isotactic, atactic), concentration (10, 20, 30 and 40 mg/ml), dry ...
... Polyurethane (PU) has been utilized in the development of various blood-contacting medical devices owing to their good biocompatibility and mechanical properties. The present study highlights the design and engineering of biomimetic polyurethanes with enhanced hemocompatibility by blending it with polyethylene glycol (PEG) and modifying its surface using gelatin as a surface modifier. The physicoc ...
... Novel films were developed by blending cactus mucilage (CM) with polyvinyl alcohol (PVA) at four different ratios (90:10, 80:20, 70:30, and 60:40, CM: PVA). The developed composites were characterized for their structural, optical, physical, barrier, mechanical and thermal properties. Optimum CM/PVA blend was obtained at the ratio 80:20 giving an increase in tensile strength, elongation at break a ...
... In this study, a SiO₂@carbon dot (CD) nanohybrid was prepared by a hydrothermal method and incorporated into waterborne polyester matrix through an in situ process to develop the polyester nanocomposite. The nanohybrid possesses a specific surface area of 348.67 m²/g and pore volume of 0.927 cc/g. The nanocomposite exhibited a wavelength-dependent photoluminescence property. The thermosetting nano ...
Fourier transform infrared spectroscopy; atomic force microscopy; coagulation; contact angle; hydrophilicity; mixing; permeability; scanning electron microscopy; separation; surface roughness; temperature
Abstract:
... A new method was presented to prepare hydrophilic PES/SPSF flat-sheet membrane by a reverse thermally induced phase separation (RTIPS) method to enhance permeability and hydrophilicity. SPSF was self-made and was blended to improve the hydrophilicity of PES flat-sheet membrane. The performance of PES/SPSF flat-sheet membrane, which varied with SPSF content and coagulation water bath temperature, w ...
... Fabricating high-flux, low-fouling gravity-driven membranes (GDM) has proved to be an extremely challenging work. In this study, a novel tailored amphiphilic multi-arms polymer poly(propylene glycol)-silane-poly(ethylene glycol) (PPG-Si-PEG) was synthesized and blended into Polyvinylidene Fluoride (PVDF) matrix to fabricate GDM via nonsolvent induced phase separation method. The incorporation of m ...
... Waterproof and flame-retardant fabrics are widely utilized in many fields, such as automotive interiors, indoor decorations, outdoor clothing and tents. Herein, a facile one-pot sol-gel approach was developed to construct superhydrophobic and flame-retardant (SFR) coatings on cotton fabrics. The cotton fabric was activated by O₂ plasma and then immersed into the ethanol suspension containing tetra ...
... Going up further on the basis of excellent mechanical properties and solving the long-standing shortcoming of the slow degradation rate were developed in parallel for polylactic acid (PLA). The polylactic acid/wood flour/polymethylmethacrylate (PLA/WF/PMMA) composites were prepared by melt blending used PLA as matrix, WF of diverse particle size with PMMA at 8:2 mass ratio totally filled with 20 w ...
alloys; biocompatibility; biocomposites; chemical reduction; contact angle; hardness; hydroxyapatite; magnetic fields; magnetic properties; mixing; particle size; powders; prostheses
Abstract:
... Hydroxyapatite (HAP)/polyetheretherketone (PEEK) composites are widely used in the new generation of bone implant materials. The use of weak magnetic fields can promote the biocompatibility of PEEK materials. In this paper, Fe₅₀Ni₅₀ alloy nanopowders and Fe₅₀Ni₅₀/HAP/PEEK composites were prepared by liquid phase chemical reduction and liquid phase mixing. The prepared Fe₅₀Ni₅₀ alloy nanopowders ha ...
... Although several approaches have been reported on the development of nanoemulsions over the last few years, studies on the formation of biodiesel nanoemulsions for bifenthrin formulation by the low-energy phase inversion composition (PIC) method are still scarce. Herein, the preparation of oil-in-water (O/W) nanoemulsions suitable for pesticide application has been achieved in biodiesel by dissolv ...
... Initially, new nanocomposite reverse osmosis (RO) membranes containing polypyrrole (PPy) coated on multiwalled carbon nanotubes (MWCNTs) were synthesized. Then, the synthesized membranes were prepared to model flux measurements using artificial neural networks (ANNs). Raw and oxidized MWCNTs were coated with the polypyrrole and then various amounts of them were mixed in m-phenylene diamine solutio ...
... PVA polymers have been well-known as water-absorbing materials but their brittle nature hinders their applicability. In this study, we enhanced the strength of hydrogel and its water-absorbing capabilities by glutaraldehyde-assisted crosslinking of starch with PVA and blending BMIM-BF₄ to enhance the plasticity and generate porosity within the hydrogel multiplying the swelling capacity up to 300% ...
... There is an increased interest on changing the synthetic based materials to biodegradable ones, especially with natural polymers, polysaccharides or proteins. In this research we prepared bio-nanocomposite formulations with different component concentrations and investigated their structural features, with focus on the interactions, sorption properties, and how the combination between them influen ...
... Bionic superhydrophobicity including high contact angle, low sliding angle and nonstick property, combined with both strong pH and ultraviolet (UV) resistance, is difficult to simultaneously achieve for large-scale preparation of superhydrophobic surfaces by blending polymer with a nonreactive inorganic nanofiller.A series of high pH and UV-irradiation-resistant superhydrophobic nanocomposite film ...
... Cellulose nanocrystals (CNCs) extracted from microcrystalline cellulose, were modified by succinic anhydride to give succinic CNCs (SCNCs). Successful surface modification of SCNCs was confirmed by results of FTIR, FE-SEM, contact angle measurement and dispersity test, and SCNCs were then subjected to melt blending with poly(butylene succinate) (PBS) to prepare nanocomposites. Meanwhile, PBS/CNC n ...
... To effectively improve the ability of water for coal dust suppression using in a coal mine in Erdos, China, surfactant compounding was proposed because of the synergy between surfactants. First, four surfactants with good coal dust wetting ability were selected from a total of 15 surfactants through surface tension, contact angle, and coal dust sedimentation experiments. Next, a compound surfactan ...
... Binary surfactant mixtures have often been used to enhance the recovery or cleanup of nonaqueous phase liquids (NAPLs) such as crude oil from subsurface formations. Through synergistic effects, these mixtures further promoted NAPL mobilization and solubilization by lowing NAPL/brine interfacial tension (IFT) and desorbing NAPL from mineral surfaces, thereby altering their wettability. While the im ...
... In this paper, bio-based waterborne polyurethane dispersions were successfully prepared from castor oil using 2, 2-dimethylolbutanoic acid as the chain extender. Then, a series of bio-based composite dispersions and films were prepared by blending different amounts of sodium alginate aqueous solution with these bio-based polyurethane dispersions. The chemical structures, thermo-mechanical properti ...